公开(公告)号：US07521504B2

公开(公告)日：2009-04-21

申请号：US12002841

申请日：2007-12-19

申请人： Alan J. Russell ,  Geraldine F. Drevon ,  Douglas A. Wicks ,  Karsten Danielmeier

发明人： Alan J. Russell ,  Geraldine F. Drevon ,  Douglas A. Wicks ,  Karsten Danielmeier

IPC分类号： C08G18/00 ,  B05D3/00

CPC分类号： C12N11/08 ,  C08G18/0866 ,  C08G18/3278 ,  C08G18/42 ,  C08G18/6446 ,  C08G18/706 ,  C08G18/798 ,  C09D175/04 ,  C12N11/04

摘要： A method of irreversibly immobilizing an enzyme in a polyurethane and an enzyme-containing polyurethane having a degree of immobilization of the enzyme of approximately 100%. The synthesis of waterborne polyurethanes in the presence of enzyme has enabled the irreversible attachment of the enzyme to the polymeric matrix. The distribution of immobilized enzyme as well as activity retention are homogeneous within the polyurethane. Decreasing ECC hydrophobicity, via the use of a less hydrophobic polyisocyanate prepolymer during polymerization, significantly enhanced the intrinsic activity of the ECC.

摘要翻译： 一种不可逆地将酶固定在聚氨酯中的方法和具有约100％酶固定度的含酶聚氨酯。 在存在酶的情况下水性聚氨酯的合成使得酶不可逆连接到聚合物基质上。 固定化酶的分布以及活性保留在聚氨酯中是均匀的。 通过在聚合过程中通过使用较少疏水性的多异氰酸酯预聚物来降低ECC疏水性，显着提高了ECC的内在活性。

公开(公告)号：US06998459B2

公开(公告)日：2006-02-14

申请号：US10690931

申请日：2003-10-22

申请人： Richard R. Roesler ,  Derek L. Crawford ,  Kurt C. Frisch ,  Dinesh Pethiyagoda ,  Karsten Danielmeier

发明人： Richard R. Roesler ,  Derek L. Crawford ,  Kurt C. Frisch ,  Dinesh Pethiyagoda ,  Karsten Danielmeier

IPC分类号： C08G77/26

CPC分类号： C09J175/08 ,  C08G18/0885 ,  C08G18/10 ,  C08G18/283 ,  C08G18/289 ,  C08G18/3821 ,  C08G18/4825 ,  C08G18/718 ,  C08G18/755 ,  C08G18/778 ,  C08G2190/00

摘要： The present invention relates to a polyether urethane containing one reactive silane group and one or more polyether segments having a number average molecular weight of 1000 to 15,000, wherein the reactive silane groups are incorporated by the reaction of an isocyanate group with a compound corresponding to the formula wherein X represents identical or different organic groups which are inert to isocyanate groups below 100° C., provided that at least two of these groups are alkoxy or acyloxy groups, Y represents a linear or branched alkylene group containing 1 to 8 carbon atoms and R1 represents an organic group which is inert to isocyanate groups at a temperature of 100° C. or less.

摘要翻译： 本发明涉及含有一个反应性硅烷基团和一个或多个数均分子量为1000至15,000的聚醚链段的聚醚型聚氨酯，其中反应性硅烷基团通过异氰酸酯基团与对应于 形成

公开(公告)号：US20060011295A1

公开(公告)日：2006-01-19

申请号：US10890873

申请日：2004-07-14

申请人： Karsten Danielmeier ,  Douglas Wicks ,  Karen Henderson ,  Evan Minnich ,  John McLafferty ,  Stephanie Strazisar ,  Kurt Frisch

发明人： Karsten Danielmeier ,  Douglas Wicks ,  Karen Henderson ,  Evan Minnich ,  John McLafferty ,  Stephanie Strazisar ,  Kurt Frisch

IPC分类号： C07C229/34

CPC分类号： C08G18/341 ,  C07C229/24 ,  C08G18/3821 ,  C08G18/6651 ,  C08G18/6685 ,  C08G18/792 ,  Y10T428/31547

摘要： A functional aspartate prepared by A) reacting an aziridine with a Michael-acceptor molecule to form an aziridinyl aspartate, and B) reacting the aziridinyl aspartate with an active hydrogen containing compound to form the functional aspartate. The functional aspartate can be used in adhesive, sealant or coating compositions that also include an isocyanate functional material. The composition can be used in a method of bonding a first substrate to a second substrate that includes applying a coating of the above-identified adhesive composition to at least one surface of the first substrate or the second substrate, and contacting a surface of the first substrate with a surface of the second substrate, where at least on of the contacting surfaces has the coating applied thereto. The composition can also be used to coat substrates.

