公开(公告)号：US20080300381A1

公开(公告)日：2008-12-04

申请号：US11664281

申请日：2004-09-30

Applicant: Hidenori Uchi ,  Kenji Tamamitsu ,  Shunzo Suematsu ,  Satoru Tsumeda ,  Alexander M. Timonov ,  Sergey A. Logvinov ,  Nikolay Shkolnik ,  Sam Kogan

Inventor： Hidenori Uchi ,  Kenji Tamamitsu ,  Shunzo Suematsu ,  Satoru Tsumeda ,  Alexander M. Timonov ,  Sergey A. Logvinov ,  Nikolay Shkolnik ,  Sam Kogan

IPC: C08G79/00

CPC classification number: H01M4/60 ,  H01G9/155 ,  H01M4/0452 ,  H01M4/0466 ,  H01M4/137 ,  H01M4/602 ,  H01M10/0525 ,  H01M2004/028 ,  Y02E60/13

Abstract: To provide an electrode material excellent in output characteristics and cycle property and an electrochemical device using the electrode material. The electrode material comprising polymer complex compound represented by the following graphical formula: and the electrochemical device using the electrode material. Even if such a large size ion is employed, enhanced output characteristics could be obtained in the present invention. Polymer complex compound is polarized due to an electron attracting substituent, or steric hindrance occurs due to a substituent having a branch structure so that interval of polymer complex compound formed on the electrode is increased and doping reaction. Therefore, even if using large size ions smooth and rapid doping and undoping reaction could take place.

Abstract translation: 提供输出特性和循环特性优异的电极材料和使用电极材料的电化学装置。 该电极材料包含由以下图示式表示的聚合物复合化合物：和使用电极材料的电化学装置。 即使采用这样大的离子，本发明也可以得到增强的输出特性。 聚合物复合化合物由于吸电子取代基而极化，或者由于具有分支结构的取代基而发生空间位阻，使得在电极上形成的聚合物络合物的间隔增加和掺杂反应。 因此，即使使用大尺寸离子，也可以进行平滑，快速的掺杂和非掺杂反应。

公开(公告)号：US07292431B2

公开(公告)日：2007-11-06

申请号：US11098698

申请日：2005-04-04

Applicant: Alexander Mikhailovich Timonov ,  Sergey Anatolijevich Logvinov ,  Dmitriy Ivanovich Pivunov ,  Svetlana Viktorovna Vasiljeva ,  Nik Shkolnik ,  Sam Kogan

Inventor： Alexander Mikhailovich Timonov ,  Sergey Anatolijevich Logvinov ,  Dmitriy Ivanovich Pivunov ,  Svetlana Viktorovna Vasiljeva ,  Nik Shkolnik ,  Sam Kogan

IPC: H01G9/00

CPC classification number: H01M4/602 ,  H01G9/042 ,  H01G9/22 ,  H01G11/02 ,  H01G11/26 ,  H01G11/32 ,  H01G11/48 ,  Y02E60/13 ,  Y10T29/417

Abstract: The invention is an electrochemical capacitor with its electrodes made on a conducting substrate with a layer of a redox polymer of the poly[Me(R-Salen)] type deposited onto the substrate. Me is a transition metal (for example, Ni, Pd, Co, Cu, Fe), R is an electron-donating substituent (for example, CH3O—, C2H5O—, HO—, —CH3), Salen is a residue of bis(salicylaldehyde)-ethylendiamine in Schiff's base. The electrolyte comprises of an organic solvent, compounds capable of dissolving in such solvents with the resulting concentration of no less than 0.01 mol/l and dissociating with the formation of ions, which are electrochemically inactive within the range of potentials from −3.0 V to +1.5 V (for example, salts of tetramethyl ammonium, tetrapropyl ammonium, tetrabutyl ammonium), and a dissolved metal complex [Me(R-Salen)]. The method of using the capacitor contemplates periodically alternating the connection polarity of the electrodes, causing the electrochemical characteristics of the electrodes to regenerate.

