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公开(公告)号：US20090312506A1
公开(公告)日：2009-12-17
申请号：US12489816
申请日：2009-06-23
申请人： Kevin J. Cann , Minghui Zhang , Jose Fernando Cevallos-Candau , John H. Moorhouse , Mark G. Goode , Daniel P. Zilker, JR. , Maria Apecetche
发明人： Kevin J. Cann , Minghui Zhang , Jose Fernando Cevallos-Candau , John H. Moorhouse , Mark G. Goode , Daniel P. Zilker, JR. , Maria Apecetche
CPC分类号： C08F10/00 , B01J21/08 , B01J31/0212 , B01J31/122 , B01J31/128 , B01J31/143 , B01J31/34 , B01J35/1019 , B01J35/1023 , B01J35/1047 , C08F110/02 , C08F210/16 , Y02P20/52 , Y10S526/901 , C08F4/69 , C08F2500/12 , C08F2500/18 , C08F2500/04 , C08F2500/10 , C08F210/14 , C08F4/025
摘要： The present invention is directed to the use of aluminum alkyl activators and co-catalysts to improve the performance of chromium-based catalysts. The aluminum alkyls allow for the variable control of polymer molecular weight, control of side branching while possessing desirable productivities, and may be applied to the catalyst directly or separately to the reactor. Adding the alkyl aluminum compound directly to the reactor (in-situ) eliminates induction times.
摘要翻译： 本发明涉及使用烷基铝活化剂和助催化剂来改进铬基催化剂的性能。 烷基铝允许聚合物分子量的可变控制，侧分枝的控制，同时具有所需的生产率，并且可以直接或分别地施加到催化剂到反应器。 将烷基铝化合物直接加入反应器（原位）消除了诱导时间。
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2.发明授权公开(公告)号：US08835582B2
公开(公告)日：2014-09-16
申请号：US13576908
申请日：2011-02-18
申请人： Kevin J. Cann , C. Jeff Harlan , Wesley R. Mariott , Lixin Sun , Daniel P. Zilker, Jr. , F. David Hussein , Phuong A. Cao , John H. Moorhouse , Mark G. Goode
发明人： Kevin J. Cann , C. Jeff Harlan , Wesley R. Mariott , Lixin Sun , Daniel P. Zilker, Jr. , F. David Hussein , Phuong A. Cao , John H. Moorhouse , Mark G. Goode
CPC分类号： C08F10/02 , C08F4/65912 , C08F4/65925 , C08F210/16 , C08F4/65916 , C08F4/02 , C08F4/64148 , C08F210/14 , C08F2500/12 , C08F2500/18 , C08F2500/24
摘要： Catalyst systems and methods for making and using the same. The catalyst system can include a single site catalyst compound, a support comprising fluorinated alumina, and an aluminoxane. The aluminoxane can be present in an amount of about 10 mmol or less per gram of the support.
摘要翻译： 催化剂体系及其制造和使用方法。 催化剂体系可以包括单中心催化剂化合物，包含氟化氧化铝的载体和铝氧烷。 铝氧烷可以以每克载体约10mmol或更少的量存在。
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3.发明申请公开(公告)号：US20130035463A1
公开(公告)日：2013-02-07
申请号：US13576908
申请日：2011-02-18
申请人： Kevin J. Cann , C. Jeff Harlan , Wesley R. Mariott , Lixin Sun , Daniel P. Zilker, JR. , F. David Hussein , Phuong A. Cao , John H. Moorhouse , Mark G. Goode
发明人： Kevin J. Cann , C. Jeff Harlan , Wesley R. Mariott , Lixin Sun , Daniel P. Zilker, JR. , F. David Hussein , Phuong A. Cao , John H. Moorhouse , Mark G. Goode
CPC分类号： C08F10/02 , C08F4/65912 , C08F4/65925 , C08F210/16 , C08F4/65916 , C08F4/02 , C08F4/64148 , C08F210/14 , C08F2500/12 , C08F2500/18 , C08F2500/24
摘要： Catalyst systems and methods for making and using the same. The catalyst system can include a single site catalyst compound, a support comprising fluorinated alumina, and an aluminoxane. The aluminoxane can be present in an amount of about 10 mmol or less per gram of the support.
