公开(公告)号：EP3212328A1

公开(公告)日：2017-09-06

申请号：EP15802225.1

申请日：2015-10-28

Applicant: The Regents of the University of California ,  BP Corporation North America Inc.

Inventor： SANKARANARAYANAPILLAI, Shylesh ,  SREEKUMAR, Sanil ,  TOSTE, F., Dean ,  BELL, Alexis, T. ,  GOKHALE, Amit, A. ,  GRIPPO, Adam ,  ARAB, George, E.

IPC: B01J31/02 ,  C07C45/74 ,  C10L1/02

CPC classification number: C07C45/74 ,  B01J31/0201 ,  B01J31/0204 ,  B01J31/0222 ,  B01J31/0225 ,  B01J31/0237 ,  B01J31/0238 ,  B01J31/0244 ,  B01J31/0251 ,  B01J31/0254 ,  B01J31/0259 ,  B01J31/0271 ,  B01J31/04 ,  B01J2231/342 ,  C07C1/2076 ,  C07C49/203 ,  C10G3/50 ,  C10L1/02 ,  C10M105/04 ,  C10M2203/022 ,  C12P7/26 ,  Y02P30/20

Abstract: Provided herein are methods for producing α,β-unsaturated ketones from the condensation of methyl ketones in the presence of an amine catalyst. Such amine catalysts may be supported, for example, on a silica-alumina support. Such amine catalysts may be used in the presence of an additional acid. The α,β-unsaturated ketones may be produced by dimerization and/or timerization of the methyl ketones. Such α,β-unsaturated ketones may be suitable for use in producing fuels, gasoline additives, and/or lubricants, or precursors thereof. The methyl ketones may be obtained from renewable sources, such as by the fermentation of biomass.

Abstract translation: 本文提供了在胺催化剂的存在下由甲基酮的缩合生产α，β-不饱和酮的方法。 这种胺催化剂可以负载在例如二氧化硅 - 氧化铝载体上。 这种胺催化剂可以在另外的酸存在下使用。 α，β-不饱和酮可以通过甲基酮的二聚和/或三聚来制备。 这种α，β-不饱和酮可适用于生产燃料，汽油添加剂和/或润滑剂或其前体。 甲基酮可以从可再生资源获得，例如通过发酵生物质。

公开(公告)号：EP3191496A1

公开(公告)日：2017-07-19

申请号：EP15840786.6

申请日：2015-09-09

Applicant: King Abdullah University of Science and Technology

Inventor： HUANG, Kuo-wei ,  ZHAO, Qianyi

IPC: C07F9/58 ,  B01J31/12 ,  C07C231/10 ,  C07C29/14 ,  C07C29/15 ,  C07D317/36 ,  C07C31/04

CPC classification number: B01J31/189 ,  B01J31/0201 ,  B01J31/0237 ,  B01J31/12 ,  B01J37/04 ,  B01J2231/323 ,  B01J2531/847 ,  C07C29/09 ,  C07C29/14 ,  C07C29/15 ,  C07C231/10 ,  C07D317/36 ,  C07F9/588 ,  C07F15/04 ,  C07F15/045 ,  Y02P20/52 ,  C07C233/65 ,  C07C33/22 ,  C07C31/04 ,  C07C33/46

Abstract: The invention describes phospho-amino pincer-type ligands, metal complexes thereof, and catalytic methods comprising such metal complexes for conversion of carbon dioxide to methanol, conversion of aldehydes into alcohols, conversion of aldehydes in the presence of a trifluoromethylation agent into trifluorinated secondary alcohols, cycloaddition of carbon dioxide to an epoxide to provide cyclic carbonates or preparation of an amide from the combination of an alcohol and an amine.

Abstract translation: 本发明描述了磷酸 - 氨基钳型配体，其金属络合物和包含这种金属络合物的催化方法，用于将二氧化碳转化为甲醇，将醛转化为醇，在三氟甲基化试剂存在下将醛转化成三氟化仲醇 ，将二氧化碳环化加成环氧化物以提供环状碳酸酯或由醇和胺的组合制备酰胺。

公开(公告)号：EP2855558A4

公开(公告)日：2015-12-16

申请号：EP13793633

申请日：2013-05-24

Applicant: NOVOMER INC

Inventor： FARMER JAY J

IPC: C08G64/32

CPC classification number: C08G64/34 ,  B01J31/0201 ,  B01J31/0202 ,  B01J31/183 ,  B01J31/184 ,  B01J31/22 ,  B01J31/2217 ,  B01J31/2243 ,  B01J2231/14 ,  B01J2531/0238 ,  B01J2531/025 ,  B01J2531/0252 ,  B01J2531/845 ,  C08G18/44 ,  C08G64/0208 ,  C08G64/0216 ,  C08G65/2603 ,  C08G65/266 ,  Y02P20/52

