公开(公告)号：US20240308937A1

公开(公告)日：2024-09-19

申请号：US18268053

申请日：2021-12-21

Applicant: Basell Poliolefine Italia S.r.l.

Inventor： Nicolò Arich de Finetti ,  Diego Brita ,  Antonio Mazzucco

IPC: C07C4/22

CPC classification number: C07C4/22

Abstract: A thermo-catalytic process for the depolymerizing waste plastic material and producing a pyrolytic oil, uses two agitated vessel depolymerization reactors, two condensation units, and a char handling section.

公开(公告)号：US11098143B2

公开(公告)日：2021-08-24

申请号：US16649044

申请日：2018-09-13

Applicant: BASELL POLIOLEFINE ITALIA S.R.L.

Inventor： Antonio Mazzucco ,  Enrico Balestra ,  Roberto Pantaleoni ,  Davide Tartari ,  Riccardo Rinaldi

IPC: B01J8/26 ,  C08F210/06 ,  B01J8/22

Abstract: A process for the polymerization of olefins in gas phase carried out in a reactor having two interconnected polymerization zones, a first zone (riser) and a second zone (downcomer), wherein growing polymer particles: a) flow through the riser under fast fluidization conditions established by feeding a mixture of gas and liquid; b) leave the riser and enter the downcomer, through which the growing polymer particles flow downward in a densified form; and c) leave the downcomer and are reintroduced into the riser, thereby establishing a circulation of polymer between the riser and the downcomer; the reactor is operated at a temperature between 0° C. and 5° C. above the dew point of the riser gas at the operating pressure, and in the riser, besides the growing polymer particles and gas flow, an amount of liquid is present.

公开(公告)号：US20160083561A1

公开(公告)日：2016-03-24

申请号：US14785558

申请日：2014-03-12

Applicant: BASELL POLIOLEFINE ITALIA S.R.L.

Inventor： Monica Galvan ,  Andreas Mann ,  Tiziana Caputo ,  Antonio Mazzucco ,  Giampaolo Pellegatti

IPC: C08K5/527 ,  C08F210/16

CPC classification number: C08K5/527 ,  C08F210/16 ,  C08K5/0083 ,  C08K5/098 ,  C08K5/1575 ,  C08F210/06 ,  C08F4/651 ,  C08L23/14

Abstract: A polyolefin composition, particularly fit for the production of extrusion blow molded articles, comprising (a) a propylene-ethylene copolymer having a content of units deriving from ethylene of 4.0% by weight or higher, and (b) a nucleating agent and having a crystallization temperature (Tc) higher than 117° C. can be obtained by copolymerizing propylene and ethylene in the presence of a catalyst system obtained by contacting a solid catalyst component comprising a magnesium halide, a titanium compound having at least a Ti-halogen bond and at least two electron donor compounds one of which being present in an amount from 40 to 90% by mol with respect to the total amount of donors and selected from succinates and the other selected from 1,3 diethers, an aluminum hydrocarbyl compound, and optionally an external electron donor compound.

Abstract translation: 一种聚烯烃组合物，特别适用于生产挤出吹塑制品，其包含（a）乙烯衍生物的含量为4.0重量％以上的丙烯 - 乙烯共聚物，和（b）成核剂并具有 在通过使包含卤化镁的固体催化剂组分，至少具有Ti-卤素键的钛化合物和 至少两种电子给体化合物，其中一种以相对于供体总量为40至90摩尔％的量存在，并且选自琥珀酸盐，另一种选自1,3-二醚，铝烃基化合物和任选的 外电子给体化合物。

公开(公告)号：US10792637B2

公开(公告)日：2020-10-06

申请号：US16477283

申请日：2017-12-15

Applicant: BASELL POLIOLEFINE ITALIA S.R.L.

Inventor： Enrico Balestra ,  Tiziana Caputo ,  Massimo Covezzi ,  Maurizio Dorini ,  Antonio Mazzucco ,  Gabriele Mei ,  Ricardo Rinaldi

IPC: B01J8/24 ,  B01J8/18 ,  C08F2/01 ,  C08F2/44

Abstract: A fluid is fed into a polymer bed of a fluidized bed gas phase polymerization reactor by introducing the fluid into the polymer bed through a distributor protruding into the fluidized bed zone of the reactor and terminating with a discharge end positioned so that the following equation is fulfilled: d/D>0.002 wherein d is the distance of the distributor's discharge end from the wall of the reactor, and D is the diameter of the reactor in the fluidized bed zone.

公开(公告)号：US09683062B2

公开(公告)日：2017-06-20

申请号：US15031913

申请日：2014-10-21

Applicant: BASELL POLIOLEFINE ITALIA S.R.L.

