公开(公告)号：US08013090B2

公开(公告)日：2011-09-06

申请号：US12223324

申请日：2007-01-26

申请人： Atsushi Ishiguro ,  Yoshihisa Takeyama ,  Yasuo Tsunogae

发明人： Atsushi Ishiguro ,  Yoshihisa Takeyama ,  Yasuo Tsunogae

IPC分类号： C08F232/08 ,  C08F232/04 ,  C09K19/32

CPC分类号： C08J5/18 ,  B32B27/08 ,  B32B27/18 ,  B32B27/20 ,  B32B27/22 ,  B32B27/306 ,  B32B27/32 ,  B32B27/325 ,  B32B27/34 ,  B32B2255/10 ,  B32B2255/20 ,  B32B2307/202 ,  B32B2307/308 ,  B32B2307/40 ,  B32B2307/412 ,  B32B2307/714 ,  B32B2307/7242 ,  B32B2307/7265 ,  B32B2307/734 ,  B32B2457/202 ,  C08F232/08 ,  C08J2345/00 ,  Y10T428/10 ,  Y10T428/31938

摘要： A film comprising a norbornene (NB) compound addition polymer that is excellent in chemical resistance, optical properties and the like, has a high Tg, a low water absorption ratio and a low linear expansion coefficient, and is soluble in an ordinary solvent.The film comprising a NB compound addition polymer essentially consisting of repeating units derived from NB compound monomers, wherein the addition polymer has a specific Mw and has a sum of the units (A1) and (A2) of 70% by mol or more based on the total units, wherein the molar number of each unit satisfies the following equations: 70/30≦[{(A1)+(A2)}/(B)]≦100 and 10/90≦(A1)/(A2)≦98/2, or the addition polymer has a specific Mw and Mn and essentially consists of the units (A1) and (B), wherein the molar number of each unit satisfies the following equation: 70/30≦[(A1)/(B)] ≦98/2.

摘要翻译： 包含耐化学性，光学特性等优异的降冰片烯（NB）化合物加成聚合物的膜具有高Tg，低吸水率和低线膨胀系数，并且可溶于普通溶剂。 该膜包含基本上由衍生自NB化合物单体的重复单元组成的NB化合物加成聚合物，其中加成聚合物具有特定的Mw，并且单位（A1）和（A2）之和为70摩尔％以上，基于 其中每个单位的摩尔数满足以下等式：70/30＆nlE; [{（A1）+（A2）} /（B）]＆nlE; 100和10/90＆nlE;（A1）/（A2） （A1）和（B），其中每个单元的摩尔数满足以下等式：70/30＆nlE; [（A1） /（B）]＆nlE; 98/2。

公开(公告)号：US20130244367A1

公开(公告)日：2013-09-19

申请号：US13877119

申请日：2011-09-29

申请人： Teiji Kohara ,  Atsushi Ishiguro ,  Ryuta Kurihara

发明人： Teiji Kohara ,  Atsushi Ishiguro ,  Ryuta Kurihara

IPC分类号： H01L31/048

CPC分类号： C08F8/42 ,  B32B7/08 ,  B32B7/12 ,  B32B27/08 ,  B32B27/18 ,  B32B27/28 ,  B32B27/283 ,  B32B27/30 ,  B32B27/302 ,  B32B27/308 ,  B32B27/32 ,  B32B27/36 ,  B32B27/365 ,  B32B2250/02 ,  B32B2250/03 ,  B32B2250/24 ,  B32B2250/40 ,  B32B2307/412 ,  B32B2307/54 ,  B32B2307/712 ,  B32B2307/7246 ,  B32B2307/748 ,  B32B2307/752 ,  B32B2457/12 ,  C08F8/04 ,  C08F287/00 ,  C08F297/04 ,  C08F2800/20 ,  C08F2810/50 ,  H01L31/0481 ,  Y02E10/50 ,  Y10T428/31663 ,  C08F230/08 ,  C08F297/046

