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    GOLD POLYMER NANO-STRUCTURE-SUPPORTED SCANDIUM CATALYST AND USE OF THE SAME
    3.
    发明公开
    GOLD POLYMER NANO-STRUCTURE-SUPPORTED SCANDIUM CATALYST AND USE OF THE SAME 有权
    金聚合物纳米结构支撑钪催化剂及其应用

    公开(公告)号：EP2545991A1

    公开(公告)日：2013-01-16

    申请号：EP11753144.2

    申请日：2011-02-16

    申请人： Japan Science and Technology Agency

    发明人： KOBAYASHI Shu ,  MIYAMURA Hiroyuki

    IPC分类号： B01J23/66 ,  B01J35/02 ,  B01J37/04 ,  C07C45/75 ,  C07C49/82 ,  C07D455/04 ,  C07B61/00

    CPC分类号： C07D455/04 ,  B01J23/52 ,  B01J31/0227 ,  B01J31/0228 ,  B01J31/165 ,  B01J31/226 ,  B01J35/0013 ,  B01J2231/326 ,  B01J2231/342 ,  B01J2231/346 ,  B01J2231/4205 ,  B01J2531/0222 ,  B01J2531/18 ,  B01J2531/35 ,  B01J2540/325 ,  B01J2540/345 ,  C07C45/75 ,  C07D491/22 ,  C07C49/82

    摘要： The present invention provides a Scandium catalyst that can be used in water or water-soluble organic solvent with no leaching of Scandium. Provided is a gold-polymer nanostructure-immobilized Scandium catalyst, which is formed by preparing, in liquid phase, a mixture comprising gold clusters with from 1 to 50 nm of diameter, disulfide monomer, sulfonic acid salt of disulfide and Lewis acid metal compound represented by ScY 3 , wherein Y is OSO 2 CF 3 etc., and polymerizing the mixture in the presence of a radical polymerization initiator, wherein the disulfide monomer is represented by the formula below:

            CH 2 =CH-R 1 -S-S-R 1 -CH=CH 2

    wherein R 1 represents a divalent hydrocarbon, which may contain an ether bond, and the sulfonic acid salt of disulfide is represented by the formula below:

            MO 3 S-R 2 -S-S-R 2 -SO 3 M

    wherein R 2 represents a divalent hydrocarbon, which may contain an ether bond, and M represents an alkali metal.
    This catalyst is useful as a catalyst for aldol reactions, cyanolation reactions, allylation reactions, Michael reactions, Mannich reactions, Diels Alder reactions and Friedel Crafts reactions in water or water-soluble organic solvent.

    摘要翻译： 本发明提供了一种可用于水或水溶性有机溶剂而不浸出钪的钪催化剂。 本发明提供一种固定有金 - 聚合物纳米结构的钪催化剂，其通过在液相中制备包含直径为1-50nm的金簇，二硫化物单体，二硫化物的磺酸盐和路易斯酸金属化合物的混合物 其中Y是OSO 2 CF 3等，并且在自由基聚合引发剂存在下聚合该混合物，其中二硫化物单体由下式表示：CH 2 = CH-R 1 -SS-R 1 -CH = CH 2其中R 1代表 可含有醚键的二价烃和二硫化物的磺酸盐由下式表示：MO3S-R2-SS-R2-SO3M其中R2表示二价烃，其可含有醚键，且M 代表碱金属。 该催化剂可用作在水或水溶性有机溶剂中用于醇醛缩合反应，氰化反应，烯丙基化反应，迈克尔反应，曼尼希反应，狄尔斯阿尔德反应和Friedel Crafts反应的催化剂。

    PROCESS FOR PRODUCTION OF DISULFONIC ACID COMPOUND, ASYMMETRIC MANNICH CATALYST, PROCESS FOR PRODUCTION OF -AMINOCARBONYL DERIVATIVE, AND NOVEL DISULFONATE SALT
    9.
    发明公开
    PROCESS FOR PRODUCTION OF DISULFONIC ACID COMPOUND, ASYMMETRIC MANNICH CATALYST, PROCESS FOR PRODUCTION OF -AMINOCARBONYL DERIVATIVE, AND NOVEL DISULFONATE SALT 审中-公开
    制造方法DISCHWEFELSÄUREVERBINDUNG不对称曼尼希催化剂，用于生产？羰基衍生物和新颖DISULFONATSALZ

    公开(公告)号：EP2208722A1

    公开(公告)日：2010-07-21

    申请号：EP08843193.7

    申请日：2008-10-01

    申请人： National University Corporation Nagoya University

    发明人： ISHIHARA, Kazuaki ,  HATANO, Manabu ,  MAKI, Toshikatsu

    IPC分类号： C07C303/16 ,  B01J31/22 ,  C07C269/06 ,  C07C271/18 ,  C07C271/22 ,  C07C309/38 ,  C07D213/06 ,  C07D263/26 ,  C07B53/00 ,  C07B61/00

    CPC分类号： C07B53/00 ,  B01J31/0217 ,  B01J31/0225 ,  B01J31/0239 ,  B01J2231/346 ,  B01J2531/0266 ,  C07C269/06 ,  C07C303/16 ,  C07D213/06 ,  C07D263/26 ,  C07C271/18 ,  C07C271/22 ,  C07C309/35

    摘要： Hexamethylphosphoramide (HMPA) was added to a reaction vessel containing (R)-1,1'-binaphthyl-2,2'-dithiol and potassium hydroxide. The vessel was purged with oxygen and stirred at 80°C for 5 days under 7 atmospheres of oxygen. After being cooled to room temperature, the reaction product was purified to yield potassium (R)-1,1'-binaphthyl-2,2'-disulfonate. The (R)-1,1'-binaphthyl-2,2'-disulfonic acid obtained from the disulfonate and 2,6-diphenylpyridine were stirred in acetonitrile, and then the solvent was evaporated under reduced pressure. Subsequently, magnesium sulfate and distilled CH 2 Cl 2 were added to the reaction product, and the mixture was stirred at room temperature for 30 minutes. The resulting solution was cooled to 0°C. Benzaldehyde imine whose nitrogen is protected with Cbz and subsequently acetyl acetone were dropped into the solution over a period of 1 hour. The resulting mixture was further stirred at 0°C for 30 minutes. A corresponding β-aminocarbonyl derivative was thus produced with an yield of 91% and an enantiomeric excess of 90% ee.

    摘要翻译： 六甲基磷酰胺（HMPA），其加入到一个反应容器中包含（R）-1,1'-联萘-2,2'-二硫醇和氢氧化钾。 其中在氧气的7个大气压与氧气吹扫并搅拌在80℃下5天的容器中。 在冷却至室温后，将反应产物纯化，得到钾（R）-1,1'-联萘-2,2'-二磺酸。 的（R）-1,1'-联萘-2,2'-二磺酸与二磺酸和2,6- diphenylpyridines获得在乙腈，然后将溶剂减压蒸发。 随后，硫酸镁和蒸馏的CH 2 Cl 2中，加入到反应产物中，并且其在室温下搅拌30分钟该混合物。 将所得溶液冷却，其至0℃ 苯甲醛亚胺保护，Cbz基并随后乙酰丙酮其氮滴入该溶液在1小时的时间。 将得到的混合物，其在0℃下进一步搅拌30分钟。 相应²氨基羰基衍生物什么因此，在91％的产率，并在对映体过量为90％ee的与生产。