摘要翻译： 通过A）将氮丙啶与迈克尔受体分子反应以形成天冬氨酸吖丙酯反应制备的功能性天冬氨酸，和B）将天冬氨酸吖丙酯与含活性氢化合物反应以形成功能性天冬氨酸。 功能性天冬氨酸可用于还包括异氰酸酯官能材料的粘合剂，密封剂或涂料组合物。 该组合物可用于将第一基底粘合到第二基底上的方法，该方法包括将上述粘合剂组合物的涂层施加到第一基底或第二基底的至少一个表面，并使第一基底 衬底，其具有第二衬底的表面，其中至少在接触表面上施加有涂层。 该组合物也可用于涂覆底物。

公开(公告)号：US06384175B1

公开(公告)日：2002-05-07

申请号：US09785091

申请日：2001-02-15

申请人： Karsten Danielmeier ,  Hans-Josef Lass ,  Martin Brahm ,  Raul Pires ,  Karl-Ludwig Noble ,  Robert Reyer ,  Burkhard Blümel

发明人： Karsten Danielmeier ,  Hans-Josef Lass ,  Martin Brahm ,  Raul Pires ,  Karl-Ludwig Noble ,  Robert Reyer ,  Burkhard Blümel

IPC分类号： C08G1875

CPC分类号： C08G18/281 ,  C08G18/706 ,  C09D175/04

摘要： The invention relates to water-dispersible polyisocyanate mixtures which is the reaction product of A) a lacquer polyisocyanate having a uretdione, isocyanurate, allophanate, biuret, iminooxadiazinedione and/or oxadiazinetrione group and prepared from monomeric diisocyanates and B) a polyalkylene oxide polyether containing at least one carboxylic acid group, wherein the polyalkylene oxide polyether is linked to the lacquer polyisocyanate through a reaction between an isocyanate group and a carboxylic acid group to form an acylated urea group or an amide bond. The invention further relates to a process for their preparation and their use as a starting component in the preparation of polyurethane plastics, in particular as crosslinking agents for water-soluble or -dispersible lacquer binders or binder components with isocyanate-reactive groups.

摘要翻译： 本发明涉及水分散性多异氰酸酯混合物，其是A）具有脲二酮，异氰脲酸酯，脲基甲酸酯，缩二脲，亚氨基恶二嗪二酮和/或恶二嗪二酮基团的漆多异氰酸酯的反应产物，并由单体二异氰酸酯制备，和B）含有至少一种 羧酸基，其中聚环氧烷聚醚通过异氰酸酯基和羧酸基团之间的反应连接到漆多异氰酸酯上以形成酰化脲基或酰胺键。 本发明还涉及其制备方法及其作为制备聚氨酯塑料的起始组分的用途，特别是作为用于水溶性或分散性漆结合剂或具有异氰酸酯反应性基团的粘合剂组分的交联剂。

公开(公告)号：US20050159560A1

公开(公告)日：2005-07-21

申请号：US10761643

申请日：2004-01-21

申请人： Karsten Danielmeier ,  Charles Gambino ,  Rolf Gertzmann ,  Richard Roesler ,  Terrell Wayt ,  Michele Vargo ,  Edward Squiller ,  Karen Henderson

发明人： Karsten Danielmeier ,  Charles Gambino ,  Rolf Gertzmann ,  Richard Roesler ,  Terrell Wayt ,  Michele Vargo ,  Edward Squiller ,  Karen Henderson

IPC分类号： C07D207/40 ,  C07D207/416 ,  C08G18/00 ,  C08G18/38 ,  C08G18/79 ,  C09D175/04 ,  C08G63/02 ,  C08G69/26

CPC分类号： C07D207/416 ,  C08G18/3821 ,  C08G18/792 ,  C09D175/04

摘要： The present invention relates to novel aspartates, their method of production and the use of these aspartates as reactive components for polyisocyanates in two-component polyurethane coating compositions and for preparing polyurethane prepolymers. The aspartates are prepared by first reacting a di- or polyamine with an unsaturated ester and then reacting the resultant product with a maleimide.

