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    Polyester compositions which comprise cyclobutanediol and certain thermal stabilizers, and/or reaction products thereof
    1.
    发明专利
    Polyester compositions which comprise cyclobutanediol and certain thermal stabilizers, and/or reaction products thereof 有权
    包含环丙沙星和某些热稳定剂的聚酯组合物和/或其反应产物

    公开(公告)号：JP2013249482A

    公开(公告)日：2013-12-12

    申请号：JP2013185077

    申请日：2013-09-06

    申请人： Eastman Chemical Co ,  イーストマン ケミカル カンパニー

    发明人： GERMROTH TED CALVIN ,  CONNELL GARY WAYNE ,  CRAWFORD EMMETT DUDLEY ,  PECORINI THOMAS JOSEPH ,  MCWILLIAMS DOUGLAS STEPHENS ,  BARTON BENJAMIN FREDRICK ,  SHACKELFORD DAMON BRYAN

    IPC分类号： C08L67/02 ,  C08G63/199 ,  C08G63/82 ,  C08K5/521 ,  C08L101/00

    CPC分类号： C08G63/183 ,  C08G63/199 ,  C08G63/82 ,  C08G63/85 ,  C08K5/521 ,  C08L67/02 ,  C08L101/00

    摘要： PROBLEM TO BE SOLVED: To provide polyester compositions that are thermally stable and cause no color formation without causing foaming, when producing a film, a sheet material, and a molded product.SOLUTION: Polyester compositions contains: (I) at least one polyester which comprises (a) a dicarboxylic acid component comprising (i) 70 to 100 mol% of terephthalic acid residues, (ii) 0 to 30 mol% of aromatic dicarboxylic acid residues having up to 20 carbon atoms, and (iii) 0 to 10 mol% of aliphatic dicarboxylic acid residues having up to 16 carbon atoms, and (b) a glycol component comprising (i) 1 to 99 mol% of 2,2,4,4-tetramethyl-1,3-cyclobutanediol residues, and (ii) 1 to 99 mol% of cyclohexanedimethanol residues; and (II) at least one thermal stabilizer chosen from at least one of alkyl phosphate esters, aryl phosphate esters, mixed alkyl aryl phosphate esters, reaction products thereof, and mixtures thereof, wherein the total mol% of the dicarboxylic acid component is 100 mol%, and wherein the total mol% of the glycol component is 100 mol%.

    摘要翻译： 要解决的问题：提供热稳定的聚酯组合物，不引起发色的聚酯组合物，当制备薄膜，片材和模塑产品时。聚酯组合物包含：（I）至少一种聚酯， 包括（a）二羧酸组分，其包含（i）70-100mol％的对苯二甲酸残基，（ii）0至30mol％的具有至多20个碳原子的芳族二羧酸残基，和（iii）0至10mol ％的具有至多16个碳原子的脂族二羧酸残基，和（b）二元醇组分，其包含（i）1至99mol％的2,2,4,4-四甲基-1,3-环丁二醇残基和（ii ）1〜99摩尔％的环己烷二甲醇残基; 和（II）选自烷基磷酸酯，芳基磷酸酯，混合烷基芳基磷酸酯，其反应产物及其混合物中的至少一种的至少一种热稳定剂，其中二羧酸组分的总摩尔％为100摩尔 ％，其中二醇组分的总摩尔％为100摩尔％。

    Copolyesters and blends with improved recyclability, processes for their manufacture, and articles prepared therefrom
    2.
    发明专利
    Copolyesters and blends with improved recyclability, processes for their manufacture, and articles prepared therefrom 有权
    具有改进可回收性的共聚物和共混物，其制备方法及其制备的制品

    公开(公告)号：JP2013249481A

    公开(公告)日：2013-12-12

    申请号：JP2013184077

    申请日：2013-09-05

    申请人： Eastman Chemical Co ,  イーストマン ケミカル カンパニー

    发明人： PECORINI THOMAS JOSEPH ,  GILLIAM SPENCER ALLEN ,  GARCIA IGNACIO

    IPC分类号： C08G63/183 ,  B29C49/04 ,  B29K67/00 ,  C08L67/02

    CPC分类号： C08G63/199 ,  B29C49/0047 ,  B29C49/04 ,  C08J5/00 ,  C08J2367/00 ,  Y10T428/1352 ,  Y10T428/139 ,  Y10T428/1393 ,  Y10T428/1397

    摘要： PROBLEM TO BE SOLVED: To provide extrusion blow molded articles of a polyester, which are useful in extrusion blow molding, profile extrusion molding and the like, have a low haze value, and cause no adhesion to an apparatus during drying and processing.SOLUTION: Described are extrusion blow molded articles comprising a polyester which comprises: (a) a dicarboxylic acid component comprising (i) about 90 to about 100 mol% of terephthalic acid residues, and (ii) about 0 to about 10 mol% of aromatic and/or aliphatic dicarboxylic acid residues having up to 20 carbon atoms; and (b) a glycol component comprising (i) about 42 to about 60 mol% ethylene glycol residues, and (ii) about 40 to about 58 mol% residues of 1,4-cyclohexanedimethanol. The inherent viscosity of the polyester is from 0.50 to 1.0 dL/g as determined in 60/40 (wt/wt) phenol/tetrachloroethane at a concentration of 0.25 g/50 ml at 25°C.

