-
1.发明授权
公开(公告)号：US3876725A
公开(公告)日：1975-04-08
申请号：US46877174
申请日：1974-05-10
Applicant: ALLIED CHEM
Inventor： WELLS RODNEY LEE , CRESCENTINI LAMBERTO
Abstract: It has been suggested that antistatic properties of fibers of polyamide could be improved by uniformly dispersing in the polyamide between about 1 percent and about 12 percent by weight of a predominantly branched, chain-extended propylene oxideethylene oxide copolymer based on a diamine. However, with incorporation of this antistatic additive in the polyamide, serious problems have been encountered in melt-spinning due to the frequent occurrence of "nubs" or enlarged places in the extruded polyamide filament. It has now been found that the occurrence of said nubs in the antistatic polyamide fiber can be greatly reduced by dispersing in the polymer about 0.5 to 12 percent by weight, based on the weight of the antistatic agent, of a phenol compound represented by the formula:
where R is an alkyl hydrocarbon group containing less than nine carbon atoms and R.sub.1 is a tertiary alkyl group containing at least four but not more than 12 carbon atoms. In comparative tests with antistatic yarns containing various commercially available hindered phenol compounds, the yarns of the present invention showed significantly greater breaking strength retention after exposure to light in standard tests.-
2.发明授权Polyamides and polyesters containing isophthalate amides of dialkanoyl polyalkylene polyamines as antisoiling agents 失效含有作为抗菌剂的二烷基聚亚烷基多胺的异癸酸酯的聚酰胺和聚酯
公开(公告)号：US3594447A
公开(公告)日：1971-07-20
申请号：US3594447D
申请日：1968-10-31
Applicant: ALLIED CHEM
Inventor： WINCKLHOFER ROBERT C , CRESCENTINI LAMBERTO
Abstract: A FILAMENT, HAVING IMPROVED RESISTANCE TO SOILING, OF A SYNTHETIC POLYMER HAVING MIXED THERETHROUGH ABOUT 0.02 TO 5 WEIGHT PERCENT, BASED ON THE WEIGHT OF THE SYNTHETIC POLYMER, OF AN AMIDE HAVING THE GENERAL FORMULA;
BIS-((CH3-R-CO-NH-(CH2)X-)2-N-CO-(CH2)N-)BENZENE
WHEREIN THE HEXAGON REPRESENTS THE BENZENE NUCLEUS, R IS A DIVALENT RADICAL CONTAINING UP TO ABOUT 30, PREFERABLY ABOUT 3 TO 18, CARBON ATOMS WHICH CAN BE LINEAR OR BRANCHED ALIPHATIC, N IS AN INTEGER FROM 0 TO ABOUT 6 BUT PREFERABLY IS 0, X IS AN INTEGER FROM 1 TO ABOUT 6 BUT PREFERABLY IS ABOUT 2 TO 3, AND THE
-(CH2)N-CO-
RADICALS CONNECTED TO THE BENZENE NUCLEUS ARE RELATIVELY DISPOSED IN THE ORTHO, META, OR PARA POSITIONS BUT PREFERABLY IN THE META POSITION.-
公开(公告)号：US3859380A
公开(公告)日：1975-01-07
申请号：US44304874
申请日：1974-02-15
Applicant: ALLIED CHEM
Inventor： CRESCENTINI LAMBERTO , WELLS RODNEY LEE
CPC classification number: C08K5/1345 , C08L77/00 , D01F1/09 , Y10S524/905 , C08L2666/20
Abstract: IN WHICH X HAS A VALUE OF FROM 1 TO 6 AND Y HAS A VALUE OF FROM 6 TO 30; AND
IN WHICH A is
WHEREIN X'' HAS A VALUE FROM 1 TO 6 AND Y'' HAS A VALUE OF 1 TO 6.
