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公开(公告)号：US07776983B2
公开(公告)日：2010-08-17
申请号：US11026706
申请日：2004-12-30
IPC分类号： C08F12/30
CPC分类号： C08F220/38 , C08F220/28 , C09D7/47 , C11D1/004 , C11D1/008
摘要： Described are polymeric surfactants which include a fluorinated moiety and a non-fluorinated moiety where the fluorinated moiety contains two perfluoro-lower-alkyl sulfonamido segments in proximity to each other ; the surfactants provide more efficient and effective lowering of the surface tension of liquids and increase of wetting of a coating on a substrate surface.
摘要翻译： 描述了包括氟化部分和非氟化部分的聚合物表面活性剂，其中氟化部分包含彼此接近的两个全氟低级烷基亚磺酰氨基部分; 表面活性剂提供更有效和有效地降低液体的表面张力和增加基材表面上的涂层的润湿性。
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公开(公告)号：US07160850B2
公开(公告)日：2007-01-09
申请号：US11027410
申请日：2004-12-30
摘要： Described are monomeric fluorosurfactants having two perfluoro-lower-alkyl sulfonamido segments which are more efficient and effective in lowering the surface tension of organic solvents and water compared to other C4-based fluorosurfactants.
摘要翻译： 描述了具有两个全氟低级烷基亚磺酰氨基链段的单体含氟表面活性剂，与其它基于C4的含氟表面活性剂相比，其降低有机溶剂和水的表面张力更有效和有效。
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公开(公告)号：US07547732B2
公开(公告)日：2009-06-16
申请号：US11215077
申请日：2005-08-30
申请人： George G. I. Moore , William M. Lamanna , Michael S. Terrazas , Rudolf J. Dams , Johan E. De Witte
发明人： George G. I. Moore , William M. Lamanna , Michael S. Terrazas , Rudolf J. Dams , Johan E. De Witte
IPC分类号： C07C143/70
CPC分类号： B01F17/0057 , B01F17/0035 , B01F17/0042 , B01F17/0064 , C07C43/178 , C07C311/09 , C11D1/004
摘要： Described are monomeric fluorochemical surfactants having two perfluoroalkyl sulfonamido segments and two hydrophilic group, which are more efficient and effective in lowering the surface tension of organic solvents and water compared to other C4-based fluorochemical surfactants.
摘要翻译： 描述了具有两个全氟烷基亚磺酰氨基链段和两个亲水基团的单体含氟表面活性剂，与其它基于C4的含氟表面活性剂相比，其降低有机溶剂和水的表面张力更有效和有效。
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4.发明授权公开(公告)号：US08678090B2
公开(公告)日：2014-03-25
申请号：US12809683
申请日：2008-12-18
IPC分类号： E21B43/16
摘要： A method of treating a hydrocarbon-bearing formation and treated hydrocarbon-bearing formations. The method includes contacting the hydrocarbon-bearing formation with a composition having solvent and a fluorinated polymer. The fluorinated polymer has units having formula (I): A method for making a composition containing these units is also disclosed.
摘要翻译： 一种处理含烃地层和经处理的含烃地层的方法。 该方法包括使含烃地层与具有溶剂和含氟聚合物的组合物接触。 氟化聚合物具有式（I）的单元：还公开了制备含有这些单元的组合物的方法。
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公开(公告)号：US07495118B2
公开(公告)日：2009-02-24
申请号：US11027404
申请日：2004-12-30
IPC分类号： C07F7/10
CPC分类号： C04B41/009 , C04B41/4933 , C04B41/84 , C07F7/1804 , C04B41/4922 , C04B33/00
摘要： Described are perfluoro lower alkyl derived silanes having two perfluoroalkyl groups in close proximity to one another which in an organic solvent are useful in treating siliceous substrates; the compositions may optionally contain an additional non-fluorinated compound in a mixture or condensation product.