Inventor： Benedetta Gaddi ,  Marco Bocchino ,  Gianni Collina ,  Ofelia Fusco ,  Simona Guidotti ,  Antonio Mazzucco ,  Roberto Pantaleoni ,  Fabrizio Piemontesi

IPC: C08J9/00 ,  C08F210/06 ,  C08F10/06 ,  C08F210/02

CPC classification number: C08F210/02 ,  C08F10/06 ,  C08J9/0052 ,  C08J9/0066 ,  C08F210/06 ,  C08F210/16 ,  C08F2500/12 ,  C08F2500/18 ,  C08F2500/24 ,  C08F4/6492 ,  C08F4/651 ,  C08F2/001 ,  C08F4/6545

Abstract: The present disclosure relates to a process for the preparation of a porous propylene carried out in the presence of a catalyst system comprising (a) a Ziegler-Natta catalyst containing at least two electron donor compounds, one of which is present in an amount from 50 to 90% by mol with respect to the total amount of donors and selected from succinates, and the other being selected from 1,3 diethers, (b) an aluminum alkyl and comprising the following steps: i) contacting the catalyst components (a) and (b) for a period of time ranging from 1 to 60 minutes, at a temperature ranging from 35 to 55° C.; optionally, ii) pre-polymerizing with one or more olefins of formula CH2═CHR, where R is H or a C1-C10 hydrocarbon group, up to forming amounts of polymer from about 0.1 up to about 1000 g per gram of solid catalyst component (a); and iii) polymerizing propylene in the optional presence of minor amounts of ethylene and/or C4-C10 alpha olefins for producing the porous propylene (co)polymer.

公开(公告)号：US11453767B2

公开(公告)日：2022-09-27

申请号：US16495289

申请日：2018-03-23

Applicant: BASELL POLIOLEFINE ITALIA S.R.L.

Inventor： Gabriele Mei ,  Antonio Mazzucco ,  Tiziana Caputo ,  Enrico Balestra ,  Davide Tartari ,  Gilberto Moscardi

IPC: C08F210/06 ,  C08L23/10 ,  C08L23/12 ,  C08L23/06

Abstract: A propylene ethylene copolymer having: (i) an ethylene derived units content (C2) ranging from 2.0 wt % to 11.0 wt %, based upon the total weight of the copolymer; (ii)) a fraction soluble in xylene (Xs) at 25° C. (Xs) ranging from 7.1 wt % to 28.5 wt %, based upon the total weight of the copolymer; (iii) an intrinsic viscosity of the fraction soluble in xylene at 25° C. ranging from 3.2 dl/g to 5.6 dl/g; (iv) a melting point (Tm) higher than 140.0° C. and fulfilling the relation (I): Tm>155−1.4×C2  (I); and (v) a flexural modulus (TM) higher than 500 MPa and fulfilling the relation (II) TM>1900−285×C2+50×Xs  (II).

公开(公告)号：US10221261B2

公开(公告)日：2019-03-05

申请号：US14346648

申请日：2012-09-17

Applicant: Basell Poliolefine Italia S.r.l.

Inventor： Monica Galvan ,  Roberto Pantaleoni ,  Ofelia Fusco ,  Benedetta Gaddi ,  Andreas Neumann ,  Antonio Mazzucco ,  Gianni Collina ,  Gabriella Sartori

IPC: C08F210/06 ,  C08F10/06 ,  C08J5/18 ,  B01J31/02

Abstract: A process for the preparation of high purity propylene polymers carried out in the presence of a catalyst comprising the product obtained by contacting:(a) a solid catalyst component comprising Mg, Ti and at least a first internal electron donor compound (1ID) selected among the succinates and a second internal electron donor compound (2ID) selected among the 1,3-diethers, wherein the molar ratio of first internal donor over second internal donor 1ID:2ID is comprised between 4:6 and 9:1, with (b) an organo-aluminum compound, and optionally with (c) an external electron donor compound, said process being carried out at a temperature equal or higher than 78° C. and by employing a molar ratio of organo-aluminum compound over solid catalyst component (b):(a) of lower than 5.

公开(公告)号：US09752023B2

公开(公告)日：2017-09-05

申请号：US14358753

申请日：2012-11-07

Applicant: Basell Poliolefine Italia S.r.l.

