Abstract:
A laminated metal sheet according to the present invention includes a metal sheet; a first polyester resin layer formed on a surface of the metal sheet, the surface forming an outer face side of a container; and a second polyester resin layer formed on a surface of the metal sheet, the surface forming an inner face side of the container. The first polyester resin layer contains polyethylene terephthalate or a copolymerized polyethylene terephthalate with a content of a copolymerized component of less than 6 mol% in a ratio of 30% by mass or more and 60% by mass or less, polybutylene terephthalate or a copolymerized polybutylene terephthalate with a content of a copolymerized component of less than 5 mol% in a ratio of 40% by mass or more and 70% by mass or less, and a polyolefinic wax in an amount of 0.01% or more and 3.0% or less in outer percentage. The second polyester resin layer is a copolymerized polyethylene terephthalate with a content of a copolymerized component of less than 22 mol%. Residual degrees of orientation of the first and the second polyester resin layers are less than 30%.
Abstract:
An object of the present invention is to provide a method for designing a metal material having mechanical properties with which a specified spring back angle can be achieved after any one of metal materials having a wide variety of mechanical properties and thicknesses has been formed by performing cylinder forming and a product formed by using the method. A method for designing a material to be subjected to cylinder forming, the method including, in the design of a metal material to be subjected to cylinder forming in which the metal material is formed by performing bending forming, calculating the yield strength YP, the Young's modulus E and the thickness t of the metal material so that a spring back angle ”¸ becomes a specified value when cylinder forming is performed under conditions of a radius of curvature of bending r of 5 mm or more and a bending angle ¸ of 90 degrees or more and 180 degrees or less and designing the metal material so that the metal material has the calculated yield strength YP and Young's modulus E.
Abstract:
A can steel plate includes: equal to or less than 0.0030% by mass of C; equal to or less than 0.02% by mass of Si; 0.05% to 0.60% by mass of Mn; equal to or less than 0.020% by mass of P; equal to or less than 0.020% by mass of S; 0.010% to 0.100% by mass of Al; 0.0010% to 0.0050% by mass of N; 0.001% to 0.050% by mass of Nb; and balance Fe and inevitable impurities, where (intensity of (111) [1-21] orientation)/(intensity of (111)[1-10] orientation) ‰¥ 0.9, in a rolling direction and a 90° direction from the rolling direction in a horizontal plane, tensile strength TS ‰¥ 550, and fracture elongation El > -0.02 x TS + 17.5.
Abstract:
A laminated metal sheet includes a metal sheet, a first polyester resin layer, and a second polyester resin layer, and the first polyester resin layer contains 30% by mass to 60% by mass of: polyethylene terephthalate; or copolymerized polyethylene terephthalate having a copolymerization component content of less than 6 mol%; and 40% by mass to 70% by mass of polybutylene terephthalate, the second polyester resin layer is copolymerized polyethylene terephthalate having a copolymerization component content of less than 14 mol%, residual orientations of the first and second polyester resin layers are less than 20%, and film thicknesses X and Y of the first and the second polyester resin layers before forming satisfy predetermined conditions.
Abstract:
A resin coated metal sheet 1 includes a metal sheet 2, a resin coating layer 3 formed on the front side of the metal sheet 2, and a resin coating layer 4 formed on the back side of the metal sheet 2. The resin coating layer 3 and the resin coating layer 4 are positioned outside and inside a metal container after forming, respectively. The resin coating layer 3 is formed of a resin material whose difference between the heat quantity of crystallization and the heat quantity of fusion after being laminated to the metal sheet is within a range of 0 J/g or more and 20 J/g or less on a unit weight basis. It is preferable that the resin coating layers 3 and 4 are formed of a resin material containing 90 mol% or more ethylene terephthalate unit and that the melting point of the resin coating layer 3 is within a range of 240°C or more and 254°C or less.