WHERE R10 is a divalent radical having 1 to 20 carbon atoms derived from aliphatic, aromatic, cycloaliphatic, aromaticaliphatic, or heterocyclic hydrocarbons. However, with incorporation of this antistatic additive in the polyamide, serious problems have been encountered in melt-spinning due to the frequent occurrence of ''''nubs'''' or enlarged places in the extruded polyamide filament. It has now been found that the occurrence of said nubs in the antistatic polyamide fiber can be greatly reduced by dispersing in the polymer an additional small proportion of a hindered phenol represented by the formulas:
WHERE R6, R7, R8 and R9 are independently selected from R1, R2, R3, R4 or another monovalent hydrocarbon radical having 1 to 20 carbon atoms as defined for R1, R2, R3 and R4, provided that at least one of R1, R2, R3, R4, R5, R6, R7, R8 or R9 is R''; where n is 3 to 6, r and u are 2, 3, or 4; m, q are 0 to 100; m + q must be >5; w is 2, 3, or 4; p is 2 or 3; f, g, are 0 or 2 to 6; s and t are 0 or a whole number and s + t must be less than 100; a and b are whole numbers; D. the reaction product of A, B and/or C with at least one compound selected from I. DIEPOXIDES, AND II. COMPOUNDS WHICH YIELD THE FOLLOWING DIVALENT RADICALS
R1, R2, R3 and R4 are independently selected from R'' and monovalent hydrocarbon radicals having 1 to 20 carbon atoms derived from aliphatic, aromatic, cycloaliphatic, aromaticaliphatic, heterocyclic hydrocarbons or -(CrH2rO)m(CpH2pO)q-H; R5 is ethylene radical, R or a divalent radical selected from:
AND -(CrH2rO)s-(CuH2uO)t-CwH2w-; where R'', R'''', R'''''' and R'''''''' are
WHERE R is at least one of the alkylene difunctional radicals having 3 to 15 carbon atoms and a radical selected from
It has been suggested that an antistatic fiber of polyamide can be prepared by uniformly dispersing in the polymer a small proportion of at least one compound having a molecular weight above 1500 selected from the group consisting of compounds represented by the formulas:-
4.发明授权Polyamide-polyester dispersions containing secondary and tertiary amino terminating moieties on the polyamides 失效含有二胺和仲胺氨基转移酶在聚酰胺上的聚酰胺 - 聚酯分散体
公开(公告)号：US3644572A
公开(公告)日：1972-02-22
申请号：US3644572D
申请日：1968-11-26
Applicant: ALLIED CHEM
Inventor： MAYER RICHARD E , CRESCENTINI LAMBERTO
Abstract: A POLYAMIDE HAVING A SUBSTANIAL PROPORTION OF PRIMARY AN XXXXXX END-GROUPS BOUND TO TERMINATING AGENTS CONTAINING XXXXXX OR UNREACTIVE SECONDARY AMINO GROUPS CAN BE SPAN XXXXX FILAMENTS. WHEN SAID POLYMER IS MELTED OR MELT-BLENDED WITH POLYESTER, WITHOUT ADVERSE INTERACTION OCURRING BETWEEN THE COPOLYMERS WHEREBY THE RESULTANT PRODUCT POSSESSES ENHANCED DYEABILITY CHARACTERISTICS WITH ACID DYES.
-
5.发明授权
公开(公告)号：US3873639A
公开(公告)日：1975-03-25
申请号：US27131672
申请日：1972-07-12
Applicant: ALLIED CHEM
Inventor： CRESCENTINI LAMBERTO , WELLS RODNEY LEE
CPC classification number: C08L77/00 , Y10S524/905 , C08L2666/20
Abstract: WHEREIN X'' HAS A VALUE FROM 1 TO 6 AND Y'' HAS A VALUE OF 1 TO 6 IS ADDED.
