摘要:
A flameless combustion heater is described that comprises an oxidation conduit and a fuel conduit having a plurality of centralizers attached to the external wall of the fuel conduit wherein at least one centralizer or portion of a centralizer is angled with respect to the longitudinal axis of the fuel conduit. A method for providing heat to a process conduit is also described that comprises providing an oxidation conduit; providing a fuel conduit having a plurality of openings that provide fluid communication from within the fuel conduit to the oxidation conduit, and a plurality of centralizers attached to the fuel conduit wherein at least one centralizer or portion of a centralizer is angled with respect to the longitudinal axis of the fuel conduit; providing a process conduit in a heat exchange relationship with the oxidation conduit; introducing fuel into the fuel conduit; introducing an oxidant into the oxidation conduit; and introducing the fuel into the oxidation conduit through the plurality of openings such that flameless combustion occurs in the oxidation conduit.
摘要:
A flameless combustion heater is described, that comprises an oxidation conduit and a fuel conduit positioned within the oxidation conduit to form an oxidation zone having an inlet and an outlet, said fuel conduit having a plurality of openings that provide fluid communication from within the fuel conduit to the oxidation conduit wherein the longitudinal axis of at least one opening forms an oblique angle with the inner surface of the oxidation conduit. A method for providing heat to a process conduit is described, that comprises providing an oxidation conduit; providing a fuel conduit having a plurality of openings that provide fluid communication from within the fuel conduit to the oxidation conduit wherein the longitudinal axis of at least one opening forms an oblique angle with the inner surface of the oxidation conduit; providing a process conduit in a heat exchange relationship with the oxidation conduit; introducing fuel into the fuel conduit; introducing an oxidant into the oxidation conduit; and introducing the fuel into the oxidation conduit through the plurality of openings such that flameless combustion occurs in the oxidation conduit.
摘要:
Included is a method of starting up a direct heating device having a fuel introduction zone, a combustion zone and a process zone that is in heat exchange relationship with said combustion zone. Prior to the introduction of a fuel fluid into said combustion zone, an oxidant fluid, having a high temperature, is passed through the combustion zone for a warm-up time period sufficient to raise the temperature of the direct heating device to a desired temperature. Steam or a process fluid is passed through the process zone followed by the introduction of a fuel fluid into the fuel introduction zone. After the device has been heated up a process fluid is introduced through the process zone. Thereafter, the introduction of steam through the process zone may be stopped.
摘要:
A flameless combustion heater system is described that comprises a flameless combustion heater; an oxidant inlet pipe; a fuel inlet pipe; and a preheater for preheating the oxidant or the fuel, said preheater comprising an oxidation catalyst. A method for starting up a flameless combustion heater is described comprising passing a fuel-oxidant mixture to a preheater comprising an oxidation catalyst to preheat the fuel or oxidant stream being fed to the heater. A method for controlling the temperature of the flameless combustion heater system is also described that comprises controlling the amount of fuel and/or oxidant that passes through the preheater.
摘要:
A four-tube heating system for combusting a fuel and transferring the heat released therefrom to a process fluid. The heating system includes, a fuel introduction zone, a combustion zone, an oxidant introduction zone, and a process fluid zone, wherein the fuel introduction zone is defined by fuel introduction means for introducing fuel into the combustion zone that is defined by a reaction tube external to and surrounding the fuel introduction means, and wherein the oxidant introduction zone is defined by an oxidant introduction tube external to and surrounding the reaction tube, and wherein the process fluid zone is defined by a process tube external to and surrounding the oxidant tube.
摘要:
The invention relates to a new and improved process and apparatus for the production of high purity hydrogen by steam reforming. The apparatus is an integrated flameless distributed combustion-membrane steam reforming (FDC-MSR) or reactor for steam reforming of a vaporizable hydrocarbon to produce H2 and CO2, with minimal CO, and minimal CO in the H2 stream. The flameless distributed combustion drives the steam reforming reaction which pro-vides great improvements in heat exchange efficiency and load following capabilities. The reactor may contain multiple flameless distributed combustion chambers and multiple hydrogen-selective, hydrogen-permeable, membrane tubes. The feed and reaction gases may flow through the reactor either radially or axially. A further embodiment of the invention involves producing high purity hydrogen by dehydrogenation using an integrated FDC-membrane de-hydrogenation reactor. A still further embodiment of the invention involves a zero emission hybrid power system wherein the produced hydrogen is used to power a high-pressure internally manifolded molten carbonate fuel cell. In addition, the design of the FDC-SMR powered fuel cell makes it possible to capture good concentrations of CO2 for sequestration or use in other processes.