Abstract: In one aspect, the present disclosure encompasses polymerization systems for the copolymerization of CO2 and epoxides comprising 1) a catalyst including a metal coordination compound having a permanent ligand set and at least one ligand that is a polymerization initiator, and 2) a chain transfer agent having one or more sites capable of initiating copolymerization of epoxides and CO2, wherein the chain transfer agent contains one or more masked hydroxyl groups. In a second aspect, the present disclosure encompasses methods for the synthesis of polycarbonate polyols using the inventive polymerization systems. In a third aspect, the present disclosure encompasses polycarbonate polyol compositions characterized in that the polymer chains have a high percentage of —OH end groups, a high percentage of carbonate linkages, and substantially all polycarbonate chains having hydroxyl end groups have no embedded chain transfer agent.

Abstract translation: 一方面，本公开涵盖用于CO 2和环氧化物共聚的聚合体系，其包括1）包含具有永久性配体组的金属配位化合物和至少一种作为聚合引发剂的配体的催化剂，和2）链转移剂 具有能够引发环氧化物和CO 2共聚的一个或多个位点，其中链转移剂含有一个或多个掩蔽的羟基。 在第二方面，本公开涵盖了使用本发明聚合体系合成聚碳酸酯多元醇的方法。 在第三方面，本公开内容包括聚碳酸酯多元醇组合物，其特征在于聚合物链具有高百分比的-OH端基，高百分比的碳酸酯键，并且基本上所有具有羟基端基的聚碳酸酯链都没有嵌入的链转移剂 。

公开(公告)号：EP2315789B1

公开(公告)日：2015-09-02

申请号：EP09789476.0

申请日：2009-02-23

Applicant: W.R. Grace & CO. - CONN.

Inventor： CHEN, Linfeng

IPC: C08F10/06 ,  C08F4/646 ,  C08F4/649

CPC classification number: B01J8/1872 ,  B01J8/1809 ,  B01J31/0201 ,  B01J31/0212 ,  B01J31/0272 ,  B01J31/128 ,  B01J31/143 ,  B01J31/2213 ,  B01J31/2226 ,  C08F10/02 ,  C08F10/06 ,  C08F110/06 ,  C08F210/06 ,  C08F2400/02 ,  C08F2/40 ,  C08F2/34 ,  C08F2/00 ,  C08F4/6465 ,  C08F4/6494 ,  C08F4/651 ,  C08F2500/12 ,  C08F2500/18 ,  C08F2500/24 ,  C08F210/16

公开(公告)号：EP2286915A3

公开(公告)日：2015-03-11

申请号：EP10185093.1

申请日：2006-01-04

Applicant: The Queen's University of Belfast

Inventor： Earle, Martyn John ,  Seddon, Kenneth Richard ,  Forsyth, Stewart ,  Frohlich, Ute ,  Gunaratne, Nimal ,  Katdare, Suhas

IPC: B01J31/02 ,  C07D301/12 ,  C07C209/60 ,  C07C45/72 ,  C07C45/69 ,  C07C45/62 ,  C07B37/04

CPC classification number: C07C217/08 ,  B01J31/0201 ,  B01J31/0204 ,  B01J31/0225 ,  B01J31/0234 ,  B01J31/0237 ,  B01J31/0277 ,  B01J31/0278 ,  B01J31/0282 ,  B01J31/0284 ,  B01J31/0287 ,  B01J31/0288 ,  B01J31/0289 ,  B01J31/0291 ,  B01J31/2208 ,  B01J2231/341 ,  B01J2231/342 ,  B01J2231/346 ,  B01J2231/348 ,  B01J2231/349 ,  B01J2231/4261 ,  B01J2231/645 ,  B01J2231/72 ,  B01J2531/824 ,  B01J2531/90 ,  C07B61/00 ,  C07C45/512 ,  C07C45/62 ,  C07C45/66 ,  C07C45/67 ,  C07C45/72 ,  C07C45/73 ,  C07C45/74 ,  C07C211/63 ,  C07D213/73 ,  C07D233/54 ,  C07D303/32 ,  Y02P20/542 ,  C07C47/228 ,  C07C49/603 ,  C07C49/647 ,  C07C49/637 ,  C07C49/203 ,  C07C49/597 ,  C07C49/497 ,  C07C49/707 ,  C07C49/17 ,  C07C49/403

Abstract: Use of ionic liquids as solvents in base-catalysed chemical reactions wherein the ionic liquid is composed of at least one species of cation and at least one species of anion, characterised in that a cation of the ionic liquid comprises a positively charge moiety and a basic moiety, and further wherein such ionic liquids may be used as promoters or catalysts for the chemical reactions.

