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公开(公告)号:US11376829B2
公开(公告)日:2022-07-05
申请号:US16971609
申请日:2019-02-13
Applicant: BASELL POLIOLEFINE ITALIA S.R.L.
Inventor: Paola Massari , Andrea Felisati , Marco Izzi , Claudio Cavalieri , Davide Tartari , Isabella Maria Vittoria Camurati , Tiziana Caputo
Abstract: A multilayer film made from or containing a core layer made from or containing a polypropylene composition made from or containing:
A) from 90 wt % to 50 wt %; of a propylene homopolymer; and
B) from 10 wt % to 50 wt %; of a propylene ethylene copolymer having: i) xylene soluble fraction at 25° C. ranging from 14 wt % to 27 wt %; ii) intrinsic viscosity of the fraction soluble in xylene at 25° C. ranging from 1.0 to 2.4 dl/g; iii) melt flow rate ranging from 1.0 g/10 min to 4.0 g/10 min; iv) an ethylene content ranging from 5.0 wt % to 12.0 wt %; v) the ethylene derived units content on the fraction insoluble in xylene at 25° C. ranging from 2.5 wt % to 6.0 wt %; vi) the ethylene derived units content on the fraction soluble in xylene at 25° C. ranging from 15.2. wt % to 30.2 wt %, the sum of A) and B) being 100 wt %.-
公开(公告)号:US11098143B2
公开(公告)日:2021-08-24
申请号:US16649044
申请日:2018-09-13
Applicant: BASELL POLIOLEFINE ITALIA S.R.L.
Inventor: Antonio Mazzucco , Enrico Balestra , Roberto Pantaleoni , Davide Tartari , Riccardo Rinaldi
IPC: B01J8/26 , C08F210/06 , B01J8/22
Abstract: A process for the polymerization of olefins in gas phase carried out in a reactor having two interconnected polymerization zones, a first zone (riser) and a second zone (downcomer), wherein growing polymer particles: a) flow through the riser under fast fluidization conditions established by feeding a mixture of gas and liquid; b) leave the riser and enter the downcomer, through which the growing polymer particles flow downward in a densified form; and c) leave the downcomer and are reintroduced into the riser, thereby establishing a circulation of polymer between the riser and the downcomer; the reactor is operated at a temperature between 0° C. and 5° C. above the dew point of the riser gas at the operating pressure, and in the riser, besides the growing polymer particles and gas flow, an amount of liquid is present.
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公开(公告)号:US11453767B2
公开(公告)日:2022-09-27
申请号:US16495289
申请日:2018-03-23
Applicant: BASELL POLIOLEFINE ITALIA S.R.L.
Inventor: Gabriele Mei , Antonio Mazzucco , Tiziana Caputo , Enrico Balestra , Davide Tartari , Gilberto Moscardi
IPC: C08F210/06 , C08L23/10 , C08L23/12 , C08L23/06
Abstract: A propylene ethylene copolymer having: (i) an ethylene derived units content (C2) ranging from 2.0 wt % to 11.0 wt %, based upon the total weight of the copolymer; (ii)) a fraction soluble in xylene (Xs) at 25° C. (Xs) ranging from 7.1 wt % to 28.5 wt %, based upon the total weight of the copolymer; (iii) an intrinsic viscosity of the fraction soluble in xylene at 25° C. ranging from 3.2 dl/g to 5.6 dl/g; (iv) a melting point (Tm) higher than 140.0° C. and fulfilling the relation (I): Tm>155−1.4×C2 (I); and (v) a flexural modulus (TM) higher than 500 MPa and fulfilling the relation (II) TM>1900−285×C2+50×Xs (II).
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公开(公告)号:US20240384080A1
公开(公告)日:2024-11-21
申请号:US18693834
申请日:2022-09-13
Applicant: Basell Poliolefine Italia S.r.l.
Inventor: Davide Tartari , Stefano Spataro , Alberto Nardin , Lelio Basile
IPC: C08L23/12
Abstract: A polypropylene composition made from or containing: A) from 90.6 wt % to 97.0 wt % of a propylene homopolymer having a melt flow rate between 40.0 g/10 min and 100.0 g/10 min; and B) from 3.0 wt % to 9.4 wt % of a propylene ethylene copolymer having an ethylene content ranging from 22 wt % to 38 wt %; wherein the polypropylene composition having: i) a xylene soluble fraction at 25° C. ranging from 5 wt % to 13.0 wt %; ii) the ethylene derived units content on the fraction insoluble in xylene at 25° C. ranging from 0.3 wt % to 1.6 wt %; iii) the ethylene derived units content on the fraction soluble in xylene at 25° C. ranging from 13.2 wt % to 27.0 wt %; and (iv) a melt flow rate, MFR between 35.0 g/10 min and 70.0 g/10 min.