    摘要翻译： 要解决的问题：为了提供可用于挤出吹塑，型材挤出成型等的聚酯的挤出吹塑制品具有低雾度值，并且在干燥和加工期间不会对装置造成粘附。解决方案： 描述了包含聚酯的挤出吹塑制品，其包含：（a）二羧酸组分，其包含（i）约90至约100摩尔％的对苯二甲酸残基，和（ii）约0至约10摩尔％的芳族和/ 或具有至多20个碳原子的脂族二羧酸残基; 和（b）二醇组分，其包含（i）约42至约60mol％的乙二醇残基，和（ii）约40至约58mol％的1,4-环己烷二甲醇残基。 如在25℃下以0.25g / 50ml浓度的60/40（wt / wt）苯酚/四氯乙烷测定的，聚酯的比浓对数粘度为0.50至1.0dL / g。

    Terephthalates as plasticizers in vinyl acetate polymer composition
    3.
    发明专利
    Terephthalates as plasticizers in vinyl acetate polymer composition 有权
    作为醋酸乙烯酯聚合物组合物中的增塑剂的癸二酸酯

    公开(公告)号：JP2013049861A

    公开(公告)日：2013-03-14

    申请号：JP2012231838

    申请日：2012-10-19

    申请人： Eastman Chemical Co ,  イーストマン ケミカル カンパニー

    发明人： STIMPSON MARTIN JAMES ,  HOLT MARK STEPHEN

    IPC分类号： C09J5/00 ,  C09J11/06 ,  C09J131/04

    CPC分类号： C08K5/12

    摘要： PROBLEM TO BE SOLVED: To provide a method of forming an adhesive bond between two or more articles or two or more parts of the same article with an adhesive including a vinyl acetate polymer and a plasticizer.SOLUTION: The method includes forming an adhesive bond between two articles or two or more parts of the same articles. The method includes applying a composition to at least one article, an opening of at least an article, joints, bonding parts or connecting parts between two or more articles, a joint, bonding parts or connecting parts between two or more parts of one or more articles, or two or more combinations thereof. The composition is aqueous, and includes (a) at least one kind of vinyl acetate polymer, and (b) at least one kind of plasticizer including at least one kind of 4 to 8 C alkyl terephthalate, wherein the 4 to 8 C alkyl terephthalate is present at least an amount of 6% as a dry mass base therein.

    摘要翻译： 要解决的问题：提供一种使用包含乙酸乙烯酯聚合物和增塑剂的粘合剂在同一物品的两个或更多个物品或两个或更多个部分之间形成粘合剂的方法。 解决方案：该方法包括在两个制品或两个或更多个相同制品的部分之间形成粘结剂。 该方法包括将组合物施用于至少一个制品，至少一个制品的开口，两个或更多个制品之间的接合部，接合部分或连接部分，一个或多个部件的两个或多个部分之间的接头，接合部件或连接部件 物品或其两种或多种组合。 该组合物是水性的，并且包括（a）至少一种乙酸乙烯酯聚合物，和（b）至少一种增塑剂，其包括至少一种4至8 C对苯二甲酸烷基酯，其中4至8个碳酸烷基对苯二甲酸酯 至少存在6％的干质量碱。 版权所有（C）2013，JPO＆INPIT

    Process for preparation of transparent shaped article
    5.
    发明专利
    Process for preparation of transparent shaped article 有权
    透明形状制品的制备方法

    公开(公告)号：JP2012207235A

    公开(公告)日：2012-10-25

    申请号：JP2012173018

    申请日：2012-08-03

    申请人： Eastman Chemical Co ,  イーストマン ケミカル カンパニー

    发明人： HALE WESLEY RAYMOND ,  PECORINI THOMAS JOSEPH ,  STEWART MARK EDWARD ,  ROGERS MARTIN EMERSON ,  GILLIAM SPENCER ALLEN ,  CLIFFTON MICHAEL DUANE ,  SHELBY MARCUS DAVID

    IPC分类号： C08L67/02 ,  C08J3/20 ,  C08L69/00 ,  C08L77/06

    CPC分类号： B29B17/0042 ,  C08K3/08 ,  C08L67/00 ,  C08L67/02 ,  C08L69/00 ,  C08L77/00 ,  C08L2205/02 ,  Y02W30/62 ,  Y10T428/13 ,  Y10T428/1334 ,  Y10T428/1352 ,  Y10T428/1355 ,  Y10T428/1359 ,  Y10T428/1379 ,  Y10T428/1383 ,  Y10T428/31725 ,  Y10T428/31736 ,  Y10T428/31739 ,  C08L2666/20 ,  C08L2666/14