Abstract:
Provided is a steel sheet having excellent surface roughening resistance and a manufacturing method thereof. The steel sheet for cans contains 0.0040 to 0.01% C and 0.02 to 0.12% Nb. An average ferrite grain size in a cross section in the rolling direction in a region ranging from a surface layer of the steel sheet to a position 1/4 of a sheet thickness away from the surface layer of the steel sheet is set to 7 µm or more and 10 µm or less, and the average ferrite grain size in a cross section in the rolling direction in a region ranging from the position 1/4 of a sheet thickness away from the surface layer of the steel sheet to a sheet thickness center portion of the steel sheet is set to 15 µm or less. The average ferrite grain size in the cross section in the rolling direction in the region ranging from the surface layer of the steel sheet to the position 1/4 of a sheet thickness away from the surface layer of the steel sheet is set smaller than the average ferrite grain size in the cross section in the rolling direction in a region ranging from the position 1/4 of a sheet thickness away from the surface layer of the steel sheet to the sheet thickness center portion of the steel sheet. The steel sheet for cans is obtained by cooling a steel sheet at 50 to 100°C/s within 1 second after final finish rolling, is wound at 500°C to 600°C, is subsequently subjected to pickling treatment, is subjected to cold rolling at a reduction rate of 90% or more, and is subjected to continuous annealing at a temperature of equal to or more than a recrystallization temperature to 800°C or below.
Abstract:
A component composition contains, by % by mass, 0.0016 to 0.01% of C, 0.05 to 0.60% of Mn, and 0.020 to 0.080% of Nb so that the C and Nb contents satisfy the expression, 0.4 ‰¤ (Nb/C) × (12/93) ‰¤ 2.5. In addition, the amount of Nb-based precipitates is 20 to 500 ppm by mass, the average grain diameter of the Nb-based precipitates is 10 to 100 nm, and the average crystal grain diameter of ferrite is 6 to 10 µm. Nb is added to ultra-low-carbon steel used as a base, and the amount and grain diameter of the Nb-based precipitates are controlled to optimize the pinning effect. Grain refinement of ferrite is achieved by specifying the Mn amount, thereby achieving softening and excellent resistance to surface roughness of steel. Therefore, it is possible to provide a steel sheet for cans with excellent surface properties which causes little surface roughness and no film exfoliation after drawing and ironing, and also provide a method for producing the steel sheet.
Abstract:
It is an object to provide a steel sheet for a can exhibiting good drawability and excellent buckling strength of a can body portion against an external pressure and a method for manufacturing the same. A steel sheet for a can contains C: 0.0030% or more and 0.0100% or less, Si: 0.05% or less, Mn: 0.10% or more and 1.0% or less, P: 0.030% or less, S: 0.020% or less, Al: 0.010% or more and 0.100% or less, N: 0.0050% or less, Nb: 0.010% or more and 0.050% or less, and the balance being Fe and incidental impurities. Contents of C and Nb satisfy 0.10 ‰¤ ([Nb]/92.9)/([C]/12)
Abstract:
A resin-coated metal sheet for can lids includes a thermoplastic resin film A based on PBT and PET heat-fused on a surface of the metal sheet 1 serving as the exterior surface of a can lid and a thermoplastic resin film B based on PET heat-fused on a surface serving as the interior surface of the can lid. In the thermoplastic resin film A, the composition ratio (wt%) of PBT/PET is (40/60) to (80/20), and the ratio between Raman band intensity I 0 of 1615±10 cm -1 on a polarization plane horizontal to the surface and the Raman band intensity I 90 of 1615±10 cm -1 on a vertical polarization plane is 0.60 or more. The thermoplastic resin film B includes 95 mol% or more of PET. The melting point derived from PET of the thermoplastic resin film B is 250°C or higher and 265°C or lower and is higher than the melting point derived from PBT of the thermoplastic resin film A by 25°C or more. The half-width of the Raman band of 1730±10 cm -1 on a polarization plane horizontal to the surface is 15 to 20 cm -1 .