Abstract translation: 本发明是一种电化学电容器，其电极在导电衬底上制成，其上沉积有一层聚[Me（R-Salen）]型氧化还原聚合物。 Me是过渡金属（例如Ni，Pd，Co，Cu，Fe），R是给电子取代基（例如CH 3 O，C 2， H 2 O-，HO-，-CH 3 3），Salen是席夫碱中双（水杨醛） - 乙二胺的残基。 电解质包括有机溶剂，能够溶解在这样的溶剂中的化合物，所得到的浓度不低于0.01mol / l，并​​且在电位从-3.0V到+ 1.5V（例如，四甲基铵，四丙基铵，四丁基铵的盐）和溶解的金属络合物[Me（R-Salen）]。 使用电容器的方法考虑周期性地交替电极的连接极性，导致电极的电化学特性再生。

公开(公告)号：US20050217998A1

公开(公告)日：2005-10-06

申请号：US11088509

申请日：2005-03-24

Applicant: Alexander Timonov ,  Sergey Logvinov ,  Dmitriy Pivunov ,  Svetlana Vasiljeva ,  Nik Shkolnik ,  Sam Kogan

Inventor： Alexander Timonov ,  Sergey Logvinov ,  Dmitriy Pivunov ,  Svetlana Vasiljeva ,  Nik Shkolnik ,  Sam Kogan

IPC: H01G9/04 ,  H01G9/155 ,  H01M4/137 ,  H01M4/60 ,  H01M4/04

CPC classification number: H01M4/0438 ,  C08G12/06 ,  H01G9/0036 ,  H01G9/155 ,  H01M4/0452 ,  H01M4/0466 ,  H01M4/137 ,  H01M4/606 ,  Y02E60/13

Abstract: Application of a redox polymer of the poly-[Me(R-Salen)] type onto a conducting substrate is accomplished by the method of electrochemical polymerization. Said polymerization is accomplished by supplying a voltage between the substrate (that serves as an anode) and a counter electrode (that serves as a cathode), with both of them being submerged into the electrolyte containing an organic solvent and the compounds capable of dissolving in said solvent. The process is accompanied by the production of electrochemically inactive (at concentrations of no less than 0.01 mol/l) ions within the range of potentials from −3.0 V to +1.5 V, and metal complex [Me(R-Salen)] dissolved at a concentration of no less than 5·10−5 mol/l, (where: Me is a transition metal having at least two different degrees of oxidation, R is an electron-donating substituent, Salen is a residue of bis-(salicylaldehyde)-ethylenediamine in Schiff's base.

Abstract translation: 聚 - [Me（R-Salen）]型氧化还原聚合物在导电基材上的应用是通过电化学聚合的方法实现的。 所述聚合是通过在衬底（用作阳极）和对电极（用作阴极）之间提供电压来实现的，两者都被浸没在含有机溶剂的电解质中，并且能够溶解在 所述溶剂。 该过程伴随着在-3.0V至+1.5V的电位范围内产生电化学惰性的（浓度不小于0.01mol / l）的离子，并且溶解在金属络合物[Me（R-Salen） 浓度不低于5.10〜5mol / l，（其中：Me是具有至少两个不同氧化程度的过渡金属，R是给电子取代基，Salen是 双（水杨醛） - 乙二胺在希夫碱。

公开(公告)号：US07888229B2

公开(公告)日：2011-02-15

申请号：US11726985

申请日：2007-03-23

Applicant: Irina Chepurnaya ,  Alexander Timonov ,  Sergey Logvinov ,  Sam Kogan

Inventor： Irina Chepurnaya ,  Alexander Timonov ,  Sergey Logvinov ,  Sam Kogan

IPC: H01L21/20

CPC classification number: H01G9/155 ,  H01G9/038 ,  H01G9/058 ,  H01G9/15 ,  H01G11/02 ,  H01G11/24 ,  H01G11/26 ,  H01G11/58 ,  Y02E60/13 ,  Y10T29/417

Abstract: The present invention relates to methods of manufacturing an electrochemical energy storage device, such as a hybrid capacitor. The method comprises saturating a porous electrically conductive material in a solution comprising an organic solvent and a metal complex or a mixture of metal complexes; assembling a capacitor comprising the positive electrode made of porous electrically conductive material saturated with a metal complex, a negative electrode, and a separator in a casing; introducing the electrolyte solution into the casing; sealing the casing; and subsequent charge-discharge cycling of the capacitor. The charge-discharge cycling deposits a layer of an energy-accumulating redox polymer on the positive electrode. The electrolyte solution for filling the hybrid capacitor contains an organic solvent, a metal complex, and substances soluble to a concentration of no less than 0.01 mol/L and containing ions that are electrochemically inactive within the range of potentials between −3.0 V to +1.5 V.