IN WHICH R is
IN WHICH X HAS A VALUE OF FROM 1 TO 6 AND Y HAS A VALUE OF FROM 6 TO 30; AND
AN ADDITIONAL SMALL PROPORTION OF A HINDERED PHENOL REPRESENTED BY THE FORMULAE:
AND AT LEAST ONE COMPOUND SELECTED FROM THE GROUP CONSISTING OF DIEPOXIDES AND COMPOUNDS WHICH YIELD THE FOLLOWING DIVALENT RADICALS:
A antistatic properties of fibers of polyamide could be improved by dispersing in the polyamide a small proportion of a reaction product of a tetrol compound represented by the formula:Abstract translation: 聚酰胺纤维的抗静电性能可以通过在聚酰胺中分散一小部分由下式表示的四元醇化合物的反应产物来改善：
-
Patent Agency Ranking
公开(公告)号：US3657386A
公开(公告)日：1972-04-18
申请号：US3657386D
申请日：1970-04-30
Applicant: ALLIED CHEM
Inventor： WEEDON GENE C , CRESCENTINI LAMBERTO
CPC classification number: C08L77/00 , C08L67/00 , C08L75/00 , C08L2201/04 , Y10S525/927 , C08L2666/14 , C08L2666/20 , C08L71/00
Abstract: IT HAS BEEN FOUND THAT AN ANTISTATIC FIBER OF POLYAMIDE, POLYESTER, POLYUREA, POLYURETHANE OR POLYSULFONAMIDE CAN BE PREPARED BY UNIFORMLY DISPERSING BETWEEN ABOUT 1 PERCENT AND ABOUT 12 PERCENT BY WEIGHT OF A COMPOUND REPRESENTED BY THE FORMULA:
H-(O-CH2-CH2)Y-(O-CH(-CH3)-CH2)C-N(-CH2-CH(-CH3)-O)D-(CH2-
CH2-O)Z-H)-CH2-CH2-N(-(CH2-CH(-CH3)-O)A-(CH2-CH2-O)X-H)-
(CH2-CH(-CH3)-O)B-(CH2-CH2-O)W-H
WHERE A,B,C,D,W,X,Y, AND Z ARE EACH A WHOLE NUMBER AND THE TOTAL OF A,B,C, AND D IS BETWEEN 8 AND 850 AND THE TOTAL OF W,X,Y, AND Z IS BETWEEN 8 AND 1,000. THE COMPOUND HAS A MOLECULAR WEIGHT BETWEEN ABOUT 4,000 AND 135,000 AND THE ETHYLENE OXIDE MOIETY MAKES UP 10 TO 90% OF THE MOLECULAR WEIGHT OF THE COMPOUND.-
7.发明授权Polyamide filaments containing polyalkylene ethers and phenolic anti-oxidants 失效含聚乙烯醚和苯酚类抗氧化剂的聚酰胺纤维
公开(公告)号：US3655819A
公开(公告)日：1972-04-11
申请号：US3655819D
申请日：1968-12-09
Applicant: ALLIED CHEM
Inventor： CRESCENTINI LAMBERTO
Abstract: A FILAMENT, HAVING IMPROVED RESISTANCE TO LIGHT, OF A POLYAMIDE HAVING INCORPORATED THERETHROUGH ABOUT 0.3 TO 7 WEIGHT PERCENT, BASED ON THE WEIGHT OF THE POLYAMIDE, OF A POLY (ALKYLENE ETHER) HAVING A MOLECULAR WEIGHT FROM ABOUT 600 TO 3,000,000, AND ABOUT 0.05 TO 2 WEIGHT PERCENT, BASED ON THE WEIGHT OF THE POLYAMIDE, OF A STERICALLY HINDERED PHENOLIC COMPOUND.
-
8.发明授权
公开(公告)号：US3923924A
公开(公告)日：1975-12-02
申请号：US52799574
申请日：1974-11-29
Applicant: ALLIED CHEM
Inventor： WELLS RODNEY LEE , CRESCENTINI LAMBERTO
CPC classification number: C08K5/13 , C08L77/00 , Y10S524/913 , C08L2666/20
Abstract: It has been suggested that antistatic properties of fibers of polyamide could be improved by uniformly dispersing in the polyamide between about 1 percent and about 12 percent by weight of a predominantly branched, chain-extended propylene oxideethylene oxide copolymer based on a diamine. However, with incorporation of this antistatic additive in the polyamide, serious problems have been encountered in melt-spinning due to the frequent occurrence of ''''nubs'''' or enlarged places in the extruded polyamide filament. It has now been found that the occurrence of said nubs in the antistatic polyamide fiber can be greatly reduced by dispersing in the polymer about 0.5 to 12% by weight, based on the weight of the antistatic agent, of a phenol compound represented by the formula:
In comparative tests with antistatic yarns containing various commercially available hindered phenol compounds, the yarns of the present invention showed significantly greater breaking strength retention after exposure to light in standard tests.Abstract translation: 已经提出通过在聚酰胺中均匀分散在基于二胺的占主要分支的，链延长的环氧丙烷 - 环氧乙烷共聚物的约1重量％和约12重量％之间来改善聚酰胺纤维的抗静电性能。 然而，通过在聚酰胺中并入该抗静电添加剂，由于在挤出的聚酰胺长丝中频繁出现“凸点”或扩大位置，在熔纺中遇到严重的问题。 现在已经发现，通过在聚合物中分散约0.5-12重量％（以抗静电剂的重量计），由式（I）表示的酚化合物分散在抗静电聚酰胺纤维中， ：其中R是含有少于9个碳原子的烷基烃基，R 1是含有至少4个但不多于12个碳原子的叔烷基。
-
公开(公告)号：US3888944A
公开(公告)日：1975-06-10
申请号：US49442374
申请日：1974-08-05
Applicant: ALLIED CHEM
Inventor： CRESCENTINI LAMBERTO , WELLS RODNEY LEE
