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    Method for producing monocyclic aromatic hydrocarbon
    2.
    发明专利
    Method for producing monocyclic aromatic hydrocarbon 有权
    生产单环芳香烃的方法

    公开(公告)号：JP2012201796A

    公开(公告)日：2012-10-22

    申请号：JP2011067691

    申请日：2011-03-25

    申请人： Jx Nippon Oil & Energy Corp ,  Chiyoda Kako Kensetsu Kk ,  Jx日鉱日石エネルギー株式会社 ,  千代田化工建設株式会社

    发明人： YANAGAWA SHINICHIRO ,  IDA RYOJI ,  IWASA YASUYUKI ,  KOBAYASHI MASAHIDE ,  YASUI SUSUMU ,  SUGI YOSHISHIGE ,  FUKUI ATSUSHI ,  NAGUMO ATSUO

    IPC分类号： C10G69/04 ,  C07B61/00 ,  C07C4/08 ,  C07C5/10 ,  C07C5/13 ,  C07C7/04 ,  C07C15/02 ,  C10G11/05 ,  C10G45/44

    摘要： PROBLEM TO BE SOLVED: To provide a method for producing a monocyclic aromatic hydrocarbon capable of suppressing extreme heat generation upon hydrogenation reaction and avoiding increase of equipment cost of a hydrogenation reactor.SOLUTION: The method for producing the monocyclic aromatic hydrocarbon having 6-8 carbon atoms has a breakdown/modification reaction step of bringing a starting material oil in reactive contact with a catalyst to obtain a product containing the monocyclic aromatic hydrocarbon, a purification/collection step of purifying and collecting monocyclic aromatic hydrocarbon isolated from the product generated in the breakdown/modification step, a dilution step of adding a dilution agent to a heavy fraction isolated from the product generated in the breakdown/modification step, a hydrogenation reaction step of hydrogenating the mixture, and a recycling step of returning a hydrogenated product of the mixture obtained in the hydrogenation reaction step to the breakdown/modification reaction step.

    摘要翻译： 解决的问题：提供一种能够抑制氢化反应时的极热发生的单环芳烃的制造方法，避免氢化反应器的设备成本的增加。 解决方案：制备具有6-8个碳原子的单环芳族烃的方法具有使原料油与催化剂反应接触的分解/改性反应步骤，得到含有单环芳烃的产物，纯化 从分解/改性步骤产生的产物中分离纯化和收集单环芳烃的收集步骤，将稀释剂加入到从分解/改性步骤产生的产物中分离的重质馏分的稀释步骤，氢化反应步骤 使氢化反应工序中得到的混合物的氢化物返回至破坏/改性反应工序。 版权所有（C）2013，JPO＆INPIT

    PRODUCTION OF REDUCED FORM FROM ALDEHYDE COMPOUND
    8.
    发明专利
    PRODUCTION OF REDUCED FORM FROM ALDEHYDE COMPOUND 失效

    公开(公告)号：JPH08283181A

    公开(公告)日：1996-10-29

    申请号：JP8903495

    申请日：1995-04-14

    申请人： UBE INDUSTRIES

    发明人： HAMAMOTO SHUNICHI ,  YAMANAKA MITSUO ,  NAKAMURA TAKAHITO ,  SHIMANO TETSUO

    IPC分类号： B01J31/24 ,  C07B37/06 ,  C07B61/00 ,  C07C1/207 ,  C07C4/08 ,  C07C4/12 ,  C07C9/00 ,  C07C9/15 ,  C07C13/02 ,  C07C15/02 ,  C07C41/18 ,  C07C43/205 ,  C07C43/23

    摘要： PURPOSE: To obtain a reduced form of an aldehyde compound at relatively low temperatures and at high reaction rate without the need of using a large quantity of a transition metal complex, by adding a ruthenium complex and an organic hydroperoxide to the aldehyde compound to carry out a decarbonylation. CONSTITUTION: This reduced form is obtained by incorporating an aldehyde compound with a ruthenium complex of the formula RuX2 Ln (PPh3 )n (Ph is phenyl; X is an anionic ligand capable coordinating with an Ru atom; L is a neutral ligand capable of coordinating with an Ru atom; (n) is 0-3; (m) is 1-4; (m+n) is a natural number of to 5×10, and the molar ratio of the organic hydroperoxide to the aldehyde compound is normally 0.5-5. The decarbonylation is pref. carried out using, a reaction solvent, e.g. an alkane as a raw material for the organic hydroperoxide at 80-160 deg.C.