Abstract translation: 本发明涉及电化学储能装置如混合电容器的制造方法。 该方法包括在包含有机溶剂和金属络合物或金属络合物的混合物的溶液中饱和多孔导电材料; 组装一个电容器，该电容器包括由壳体中的金属络合物，负极和隔板饱和的多孔导电材料制成的正电极; 将电解质溶液引入壳体中; 密封套管; 以及随后的电容器的充放电循环。 充电 - 放电循环在正电极上沉积一层能量聚集的氧化还原聚合物。 用于填充混合电容器的电解液包含有机溶剂，金属络合物和可溶于0.01mol / L浓度的物质，并且在-3.0V至+1.5之间的电势范围内含有电化学惰性的离子 五

公开(公告)号：US07563354B2

公开(公告)日：2009-07-21

申请号：US11088509

申请日：2005-03-24

Applicant: Alexander Mikhailovich Timonov ,  Sergey Anatolijevich Logvinov ,  Dmitriy Ivanovich Pivunov ,  Svetlana Viktorovna Vasiljeva ,  Nik Shkolnik ,  Sam Kogan

Inventor： Alexander Mikhailovich Timonov ,  Sergey Anatolijevich Logvinov ,  Dmitriy Ivanovich Pivunov ,  Svetlana Viktorovna Vasiljeva ,  Nik Shkolnik ,  Sam Kogan

IPC: C25D9/00

CPC classification number: H01M4/0438 ,  C08G12/06 ,  H01G9/0036 ,  H01G9/155 ,  H01M4/0452 ,  H01M4/0466 ,  H01M4/137 ,  H01M4/606 ,  Y02E60/13

Abstract: Application of a redox polymer of the poly-[Me(R-Salen)] type onto a conducting substrate is accomplished by the method of electrochemical polymerization. Said polymerization is accomplished by supplying a voltage between the substrate (that serves as an anode) and a counter electrode (that serves as a cathode), with both of them being submerged into the electrolyte containing an organic solvent and the compounds capable of dissolving in said solvent. The process is accompanied by the production of electrochemically inactive (at concentrations of no less than 0.01 mol/l) ions within the range of potentials from −3.0 V to +1.5 V, and metal complex [Me(R-Salen)] dissolved at a concentration of no less than 5-10−5 mol/l, (where: Me is a transition metal having at least two different degrees of oxidation, R is an electron-donating substituent, Salen is a residue of bis-(salicylaldehyde)-ethylenediamine in Schiff's base.

Abstract translation: 聚 - [Me（R-Salen）]型氧化还原聚合物在导电基材上的应用是通过电化学聚合的方法实现的。 所述聚合是通过在衬底（用作阳极）和对电极（用作阴极）之间提供电压来实现的，两者都被浸没在含有机溶剂的电解质中，并且能够溶解在 所述溶剂。 该过程伴随着在-3.0V至+1.5V的电位范围内产生电化学惰性的（浓度不小于0.01mol / l）的离子，并且溶解在金属络合物[Me（R-Salen） 浓度不小于5-10-5mol / l（其中：Me是具有至少两个不同氧化程度的过渡金属，R是给电子取代基，Salen是双 - （水杨醛）的残基， 乙二胺在希夫的基地。

公开(公告)号：US20050258042A1

公开(公告)日：2005-11-24

申请号：US11100036

申请日：2005-04-06

Applicant: Alexander Lyubomirskiy ,  Valeriy Pavlov ,  Alexander Timonov ,  Sergey Logvinov ,  Dmitriy Pivunov ,  Svetlana Vasiljeva ,  Nik Shkolnik ,  Sam Kogan

Inventor： Alexander Lyubomirskiy ,  Valeriy Pavlov ,  Alexander Timonov ,  Sergey Logvinov ,  Dmitriy Pivunov ,  Svetlana Vasiljeva ,  Nik Shkolnik ,  Sam Kogan