摘要翻译:本发明涉及通过蒸汽重整生产高纯度氢的新的和改进的方法和装置。 该装置是用于蒸发重整可汽化烃以产生H 2 CO 2和CO 2 2的集成无火焰分布式燃烧膜蒸汽重整(FDC-MSR)或反应器,其中最小 CO和H 2 H 2流中的最小CO。 无焰分布式燃烧驱动蒸汽重整反应,提高了热交换效率和负载跟随能力。 反应器可以包含多个无焰分布式燃烧室和多个氢选择性,氢气可渗透的膜管。 进料和反应气体可以径向或轴向流过反应器。 本发明的另一个实施方案涉及使用集成的FDC膜去氢反应器通过脱氢制备高纯度氢。 本发明的另一个实施例涉及一种零排放混合动力系统,其中所产生的氢气用于为高压内部歧管的熔融碳酸盐燃料电池供电。 此外,FDC-SMR动力燃料电池的设计使得可以捕获高浓度的CO 2,用于螯合或用于其它工艺。
摘要:
The invention provides a process and a reactor for the preparation of an alkylene glycol from an alkylene oxide. Alkylene oxide, water, a homogeneous carboxylation catalyst and a homogenous hydrolysis catalyst are supplied to a reactor comprising a carboxylation zone and a hydrolysis zone. One or more ejectors are used to mix carbon dioxide and the liquid reagents in the carboxylation zone so that alkylene oxide reacts with carbon dioxide in the presence of water in the carboxylation zone to form a reaction solution comprising alkylene carbonate, water, the homogeneous carboxylation catalyst and the homogeneous hydrolysis catalyst. The reaction solution is supplied from the carboxylation zone to a hydrolysis zone, wherein alkylene carbonate and water react to form a product solution comprising alkylene glycol, the homogeneous carboxylation catalyst and the homogeneous hydrolysis catalyst. Carbon dioxide released by the reaction of alkylene carbonate and water in the hydrolysis zone is supplied to the carboxylation zone. Product solution is withdrawn from the hydrolysis zone.
摘要:
A process and apparatus for separating at least part of a gaseous product from a feed stream which comprises contaminants. The process comprises: 1) providing the feed stream; 2) cooling the feed stream to a temperature at which a slurry stream is formed which comprises solid contaminant, liquid phase contaminant and the gaseous product; 3) introducing the slurry stream as obtained in step 2) via a plurality of tangentially directed inlet means into an upper part of a separation device, thereby creating a swirl of the slurry stream which allows at least part of the gaseous product to flow upwardly and solid contaminant and liquid phase contaminant to flow downwardly; 4) removing at least part of the gaseous product from the upper part of the device; and 5) removing a stream comprising liquid phase contaminant from a lower part of the device.
摘要:
A process and a system are provided for producing and separating hydrogen and carbon dioxide from a hydrocarbon and steam. A hydrocarbon and steam are steam reformed and the reformed gas is shift reacted to produce a shift gas. Hydrogen is removed from the shift gas, and the hydrogen-depleted gas is reformed and shift reacted again to produce more hydrogen and carbon dioxide. The hydrogen and carbon dioxide are then separated.
摘要:
A four-tube heating system for combusting a fuel and transferring the heat released therefrom to a process fluid. The heating system includes, a fuel introduction zone, a combustion zone, an oxidant introduction zone, and a process fluid zone, wherein the fuel introduction zone is defined by fuel introduction means for introducing fuel into the combustion zone that is defined by a reaction tube external to and surrounding the fuel introduction means, and wherein the oxidant introduction zone is defined by an oxidant introduction tube external to and surrounding the reaction tube, and wherein the process fluid zone is defined by a process tube external to and surrounding the oxidant tube.