摘要翻译： 催化剂体系及其制造和使用方法。 催化剂体系可以包括单中心催化剂化合物，包含氟化氧化铝的载体和铝氧烷。 铝氧烷可以以每克载体约10mmol或更少的量存在。
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公开(公告)号：US08129484B2
公开(公告)日：2012-03-06
申请号：US11988712
申请日：2006-07-21
申请人： Kevin J. Cann , Ronald S. Eisinger , Mark G. Goode , John H. Moorhouse , Cliff R. Mure , Stephen P. Jaker , Maria A. Apecetche
发明人： Kevin J. Cann , Ronald S. Eisinger , Mark G. Goode , John H. Moorhouse , Cliff R. Mure , Stephen P. Jaker , Maria A. Apecetche
CPC分类号： C08F210/16 , C08F2/34 , C08F4/24 , C08F210/14 , C08F2500/14 , C08F2500/13 , C08F2500/12 , C08F2500/04 , C08F210/08
摘要： Disclosed herein are various processes, including continuous fluidized-bed gas-phase polymerization processes for making a high strength, high density polyethylene copolymer, comprising (including): contacting monomers that include ethylene and optionally at least one non-ethylene monomer with fluidized catalyst particles in a gas phase in the presence of hydrogen gas at an ethylene partial pressure of 100 psi or more and a polymerization temperature of 120° C. or less to produce a polyethylene copolymer having a density of 0.945 g/cc or more and an ESCR Index of 1.0 or more wherein the catalyst particles are prepared at an activation temperature of 700° C. or less, and include silica, chromium, and titanium.
摘要翻译： 本文公开了各种方法，包括用于制备高强度，高密度聚乙烯共聚物的连续流化床气相聚合方法，包括（包括）：使包含乙烯和任选的至少一种非乙烯单体的单体与流化催化剂颗粒接触 在气相中，在乙烯分压为100psi以上，聚合温度为120℃以下的氢气存在下，制成密度为0.945g / cc以上的聚乙烯共聚物，ESCR指数 为1.0以上，其中催化剂颗粒在700℃或更低的活化温度下制备，并且包括二氧化硅，铬和钛。
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公开(公告)号：US20100291334A1
公开(公告)日：2010-11-18
申请号：US12782453
申请日：2010-05-18
CPC分类号： C08F10/00 , B01J21/08 , B01J23/26 , B01J31/0212 , B01J31/143 , B01J31/34 , B01J35/1019 , B01J35/1023 , B01J35/1047 , C08F110/02 , C08F210/16 , Y10T428/139 , C08F4/69 , C08F2500/12 , C08F2500/18 , C08F2500/04 , C08F2500/10 , C08F210/14
摘要： Disclosed herein is a polyolefin polymer having improved properties wherein the polymer is produced using a chromium based catalyst in combination with aluminum alkyl activators and co-catalysts. Also disclosed is a pipe comprising the inventive polymer and a film comprising the inventive polymer, each having improved properties over those known in the art.
摘要翻译： 本文公开了具有改进性能的聚烯烃聚合物，其中使用基于铬的催化剂与烷基铝活化剂和助催化剂组合制备聚合物。 还公开了包含本发明聚合物的管和包含本发明聚合物的膜，其各自具有比本领域已知的那些更好的性能。
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6.发明授权公开(公告)号：US09303103B2
公开(公告)日：2016-04-05
申请号：US12919979
申请日：2008-12-10
IPC分类号： B01J21/00 , B01J23/00 , C08F4/24 , C08F4/52 , C08F4/12 , C08F110/02 , C08F10/00 , C08F210/16
CPC分类号： C08F10/00 , C08F210/16 , Y10T29/49345 , C08F4/025 , C08F4/24 , C08F4/69 , C08F210/14 , C08F2500/18 , C08F2500/12 , C08F2500/24
摘要： Embodiments disclosed herein generally relate to olefin polymerization catalysts, and more specifically to chromium-based catalysts and methods of use of chromium-based catalysts for the production of polyolefins, and even more specifically to methods for controlling or tailoring the flow index response of chromium-based catalysts through the controlled addition of a reducing agent to the catalysts under controlled mixing conditions.