IPC: H01G9/00 ,  H01G9/04 ,  H01G9/058 ,  H01M4/137 ,  H01M4/60 ,  H01M4/66 ,  H01M4/04

CPC classification number: H01M4/137 ,  H01G9/0032 ,  H01G9/0036 ,  H01G9/04 ,  H01G11/48 ,  H01M4/0438 ,  H01M4/0466 ,  H01M4/60 ,  H01M4/66 ,  H01M4/663 ,  H01M4/667 ,  H01M4/668 ,  Y02E60/13

Abstract: Deposition of a redox polymer of the poly-Me(R-Salen) type onto a conducting substrate by electrochemical polymerization is disclosed. Said polymerization occurs at a voltage applied between the substrate and a counter-electrode, both of which are submerged into the electrolyte. The electrolyte contains an organic solvent, compounds capable of dissolving in the solvent and forming electrochemically inactive ions at concentrations of no less than 0.01 mol/l within the range of potentials from −3.0 V to +1.5 V, and a metal complex poly-[Me(R-Salen)] dissolved at a concentration of no less than 5×10−5 mole/liter. Me is transition metal having at least two different degrees of oxidation, R is an electron-donating substituent, Salen is a residue of bis(salicylaldehyde)-ethylenediamine in Schiff' s base). Deposition of the redox occurs in the electrolyte where the cations of the compounds have a diameter larger than that of the electrolyte cations of energy storing device containing the electrode.

Abstract translation: 公开了通过电化学聚合将poly-Me（R- Salen）型氧化还原聚合物沉积到导电基底上。 所述聚合发生在施加在基板和反电极之间的电压，两者都被浸没在电解质中。 电解质含有有机溶剂，能够溶解在溶剂中的化合物和在-3.0V至+1.5V的电位范围内以不低于0.01mol / l的浓度形成电化学惰性离子的化合物，以及金属络合物聚[ Me（R-Salen）]以不低于5×10 -5摩尔/升的浓度溶解。 Me是具有至少两个不同氧化程度的过渡金属，R是给电子取代基，Salen是Schiff碱中的双（水杨醛） - 乙二胺的残基）。 在电解质中发生氧化还原的沉积，其中化合物的阳离子的直径大于含有电极的储能装置的电解质阳离子的直径。

公开(公告)号：US20100188801A1

公开(公告)日：2010-07-29

申请号：US12752735

申请日：2010-04-01

Applicant: Alexander Lyubomirskiy ,  Valeriy Valentinovich Pavlov ,  Alexander Mikhailovich Timonov ,  Sergey Anatolijevich Logvinov ,  Dmitriy Ivanovich Pivunov ,  Svetlana Viktorovna Vasiljeva ,  Nik Shkolnik ,  Sam Kogan

Inventor： Alexander Lyubomirskiy ,  Valeriy Valentinovich Pavlov ,  Alexander Mikhailovich Timonov ,  Sergey Anatolijevich Logvinov ,  Dmitriy Ivanovich Pivunov ,  Svetlana Viktorovna Vasiljeva ,  Nik Shkolnik ,  Sam Kogan

IPC: H01G9/042 ,  C08F2/58 ,  B05D3/00 ,  H01G9/035

CPC classification number: H01M4/137 ,  H01G9/0032 ,  H01G9/0036 ,  H01G9/04 ,  H01G11/48 ,  H01M4/0438 ,  H01M4/0466 ,  H01M4/60 ,  H01M4/66 ,  H01M4/663 ,  H01M4/667 ,  H01M4/668 ,  Y02E60/13

Abstract: A method of preparing an energy-storage device is disclosed, which involves deposition of a redox polymer of the poly-Me(R-Salen) type onto a conducting substrate by electrochemical polymerization to prepare an electrode for use in the energy-storage device. Polymerization occurs at a voltage applied between the substrate and a counter-electrode, both of which are submerged in an electrolyte. The electrolyte contains an organic solvent, compounds capable of dissolving in the solvent and forming electrochemically inactive ions at concentrations of no less than 0.01 mol/L within the range of potentials from −3.0 V to +1.5 V, and a metal complex polymer represented by the formula poly-[Me(R-Salen)] dissolved at a concentration of no less than 5×10−5 mol/L, wherein Me is a transition metal having at least two different degrees of oxidation, R is an electron-donating substituent, and Salen is a residue of bis(salicylaldehyde)-ethylenediamine. Deposition of the redox polymer occurs in an electrolyte in which the cations have a diameter that is larger than the diameter of the cations of the electrolyte employed in the energy-storage device for which the electrode is manufactured.