摘要翻译： 本发明涉及新型天冬氨酸盐，其制备方法和这些天冬氨酸盐作为双组分聚氨酯涂料组合物中多异氰酸酯的反应性组分和用于制备聚氨酯预聚物的用途。 天冬氨酸酯通过首先使二胺或多胺与不饱和酯反应，然后使所得产物与马来酰亚胺反应来制备。

公开(公告)号：US20050075476A1

公开(公告)日：2005-04-07

申请号：US10678491

申请日：2003-10-03

申请人： Richard Roesler ,  Douglas Wicks ,  Terrell Wayt ,  Brian Long ,  Karsten Danielmeier ,  Charles Gambino

发明人： Richard Roesler ,  Douglas Wicks ,  Terrell Wayt ,  Brian Long ,  Karsten Danielmeier ,  Charles Gambino

IPC分类号： C07C233/00 ,  C07C235/10 ,  C07C269/04 ,  C07C271/00 ,  C07C271/20 ,  C07C271/24 ,  C08G18/38 ,  C08G18/79 ,  C08G69/02 ,  C09D175/02 ,  C08G18/00 ,  C08G2/00

CPC分类号： C07C235/10 ,  C07C271/20 ,  C07C271/24 ,  C07C2601/14 ,  C08G18/3821 ,  C08G18/792 ,  C09D175/02

摘要： The present invention relates to novel aspartates, their method of produciotn and the use of these mono and polyaspartates as reactive components for polyisocyanates in two-component polyurethane coating compositions and for preparing polyurethane prepolymers.

公开(公告)号：US06833423B2

公开(公告)日：2004-12-21

申请号：US10690954

申请日：2003-10-22

申请人： Richard R. Roesler ,  Derek L. Crawford ,  Kurt C. Frisch ,  Dinesh Pethiyagoda ,  Karsten Danielmeier

发明人： Richard R. Roesler ,  Derek L. Crawford ,  Kurt C. Frisch ,  Dinesh Pethiyagoda ,  Karsten Danielmeier

IPC分类号： C08G7724

CPC分类号： C08G18/3893 ,  C08G18/0885 ,  C08G18/10 ,  C08G18/283 ,  C08G18/3821 ,  C08G18/4866 ,  C08G18/718 ,  C08G2190/00 ,  C09J175/04 ,  C09K3/1021 ,  C08G18/289

摘要： A moisture curable, alkoxysilane-functional polyether urethanes containing a) 20 to 90% by weight, of a polyether urethane containing two or more reactive silane groups and polyether segments having a number average molecular weight (Mn) of at least 3000 and a degree of unsaturation of less than 0.04 milliequivalents/g, where the sum of Mn of the polyether segments averages 6000 to 20,000, and the reactive silane groups are incorporated by reaction of an isocyanate-reactive group with a compound of formula OCN—Y—Si—(X)3  (I) b) 10 to 80% by weight, of a polyether urethane containing one reactive silane group and one or more polyether segments having Mn of 1000 to 15,000, where the reactive silane groups are incorporated by the reaction of an isocyanate group with a compound of formula

摘要翻译： 含有a）20〜90重量％的含有两个以上反应性硅烷基团的聚醚型聚氨酯和数均分子量（Mn）为3000以上且不饱和度的聚醚链段的湿气固化型烷氧基硅烷官能团聚氨酯 小于0.04毫当量/克，其中聚醚片段的Mn的平均值为6000至20,000，并且反应性硅烷基团通过异氰酸酯反应性基团与公式的化合物的反应引入）10至80重量％ 含有一个反应性硅烷基团和一个或多个Mn为1000至15,000的聚醚链段的聚醚型聚氨酯，其中反应性硅烷基团通过异氰酸酯基与式

公开(公告)号：US06774206B2

公开(公告)日：2004-08-10

申请号：US10255388

申请日：2002-09-26

申请人： Karsten Danielmeier ,  Catherine M. Britsch ,  Rolf Gertzmann ,  Michele E. Vargo ,  Terrell D. Wayt ,  Edward P. Squiller

发明人： Karsten Danielmeier ,  Catherine M. Britsch ,  Rolf Gertzmann ,  Michele E. Vargo ,  Terrell D. Wayt ,  Edward P. Squiller

IPC分类号： C08G7300

CPC分类号： C07C229/24 ,  C08G18/3821 ,  C08G18/792

摘要： The present invention relates to polyaspartates corresponding to the formula wherein X1 represents the residue obtained by removing the amino groups from a polyether polyamine having a functionality of n and a number average molecular weight of less than 600, wherein the amino groups are attached to primary carbon atoms and the ether groups are separated by at least two carbon atoms, R1 and R2 are identical or different and represent organic groups which are inert to isocyanate groups at a temperature of 100° C. or less, R3 and R4 are identical or different and represent hydrogen or organic groups which are inert towards isocyanate groups at a temperature of 100° C. or less and n is 2 to 4. The present invention also relates to polyureas prepared by reacting the polyaspartates and optionally other isocyanate-reactive compounds with polyisocyanates.