摘要翻译： 本文公开的实施方案通常涉及烯烃聚合催化剂，更具体地涉及铬基催化剂和用于生产聚烯烃的铬基催化剂的方法，甚至更具体地涉及用于控制或定制铬 - 通过在受控的混合条件下将还原剂控制加入到催化剂中。
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7.发明申请公开(公告)号：US20110010938A1
公开(公告)日：2011-01-20
申请号：US12919979
申请日：2008-12-10
IPC分类号： B21D51/16
CPC分类号： C08F10/00 , C08F210/16 , Y10T29/49345 , C08F4/025 , C08F4/24 , C08F4/69 , C08F210/14 , C08F2500/18 , C08F2500/12 , C08F2500/24
摘要： Embodiments disclosed herein generally relate to olefin polymerization catalysts, and more specifically to chromium-based catalysts and methods of use of chromium-based catalysts for the production of polyolefins, and even more specifically to methods for controlling or tailoring the flow index response of chromium-based catalysts through the controlled addition of a reducing agent to the catalysts under controlled mixing conditions.
摘要翻译： 本文公开的实施方案通常涉及烯烃聚合催化剂，更具体地涉及铬基催化剂和用于生产聚烯烃的铬基催化剂的方法，甚至更具体地涉及用于控制或定制铬 - 通过在受控的混合条件下将还原剂控制加入到催化剂中。
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公开(公告)号：US20110237763A1
公开(公告)日：2011-09-29
申请号：US13128160
申请日：2009-12-17
申请人： Mark G. Goode , Maria Pollard , Kevin J. Cann , Ronald S. Eisinger , Barbara J. Kopp , John H. Moorhouse
发明人： Mark G. Goode , Maria Pollard , Kevin J. Cann , Ronald S. Eisinger , Barbara J. Kopp , John H. Moorhouse
CPC分类号： C08F10/00 , C08F210/16 , Y10S526/905 , C08F4/24 , C08F4/78 , C08F2/34 , C08F2500/12
摘要： Disclosed herein are various methods and systems for gas and liquid phase polymer production. In certain embodiments, the methods comprise manipulating properties of polymers produced by adjusting the hydrogen feed rate.
摘要翻译： 本文公开了用于气相和液相聚合物生产的各种方法和系统。 在某些实施方案中，所述方法包括操纵通过调节氢气进料速率产生的聚合物的性质。
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公开(公告)号：US20140179882A9
公开(公告)日：2014-06-26
申请号：US13127937
申请日：2009-12-11
CPC分类号： C08F210/16 , C08F4/69 , C08F2/34 , C08F210/14 , C08F2500/12 , C08F2500/07
摘要： The present invention is broadly directed to various methods and systems for gas and liquid phase polymer production. In certain embodiments, the methods are performed in conjunction with a polymerization reactor system such as gas phase reactor system or liquid phase reactor system. The invention is also broadly directed to various systems in which polymer properties are manipulated by addition of DEALE directly to a polymerization reactor system.
摘要翻译： 本发明广泛地涉及用于气相和液相聚合物生产的各种方法和系统。 在某些实施方案中，该方法与聚合反应器系统如气相反应器系统或液相反应器系统一起进行。 本发明还广泛地涉及通过将DEALE直接加入聚合反应器系统来操作聚合物性质的各种体系。
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公开(公告)号：US08101691B2
公开(公告)日：2012-01-24
申请号：US13128160
申请日：2009-12-17
申请人： Mark G. Goode , Maria Pollard , Kevin J. Cann , Ronald S. Eisinger , Barbara J. Kopp , John H. Moorhouse
发明人： Mark G. Goode , Maria Pollard , Kevin J. Cann , Ronald S. Eisinger , Barbara J. Kopp , John H. Moorhouse
CPC分类号： C08F10/00 , C08F210/16 , Y10S526/905 , C08F4/24 , C08F4/78 , C08F2/34 , C08F2500/12
摘要： Disclosed herein are various methods and systems for gas and liquid phase polymer production. In certain embodiments, the methods comprise manipulating properties of polymers produced by adjusting the hydrogen feed rate.
摘要翻译： 本文公开了用于气相和液相聚合物生产的各种方法和系统。 在某些实施方案中，所述方法包括操纵通过调节氢气进料速率产生的聚合物的性质。
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