Abstract translation: 公开了一种制备储能装置的方法，其包括通过电化学聚合将poly-Me（R- Salen）型氧化还原聚合物沉积到导电基底上，以制备用于储能装置的电极。 聚合发生在施加在基板和对电极之间的电压上，两者都被浸没在电解液中。 电解质含有有机溶剂，能够溶解在溶剂中的化合物，在-3.0V〜+1.5V的电位范围内，以不低于0.01mol / L的浓度形成电化学惰性离子的化合物，以及由 以不低于5×10 -5 mol / L的浓度溶解的聚[Me（R- Salen）]式，其中Me是具有至少两个不同氧化程度的过渡金属，R是给电子 取代基，Salen是双（水杨醛） - 乙二胺的残基。 氧化还原聚合物的沉积发生在其中阳离子的直径大于制造电极的储能装置中所用电解质的阳离子的直径的电解质中。

公开(公告)号：US20070234537A1

公开(公告)日：2007-10-11

申请号：US11726985

申请日：2007-03-23

Applicant: Irina Chepurnaya ,  Alexander Timonov ,  Sergey Logvinov ,  Sam Kogan

Inventor： Irina Chepurnaya ,  Alexander Timonov ,  Sergey Logvinov ,  Sam Kogan

IPC: H01G9/00

CPC classification number: H01G9/155 ,  H01G9/038 ,  H01G9/058 ,  H01G9/15 ,  H01G11/02 ,  H01G11/24 ,  H01G11/26 ,  H01G11/58 ,  Y02E60/13 ,  Y10T29/417

Abstract: The present invention relates to methods of manufacturing an electrochemical energy storage device, such as a hybrid capacitor. The method comprises saturating a porous electrically conductive material in a solution comprising an organic solvent and a metal complex or a mixture of metal complexes; assembling a capacitor comprising the positive electrode made of porous electrically conductive material saturated with a metal complex, a negative electrode, and a separator in a casing; introducing the electrolyte solution into the casing; sealing the casing; and subsequent charge-discharge cycling of the capacitor. The charge-discharge cycling deposits a layer of an energy-accumulating redox polymer on the positive electrode. The electrolyte solution for filling the hybrid capacitor contains an organic solvent, a metal complex, and substances soluble to a concentration of no less than 0.01 mol/L and containing ions that are electrochemically inactive within the range of potentials between −3.0 V to +1.5 V.

Abstract translation: 本发明涉及电化学储能装置如混合电容器的制造方法。 该方法包括在包含有机溶剂和金属络合物或金属络合物的混合物的溶液中饱和多孔导电材料; 组装一个电容器，该电容器包括由壳体中的金属络合物，负极和隔板饱和的多孔导电材料制成的正电极; 将电解质溶液引入壳体中; 密封套管; 以及随后的电容器的充放电循环。 充电 - 放电循环在正电极上沉积一层能量聚集的氧化还原聚合物。 用于填充混合电容器的电解液包含有机溶剂，金属络合物和可溶于0.01mol / L浓度的物质，并且在-3.0V至+1.5之间的电势范围内含有电化学惰性的离子 五

公开(公告)号：US20050225928A1

公开(公告)日：2005-10-13

申请号：US11098698

申请日：2005-04-04

Applicant: Alexander Timonov ,  Sergey Logvinov ,  Dmitriy Pivunov ,  Svetlana Vasiljeva ,  Nik Shkolnik ,  Sam Kogan

Inventor： Alexander Timonov ,  Sergey Logvinov ,  Dmitriy Pivunov ,  Svetlana Vasiljeva ,  Nik Shkolnik ,  Sam Kogan