    摘要： PROBLEM TO BE SOLVED: To provide a process for the preparation of shaped articles that has high transparency and low haze, and comprises immiscible blends of thermoplastic polymers and a copolyamide, or a transamidized homogeneous blend.SOLUTION: The method includes: a step (A) of melt-blending a first component comprising a thermoplastic polymer of polyesters, polycarbonates and/or polyarylates with a second component comprising a copolyamide or a homogeneous, transamidized blend of polyamides, wherein the first component and second component form an immiscible blend, the second component and the first component have a difference in refractive index of 0.006 to -0.0006, and the immiscible blend has a percent transmittance of at least 75%, and a haze of 10% or less; a step (B) of forming a shaped article; a step (C) of recovering a scrap polymer composition comprising the blended first and second components; a step (D) of grinding the scrap polymer composition to produce a polymer regrind; a step (E) of optionally drying the scrap polymer composition; and a step (F) of combining the polymer regrind with the first and second components of the step (A).

    摘要翻译： 要解决的问题：提供一种制备具有高透明度和低雾度的成型制品的方法，并且包括热塑性聚合物和共聚酰胺的不混溶共混物，或者是酰胺化的均匀混合物。 解决方案：该方法包括：将包含聚酯，聚碳酸酯和/或多芳基化合物的热塑性聚合物的第一组分与包含共聚酰胺或均匀的，酰胺化的聚酰胺共混物的第二组分熔融共混的步骤（A），其中 第一组分和第二组分形成不混溶共混物，第二组分和第一组分的折射率差为0.006至-0.0006，并且不混溶共混物的透光率百分比至少为75％，雾度为10％ 或更少; 形成成形品的工序（B） 回收包含混合的第一和第二组分的废聚合物组合物的步骤（C）; 研磨废料聚合物组合物以制备聚合物回收料的步骤（D）; 任选地干燥废聚合物组合物的步骤（E）; 和将聚合物再研磨与步骤（A）的第一和第二组分组合的步骤（F）。 版权所有（C）2013，JPO＆INPIT

    Polymer blend with improved notched impact strength
    6.
    发明专利
    Polymer blend with improved notched impact strength 审中-公开
    聚合物混合物具有改进的注入冲击强度

    公开(公告)号：JP2012193387A

    公开(公告)日：2012-10-11

    申请号：JP2012157700

    申请日：2012-07-13

    申请人： Eastman Chemical Co ,  イーストマン ケミカル カンパニー

    发明人： HALE WESLEY RAYMOND ,  TANNER CANDACE MICHELE

    IPC分类号： C08L67/02 ,  C08J5/00 ,  C08K3/26 ,  C08L67/00 ,  C08L67/04 ,  C08L101/16

    CPC分类号： C08J5/18 ,  C08J2367/02 ,  C08J2367/04 ,  C08K5/0016 ,  C08L67/02 ,  C08L67/04 ,  C08L2205/02 ,  C08L2666/18

    摘要： PROBLEM TO BE SOLVED: To provide injection-molded polymer blends with improved notched Izod impact strength and temperature stability.SOLUTION: The polymer blends contains: (A) 70 to 75 wt.% of at least one flexible biodegradable polymer (A) having a glass transition temperature of less than about 0°C, selected from aliphatic-aromatic polyesters; (B) 25 wt.% of at least one rigid biodegradable polymer (B) having a glass transition temperature of greater than about 10°C, selected from biopolymers based on polylactic acid; and (C) 0 to 5 wt.% of at least one biodegradable additive, wherein the polymer blend has a notched Izod impact strength according to ASTM D256 of at least 397.5 J/m (7.5 ft-lbs/in).

    摘要翻译： 要解决的问题：提供具有改进的缺口伊佐德冲击强度和温度稳定性的注塑聚合物共混物。 聚合物共混物包含：（A）70至75重量％的玻璃化转变温度低于约0℃的至少一种柔性可生物降解的聚合物（A），其选自脂族 - 芳族聚酯; （B）25重量％的玻璃化转变温度大于约10℃的至少一种刚性可生物降解聚合物（B），其选自基于聚乳酸的生物聚合物; 和（C）0至5重量％的至少一种可生物降解的添加剂，其中所述聚合物共混物根据ASTM D256具有至少397.5J / m（7.5ft-lbs / in）的缺口伊佐德冲击强度。 版权所有（C）2013，JPO＆INPIT

    Method of packaging elastic fiber
    8.
    发明专利
    Method of packaging elastic fiber 有权
    包装弹性纤维的方法

