摘要:
A lubricating composition suited to use in a marine diesel engine includes an oil of lubricating viscosity and an amino carboxylate compound of formula (I): NR1R2—((CHR3)xNR4)n—(CHR5)2—COY, where R1 and R2 are independently selected from —(CHR6)2—COY′, H, and C1C3 alkyl and wherein at least one of R1 and R2 is —(CHR6)2—COY′; or wherein NR1R2 is a cyclic structure; Y and Y′ are independently selected from —OR4, NHR7, and —N(R7)2; each R7 is independently selected from C6-C12 alkyl and C6-C12 alkenyl; R3, R5 and R6 are independently selected from H and C1-C4 alkyl; R4 is selected from H, C1-C4 alkyl, and (CHR3)xNH2; x is from 2 to 4; and n is at least 1, except where NR1R2 is a cyclic structure, where n is at least 0.
摘要:
This invention relates to a low-sulfur consumable lubricating oil composition, comprising: a base oil; an acylated nitrogen-containing compound having a substituent of at least about 10 aliphatic carbon atoms; and a sulfur content of about 5 to about 250 ppm; said composition being characterized by the absence of an extreme-pressure additive comprised of metal and phosphorus. This invention further relates to a a method of operating an internal combustion engine equipped with an exhaust gas after treatment device, said method comprising: (A) operating said engine using a normally liquid or gaseous fuel; (B) lubricating said engine using the foregoing low-sulfur consumable lubricating oil composition; (C) removing part of said low-sulfur consumable lubricating oil composition from said engine, said removed part of said low-sulfur consumable lubricating oil composition (i) being combined with said fuel and consumed with said fuel as said engine is operated or (ii) being combined with the exhaust gas from said engine and removed from said engine with said exhaust gas; and (D) adding an additional amount of said low-sulfur consumable lubricating oil composition to said engine to replace said removed part of said low-sulfur consumable lubricating oil composition.
摘要:
A method of operating an internal combustion engine comprising a valve train, comprises: (A) operating said engine using a normally liquid or gaseous fuel; (B) lubricating components of said valve train using a solid film lubricant; and (C) lubricating said engine, including said components of said valve train, using a low-phosphorus or phosphorus-free lubricating oil composition.
摘要:
This invention relates to a low-sulfur consumable lubricating oil composition, comprising: a base oil; an acylated nitrogen-containing compound having a substituent of at least about 10 aliphatic carbon atoms; and a sulfur content of about 5 to about 250 ppm; said composition being characterized by the absence of an extreme-pressure additive comprised of metal and phosphorus. This invention further relates to a a method of operating an internal combustion engine equipped with an exhaust gas after treatment device, said method comprising: (A) operating said engine using a normally liquid or gaseous fuel; (B) lubricating said engine using the foregoing low-sulfur consumable lubricating oil composition; (C) removing part of said low-sulfur consumable lubricating oil composition from said engine, said removed part of said low-sulfur consumable lubricating oil composition (i) being combined with said fuel and consumed with said fuel as said engine is operated or (ii) being combined with the exhaust gas from said engine and removed from said engine with said exhaust gas; and (D) adding an additional amount of said low-sulfur consumable lubricating oil composition to said engine to replace said removed part of said low-sulfur consumable lubricating oil composition.
摘要:
A lubricating composition includes an oil of lubricating viscosity and an ionic tetrahedral borate compound which includes a cation and a tetrahedral borate anion which includes a boron atom, the boron atom having at least one aromatic bidentate di-oxo ligand. The compound may be represented by formula (I), where R1 and R2 are selected from C1-48 hydrocarbyl groups or together form a substituted or unsubstituted 5- or 6-membered ring; R3 and R4 together represent a substituted or unsubstituted aromatic ring; m is 0 or 1; X is hydrogen, a C1-24 hydrocarbyl group, -OR5, -NHR5, or =O, R5 is a C1-24 hydrocarbyl group; M represents the cation; and n is at least 1. The cation may be selected to provide detergent and/or dispersant properties to the lubricating composition. In the case of ammonium cations, the molecular weight may be 260 g/mol or higher for providing a highly soluble compound, particularly when X is =O.
摘要:
An internal combustion engine with a catalyst-containing exhaust-gas aftertreatment device is lubricated with a composition of a base oil; and a zinc salt of a mixture of phosphorus-containing compounds having hydrocarbyl groups R1 and R2 where the average total number of carbon atoms in R1 plus R2 for the mixture of phosphorus-containing compounds is at least 9.5, where 4 to 30 weight percent of such groups contain 2 to 4 carbon atoms and where in less than 8 mole percent of the phosphorus-containing molecules in the mixture of phosphorus- containing compounds each of R1 and R2 contain 2 to 4 carbon atoms.