IPC: H01G9/00 ,  H01G9/022 ,  H01G9/04 ,  H01G9/042 ,  H01G9/22 ,  H01M4/04 ,  H01M4/60

CPC classification number: H01M4/602 ,  H01G9/042 ,  H01G9/22 ,  H01G11/02 ,  H01G11/26 ,  H01G11/32 ,  H01G11/48 ,  Y02E60/13 ,  Y10T29/417

Abstract: The invention is an electrochemical capacitor with its electrodes made on a conducting substrate with a layer of a redox polymer of the poly[Me(R-Salen)] type deposited onto the substrate. Me is a transition metal (for example, Ni, Pd, Co, Cu, Fe), R is an electron-donating substituent (for example, CH3O—, C2H5O—, HO—, —CH3), Salen is a residue of bis(salicylaldehyde)-ethylendiamine in Schiff's base. The electrolyte comprises of an organic solvent, compounds capable of dissolving in such solvents with the resulting concentration of no less than 0.01 mol/l and dissociating with the formation of ions, which are electrochemically inactive within the range of potentials from −3.0 V to +1.5 V (for example, salts of tetramethyl ammonium, tetrapropyl ammonium, tetrabutyl ammonium), and a dissolved metal complex [Me(R-Salen)]. The method of using the capacitor contemplates periodically alternating the connection polarity of the electrodes, causing the electrochemical characteristics of the electrodes to regenerate.

Abstract translation: 本发明是一种电化学电容器，其电极在导电衬底上制成，其上沉积有一层聚[Me（R-Salen）]型氧化还原聚合物。 Me是过渡金属（例如Ni，Pd，Co，Cu，Fe），R是给电子取代基（例如CH 3 O，C 2， H 2 O-，HO-，-CH 3 3），Salen是席夫碱中双（水杨醛） - 乙二胺的残基。 电解质包括有机溶剂，能够溶解在这样的溶剂中的化合物，所得到的浓度不低于0.01mol / l，并​​且在电位从-3.0V到+ 1.5V（例如四甲基铵，四丙基铵，四丁基铵的盐）和溶解的金属络合物[Me（R-Salen）]。 使用电容器的方法考虑周期性地交替电极的连接极性，导致电极的电化学特性再生。

公开(公告)号：US06795293B2

公开(公告)日：2004-09-21

申请号：US10350167

申请日：2003-01-23

Applicant: Alexander Timonov ,  Sergey Logvinov ,  Nikolay Shkolnik ,  Sam Kogan

Inventor： Alexander Timonov ,  Sergey Logvinov ,  Nikolay Shkolnik ,  Sam Kogan

IPC: H01G4005

CPC classification number: H01M6/36 ,  H01G9/22 ,  H01G11/02 ,  H01G11/26 ,  H01G11/48 ,  H01M4/137 ,  H01M4/60 ,  H01M4/602 ,  H01M4/606 ,  Y02E60/13

Abstract: An energy storage device, such as a battery or supercapacitor, that includes at least two electrodes, at least one of the electrodes includes an electrically conducting substrate having a layer of energy accumulating redox polymer complex compound of transition metal having at least two different degrees of oxidation, which polymer complex compound is formed of stacked transition metal complex monomers. The stacked transition metal complex monomers have a planar structure with the deviation from the plane of no greater than 0.1 nm and a branched system of conjugated &pgr;-bonds. The polymer complex compound of transition metal can be formed as a polymer metal complex with substituted tetra-dentate Schiff's base. The layer thickness of redox polymer is within the range 1 nm-20 &mgr;m.

Abstract translation: 包括至少两个电极的能量存储装置，例如电池或超级电容器，至少一个电极包括导电基底，该导电基底具有积聚具有至少两个不同程度的过渡金属的氧化还原聚合物复合化合物的能量层 氧化，该聚合物络合物由堆叠的过渡金属络合物单体形成。 堆叠的过渡金属络合物单体具有平面结构，其平面偏离不大于0.1nm，并且具有共轭π-键的分支系统。 过渡金属的聚合物复合化合物可以形成为具有取代的四齿希夫碱的聚合物金属络合物。 氧化还原聚合物的层厚度在1nm〜20μm的范围内。