PROCESS FOR MAKING PHENOL AND/OR CYCLOHEXANONE
    83.
    发明公开
    PROCESS FOR MAKING PHENOL AND/OR CYCLOHEXANONE 审中-公开
    制备苯酚和/或环己酮的方法

    公开(公告)号:EP3071540A2

    公开(公告)日:2016-09-28

    申请号:EP14790970.9

    申请日:2014-10-17

    摘要: A process for making phenol and/or cyclohexanone comprises: (A) oxidizing a cyclohexylbenzene feed to obtain an oxidation product comprising cyclohexylbenzene, cyclohexyl-1-phenyl-1-hydroperoxide and phenol; (B) separating at least a portion of the oxidation product to obtain a first fraction comprising cyclohexyl-1-phenyl-1-hydroperoxide and a second fraction comprising cyclohexylbenzene and phenol; (C) removing at least a portion of the phenol from at least a portion of the second fraction to obtain a third fraction; (D) recycling at least a portion of the cyclohexylbenzene in the third fraction to the oxidizing step (A); and (E) contacting at least a portion of the cyclohexyl-1-phenyl-1-hydroperoxide in the first fraction with an acid catalyst in a cleavage reactor under cleavage conditions to obtain a cleavage product comprising phenol and cyclohexanone.

    摘要翻译: 制备苯酚和/或环己酮的方法包括:(A)氧化环己基苯进料以获得包含环己基苯,环己基-1-苯基-1-氢过氧化物和苯酚的氧化产物; (B)分离至少一部分氧化产物以获得包含环己基-1-苯基-1-氢过氧化物的第一馏分和包含环己基苯和苯酚的第二馏分; (C)从所述第二馏分的至少一部分除去至少一部分所述酚以获得第三馏分; (D)将第三馏分中的至少一部分环己基苯循环至氧化步骤(A); 和(E)在裂解反应条件下,在裂解反应器中使第一馏分中的至少一部分环己基-1-苯基-1-氢过氧化物与酸催化剂接触以获得包含苯酚和环己酮的裂解产物。

    CYCLIC COMPOUND PURIFICATION METHOD
    85.
    发明公开
    CYCLIC COMPOUND PURIFICATION METHOD 审中-公开
    VERFAHREN ZUR REINIGUNG EINER ZYKLISCHEN VERBINDUNG

    公开(公告)号:EP2578562A1

    公开(公告)日:2013-04-10

    申请号:EP11786306.8

    申请日:2011-05-20

    IPC分类号: C07C37/72 C07C39/15

    CPC分类号: C07C29/86 C07C37/72 C07C39/15

    摘要: An industrially advantageous purification method for a cyclic compound with a particular structure is provided.
    A purification method for a cyclic compound, including a step of contacting a solution containing a cyclic compound with a particular structure and an organic solvent with water or an acidic aqueous solution.

    摘要翻译: 提供了具有特殊结构的环状化合物的工业上有利的纯化方法。 一种环状化合物的纯化方法,包括使含有特定结构的环状化合物和有机溶剂的溶液与水或酸性水溶液接触的工序。

    FRACTIONATION OF CASHEW NUT SHELL LIQUID
    86.
    发明公开
    FRACTIONATION OF CASHEW NUT SHELL LIQUID 审中-公开
    CASHEW坚果壳液的分级

    公开(公告)号:EP2566596A2

    公开(公告)日:2013-03-13

    申请号:EP11725951.5

    申请日:2011-05-04

    申请人: Bangor University

    IPC分类号: B01D11/04 C07C37/72

    摘要: A method for the fractionation of cashew nut shell liquid comprises solvent-solvent extraction using a polar solvent component and a non-polar, non-acidic, non-basic solvent component; wherein the polar solvent component is a mixture comprising: i) a first solvent comprising a fluorinated solvent; and ii) a second solvent comprising a solvent satisfying the following parameters: a) Hildebrand parameter greater than 10 (kcal dnT
    -3 )
    0,5 and b) dipolarity/polarizability (π), hydrogen bond acidity (a), and hydrogen bond basicity (β) having the following relationship: α/(α + β + π) > 0.5; β/(α + β + π) 0.3.

    摘要翻译: 用于分级腰果壳油的方法包括使用极性溶剂组分和非极性非酸性非碱性溶剂组分提取溶剂 - 溶剂; 其中所述极性溶剂组分是包含以下的混合物:i)包含氟化溶剂的第一溶剂; 和ii)包含满足以下参数的溶剂的第二溶剂:a)Hildebrand参数大于10(kcal dnT-3)0.5和b)偶极性/极化率(π),氢键酸度(a)和氢键 碱度(β)具有以下关系:α/(α+β+π)> 0.5; β/(α+β+π)<0.8; 和π/(α+β+π)> 0.3。

    METHOD FOR THE INDUSTRIAL USE OF TYROSOL AND HYDROXYTYROSOL CONTAINED IN THE SOLID BY-PRODUCTS OF INDUSTRIAL OLIVE CRUSHING
    90.
    发明公开
    METHOD FOR THE INDUSTRIAL USE OF TYROSOL AND HYDROXYTYROSOL CONTAINED IN THE SOLID BY-PRODUCTS OF INDUSTRIAL OLIVE CRUSHING 审中-公开
    PROCEDURE工业用在固体副产品的产业OLIVE按所含酪醇羟基酪醇及

    公开(公告)号:EP1987868A1

    公开(公告)日:2008-11-05

    申请号:EP07730328.7

    申请日:2007-02-16

    IPC分类号: B01D11/02 C07C39/10 C07C39/11

    摘要: The invention relates to a method for using the natural biophenols, tyrosol and hydroxytyrosol, contained in the industrial by-products that result from the crushing and processing of olives, whether from three-phase or two-phase presses, and the husks and cakes thereof. The method produces a mixture of the two biophenols with a purity of more than 90% and yields of between 0.1 and 1.5% depending on the product and the processed raw material. The invention essentially comprises the selective extraction and fractionation of the resulting mixtures using solvents

    摘要翻译: 本发明涉及一种用于使用自然生物酚,酪醇和羟基酪醇,副产物包含在工业从橄榄的压碎和处理确实导致,无论是从三相或两相印刷机,以及壳和蛋糕其 , 该方法产生两个生物酚的混合物与90%以上的纯度和0.1之间和1.5%的产品和处理后的原始材料根据产量。 本发明基本上包括使用溶剂所得到的混合物的选择性提取和分馏