摘要： Provided are: an alkoysilyl group-containing hydrogenated block copolymer produced by introducing an alkoxysilyl group into a hydrogenated block copolymer that is obtained by hydrogenating 90% or more of unsaturated bonds of a block copolymer that includes at least two polymer blocks [A] and at least one polymer block [B], the polymer block [A] including a repeating unit derived from an aromatic vinyl compound as a main component, the polymer block [B] including a repeating unit derived from a linear conjugated diene compound as a main component, and a ratio (wA:wB) of a weight fraction wA of the polymer block [A] in the block copolymer to a weight fraction wB of the polymer block [B] in the block copolymer being 20:80 to 60:40; a method for producing the same; a solar cell element encapsulating material; a sheet, a laminated sheet; a multilayer sheet; and a method for encapsulating a solar cell element. The alkoxysilyl group-containing hydrogenated block copolymer exhibits low hygroscopicity, a low water vapor permeability, transparency, weatherability, and flexibility, maintains excellent adhesion to glass even when exposed to a high-temperature/high-humidity environment for a long time, and can encapsulate a solar cell element without applying a special waterproof treatment.

摘要翻译： 提供：通过将烷氧基甲硅烷基引入氢化嵌段共聚物中制备的含有链烷醚基的氢化嵌段共聚物，该氢化嵌段共聚物是通过使含有至少两个聚合物嵌段[A]的嵌段共聚物的90％以上的不饱和键氢化而得到的， 至少一个聚合物嵌段[B]，聚合物嵌段[A]包含衍生自芳族乙烯基化合物作为主要成分的重复单元，聚合物嵌段[B]包含以线性共轭二烯化合物为主要成分的重复单元 ，嵌段共聚物中聚合物嵌段[A]的重量分数wA与嵌段共聚物中聚合物嵌段[B]的重量分数wB的比（wA：wB）为20:80〜60:40; 其制造方法; 太阳能电池元件封装材料; 片材，层压片材; 多层片材 以及封装太阳能电池元件的方法。 含有烷氧基甲硅烷基的氢化嵌段共聚物具有低吸湿性，低透湿性，耐候性和柔软性，即使长时间暴露于高温/高湿度环境下，也能保持对玻璃的优异粘合性，并且可以 封装太阳能电池元件而不进行特殊的防水处理。

公开(公告)号：US20090297870A1

公开(公告)日：2009-12-03

申请号：US12225408

申请日：2007-03-19

申请人： Yoshihisa Takeyama ,  Atsushi Ishiguro ,  Shingo Okuno

发明人： Yoshihisa Takeyama ,  Atsushi Ishiguro ,  Shingo Okuno

IPC分类号： B32B27/32 ,  C08F32/02 ,  C08K5/13 ,  C08K5/151 ,  C08K3/32 ,  C08L55/00

CPC分类号： C08J5/18 ,  C08F232/08 ,  C08J2365/00 ,  C08K5/005 ,  C08L45/00 ,  G11B7/2538 ,  Y10T428/31938

摘要： [Problems] To provide a norbornene compound addition polymer film that is excellent in heat resistance, chemical resistance, dimensional stability and the like and favorable for use for optical parts and electric insulating parts.[Means for Solving Problems] The norbornene compound addition polymer film satisfies at least either one of the following: when it is heated from 25° C. up to 200° C. and then again cooled to 25° C., the dimensional change rate thereof between before heating and after cooling is at most 100 ppm, or the dimensional change rate thereof between before and after dipping in propylene glycol monomethyl ether acetate at 25° C. for 1 hour is at most 100 ppm. The method for producing the norbornene compound addition polymer film comprises a step of maintaining the film having a residual solvent content of at most 5,000 ppm of the norbornene compound addition polymer having a glass transition temperature of T° C., at a temperature falling within a range of from the higher temperature of either (T-150)° C. or 180° C. to T° C.

摘要翻译： [问题]提供耐热性，耐化学性，尺寸稳定性等优异的降冰片烯化合物加成聚合物膜，有利于光学部件和电绝缘部件的使用。 解决问题的方法降冰片烯化合物加成聚合物膜满足以下至少任意一种：当将其从25℃加热至200℃，然后再次冷却至25℃时，尺寸变化率 在加热至冷却至100ppm之间，或者在丙二醇单甲醚乙酸酯在25℃下浸渍1小时之前和之后的尺寸变化率为至多100ppm。 制备降冰片烯化合物加成聚合物膜的方法包括将玻璃化转变温度为T℃的降冰片烯化合物加成聚合物的残留溶剂含量保持在5000ppm以下的温度的步骤， （T-150）℃或180℃至更高的温度范围。