公开(公告)号：EP1668046B1

公开(公告)日：2015-03-04

申请号：EP04784378.4

申请日：2004-09-17

Applicant: W.R. Grace & CO. - CONN.

Inventor： CHEN, Linfeng ,  CAMPBELL, Richard, E., Jr.

IPC: C08F4/649 ,  C08F10/06 ,  C08F4/646 ,  C08F110/06

CPC classification number: C08F10/00 ,  B01J31/0201 ,  B01J31/0272 ,  B01J31/04 ,  B01J31/143 ,  C08F10/06 ,  C08F110/06 ,  C08F4/6496 ,  C08F4/6495 ,  C08F4/6494 ,  C08F4/6465 ,  C08F2500/12 ,  C08F2500/18

公开(公告)号：EP2650049A2

公开(公告)日：2013-10-16

申请号：EP11847713.2

申请日：2011-12-09

Applicant: SK Innovation Co., Ltd.

Inventor： LEE, Sang Il ,  KIM, Do Woan ,  KOH, Jae Hyun ,  OH, Seung Hoon ,  JEON, Hee Jung ,  MOON, Sang Heup ,  CHO, A Ra ,  PARK, Young Moo

IPC: B01J31/12 ,  B01J21/12 ,  B01J29/076 ,  C01B3/40

CPC classification number: B01J31/38 ,  B01J23/88 ,  B01J23/882 ,  B01J23/888 ,  B01J31/0201 ,  B01J31/0207 ,  B01J31/0208 ,  B01J31/0209 ,  B01J31/12 ,  B01J31/2208 ,  B01J31/2213 ,  B01J31/2234 ,  B01J31/34 ,  B01J35/023 ,  B01J37/0201 ,  B01J37/0205 ,  B01J37/0219 ,  B01J37/06 ,  B01J37/18 ,  B01J37/20 ,  B01J2531/64 ,  B01J2531/66 ,  B01J2531/845 ,  B01J2531/847

Abstract: The present invention relates to a hydroprocessing catalyst comprising: (i) one or more hydrogenation metal components selected from a group consisting of VIB group metal, VIIB group metal and VIII group metal; and (ii) an organic compound expressed by the following chemical formula 1 or an organometallic compound expressed by the following chemical formula 2. Chemical formula 1: R 1 COCH 2 COR 2 (wherein, R 1 and R 2 are the same or different from each other, and are one or more groups selected from a group consisting of C1 to C12 alkyl, C6 to C12 allyl, C1 to C12 alkoxy and hydroxy). Chemical formula 2: X( R 1 COCH 1 COR 2 )n (wherein, X is selected from a group consisting of VIB group metal, VIIB group metal and VIII group metal, R 1 and R 2 are the same or different from each other, and are one or more groups selected from a group consisting of C1 to C12 alkyl, C6 to C12 allyl, C1 to C12 alkoxy and hydroxy, and n is an integer of 1 to 6).

Abstract translation: 本发明涉及一种加氢处理催化剂，其包括：（i）一种或多种选自VIB族金属，VIIB族金属和VIII族金属的氢化金属组分; 化学式1：R 1 COCH 2 COR 2（其中，R 1和R 2与下述化学式1表示的有机化合物相同或不同。 并且是选自C1-C12烷基，C6-C12烯丙基，C1-C12烷氧基和羟基的一个或多个基团。 化学式2：X（R 1 COCH 1 COR 2）n（其中，X选自VIB族金属，VIIB族金属和VIII族金属，R 1和R 2彼此相同或不同 并且是选自C1〜C12烷基，C6〜C12烯丙基，C1〜C12烷氧基和羟基，n为1〜6的整数的一个以上的基团。

公开(公告)号：EP2644270A1

公开(公告)日：2013-10-02

申请号：EP12162154.4

申请日：2012-03-29

Applicant: HUNTSMAN INTERNATIONAL LLC

Inventor： The designation of the inventor has not yet been filed

IPC: B01J31/02 ,  C08G18/09 ,  C08G18/22 ,  C08G18/28 ,  C08G18/38 ,  C08G18/48 ,  C08G18/58 ,  C08G18/72 ,  C08G18/76 ,  C08G18/79 ,  C08K5/21

