PROCESS FOR CONTINUOUS POLYMERIZATION OF OLEFIN MONOMERS IN A REACTOR
    7.
    发明申请
    PROCESS FOR CONTINUOUS POLYMERIZATION OF OLEFIN MONOMERS IN A REACTOR 有权
    烯烃单体在反应器中连续聚合的方法

    公开(公告)号:US20160297899A1

    公开(公告)日:2016-10-13

    申请号:US15100491

    申请日:2014-11-24

    IPC分类号: C08F10/06 C08F10/02

    摘要: The invention relates to a process for the continuous polymerization α-olefin monomers comprising: feeding the α-olefins to a vertically extended reactor for the continuous fluidized bed polymerization of α-olefin monomers, wherein the reactor comprises a distribution plate and an integral gas/liquid separator, withdrawing the polyolefin from the reactor, withdrawing fluids from the reactor, cooling the fluids to below their dew point, resulting in a bottom recycle stream, (5) introducing the bottom recycle stream, separating at least part of the liquid from the bottom recycle stream, feeding a liquid phase to an external pipe, adding a solid polymerization catalyst to the liquid phase in the external pipe and (9) feeding a slurry stream comprising the prepolymer and/or polymer into the reactor, wherein the prepolymer and/or polymer are present in the slurry stream in an amount of 0.01 to 99 wt % based on the total slurry stream upon introduction into the reactor.

    摘要翻译: 本发明涉及一种连续聚合α-烯烃单体的方法,包括:将α-烯烃进料到用于α-烯烃单体的连续流化床聚合的垂直延伸的反应器中,其中反应器包括分配板和整体气体/ 液体分离器,从反应器中取出聚烯烃,从反应器中取出流体,将流体冷却至低于其露点,导致底部循环流,(5)引入底部循环流,将至少部分液体从 将液相进料到外管,向外管中的液相中加入固体聚合催化剂,和(9)将包含预聚物和/或聚合物的浆料流进料到反应器中,其中预聚物和/ 或聚合物在引入反应器中时基于总浆液流量以0.01至99重量%的量存在于浆料流中。