公开(公告)号：US20090221750A1

公开(公告)日：2009-09-03

申请号：US11886727

申请日：2006-03-20

申请人： Yasuo Tsunogae ,  Shigetaka Hayano ,  Atsushi Ishiguro

发明人： Yasuo Tsunogae ,  Shigetaka Hayano ,  Atsushi Ishiguro

IPC分类号： C08L51/06 ,  C08L53/00

CPC分类号： C08G81/021 ,  C08G61/06 ,  C08G61/08

摘要： A thermoplastic resin comprising a block copolymer or a graft copolymer possessing (A) a crystalline hydrogenated norbornene ring-opening polymer unit and (B) a non-crystalline polymer unit having a glass transition temperature of 40 to 300° C.; A method for producing thermoplastic resin comprising hydrogenating a block copolymer or a graft copolymer possessing a norbornene ring-opening polymer unit (C) and a polymer unit (D) which is converted into the above-mentioned non-crystalline polymer unit (B) after hydrogenation, in the presence of a hydrogenation catalyst; and a molding material comprising the thermoplastic resin are provided. The thermoplastic resin of the present invention excels in transparency, heat resistance, and mechanical strength.

摘要翻译： 包含具有（A）结晶氢化降冰片烯开环聚合物单元的嵌段共聚物或接枝共聚物的热塑性树脂和（B）玻璃化转变温度为40〜300℃的非结晶性聚合物单元。 一种制备热塑性树脂的方法，包括将具有降冰片烯开环聚合物单元（C）的嵌段共聚物或接枝共聚物和聚合物单元（D）氢化，所述聚合物单元（D）经过转化成上述非晶态聚合物单元（B） 在氢化催化剂的存在下进行氢化; 并且提供包含热塑性树脂的成型材料。 本发明的热塑性树脂的透明性，耐热性和机械强度优异。

公开(公告)号：US20050237908A1

公开(公告)日：2005-10-27

申请号：US11102817

申请日：2005-04-11

申请人： Yasuo Takano ,  Atsushi Ishiguro ,  Keiji Aruga ,  Kei Funabashi ,  Kenji Tanaka ,  Naoto Tsuchiya

发明人： Yasuo Takano ,  Atsushi Ishiguro ,  Keiji Aruga ,  Kei Funabashi ,  Kenji Tanaka ,  Naoto Tsuchiya

IPC分类号： F16F15/02 ,  G11B5/48 ,  G11B7/08 ,  G11B21/02 ,  G11B33/08

CPC分类号： G11B5/4833

摘要： To provide a novel method for arranging a vibration suppressing plate to be arranged in an arm of a magnetic disc actuator, a method for arranging a vibration suppressing plate 3 to an arm 2, projected from a magnetic disc actuator 1, for retaining a magnetic head 63 on a tip end side, includes the following steps of: peeling a first one 5 of peelable members 5 and 6 from a planar adhesive member 7 provided on both surfaces of a both-sided adhesive member 4 with the peelable members 5 and 6, the both-sided adhesive member 4 having the same shape as a predetermined shape of the vibration suppressing plate 3; subsequently, applying, aligning and attaching to the vibration suppressing member 3 the planar adhesive member 7 from which the first peelable member 5 has been peeled and removed; subsequently, peeling the other peeling member 6 to form the vibration suppressing plate 3 having one surface attached to the both-sided adhesive member 4; and subsequently, aligning and attaching the vibration suppressing plate 3 in a predetermined position of the arm 2 to arrange the vibration suppressing plate 3 in the arm 2.

摘要翻译： 为了提供一种用于布置在磁盘驱动器的臂中的振动抑制板的新颖方法，一种用于将振动抑制板3布置在从磁盘驱动器1突出的臂2上的方法，用于保持磁头 63包括以下步骤：将剥离构件5和6的第一个5从设置在双面粘合构件4的两个表面上的平面粘合构件7与可剥离构件5和6分离， 具有与振动抑制板3的预定形状相同形状的双面粘合构件4; 随后，对振动抑制构件3施加，对准和附接第一可剥离构件5已经被剥离和去除的平面粘合构件7; 随后剥离另一个剥离构件6，形成一个表面附着在双面粘合构件4上的振动抑制板3; 并且随后将振动抑制板3对准并附接到臂2的预定位置，以将振动抑制板3布置在臂2中。

