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公开(公告)号:US11344868B2
公开(公告)日:2022-05-31
申请号:US16323154
申请日:2017-08-04
Applicant: BASF Corporation
Inventor: Jeff H. Yang , Wen-Mei Xue , Stanley A. Roth , Kenneth E. Voss , Qi Fu , Subramanian Prasad , Barbara K. Slawski , Jaya L. Mohanan , Sandip D. Shah
IPC: B01J29/072 , B01J29/76 , B01J37/02 , B01J35/00 , B01J37/00 , B01D53/94 , B01J37/08 , C01B39/02 , F01N3/20 , B01J35/04 , B01J37/06 , B01J37/10 , B01J37/30 , F01N3/035 , F01N3/10
Abstract: Certain selective catalytic reduction (SCR) articles, systems and methods provide for high NOx conversion while at the same time low N2O formation. The articles, systems and methods are suitable for instance for the treatment of exhaust gas of diesel engines. Certain articles have zoned coatings disposed thereon, for example, a zoned coating comprising an upstream zone comprising a coating layer comprising a steam-activated iron-containing molecular sieve and a downstream zone comprising a coating layer comprising a high copper-containing molecular sieve.
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公开(公告)号:US09662636B2
公开(公告)日:2017-05-30
申请号:US14681552
申请日:2015-04-08
Applicant: BASF Corporation
Inventor: Gary A Gramiccioni , Andreas Richard Munding , Kenneth E. Voss , Torsten Neubauer , Stanley A. Roth
IPC: B01D53/94 , B01J23/00 , B01J23/02 , B01J23/10 , B01J23/40 , B01J23/56 , B01J23/58 , B01J37/02 , B01J29/00 , B01J35/02 , B01J23/46 , B01J23/44 , B01J23/42 , B01J35/00 , B05D1/18 , B05D3/04 , B05D7/22 , B01J29/74 , B01J35/04
CPC classification number: B01J23/464 , B01D53/9418 , B01D53/944 , B01D53/945 , B01D2255/1021 , B01D2255/1023 , B01D2255/1025 , B01D2255/20715 , B01D2255/2092 , B01D2255/50 , B01D2255/9022 , B01D2255/9032 , B01D2255/908 , B01D2255/9202 , B01J23/42 , B01J23/44 , B01J29/7415 , B01J35/0006 , B01J35/002 , B01J35/04 , B01J37/0219 , B01J37/0244 , B01J37/0246 , B01J2229/37 , B05D1/18 , B05D3/0493 , B05D7/22 , Y02T10/22
Abstract: Provided herein are zoned catalysts that utilize components efficiently in that relatively short zones are provided to achieve specific functionalities to convert and/or trap one or more components in the exhaust stream. Highly controlled zoned are formed from one end of a monolithic carrier. The zones have a flat profile such that the zoned catalytic material within each passage of the substrate is at a substantially uniform distance from one end of the carrier. Methods of making and using the same are also provided.
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公开(公告)号:US20240307822A1
公开(公告)日:2024-09-19
申请号:US18675217
申请日:2024-05-28
Applicant: BASF Corporation
Inventor: Kenneth E. Voss , Kevin A. Hallstrom , Sanath V. Kumar , Susanne Stiebels , Marius Vaarkamp
CPC classification number: B01D53/9418 , B01D53/944 , B01D53/945 , B01D53/9495 , F01N3/0231 , F01N3/0821 , F01N3/2066 , B01D53/9477 , B01D2251/2067 , B01D2255/1021 , B01D2255/1023 , B01D2255/1025 , B01D2255/9155 , B01D2258/012 , F01N2510/0682 , F01N2570/18 , F01N2610/02 , Y02T10/12
Abstract: Zoned diesel oxidation catalysts containing a higher precious metal loading in the inlet zone that the outlet zone and an equal or shorter length inlet zone are described. Emission treatment systems and methods of remediating nitrogen oxides (NOx), particulate matter, and gaseous hydrocarbons using zoned diesel oxidation catalysts are also described.
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公开(公告)号:US11344845B2
公开(公告)日:2022-05-31
申请号:US15995316
申请日:2018-06-01
Applicant: BASF Corporation
Inventor: Kenneth E. Voss , Kevin A. Hallstrom , Sanath V. Kumar , Susanne Stiebels , Marius Vaarkamp
Abstract: Zoned diesel oxidation catalysts containing a higher precious metal loading in the inlet zone that the outlet zone and an equal or shorter length inlet zone are described. Emission treatment systems and methods of remediating nitrogen oxides (NOx), particulate matter, and gaseous hydrocarbons using zoned diesel oxidation catalysts are also described.
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公开(公告)号:US12203403B2
公开(公告)日:2025-01-21
申请号:US15552305
申请日:2016-03-18
Applicant: BASF CORPORATION
Inventor: Weiyong Tang , Sanath V. Kumar , Kevin A. Hallstrom , David M. Youngren , Kenneth E. Voss
Abstract: Provided are catalyst articles, methods and systems for treating lean burn engine exhaust. Catalyst articles include selective catalytic reduction catalyst on a particulate filter. The SCR catalyst on the particulate filter provides limited NOx conversion so that unconverted NO2 is available to facilitate passive oxidation of soot trapped on the particulate filter by reaction with NO2. Systems and methods utilize such catalytic articles, and further include, e.g., a downstream selective catalytic reduction catalyst on a flow through substrate.
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6.