摘要翻译： 本发明涉及对应于制备方法的聚天冬氨酸X 1表示通过从官能度为n且数均分子量小于600的聚醚多胺除去氨基而获得的残基，其中氨基与伯碳原子连接， 醚基通过至少两个碳原子分开，R 1和R 2相同或不同，表示在100℃或更低的温度下对异氰酸酯基团呈惰性的有机基团，R 3和R 4相同或不同，表示氢 或在100℃或更低的温度下对异氰酸酯基团呈惰性的有机基团，并且为2至4.本发明还涉及通过聚天冬氨酸酯和任选的其它异氰酸酯反应性化合物与多异氰酸酯反应制备的聚脲。

公开(公告)号：US06222066B1

公开(公告)日：2001-04-24

申请号：US09532259

申请日：2000-03-22

申请人： Karsten Danielmeier ,  Harald Leps ,  Dieter Mager ,  Reinhard Halpaap ,  Martin Brahm ,  Reinhold Klipper ,  Andreas Hauner

发明人： Karsten Danielmeier ,  Harald Leps ,  Dieter Mager ,  Reinhard Halpaap ,  Martin Brahm ,  Reinhold Klipper ,  Andreas Hauner

IPC分类号： C07C24900

CPC分类号： C07C263/20 ,  C07C265/14

摘要： A process for the purification of organic isocyanates or isocyanate mixtures in which the amount of chlorine compound(s) present is reduced by mixing the isocyanate(s) or isocyanate mixtures with a gel-type or macroporous, anion-exchanging organic material having tertiary and/or quaternary amino groups. The process renders possible a purification of the isocyanates from chlorine-containing compounds which is milder than in conventional processes and is therefore particularly suitable for temperature-sensitive isocyanates.

摘要翻译： 有机异氰酸酯或异氰酸酯混合物的纯化方法，其中存在的氯化合物的量通过将异氰酸酯或异氰酸酯混合物与凝胶型或大孔阴离子交换有机材料混合而降低，所述有机异氰酸酯或异氰酸酯混合物具有叔和 /或季氨基。 该方法可以从含氯化合物中纯化异氰酸酯，其比常规方法温和，因此特别适用于温度敏感的异氰酸酯。

公开(公告)号：US20090142601A1

公开(公告)日：2009-06-04

申请号：US12354036

申请日：2009-01-15

申请人： Karsten Danielmeier ,  Douglas A. Wicks ,  Karen Marie Henderson ,  Evan Randall Minnich ,  John J. McLafferty ,  Stephanie A. Strazisar ,  Kurt C. Frisch, JR.

发明人： Karsten Danielmeier ,  Douglas A. Wicks ,  Karen Marie Henderson ,  Evan Randall Minnich ,  John J. McLafferty ,  Stephanie A. Strazisar ,  Kurt C. Frisch, JR.

IPC分类号： B32B27/40 ,  C08L75/04 ,  C08L67/00 ,  C09J4/00

CPC分类号： C08G18/341 ,  C07C229/24 ,  C08G18/3821 ,  C08G18/6651 ,  C08G18/6685 ,  C08G18/792 ,  Y10T428/31547

摘要： A functional aspartate prepared by A) reacting an aziridine with a Michael-acceptor molecule to form an aziridinyl aspartate, and B) reacting the aziridinyl aspartate with an active hydrogen containing compound to form the functional aspartate. The functional aspartate can be used in adhesive, sealant or coating compositions that also include an isocyanate functional material. The composition can be used in a method of bonding a first substrate to a second substrate that includes applying a coating of the above-identified adhesive composition to at least one surface of the first substrate or the second substrate, and contacting a surface of the first substrate with a surface of the second substrate, where at least on of the contacting surfaces has the coating applied thereto. The composition can also be used to coat substrates.

摘要翻译： 通过A）将氮丙啶与迈克尔受体分子反应以形成天冬氨酸吖丙酯反应制备的功能性天冬氨酸，和B）将天冬氨酸吖丙酯与含活性氢化合物反应以形成功能性天冬氨酸。 功能性天冬氨酸可用于还包括异氰酸酯官能材料的粘合剂，密封剂或涂料组合物。 该组合物可用于将第一基底粘合到第二基底上的方法，该方法包括将上述粘合剂组合物的涂层施加到第一基底或第二基底的至少一个表面，并使第一基底 衬底，其具有第二衬底的表面，其中至少在接触表面上施加有涂层。 该组合物也可用于涂覆底物。