公开(公告)号：US20090275719A1

公开(公告)日：2009-11-05

申请号：US12223324

申请日：2007-01-26

申请人： Atsushi Ishiguro ,  Yoshihisa Takeyama ,  Yasuo Tsunogae

发明人： Atsushi Ishiguro ,  Yoshihisa Takeyama ,  Yasuo Tsunogae

IPC分类号： C08F32/04

CPC分类号： C08J5/18 ,  B32B27/08 ,  B32B27/18 ,  B32B27/20 ,  B32B27/22 ,  B32B27/306 ,  B32B27/32 ,  B32B27/325 ,  B32B27/34 ,  B32B2255/10 ,  B32B2255/20 ,  B32B2307/202 ,  B32B2307/308 ,  B32B2307/40 ,  B32B2307/412 ,  B32B2307/714 ,  B32B2307/7242 ,  B32B2307/7265 ,  B32B2307/734 ,  B32B2457/202 ,  C08F232/08 ,  C08J2345/00 ,  Y10T428/10 ,  Y10T428/31938

摘要： [Problems] To provide a film comprising a norbornene (NB) compound addition polymer that is excellent in chemical resistance, optical properties and the like, has a high Tg, a low water absorption ratio and a low linear expansion coefficient, and is soluble in an ordinary solvent.[Means for Solving Problems] A film comprising a NB compound addition polymer essentially consisting of repeating units derived from NB compound monomers, wherein the addition polymer has a specific Mw and has a sum of the units (A1) and (A2) of 70% by mol or more based on the total units, wherein the molar number of each unit satisfies the following equations: 70/30≦[{(A1)+(A2)}/(B)]≦100 and 10/90≦(A1)/(A2)≦98/2, or the addition polymer has a specific Mw and Mn and essentially consists of the units (A1) and (B), wherein the molar number of each unit satisfies the following equation: 70/30≦[(A1)/(B)]≦98/2: (A1) a unit derived from a NB compound monomer (a1) consisting of carbon atoms and hydrogen atoms with all the carbon atoms being involved in constitution of a condensed ring skeleton; (A2) a unit derived from a monomer having a structure wherein a part of hydrogen atoms of the monomer (a1) is substituted with only a hydrocarbon group having 2 or less carbon atoms; and (B) a unit derived from a monomer having a structure wherein a part of hydrogen atoms of the monomer (a1) is substituted with only a functional group having 2 or less carbon atoms, or with only a functional group having 2 or less carbon atoms and a hydrocarbon group having 2 or less carbon atoms.

摘要翻译： [问题]为了提供具有耐化学性，光学特性等优异的降冰片烯（NB）化合物加成聚合物的膜，具有高Tg，低吸水率和低线膨胀系数，并且可溶于 普通溶剂。 解决问题的手段一种包含NB化合物加成聚合物的膜，其基本上由衍生自NB化合物单体的重复单元组成，其中加成聚合物具有特定的Mw，单元（A1）和（A2）之和为70％ 其中每个单位的摩尔数满足以下等式：70/30 <= [{（A1）+（A2）} /（B）] <= 100和10/90 < =（A1）/（A2）<= 98/2，或加成聚合物具有特定的Mw和Mn，并且基本上由单元（A1）和（B）组成，其中每个单元的摩尔数满足以下等式： 70/30 <= [（A1）/（B）] <= 98/2：（A1）衍生自由碳原子和氢原子构成的NB化合物单体（a1）的单元，其全部碳原子参与构成 的稠环骨架; （A2）来自具有单体（a1）的一部分氢原子仅被碳原子数2以下的烃基取代的单体的单元， 和（B）单体衍生自单体的单体，其中单体（a1）的一部分氢原子仅被碳原子数2以下的官能团取代，或者仅具有碳原子数为2以下的官能团 原子和碳原子数为2以下的烃基。