公开(公告)号:US20170333883A1
公开(公告)日:2017-11-23
申请号:US15522440
申请日:2015-10-30
Applicant: BASF Corporation
Inventor: Jaya L. Mohanan , Jeff Yang , Patrick Burk , Kenneth E. Voss
Abstract: Described are compositions and catalytic articles comprising both a first molecular sieve promoted with copper and a second molecular sieve promoted with iron, the first and second molecular sieves having a d6r unit and the first molecular sieves having cubic shaped crystals with an average crystal size of about 0.5 to about 2 microns. The weight ratio of the copper-promoted molecular sieve to the iron-promoted molecular sieve can be about 1:1 to about 4:1. The catalytic articles are useful in methods and systems to catalyze the reduction of nitrogen oxides in the presence of a reductant.
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公开(公告)号:US20140271429A1
公开(公告)日:2014-09-18
申请号:US14205469
申请日:2014-03-12
Applicant: BASF Corporation
Inventor: M. Shahjahan Kazi , Fabien A. Rioult , Stanley A. Roth , Kenneth E. Voss
CPC classification number: B01J23/44 , B01D53/944 , B01D53/945 , B01D53/9454 , B01D53/9472 , B01D2255/1021 , B01D2255/1023 , B01D2255/9032 , B01D2258/012 , B01J23/58 , B01J23/63 , B01J35/0006 , B01J35/04 , B01J35/10 , B01J35/1033 , B01J35/1061 , B01J37/0219 , B01J37/0234 , B01J37/0244 , B01J37/0248 , B01J2523/00 , F01N3/103 , F01N2510/0682 , Y02T10/22 , B01J2523/31 , B01J2523/3706 , B01J2523/48 , B01J2523/824 , B01J2523/828
Abstract: An oxidation catalyst composite, methods, and systems for the treatment of exhaust gas emissions from a diesel engine are described. More particularly, an oxidation catalyst composite including a zoned diesel oxidation catalyst with a first washcoat zone with a Pt/Pd ratio that is less than 3:1 and a PGM loading at least twice that of a second washcoat zone.
Abstract translation: 描述了用于处理来自柴油发动机的废气排放物的氧化催化剂复合材料,方法和系统。 更具体地,涉及一种氧化催化剂复合材料,其包括具有小于3:1的Pt / Pd比率的第一修补基面涂层区域的分区式柴油氧化催化剂和至少两次第二洗涂层区域的PGM负载量的氧化催化剂复合材料。
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公开(公告)号:US12023627B2
公开(公告)日:2024-07-02
申请号:US17661058
申请日:2022-04-28
Applicant: BASF Corporation
Inventor: Kenneth E. Voss , Kevin A. Hallstrom , Sanath V. Kumar , Susanne Stiebels , Marius Vaarkamp
CPC classification number: B01D53/9418 , B01D53/944 , B01D53/945 , B01D53/9495 , F01N3/0231 , F01N3/0821 , F01N3/2066 , B01D53/9477 , B01D2251/2067 , B01D2255/1021 , B01D2255/1023 , B01D2255/1025 , B01D2255/9155 , B01D2258/012 , F01N2510/0682 , F01N2570/18 , F01N2610/02 , Y02T10/12
Abstract: Zoned diesel oxidation catalysts containing a higher precious metal loading in the inlet zone that the outlet zone and an equal or shorter length inlet zone are described. Emission treatment systems and methods of remediating nitrogen oxides (NOx), particulate matter, and gaseous hydrocarbons using zoned diesel oxidation catalysts are also described.
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公开(公告)号:US11448110B2
公开(公告)日:2022-09-20
申请号:US16323145
申请日:2017-08-04
Applicant: BASF Corporation
Inventor: Wen-Mei Xue , Jeff H. Yang , Stanley A. Roth , Kenneth E. Voss , Sandip D. Shah , Jaya L. Mohanan
IPC: F01N3/20 , B01J29/072 , B01J37/02 , B01J37/08 , B01J35/00 , B01J29/76 , B01D53/94 , B01J29/06 , B01J29/068 , B01J29/80 , B01J29/72 , B01J29/74 , B01J29/00 , B01J29/54 , B01J29/56 , B01J37/30
Abstract: Certain selective catalytic reduction (SCR) articles, systems and methods provide for high NOx conversion while at the same time low N2O formation. The articles, systems and methods are suitable for instance for the treatment of exhaust gas of diesel engines. Certain articles have zoned coatings containing copper-containing molecular sieves disposed thereon, where for example a concentration of catalytic copper in an upstream zone is lower than the concentration of catalytic copper in a downstream zone.
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10.
公开(公告)号:US10792648B2
公开(公告)日:2020-10-06
申请号:US15522440
申请日:2015-10-30
Applicant: BASF Corporation
Inventor: Jaya L. Mohanan , Jeff Yang , Patrick Burk , Kenneth E. Voss
IPC: B01J29/06 , B01J29/76 , B01D53/94 , B01J29/80 , B01D53/86 , B01J37/02 , B01J35/00 , C01B39/48 , B01J35/04 , B01J29/87 , B01J29/86 , B01J29/83 , B01J29/85 , B01J29/84 , B01J29/89
Abstract: Described are compositions and catalytic articles comprising both a first molecular sieve promoted with copper and a second molecular sieve promoted with iron, the first and second molecular sieves having a d6r unit and the first molecular sieves having cubic shaped crystals with an average crystal size of about 0.5 to about 2 microns. The weight ratio of the copper-promoted molecular sieve to the iron-promoted molecular sieve can be about 1:1 to about 4:1. The catalytic articles are useful in methods and systems to catalyze the reduction of nitrogen oxides in the presence of a reductant.
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