Abstract:
Described is a process for the treatment of a gas stream containing nitrogen oxides. The process comprises the steps of: (1) providing a gas stream containing one or more nitrogen oxides; (2) contacting the gas stream provided in step (1) with a transition metal containing zeolitic material having a BEA-type framework structure for reacting one or more of the nitrogen oxides; wherein the zeolitic material is obtainable from an organotemplate-free synthetic process. Also described is an apparatus for the treatment of a gas stream comprising containing nitrogen oxides.
Abstract:
The present invention relates to a nitrous oxide decomposition catalyst, the preparation and use. The catalyst contains rhodium on a catalyst carrier. The carrier is obtained by mixing zirconium dioxide powder with a silicon compound as binder, to form a kneadable composition, homogenizing the composition, shaping the composition into shaped articles, drying and calcination, wherein the binder is selected from silicon compounds of general formulae (I) to (VI) (Hal)xSiR4-x (I) (Hal)xSi(OR1)4-x (II) (Hal)xSi(NR1R2)4-x (III) RxSi(OR1)4-x (IV) RxSi(NR1R2)4-x (V) (R1O)xSi(NR1R2)4-x (VI) where Hal in each occurrence is independently halogen, R in each occurrence is independently H or a substituted or unsubstituted alkyl, alkenyl, alkynyl, cycloalkyl, cycloalkenyl, arylalkyl or aryl radical, R1 and R2 in each occurrence are each independently H or a substituted or unsubstituted alkyl, acyl, arylalkyl or aryl radical, and x is from 0 to 4.
Abstract:
Provided is a process for the production of a zeolitic material having a BEA-type framework structure comprising YO2 and X2O3. The process comprises the steps of (1) preparing a mixture comprising one or more sources for YO2, one or more sources for X2O3, and seed crystals comprising one or more zeolitic materials having a BEA-type framework structure; (2) crystallizing the mixture; and (3) subjecting the zeolitic material having a BEA-type framework structure to an ion-exchange procedure with Cu and/or Fe. Y is a tetravalent element, and X is a trivalent element. The mixture does not contain an organotemplate as structure-directing agent, and the total amount of Cu and/or Fe in the ion-exchanged material ranges from 0.1 to 25 wt.-% calculated as Fe2O3 and CuO. Also provided is a zeolitic material having a BEA-type framework structure, and a method for the treatment of NOx by selective catalytic reduction (SCR).
Abstract translation:提供了一种生产具有包含YO 2和X 2 O 3的BEA型骨架结构的沸石材料的方法。 该方法包括以下步骤:(1)制备包含一种或多种YO源,X2O3的一种或多种来源的混合物,以及包含一种或多种具有BEA型骨架结构的沸石材料的晶种; (2)使混合物结晶; 和(3)使具有BEA型骨架结构的沸石材料与Cu和/或Fe进行离子交换程序。 Y是四价元素,X是三价元素。 该混合物不含作为结构导向剂的有机模板,并且离子交换材料中的Cu和/或Fe的总量为0.1至25重量%,以Fe 2 O 3和CuO计算。 还提供了具有BEA型骨架结构的沸石材料和通过选择性催化还原(SCR)处理NOx的方法。
Abstract:
A single-screw extruder for changing a morphology of a superabsorbent polymer, specifically a polymer gel. The single-screw extruder has an input aperture, a channel, a screw and an output aperture. The screw has a pitch value of a pitch of the screw flights along the conveying zone of the channel, where the channel has a mixing-element arrangement with at least one mixing element which protrudes into the channel of the single-screw extruder and which is configured for the mixing of the SAP polymer gel.
Abstract:
Crosslinked polymer particles having a) a proportion of particles having a particle size of 150 to 300 μm of at least 20% by weight, b) a free swell rate of the entirety of the polymer particles FSRoverall of at least 0.25 g/g·s, c) a difference ΔFSR of at least 0.15, d) a centrifuge retention capacity CRC of at least 25.0 g/g, and e) a permeability of the swollen gel bed SFC of at least 90×10−7 cm3·s/g are disclosed.
Abstract:
Water-absorbing polymer particles are formed from crosslinked polymer chains comprising predominantly polymerized units of at least partly neutralized acrylic acid. They have a) a proportion of particles having a particle size of 150 to 300 μm of at least 20% by weight, b) a free swell rate of the entirety of the polymer particles FSRoverall of at least 0.25 g/g·s, c) a difference ΔFSR of at least 0.15, d) a centrifuge retention capacity CRC of at least 25.0 g/g, and e) a permeability of the swollen gel bed SFC of at least 90×10−7 cm3·s/g. ΔFSR is defined as =ΔFSR=FSR150-300 μm−FSRoverall in which FSR150-300 μm represents the free swell rate of the polymer particles having a particle size of 150 to 300 μm. The absorption capacity of the entirety of the polymer particles is substantially utilized even in the case of segregation of particles of different size.
Abstract:
The present invention relates to a process for preparing cyclic compounds having at least eight carbon atoms and at least one keto group, to the cyclic compounds obtained by this process and to the use thereof, in particular as fragrance or for providing a fragrance.
Abstract:
A single-screw extruder for changing a morphology of superabsorbent polymer gel. The single-screw extruder has an input aperture, a channel, a screw and an output aperture. The screw in the invention has a first pitch value of a pitch of the screw flights along the conveying zone of the channel and, following in conveying direction, has a second pitch value of the pitch of the screw flights along the conveying zone of the channel, where the second pitch value is smaller than the first pitch value.
Abstract:
A single-screw extruder for changing a morphology of superabsorbent polymer gel. The single-screw extruder has an input aperture, a channel, a screw and an output aperture. The screw in the invention has a first pitch value of a pitch of the screw flights along the conveying zone of the channel and, following in conveying direction, has a second pitch value of the pitch of the screw flights along the conveying zone of the channel, where the second pitch value is smaller than the first pitch value.
Abstract:
Described is a product comprising an amount of particles having one or more multi-layered dots on their surface, each multi-layered dot consisting of two or more layers and having an innermost layer contacting the surface of the particle, and an outermost layer, wherein the innermost layer of the multi-layered dots consists of a first metal and the outermost layer of the multi-layered dots consists of a second metal, different from the first metal.