    公开(公告)号：JP2011084343A

    公开(公告)日：2011-04-28

    申请号：JP2010270441

    申请日：2010-12-03

    申请人： Eastman Chemical Co ,  イーストマン ケミカル カンパニー

    发明人： MCLAUGHLIN MICHAEL RAY ,  MULLINS CHARLES DUANE ,  SANDERS CHARLES CLIFTON ,  SMITHERS HILLARD BIRDELL III ,  NELSON GREGORY KYLE

    IPC分类号： B65D81/20 ,  B65D85/07 ,  B65B27/12 ,  B65B31/04 ,  B65D6/28 ,  B65D30/02

    CPC分类号： B65B1/24 ,  B30B9/3032 ,  B65B27/125 ,  B65B31/047 ,  B65B61/182 ,  B65D81/2023 ,  B65D85/07

    摘要： PROBLEM TO BE SOLVED: To provide a method of forming cellulose acetate tow fiber into a bale configured to include a sealed chamber with an internal volume in lower pressure relative to environmental atmospheric pressure. SOLUTION: In the method of packaging the elastic cellulose acetate tow fiber, the fiber is prepared, compressed and provided with an evacuator as a check valve thereon thereby forming a chamber which can be sealed, and the chamber is sealed and evacuated by way of the evacuator including release of compression with a density of 0.50-0.78 g/cm 3 and an internal pressure of ≥16,000 and COPYRIGHT: (C)2011,JPO&INPIT

    摘要翻译： 要解决的问题：提供一种将乙酸纤维素丝束纤维形成为包括相对于环境大气压力的具有较低压力的内部体积的密封室的捆包的方法。 解决方案：在包装弹性纤维素醋酸纤维素纤维的方法中，纤维被制备，压缩并在其上设置有作为止回阀的排气器，从而形成可以被密封的室，并且将室密封并抽真空 排气装置的方式包括在所获得的捆包中释放密度为0.50-0.78g / cm 3 / SP的压缩和内部压力≥16,000和<101,325Pa。 版权所有（C）2011，JPO＆INPIT

    Spheroidal polyester polymer particle
    10.
    发明专利
    Spheroidal polyester polymer particle 有权
    SPHEROIDAL POLYESTER聚合物颗粒

    公开(公告)号：JP2013177647A

    公开(公告)日：2013-09-09

    申请号：JP2013134174

    申请日：2013-06-26

    申请人： Eastman Chemical Co ,  イーストマン ケミカル カンパニー

    发明人： WEINHOLD STEPHEN ,  COLHOUN FREDERICK LESLIE ,  EKART MICHAEL PAUL ,  GAMBLE BENJAMIN BRADFORD

    IPC分类号： C08G63/181 ,  C08G63/78

    CPC分类号： C08G63/88 ,  Y10T428/1334 ,  Y10T428/1355

    摘要： PROBLEM TO BE SOLVED: To provide bulk of spheroidal polyester particles in specific physical and geometrical configuration.SOLUTION: A bulk of spheroidal polyester particles has (a) an It.V. of at least 0.72 dL/g, (b) (i) at least two melting peaks having a low peak melting point having a peak temperature of 140-220°C and a melting endothermic area of the absolute value of at least 1 J/g, or (ii) at least one melting point having a heating curve which separates from the base line in the endothermic direction at a temperature of 200°C or less, and/or (c) a degree of crystallinity of 45% or less. The polyester includes 20 mol% or less of carboxylic acid residues other than terephthalic acid residues relative to 100 mol% of the carboxylic acid residues, and the polyester includes at least 4 mol% of 1,4-cyclohexane dimethanol residues and 20 mol% or less of a hydroxy functional compound residues other than ethylene glycol relative to 100 mol% of the hydroxyfunctional compound. The polyester particles are not subjected to solid-phase polymerization, and a repose angle is 34° or less.

    摘要翻译： 要解决的问题：提供大量具有特定物理和几何结构的球状聚酯颗粒。解决方案：大量的球形聚酯颗粒具有（a）It.V。 至少0.72dL / g，（b）（i）至少两个具有峰值熔点低峰值熔点的熔融峰，其峰温度为140-220℃，熔融吸热面积绝对值至少为1J / g，或（ii）至少一个具有加热曲线的熔点，该加热曲线在200℃或更低的温度下在吸热方向上与基线分离，和/或（c）结晶度为45％以下 。 相对于100摩尔％的羧酸残基，聚酯包含20摩尔％以下的除对苯二甲酸残基之外的羧酸残基，聚酯包括至少4摩尔％的1,4-环己烷二甲醇残基和20摩尔％ 相对于100摩尔％的羟基官能化合物，少于乙二醇以外的羟基官能化合物残基。 聚酯粒子不进行固相聚合，休止角为34°以下。