摘要翻译： 描述了具有两个彼此紧邻的全氟烷基的全氟低级烷基衍生硅烷，其在有机溶剂中可用于处理硅质底物; 组合物可以任选地在混合物或缩合产物中含有另外的非氟化化合物。
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6.发明授权Aqueous compositions of fluorinated surfactants and methods of using the same 失效氟化表面活性剂的水性组合物及其使用方法公开(公告)号：US08338517B2
公开(公告)日：2012-12-25
申请号：US12601143
申请日：2008-05-21
IPC分类号： C08K5/00
摘要： Aqueous compositions comprising surfactant represented by a formula selected from the group consisting of: [Rf—(O)t—CHF—(CF2)n—COO−]iXi+; {[Rf—(O)t—CQH—CF2—O]m—R—COO−}iXi+; {[Rf—(O)t—CQH—CF2—O]m—R—SO3−}iXi+; and [CF3CFH—O—(CF2)p—COO−]iXi+; wherein Rf represents a partially or fully fluorinated aliphatic group optionally interrupted with at least one oxygen atom; Q is selected from the group consisting of F and CF3; R is selected from the group consisting of alkylene and arylene; Xi+ represents a cation having a valence i, wherein i is 1, 2 or 3; t is 0 or 1; m is 1, 2, or 3; n is 0 or 1; and p is an integer from 1 to 6. The aqueous composition comprises a non-fluorinated polymer and is essentially free of fluoropolymers. Methods of coating a surface and an article having a surface in contact with the composition are provided.
摘要翻译： 包含由选自以下的式的表面活性剂组成的水性组合物：[Rf-（O）t-CHF-（CF 2）n -CO 2 - ] i X i + {[Rf-（O）t-CQH-CF2-O] m -R-COO-} iXi +; {[Rf-（O）t-CQH-CF2-O] m -R-SO3-} iXi +; 和[CF 3 CFH-O-（CF 2）p-COO-] i X i +; 其中Rf表示任选被至少一个氧原子间断的部分或完全氟化的脂族基团; Q选自F和CF 3; R选自亚烷基和亚芳基; Xi +表示具有i价的阳离子，其中i为1,2或3; t为0或1; m为1,2或3; n为0或1; 并且p是1至6的整数。水性组合物包含非氟化聚合物并且基本上不含含氟聚合物。 提供涂覆表面和具有与组合物接触的表面的制品的方法。
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公开(公告)号：US07321018B2
公开(公告)日：2008-01-22
申请号：US10745003
申请日：2003-12-23
IPC分类号： C08G77/20
CPC分类号： C04B41/009 , C03C17/30 , C04B41/495 , C04B41/52 , C04B41/84 , C08F30/08 , C08L27/12 , C09D127/12 , Y10T428/31612 , Y10T428/31663 , C04B41/502 , C04B2103/40 , C04B41/5022 , C04B33/00 , C08L33/00
摘要： The invention relates to a dilutable, non-aqueous concentrate and an aqueous dilution used for aqueous delivery of fluorinated oligomeric silanes to a substrate, a method of treating a substrate with the aqueous dilution composition to render it oil and water repellent, and articles having coatings made from the aqueous dilution.
摘要翻译： 本发明涉及一种可稀释的非水性浓缩物和用于将氟化低聚硅烷水性输送到底物的水性稀释液，用水稀释组合物处理底物以使其具有防水和防水性的方法，以及具有涂层的制品 由水稀释制成。
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8.发明授权Compositions for aqueous delivery of self-emulsifying fluorinated alkoxysilanes 失效用于自乳化氟化烷氧基硅烷的水输送组合物公开(公告)号：US06861149B2
公开(公告)日：2005-03-01
申请号：US10447802
申请日：2003-05-29
IPC分类号： B05D7/24 , C03C17/30 , C03C17/32 , C04B41/49 , C04B41/52 , C04B41/84 , C08G65/00 , C08G65/336 , C08G65/337 , C08J3/09 , C09D183/08 , C09D183/12 , C09D201/02 , C09K3/18 , B32B17/06
CPC分类号： C08G65/337 , C03C17/32 , C03C17/328 , C04B41/009 , C04B41/4933 , C04B41/52 , C08G65/007 , C08G65/336 , C08J3/09 , C08J2383/12 , C09D183/12 , Y10S528/901 , Y10T428/31663 , C04B41/0072 , C04B41/4535 , C04B41/502 , C04B2103/40 , C04B41/5022 , C04B33/00
摘要： The invention relates to compositions used for aqueous delivery of self-emulsifying fluorinated alkoxysilanes to substrates to provide oil and water resistive coatings for the substrates, a method of treating a substrate to render it oil and water repellent, and articles having coatings made from the compositions.