CPC classification number: C08L77/00 , Y10S260/17 , Y10S260/21 , Y10S524/905 , C08L2666/20
Abstract: It has been suggested that antistatic properties of fibers of polyamide could be improved by dispersing in the polyamide a small proportion of a reaction product of a tetrol compound represented by the formula:
WHERE A'' is a difunctional radical from a hydrocarbon containing 1 to 30 carbon atoms. However, with incorporation of this antistatic additive in the polyamide, serious problems have been encountered in meltspinning due to the frequent occurrence of ''''nubs'''' or enlarged places in the extruded polyamide filament. It has now been found that the occurrence of said nubs in the antistatic polyamide fiber can be greatly reduced by dispersing in the polymer an additional small proportion of a hindered phenol represented by the formulae:
IN WHICH X HAS A VALUE OF FROM 1 TO 6 AND Y HAS A VALUE OF FROM 6 TO 30; AND
IN WHICH R is
WHEREIN X'' HAS A VALUE FROM 1 TO 6 AND Y'' HAS A VALUE OF 1 TO 6. When the term ''''alkyl'''' is qualified by the designation ''''(lower)'''', there is intended a branched or straight chain hydrocarbon of from 1 to about 6 carbon atoms. Preferably, the phenol complound is used with at least 0.1% by weight, based on the weight of the antistatic additive, of a sulfur compound of the formula:
WHEREIN R'''' is an alkyl radical containing 8 to 18 carbon atoms and n is 1 to 3.
WHERE A, B, C, D, E, F, G, AND H ARE EACH A WHOLE NUMBER AND A is a difunctional radical from a hydrocarbon containing 1 to 13 carbon atoms, said tetrol compound having a molecular weight between about 4,000 and about 50,000, and at least one compound selected from the group consisting of diepoxides and compounds which yield the following divalent radicals:-
10.发明授权
公开(公告)号：US3887638A
公开(公告)日：1975-06-03
申请号：US49442174
申请日：1974-08-05
Applicant: ALLIED CHEM
Inventor： CRESCENTINI LAMBERTO , WELLS RODNEY LEE
CPC classification number: C08K5/1345 , C08L77/00 , Y10S260/17 , Y10S260/21 , Y10S524/913 , C08L2666/20
Abstract: It has been suggested that antistatic properties of fibers of polyamide could be improved by dispersing in the polyamide a small proportion of a reaction product of a tetrol compound represented by the formula:
WHERE A, B, C, D, E, F, G, AND H ARE EACH A WHOLE NUMBER AND A is a difunctional radical from a hydrocarbon containing 1 to 13 carbon atoms, said tetrol compound having a molecular weight between about 4,000 and about 50,000, and at least one compound selected from the group consisting of diepoxides and compounds which yield the following divalent radicals:
WHERE A'' is a difunctional radical from a hydrocarbon containing 1 to 30 carbon atoms. However, with incorporation of this antistatic additive in the polyamide, serious problems have been encountered in meltspinning due to the frequent occurrence of ''''nubs'''' or enlarged places in the extruded polyamide filament. It has now been found that the occurrence of said nubs in the antistatic polyamide fiber can be greatly reduced by dispersing in the polymer an additional small proportion of a hindered phenol represented by the formulae:
IN WHICH X HAS A VALUE OF FROM 1 TO 6 AND Y HAS A VALUE OF FROM 6 TO 30; AND
IN WHICH R is
WHEREIN X'' HAS A VALUE FROM 1 TO 6 AND Y'' HAS A VALUE OF 1 TO 6. When the term ''''alkyl'''' is qualified by the designation ''''(lower),'''' there is intended a branched or straight chain hydrocarbon of from 1 to about 6 carbon atoms. Preferably, the phenol compound is used with at least 0.1% by weight, based on the weight of the antistatic additive, of a sulfur compound of the formula:
WHEREIN R'''' is an alkyl radical containing 8 to 18 carbon atoms and n is 1 to 3.Abstract translation: 已经提出通过在聚酰胺中分散一小部分由下式表示的四元醇化合物的反应产物可以提高聚酰胺纤维的抗静电性能：
-
-
-
-
-
-
-
-
-
Search Results
13
records
(took 0.009 seconds)