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公开(公告)号:US20240352165A1
公开(公告)日:2024-10-24
申请号:US18684539
申请日:2022-08-16
Applicant: Basell Poliolefine Italia S.r.l.
Inventor: Davide Tartari , Gilberto Moscardi , Monica Galvan
IPC: C08F210/16 , C08J5/18 , E02D17/20 , E04D5/08
CPC classification number: C08F210/16 , C08J5/18 , C08F2800/20 , C08J2323/16 , E02D17/20 , E02D2300/0006 , E04D5/08
Abstract: A propylene ethylene copolymer having:
i) a xylene soluble fraction at 25° C. ranging from 30 wt % to 48 wt %;
ii) an intrinsic viscosity of the xylene soluble fraction, ranging from 2.8 to 4.3 dl/g;
iii) a melt flow rate, measured according to ISO 1133 at 230° C. with a load of 2.16 kg, ranging from 0.2 g/10 min to 10 g/10 min;
iv) an ethylene derived units content ranging from 10.3 wt % to 15.4 wt %;
v) the ethylene derived units content on the xylene insoluble fraction, ranging from 6.1 wt % to 9.0 wt %;
vi) the ethylene derived units content on the xylene soluble fraction, ranging from 18.2. wt % to 30.2 wt %;
vii) the 13C-NMR sequences PEP measured on the xylene insoluble fraction, ranging from 4.1 mol % to 6.5 mol %; and
(viii) the 13C-NMR sequences PEP measured on the xylene soluble fraction, ranging from 10.5 mol % to 14.2 mol %.-
公开(公告)号:US11840775B2
公开(公告)日:2023-12-12
申请号:US17617325
申请日:2020-05-26
Applicant: BASELL POLIOLEFINE ITALIA S.R.L.
Inventor: Roberto De Palo , Davide Tartari , Monica Galvan , Claudio Cavalieri , Isabella Maria Vittoria Camurati
IPC: D01F6/30 , C08F210/06 , D01F8/06
CPC classification number: D01F6/30 , C08F210/06 , D01F8/06 , C08F2800/20
Abstract: A fiber of a propylene ethylene copolymer having:
i) xylene soluble fraction at 25° C. ranging from 14 wt % to 27 wt %;
ii) intrinsic viscosity of the fraction soluble in xylene at 25° C. ranging from 1.0 to 2.4 dl/g;
iii) melt flow rate, MFR, ranging from 12 g/10 min to 60 g/10 min;
iv) an ethylene derived units content ranging from 5.0 wt % to 12.0 wt %;
v) the ethylene derived units content of the fraction insoluble in xylene at 25° C. ranging from 2.5 wt % to 6.0 wt %;
vi) the ethylene derived units content of the fraction soluble in xylene at 25° C. ranging from 15.2. wt % to 30.2 wt %
vii) C13 NMR sequences PEP measured on the fraction insoluble in xylene at 25° C. ranging from 3.5 mol % to 5.5 mol %; and
viii) the C13 NMR sequences PEP measured on the fraction soluble in xylene at 25° C. ranging from 11.0 mol % to 14.2 mol %.-
公开(公告)号:US11186664B2
公开(公告)日:2021-11-30
申请号:US16647672
申请日:2018-08-30
Applicant: BASELL POLIOLEFINE ITALIA S.R.L.
Inventor: Paola Massari , Claudio Cavalieri , Davide Tartari , Tiziana Caputo , Isabella Maria Vittoria Camurati
IPC: C08F210/16 , C08F210/06 , C08F2/34 , C08L23/14
Abstract: A propylene ethylene copolymer having: i) xylene soluble fraction at 25° C. ranging from 14 wt % to 27 wt %; ii) intrinsic viscosity of the fraction soluble in xylene at 25° C. ranging from 1.0 to 2.4 dl/g; iii) melt flow rate, MFR, ranging from 1.0 g/10 min to 50.0 g/10 min; iv) an ethylene derived units content ranging from 5.0 wt % to 12.0 wt %; v) the ethylene derived units content on the fraction insoluble in xylene at 25° C. ranging from 2.5 wt % to 6.0 wt %; vi) the ethylene derived units content on the fraction soluble in xylene at 25° C. ranging from 15.2. wt % to 30.2 wt %; and vii) C13 NMR sequences PEP measured on the fraction insoluble in xylene at 25° C. ranging from 3.5 mol % to 5.5 mol % and C13 NMR sequences PEP measured on the fraction soluble in xylene at 25° C. ranging from 11.0 mol % to 14.2 mol %.