摘要翻译： 本发明涉及用于将自乳化氟化烷氧基硅烷水性输送到基材以提供用于基材的油和水电阻涂层的组合物，一种处理基材以使其具有防油和防水性的方法，以及具有由组合物制成的涂层的制品 。
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9.发明授权Compositions comprising fluorinated polyether silanes for rendering substrates oil and water repellent 有权包含氟化聚醚硅烷的组合物，用于使底物油和憎水性公开(公告)号：US06613860B1
公开(公告)日：2003-09-02
申请号：US09689013
申请日：2000-10-12
申请人： Rudolf J. Dams , Franceska M. Fieuws , Steven J. Martin , Michael S. Terrazas , Mark J. Pellerite
发明人： Rudolf J. Dams , Franceska M. Fieuws , Steven J. Martin , Michael S. Terrazas , Mark J. Pellerite
IPC分类号： C08G7760
CPC分类号： C04B41/009 , C03C17/30 , C04B41/4933 , C04B41/84 , C08G65/007 , C08G65/336 , C04B41/46 , C04B41/463 , C04B41/502 , C04B33/00
摘要： The present invention provides composition for treating a substrate comprising a homogeneous mixture of: (a) a fluorinated polyether silane of the formula: Rf1—[—Q—SiY3−xR1x]y (I) wherein Rf1 represents a monovalent or divalent polyfluoropolyether group, Q represents an organic divalent linking group, R1 represents a C1-C4 alkyl group, Y represents a hydrolysable group; x is 0 or 1 and y is 1 or 2; (b) an organic or an inorganic acid; (c) water; and (d) an organic solvent. The invention further provides a method of making such a composition and the use thereof to treat substrates to render them oil and water repellent.
摘要翻译： 本发明提供了一种用于处理底物的组合物，其包含以下均匀混合物：（a）下式的氟化聚醚硅烷：其中Rf1表示一价或二价多氟聚醚基团，Q表示有机二价连接基团，R1表示C1-C4 烷基，Y表示可水解基团; x为0或1，y为1或2;（b）有机或无机酸;（c）水; 和（d）有机溶剂。 本发明还提供了一种制备这种组合物的方法及其用途来处理基材以使其具有防水和防水性。
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公开(公告)号：US20110124782A1
公开(公告)日：2011-05-26
申请号：US13054601
申请日：2009-07-15
申请人： Rudolf J. Dams , Michael S. Terrazas , Klaus Hintzer , Zai-Ming Qiu , Miguel A. Guerra , Andreas R. Maurer , Harald Kaspar , Kai H. Lochhaas , Michael Juergens , Tilman C. Zipplies , Werner Schwertfeger
发明人： Rudolf J. Dams , Michael S. Terrazas , Klaus Hintzer , Zai-Ming Qiu , Miguel A. Guerra , Andreas R. Maurer , Harald Kaspar , Kai H. Lochhaas , Michael Juergens , Tilman C. Zipplies , Werner Schwertfeger
IPC分类号： C08K5/53 , C07F9/28 , C08K5/19 , C08K5/095 , C08K5/06 , C08K5/101 , C08K5/20 , C07C229/04 , C08K5/36 , C07C53/21 , C07C211/02 , C07F9/06 , C09K3/00
CPC分类号： C07C235/10 , C07C69/708 , C07C211/11 , C07C211/14 , C07C291/04 , C07C309/14 , C07F9/091 , C07F9/3808 , C08G65/007
摘要： Compounds represented by formula (Rf-Q-X)s—Z. Each Rf is independently a partially fluorinated or fully fluorinated group selected from Rfa-(O)r—CHF—(CF2)n—; [Rfb-(O)tC(L)H—CF2—O]m—W—; CF3CFH—O—(CF2)p—; CF3—(O—CF2)z—; and CF3—O—(CF2)3—O—CF2—. Methods of reducing surface tension of a liquid, making foams, and treating a surface using the compounds are also disclosed.
摘要翻译： 由式（Rf-Q-X）s-Z表示的化合物。 每个Rf独立地是选自Rfa-（O）r -CHF-（CF 2）n - 的部分氟化或完全氟化基团; [Rfb-（O）tC（L）H-CF2-O] m -W-; CF 3 CFH-O-（CF 2）p-; CF 3 - （O-CF 2）z - ; 和CF 3 -O-（CF 2）3 -O-CF 2 - 。 还公开了降低液体的表面张力，制造泡沫以及使用该化合物处理表面的方法。
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