Fluorinated ether compositions and methods of using the same
    4.
    发明授权
    Fluorinated ether compositions and methods of using the same 失效
    氟化醚组合物及其使用方法

    公开(公告)号:US08476385B2

    公开(公告)日:2013-07-02

    申请号:US12602877

    申请日:2008-06-06

    IPC分类号: C08F18/20

    摘要: A composition including at least one first divalent unit represented by formula: Each Rf is independently selected from the group consisting of Rfa—(O)t—CHF—(CF2)n—; [Rfa—(O)t—C(L)H—CF2—O]m—W—; Rfb-O—(CF2)p-; F(CkF2k)—(O—CkF2k)P—O—CF2—; and CF3—O—(CF2)3—(OCF(CF3)—CF2)Z—O-L1-. Each Q is independently selected from the group consisting of a bond, —C(O)—N(R1)—, and —C(O)—O—. Each X is independently selected from the group consisting of alkylene and arylalkylene, wherein alkylene and arylalkylene are each optionally interrupted by at least one ether linkage and optionally terminated by —N(R1)—C(O)— or —O—C(O)—. R and R1 are each independently selected from the group consisting of hydrogen and alkyl having from 1 to 4 carbon atoms. Rfa represents a partially or fully fluorinated alkyl group having from 1 to 10 carbon atoms and optionally interrupted with at least one oxygen atom. Rfb is selected from the group consisting of CF3CFH— and F(CjF2j)-. Methods of reducing surface tension of a liquid, making foams, and treating a surface using the compositions are also disclosed.

    摘要翻译: 包含至少一个由式表示的第一二价单元的组合物:每个Rf独立地选自Rfa-(O)t-CHF-(CF 2)n - ; [Rfa-(O)t -C(L)H-CF 2 -O] m -W-; Rfb-O-(CF2)p-; F(CkF2k) - (O-CkF2k)P-O-CF2-; 和CF 3 -O-(CF 2)3 - (OCF(CF 3)-CF 2)Z-O-L 1。 每个Q独立地选自由键,-C(O)-N(R 1) - 和-C(O)-O-组成的组。 每个X独立地选自亚烷基和芳基亚烷基,其中亚烷基和芳基亚烷基各自任选地被至少一个醚键中断,并且任选地被-N(R 1)-C(O) - 或-OC(O) - 。 R和R 1各自独立地选自氢和具有1至4个碳原子的烷基。 Rfa表示具有1至10个碳原子并且任选被至少一个氧原子中断的部分或完全氟化的烷基。 Rfb选自CF 3 CFH-和F(C 1 F 2)) - 。 还公开了降低液体的表面张力,制造泡沫和使用组合物处理表面的方法。

    Urethane-based stain-release coatings
    6.
    发明授权
    Urethane-based stain-release coatings 有权
    基于聚氨酯的防污涂层

    公开(公告)号:US06646088B2

    公开(公告)日:2003-11-11

    申请号:US10106616

    申请日:2002-03-26

    IPC分类号: C08G1830

    摘要: This invention relates to chemical compositions comprising one or more urethane oligomers of at least two repeating units selected from the group consisting of fluorine-containing urethane oligomers and long-chain hydrocarbon-containing urethane oligomers. These urethane oligomers comprise the reaction product of (a) one or, more polyfunctional isocyanate compounds; (b) one or more polyols; (c) one or more monoalcohols selected from the group consisting of fluorochemical monoalcohols, optionally substituted long-chain hydrocarbon monoalcohols, and mixtures thereof; (d) one or more silanes; and optionally (e) one or more water-solubilizing compounds comprising one or more water-solubilizing groups and at least one isocyanate-reactive hydrogen containing group. The chemical compositions of the present invention can be applied as coatings and these coatings can impart stain-release characteristics and resist being worn-off due to wear and abrasion.

    摘要翻译: 本发明涉及包含一种或多种选自含氟氨基甲酸酯低聚物和长链含烃氨基甲酸酯低聚物中的至少两个重复单元的氨基甲酸酯低聚物的化学组合物。 这些氨基甲酸酯低聚物包含(a)一种或多种多官能异氰酸酯化合物的反应产物; (b)一种或多种多元醇; (c)一种或多种选自氟化合物一元醇,任选取代的长链烃一元醇及其混合物的一元醇; (d)一种或多种硅烷; 和任选的(e)一种或多种包含一种或多种水溶性基团和至少一种含异氰酸酯反应性氢的基团的水溶性化合物。 本发明的化学组合物可以作为涂料使用,并且这些涂料可以赋予污渍释放特性并且抵抗由于磨损而磨损。

    Aqueous compositions of fluorinated surfactants and methods of using the same
    9.
    发明授权
    Aqueous compositions of fluorinated surfactants and methods of using the same 失效
    氟化表面活性剂的水性组合物及其使用方法

    公开(公告)号:US08338517B2

    公开(公告)日:2012-12-25

    申请号:US12601143

    申请日:2008-05-21

    IPC分类号: C08K5/00

    摘要: Aqueous compositions comprising surfactant represented by a formula selected from the group consisting of: [Rf—(O)t—CHF—(CF2)n—COO−]iXi+; {[Rf—(O)t—CQH—CF2—O]m—R—COO−}iXi+; {[Rf—(O)t—CQH—CF2—O]m—R—SO3−}iXi+; and [CF3CFH—O—(CF2)p—COO−]iXi+; wherein Rf represents a partially or fully fluorinated aliphatic group optionally interrupted with at least one oxygen atom; Q is selected from the group consisting of F and CF3; R is selected from the group consisting of alkylene and arylene; Xi+ represents a cation having a valence i, wherein i is 1, 2 or 3; t is 0 or 1; m is 1, 2, or 3; n is 0 or 1; and p is an integer from 1 to 6. The aqueous composition comprises a non-fluorinated polymer and is essentially free of fluoropolymers. Methods of coating a surface and an article having a surface in contact with the composition are provided.

    摘要翻译: 包含由选自以下的式的表面活性剂组成的水性组合物:[Rf-(O)t-CHF-(CF 2)n -CO 2 - ] i X i + {[Rf-(O)t-CQH-CF2-O] m -R-COO-} iXi +; {[Rf-(O)t-CQH-CF2-O] m -R-SO3-} iXi +; 和[CF 3 CFH-O-(CF 2)p-COO-] i X i +; 其中Rf表示任选被至少一个氧原子间断的部分或完全氟化的脂族基团; Q选自F和CF 3; R选自亚烷基和亚芳基; Xi +表示具有i价的阳离子,其中i为1,2或3; t为0或1; m为1,2或3; n为0或1; 并且p是1至6的整数。水性组合物包含非氟化聚合物并且基本上不含含氟聚合物。 提供涂覆表面和具有与组合物接触的表面的制品的方法。