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公开(公告)号:US20240309134A1
公开(公告)日:2024-09-19
申请号:US18577637
申请日:2022-06-24
Applicant: Basell Poliolefine Italia S.r.l.
Inventor: Marco Bocchino , Davide Tartari , Alberto Nardin , Benedetta Gaddi , Gianni Colina , Nicola Pazi
IPC: C08F210/06 , C08J5/18
CPC classification number: C08F210/06 , C08J5/18 , C08J2323/16
Abstract: A biaxially oriented polypropylene (BOPP) film made from or containing a copolymer of propylene and ethylene having:
i) the content of ethylene derived units ranging from 0.5 wt % to 2.2 wt %;
ii) a xylene soluble fraction at 25°° C. ranging from 4.3 wt % to 6.5 wt %; and
iii) a melt flow rate, MFR, measured according to ISO 1133-1:2012 at 230° C. with a load of 2.16 kg, ranging from 0.5 g/10 min to 7.0 g/10 min.-
公开(公告)号:US11708468B2
公开(公告)日:2023-07-25
申请号:US17275939
申请日:2019-09-04
Applicant: BASELL POLIOLEFINE ITALIA S.R.L.
Inventor: Paola Massari , Claudio Cavalieri , Caroline Cathelin , Davide Tartari , Marco Ciarafoni , Roberto Pantaleoni
IPC: C08L23/16 , C08L23/20 , C08F210/08 , C08F210/02 , C08F210/06 , C08F210/16 , C08J5/18 , C08L23/14 , C08F2/00
CPC classification number: C08J5/18 , C08L23/14 , C08F2/001 , C08F210/02 , C08F210/06 , C08F210/08 , C08F210/16 , C08J2323/14 , C08J2423/14 , C08L23/16 , C08L23/20 , C08L2203/162 , C08L2205/025 , C08L23/16 , C08L23/20 , C08F2500/12 , C08F2500/34 , C08F2500/35 , C08F2500/36 , C08F2800/20
Abstract: A terpolymer compositions made from or containing:
A) From 80 wt % to 97 wt %; of a first propylene, ethylene, 1-butene terpolymer having:
i) the content of ethylene derived units ranging from 0.5 wt % to 3.2 wt %;
ii) the content of 1-butene derived units ranging from 7.2 wt % to 14.8 wt %; and
B) From 20 wt % to 3 wt %; of a second propylene, ethylene, 1-butene terpolymer having:
i) the content of ethylene derived units ranging from 0.5 wt % to 3.2 wt %;
ii) the content of 1-butene derived units ranging from 14.4 wt % to 26.5 wt %; and
the terpolymer composition having the melt flow rate, MFR, measured according to ISO 1133 at 230° C. with a load of 2.16 kg, ranging from 3.0 g/10 min to 20.0 g/10 min; the sum of the amounts of A) and B) being 100 wt %.-
公开(公告)号:US09676883B2
公开(公告)日:2017-06-13
申请号:US15309042
申请日:2015-05-06
Applicant: BASELL POLIOLEFINE ITALIA S.R.L.
Inventor: Fabrizio Piemontesi , Caroline Cathelin , Simona Guidotti , Dario Liguori , Giampiero Morini , Davide Tartari , Gianni Vitale
IPC: C08L23/00 , C08F2/00 , C08F210/00 , C08F210/06
CPC classification number: C08F210/06 , C08F210/16 , C08F2500/04 , C08F2500/12 , C08F2500/26 , C08F4/6574
Abstract: The present disclosure relates to propylene-ethylene copolymers comprising an ethylene content of 0.1-10% by weight, a molecular weight distribution (MWD), expressed in terms of Mw/Mn, of greater than 3.0 and a xylene soluble (XS) fraction content defined by values that fall below the line given by the equation XS=1.0296·e0.435C2. The propylene-ethylene copolymers advantageously exhibit high transparency and low melting temperatures.
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