公开(公告)号：US20090269601A1

公开(公告)日：2009-10-29

申请号：US11992307

申请日：2006-08-28

申请人： Atsushi Ishiguro ,  Shingo Okuno ,  Yasuo Tsunogae

发明人： Atsushi Ishiguro ,  Shingo Okuno ,  Yasuo Tsunogae

IPC分类号： B32B27/28 ,  C08F30/04 ,  C08F4/80

CPC分类号： G02B1/04 ,  C08F6/02 ,  C08F232/08 ,  Y10T428/31855 ,  C08L23/18 ,  C08L45/00

摘要： [PROBLEMS] To provide: a norbornene compound addition polymer which has excellent heat resistance and suffers no decrease in the excellent transparency and mechanical properties even when exposed to high temperatures during molding, processing, or use; and a process for producing the polymer.[MEANS FOR SOLVING PROBLEMS] The norbornene compound addition polymer comprises, as an essential ingredient, repeating structural units derived from a substituted norbornene compound monomer, wherein the total content of atoms of the transition metals in Group 10 of the Periodic Table, halogen atoms, phosphorus atoms, aluminum atoms, boron atoms, and sulfur atoms is 50 wt. ppm or lower. The process for producing a norbornene compound addition polymer comprises bringing a norbornene compound addition polymer comprising, as an essential ingredient, repeating structural units derived from a substituted norbornene compound monomer into contact with an ion-exchanging lamellar inorganic compound.

摘要翻译： 提供：即使在模塑，加工或使用中暴露于高温下，具有优异的耐热性也不会降低优异的透明性和机械性能的降冰片烯化合物加成聚合物; 和聚合物的制造方法。 解决问题的手段降冰片烯化合物加成聚合物作为必要成分，含有衍生自取代的降冰片烯化合物单体的重复结构单元，其中周期表第10族中的过渡金属的原子总量，卤素原子， 磷原子，铝原子，硼原子和硫原子为50重量％。 ppm以下。 制备降冰片烯化合物加成聚合物的方法包括使作为主要成分的降冰片烯化合物加成聚合物包含重复取代的降冰片烯化合物单体的结构单元与离子交换层状无机化合物接触。

公开(公告)号：US20090182117A1

公开(公告)日：2009-07-16

申请号：US12301760

申请日：2007-05-15

申请人： Yoshihisa Takeyama ,  Atsushi Ishiguro

发明人： Yoshihisa Takeyama ,  Atsushi Ishiguro

IPC分类号： C08G61/02

CPC分类号： B29C55/04 ,  B29C55/005 ,  B29C71/009 ,  B29K2023/38 ,  B29K2105/0038 ,  B29K2105/246 ,  C08J5/18 ,  C08J2345/00

摘要： [Problems] To provide a stretched film of an addition polymer consisting of norbornene compounds favorable for use in manufacturing steps of electric insulating parts and optical parts that exhibits excellent film stability, does not suffer from coloration and has a low linear expansion coefficient.[Means for Solving Problems] A stretched film of an addition polymer consisting of norbornene compounds produced by stretching a film of the addition polymer consisting of norbornene compounds and having a linear expansion coefficient of at most 50 ppm/° C. The draw ratio is preferably from 1.2 times to 10 times. The stretched film is preferably a non-crosslinked film. A method for producing the stretched film comprises stretching a film of the addition polymer consisting of norbornene compounds at least in one direction in an inert gas atmosphere within a temperature range of the glass transition temperature (Tg) thereof ±50° C., or stretching a film of the addition polymer consisting of norbornene compounds containing an organic compound having a specific boiling point at least in one direction.

摘要翻译： [问题]提供一种由有利于电绝缘部件的制造工序的降冰片烯化合物和显示优异的膜稳定性的光学部件组成的加成聚合物的拉伸膜，不会发生着色并具有低的线膨胀系数。 解决问题的手段一种由降冰片烯化合物组成的加成聚合物的拉伸膜，其通过拉伸由降冰片烯化合物构成的加成聚合物的膜，并且线膨胀系数为至多50ppm /℃。拉伸比优选 从1.2倍到10倍。 拉伸膜优选为非交联膜。 制造拉伸膜的方法包括在惰性气体气氛中，在玻璃化转变温度（Tg）±50℃的温度范围内，至少在一个方向上将由降冰片烯化合物构成的加成聚合物的膜拉伸，或拉伸 由含有至少在一个方向上具有特定沸点的有机化合物的降冰片烯化合物组成的加成聚合物膜。

