Polymerizable photoacid generators
    1.
    发明公开
    Polymerizable photoacid generators 审中-公开
    PolymerisierbareFotosäuregeneratoren

    公开(公告)号:EP2472323A2

    公开(公告)日:2012-07-04

    申请号:EP11195707.2

    申请日:2011-12-23

    摘要: A compound has formula (I):

             Q-O-(A)-Z - G +      (I)

    wherein Q is a halogenated or non-halogenated, C 2-30 olefin-containing group, A is a fluorine-substituted C 1-30 alkylene group, a fluorine-substituted C 3-30 cycloalkylene group, a fluorine-substituted C 6-30 arylene group, or a fluorine-substituted C 7-30 alkylene-arylene group, Z is an anionic group comprising sulfonate, sulfonamide, or sulfonamide, and G + has formula (II):

    wherein X is S or I, each R 0 is halogenated or non-halogenated and is independently C 1-30 alkyl group; a polycyclic or monocyclic C 3-30 cycloalkyl group; a polycyclic or monocyclic C 4-30 aryl group; or a combination of these, wherein when X is S, one of the R 0 groups is optionally attached to one adjacent R 0 group by a single bond, and a is 2 or 3, wherein when X is I, a is 2, or when X is S, a is 3. A copolymer, a photoresist, a coated substrate and method of patterning are disclosed.

    摘要翻译: 一个复合体有公式(I):€ƒ€ƒ€ƒ€ƒ€ƒ€ƒQO-(A)-Z - G +€ƒ€ƒ€ƒ€ƒ(I)其中Q是 卤代或非卤代的含C 2-30烯烃的基团,A是氟取代的C 1-30亚烷基,氟取代的C 3-30亚环烷基,氟取代的C 6-30亚芳基 ,或氟取代的C 7-30亚烷基 - 亚芳基,Z是包含磺酸盐,磺酰胺或磺酰胺的阴离子基团,G +具有式(II):其中X是S或I,每个R 0是卤素或 非卤代,独立地为C 1-30烷基; 多环或单环C 3-30环烷基; 多环或单环C 4-30芳基; 或这些的组合,其中当X是S时,R 0中的一个任选地通过单键连接到一个相邻的R 0基团,a是2或3,其中当X是I时,a是2或 当X为S时,a为3.共聚物,光致抗蚀剂,涂布基材和图案化方法。

    Photoacid generators
    3.
    发明公开
    Photoacid generators 审中-公开
    Fotosäuregeneratoren

    公开(公告)号:EP2458440A1

    公开(公告)日:2012-05-30

    申请号:EP11190453.8

    申请日:2011-11-24

    IPC分类号: G03F7/004 G03F7/038 G03F7/039

    摘要: A photoacid generator compound has the formula (I):

             G + Z-     (I)

    wherein G has the formula (II):

    wherein in formula (II), X is S or I, each R 0 is commonly attached to X and is independently a C 1-30 alkyl group; a polycyclic or monocyclic C 3-30 cycloalkyl group; a polycyclic or monocyclic C 6-30 aryl group; or a combination comprising at least one of the foregoing, G has a molecular weight of greater than 263.4 g/mol, or G has a molecular weight of less than 263.4 g/mol and one or more R 0 groups are further attached to an adjacent R 0 group, a is 2 or 3, wherein when X is I, a is 2, or when X is S, a is 2 or 3, and Z in formula (I) comprises the anion of a sulfonic acid, a sulfonimide, or a sulfonamide. A photoresist and coated film also includes the photoacid generator and a polymer, and a method of forming an electronic device uses the photoresist.

    摘要翻译: 光致酸发生剂化合物具有式(I):ƒ€ƒ€ƒ€ƒ€ƒ€ƒG + Z-ƒ€ƒ€ƒ€ƒ(I)其中G具有式( II):其中在式(II)中,X为S或I,每个R 0通常与X连接,独立地为C 1-30烷基; 多环或单环C 3-30环烷基; 多环或单环C 6-30芳基; 或包含上述至少一种的组合,G具有大于263.4g / mol的分子量,或G具有小于263.4g / mol的分子量,并且一个或多个R 0基团进一步连接到相邻的 R 0基团,a为2或3,其中当X为I时,a为2,或当X为S时,a为2或3,式(I)中的Z为磺酸阴离子,磺酰亚胺, 或磺酰胺。 光致抗蚀剂和涂膜也包括光致酸产生剂和聚合物,并且形成电子器件的方法使用光致抗蚀剂。