Inventor： Monica Galvan ,  Roberto Pantaleoni ,  Ofelia Fusco ,  Benedetta Gaddi ,  Andreas Neumann ,  Antonio Mazzucco ,  Gianni Collina ,  Marco Ciarafoni

IPC: C08L23/12 ,  C08F10/06

CPC classification number: C08L23/12 ,  C08F10/06 ,  C08F4/651 ,  C08F4/6543 ,  C08F2/00 ,  C08F210/16 ,  C08F210/06 ,  C08F2500/11 ,  C08F2500/12 ,  C08F2500/17 ,  C08F2500/21 ,  C08F2/001 ,  C08F110/06 ,  C08L23/16

Abstract: Preparing propylene polymer compositions comprising 50 to 90% by weight of a propylene (co)polymer, and 10 to 50% by weight of an ethylene copolymer. The polymerization process includes, in the presence of a catalyst system: (i) a first step of polymerizing propylene to produce the propylene (co)polymer; and (ii) a successive gas-phase polymerization step performed in the presence of the propylene (co)polymer, ethylene, and one or more α-olefins to produce the ethylene copolymer. The catalyst system contains the product obtained by contacting: (a) a solid catalyst component comprising at least two internal electron donor compounds, a succinate and a 1,3-diether; (b) an aluminum hydrocarbyl compound, and (c) optionally, an external electron donor compound.

公开(公告)号：US20150284488A1

公开(公告)日：2015-10-08

申请号：US14436412

申请日：2013-10-03

Applicant: BASELL POLIOLEFINE ITALIA S.R.L.

Inventor： Monica Galvan ,  Andreas Neumann ,  Tiziana Caputo ,  Stefano Squarzoni ,  Antonio Mazzucco ,  Ofelia Fusco ,  Benedetta Gaddi ,  Gianni Collina

IPC: C08F210/06

CPC classification number: C08F210/06 ,  C08F4/651 ,  C08F210/16 ,  C08F2500/03 ,  C08F2500/26

Abstract: A process for the preparation of random copolymer of propylene containing up to 6.0% by weight of ethylene units, suitable for the manufacture of pipes, by copolymerizing propylene and ethylene in the presence of a catalyst system comprising the product obtained by contacting the following components:(a) a solid catalyst component comprising a magnesium halide, a titanium compound having at least a Ti-halogen bond and at least two electron donor compounds one of which being present in an amount from 40 to 90% by mol with respect to the total amount of donors and selected from succinates and the other being selected from 1,3 diethers,(b) an aluminum hydrocarbyl compound, and(c) optionally an external electron donor compound.

Abstract translation: 一种制备含有至多6.0重量％乙烯单元的丙烯无规共聚物的方法，该乙烯单元通过在包含通过接触以下组分获得的产物的催化剂体系存在下共聚丙烯和乙烯来制备管道： （a）固体催化剂组分，其包含卤化镁，至少具有Ti-卤素键的钛化合物和至少两种电子给体化合物，其中一种以相对于总量为40至90摩尔％的量存在 选自琥珀酸盐，另一种选自1,3-二醚，（b）铝烃基化合物，和（c）任选的外电子给体化合物。

公开(公告)号：US20150232588A1

公开(公告)日：2015-08-20

申请号：US14429585

申请日：2013-09-05

Applicant: BASELL POLIOLEFINE ITALIA S.R.L.

Inventor： Enrico Balestra ,  Tiziana Caputo ,  Maurizio Dorini ,  Antonio Mazzucco ,  Silvia Soffritti

IPC: C08F10/06 ,  B01J19/24

CPC classification number: C08F10/06 ,  B01J8/24 ,  B01J8/26 ,  B01J8/388 ,  B01J19/24 ,  B01J2208/00274 ,  B01J2208/00283 ,  B01J2208/00734 ,  B01J2219/00164 ,  B01J2219/24 ,  C08F10/00 ,  C08F210/06 ,  C08F2/34 ,  C08F2/005 ,  C08F2/001 ,  C08F210/16 ,  C08F2500/12 ,  C08F2/01

Abstract: A process and apparatus for producing olefin polymers are disclosed, comprising:a. polymerizing one or more olefins in the gas phase, in the presence of an olefin polymerization catalyst, whereby growing polymer particles flow along a cylindrically-shaped downward path in densified form under the action of gravity so as to form a densified bed of downward-flowing polymer particles b. allowing said polymer particles to flow through a restriction of the densified bed, such restriction being positioned in a restriction zone extending from the bed upward to a distance of 15% of the total height of the densified bed; and c. metering an antistatic agent through a feed line connected to the densified bed at a feed point being located in a feed zone extending from the top of the restriction upward, to a distance five times the diameter of the section of the densified bed above the restriction.

Abstract translation: 公开了一种用于生产烯烃聚合物的方法和设备，包括：a。 在气相中聚合一种或多种烯烃，在烯烃聚合催化剂的存在下，由此生长的聚合物颗粒在致密形式的重力作用下沿着圆柱形的向下的路径流动，以形成向下流动的致密化床 聚合物颗粒b。 允许所述聚合物颗粒流过致密化床的限制，这种限制被定位在从床向上延伸到致密化床的总高度的15％的距离的限制区域中; 和c。 通过连接到致密化床的供给管线的计量抗静电剂，所述供给管线位于从限制件的顶部向上延伸的进料区域中的进料点，距离所述限制物上方的致密化床部分的直径的五倍。