CPC classification number: B01J31/0247 ,  B01J31/0201 ,  B01J31/04 ,  C08G18/092 ,  C08G18/10 ,  C08G18/225 ,  C08G18/285 ,  C08G18/3829 ,  C08G18/4829 ,  C08G18/58 ,  C08G18/725 ,  C08G18/7664 ,  C08G18/7671 ,  C08G18/794 ,  C08G18/797 ,  C08G2105/02 ,  C08K5/21

Abstract: A trimerization catalyst composition comprising a trimerization catalyst compound selected from one or more organic metal salt, preferably alkali or earth alkali metal salts, and one or more compounds selected from compounds which comprise a carboxamide group having the structure -CO-NH 2 and/or from compounds which comprise a group having the structure -CO-NH-CO- is disclosed.
Further a stable polyisocyanate composition comprising the catalyst composition and a process for making the polyisocyanate composition is disclosed.
A curable polyisocyanate composition is obtained comprising the catalyst composition, a polyisocyanate composition, an epoxy resin and optionally a polyol/monool composition and a polyisocyanurate comprising material made by allowing the curable composition to react at elevated temperature and a process for making the polyisocyanurate comprising material.

Abstract translation: 一种三聚催化剂组合物，其包含选自一种或多种有机金属盐，优选碱金属或碱土金属盐的三聚催化剂化合物和一种或多种选自具有-CO-NH 2结构的羧酰胺基团和/或来自 公开了包含具有结构-CO-NH-CO-的基团的化合物。 此外公开了包含该催化剂组合物的稳定多异氰酸酯组合物和制备该多异氰酸酯组合物的方法。 获得包含催化剂组合物，多异氰酸酯组合物，环氧树脂和任选的多元醇/一元醇组合物和通过使可固化组合物在高温下反应制备的包含聚异氰脲酸酯的材料的可固化多异氰酸酯组合物，以及制备包含聚异氰脲酸酯的材料 。

公开(公告)号：EP2449058A4

公开(公告)日：2013-02-27

申请号：EP10794645

申请日：2010-06-29

Applicant: CHEVRON USA INC

Inventor： ZHAN BI-ZENG ,  MAESEN THEODORUS ,  LICHTENBERGER JANINE ,  RAINIS ANDREW ,  TIMKEN HYE-KYUNG

IPC: C10G45/12 ,  B01J29/10 ,  B01J37/20 ,  C10G47/18 ,  C10G49/08

CPC classification number: B01J31/0209 ,  B01J21/12 ,  B01J29/084 ,  B01J29/106 ,  B01J29/126 ,  B01J29/146 ,  B01J29/166 ,  B01J31/0201 ,  B01J31/0207 ,  B01J31/0237 ,  B01J31/0238 ,  B01J31/0244 ,  B01J31/0249 ,  B01J31/04 ,  B01J35/1019 ,  B01J35/1023 ,  B01J35/1038 ,  B01J35/1042 ,  B01J35/1047 ,  B01J35/1061 ,  B01J35/1066 ,  B01J37/0203 ,  B01J2229/20 ,  B01J2229/34 ,  B01J2229/42 ,  B01J2231/641 ,  C10G45/00 ,  C10G45/04 ,  C10G45/12 ,  C10G45/54 ,  C10G47/06 ,  C10G47/12 ,  C10G47/14 ,  C10G49/04 ,  C10G49/06 ,  C10G49/08 ,  C10G2300/4018 ,  C10G2400/04

公开(公告)号：EP2493948A1

公开(公告)日：2012-09-05

申请号：EP10770534.5

申请日：2010-10-26

Applicant: Bayer MaterialScience AG

Inventor： RICHTER, Frank ,  PIRES, Raul ,  REITER, Stephan ,  KRAUSE, Jens ,  JURKSCHAT, Klaus ,  IOVKOVA, Ljuba ,  SCHÜRMANN, Markus ,  BRADTMÖLLER, Gerrit

IPC: C08G18/24 ,  C08G18/28 ,  C08G18/79 ,  B01J31/02

CPC classification number: C08G18/24 ,  B01J31/0201 ,  B01J31/12 ,  B01J2231/14 ,  C08G18/2825 ,  C08G18/792

Abstract: The invention relates to the use of special catalysts for producing polyisocyanate polyaddition products, particularly for use in coating applications.