公开(公告)号：US08609005B2

公开(公告)日：2013-12-17

申请号：US12301760

申请日：2007-05-15

申请人： Yoshihisa Takeyama ,  Atsushi Ishiguro

发明人： Yoshihisa Takeyama ,  Atsushi Ishiguro

IPC分类号： B29C51/04 ,  B29C55/00 ,  C08F10/14 ,  C08F132/08

CPC分类号： B29C55/04 ,  B29C55/005 ,  B29C71/009 ,  B29K2023/38 ,  B29K2105/0038 ,  B29K2105/246 ,  C08J5/18 ,  C08J2345/00

摘要： [Problems] To provide a stretched film of an addition polymer consisting of norbornene compounds favorable for use in manufacturing steps of electric insulating parts and optical parts that exhibits excellent film stability, does not suffer from coloration and has a low linear expansion coefficient.[Means for Solving Problems] A stretched film of an addition polymer consisting of norbornene compounds produced by stretching a film of the addition polymer consisting of norbornene compounds and having a linear expansion coefficient of at most 50 ppm/° C. The draw ratio is preferably from 1.2 times to 10 times. The stretched film is preferably a non-crosslinked film. A method for producing the stretched film comprises stretching a film of the addition polymer consisting of norbornene compounds at least in one direction in an inert gas atmosphere within a temperature range of the glass transition temperature (Tg) thereof ±50° C., or stretching a film of the addition polymer consisting of norbornene compounds containing an organic compound having a specific boiling point at least in one direction.

摘要翻译： [问题]提供一种由有利于电绝缘部件的制造工序的降冰片烯化合物和显示优异的膜稳定性的光学部件组成的加成聚合物的拉伸膜，不会发生着色并具有低的线膨胀系数。 解决问题的手段一种由降冰片烯化合物组成的加成聚合物的拉伸膜，其通过拉伸由降冰片烯化合物构成的加成聚合物的膜，并且线膨胀系数为至多50ppm /℃。拉伸比优选 从1.2倍到10倍。 拉伸膜优选为非交联膜。 制造拉伸膜的方法包括在惰性气体气氛中，在玻璃化转变温度（Tg）±50℃的温度范围内，至少在一个方向上将由降冰片烯化合物构成的加成聚合物的膜拉伸，或拉伸 由含有至少在一个方向上具有特定沸点的有机化合物的降冰片烯化合物组成的加成聚合物膜。

公开(公告)号：US20090143523A1

公开(公告)日：2009-06-04

申请号：US11990700

申请日：2006-08-11

申请人： Atsushi Ishiguro ,  Shintaro Ikeda ,  Yasuo Tsunogae

发明人： Atsushi Ishiguro ,  Shintaro Ikeda ,  Yasuo Tsunogae

IPC分类号： C08K3/36 ,  C08F112/08 ,  C08L25/06 ,  C08K3/22

CPC分类号： C08F232/08 ,  C08F32/08

摘要： [Problems] To provide a cycloolefin addition polymer that is capable of satisfying high heat resistance and high refractive index simultaneously, a composite material of the cycloolefin addition polymer with an inorganic material, and a molded article thereof.[Means for Solution] A cycloolefin addition polymer consisting essentially of a cycloolefin monomer unit and containing as an essential component a norbornene monomer unit having an aromatic ring. The cycloolefin addition polymer is preferably a cycloolefin addition polymer that consists essentially of a norbornene monomer unit having an aromatic ring. The cycloolefin addition polymers are excellent in heat resistance and have a high refractive index. The composite material is comprised of the cycloolefin addition polymer and an inorganic material. The molded article is obtained by molding the cycloolefin addition polymer or the composite material.

摘要翻译： [问题]为了提供能够同时满足高耐热性和高折射率的环烯加成聚合物，可以使环烯烃加成聚合物与无机材料的复合材料及其成型体。 [解决方案]一种环烯烃加成聚合物，主要由环烯烃单体单元组成，并含有具有芳香环的降冰片烯单体单元作为必需组分。 环烯加成聚合物优选是基本上由具有芳环的降冰片烯单体单元组成的环烯加成聚合物。 环烯加成聚合物的耐热性优异，折射率高。 复合材料由环烯加成聚合物和无机材料组成。 模塑制品通过模制环烯加成聚合物或复合材料而获得。