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公开(公告)号：US20170298181A1
公开(公告)日：2017-10-19
申请号：US15515624
申请日：2015-10-01
Applicant: DSM IP ASSETS B.V
Inventor： Rudy RULKENS , Martin WOLFFS
CPC classification number: C08G69/30 , C08G69/26 , C08L77/06 , C08L2205/025
Abstract: The invention relates to a process for the preparation of a PA XY/XZ polyamide, more particular a copolyamide having alternating XY units and XZ units and a process for the manufacture thereof. Further, the present invention relates to compositions and articles comprising said copolyamide. Furthermore, the present invention relates to diamines and salts which are intermediary products of the process for the manufacture of said copolyamide.
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公开(公告)号：US20150368400A1
公开(公告)日：2015-12-24
申请号：US14763606
申请日：2014-01-30
Applicant: DSM IP ASSETS B.V.
Inventor： Rudy RULKENS , Renier Henricus Maria KIERKELS , Theo Joseph CUYPERS , Geert Adelina Rudolf VANDEN POEL , Eric GROLMAN
IPC: C08G69/36
Abstract: The invention relates to process for the production of a PA-MXDT/ZT polyamide comprising the following steps: (i) providing a solid MXDT/ZT salt, wherein MXD is meta-xylylenediamine, T is terephthalic acid, Z is a linear aliphatic diamine having from 2 to 12 carbon atoms and wherein the amount of Z is from 0 to 40 mole % with respect to the total of the amount of MXD and Z units in the polymer, (ii) solid state polymerizing the MXDT/ZT salt to obtain the polyamide, wherein the solid state polymerization is carried out at least partly under a diamine atmosphere. The invention further relates to a PA-MXDT/ZT polyamide, wherein the polymer has a glass transition temperature fulfilling the following relation: Tg>226−475*Y, wherein Y is the weight ratio g/g of all CH2 groups in the polymer with respect to the total weight of the polyamide.
Abstract translation: 本发明涉及生产PA-MXDT / ZT聚酰胺的方法，包括以下步骤：（i）提供固体MXDT / ZT盐，其中MXD为间苯二甲胺，T为对苯二甲酸，Z为直链脂族二胺 具有2至12个碳原子，并且其中Z的量相对于聚合物中MXD和Z单元的总量为0至40摩尔％，（ii）使MXDT / ZT盐的固态聚合以获得 聚酰胺，其中固态聚合至少部分地在二胺气氛下进行。 本发明还涉及PA-MXDT / ZT聚酰胺，其中聚合物具有满足以下关系的玻璃化转变温度：Tg> 226-475×Y，其中Y是聚合物中所有CH 2基团的重量比g / g 相对于聚酰胺的总重量。
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公开(公告)号：US20160137781A1
公开(公告)日：2016-05-19
申请号：US14899404
申请日：2014-06-16
Applicant: DSM IP ASSETS B.V.
Inventor： Rudy RULKENS , Eric GROLMAN , Geert Adelina Rudolf VANDEN POEL , Renier Henricus Maria KIERKELS , Theo Joseph CUYPERS , Constantine D. PAPASPYRIDES , Athanasios D. PORFYRIS
CPC classification number: C08G69/265 , C08G69/30 , C08L77/00 , C08L77/06
Abstract: The invention relates to a process for the preparation of semi-crystalline semi-aromatic polyamide by direct solid-state polymerization of a diamine-dicarboxylic acid salt, comprising steps of (a) providing at least two salts of terephthalic acid and diamine, wherein each of these diamine/terephthalic acid salts is in solid state and has a melting temperature of at least Tx, wherein Tx is at least 260° C.; (b) preparing a mixture of the diamine/terephthalic acid salts, while retaining the salts in solid state; and (c) heating the mixture obtained from step (b) in the solid state to a temperature (T-c) in the range from 200° C. to 260° C., under a pressure below the saturation vapour pressure of water at said temperature, thereby condensing and polymerizing the salts and forming a semi-crystalline semi-aromatic polyamide in solid form.
Abstract translation: 本发明涉及通过二胺二羧酸盐的直接固态聚合制备半结晶半芳族聚酰胺的方法，包括以下步骤：（a）提供至少两种对苯二甲酸和二胺的盐，其中各 的这些二胺/对苯二甲酸盐是固态的，其熔融温度至少为Tx，其中Tx至少为260℃。 （b）制备二胺/对苯二甲酸盐的混合物，同时保持固体状态的盐; 和（c）在所述温度下在低于饱和蒸汽压的压力下，将从固体状态得到的混合物加热至温度（Tc）在200℃至260℃的范围内 从而使盐缩合和聚合并形成固体形式的半结晶半芳族聚酰胺。
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4.发明申请PROCESS FOR THE PREPARATION OF DIAMINE/DICARBOXYLIC ACID SALTS AND POLYAMIDES THEREOF 审中-公开二胺/二羧酸盐及其多胺的制备方法公开(公告)号：US20150353682A1
公开(公告)日：2015-12-10
申请号：US14763617
申请日：2014-01-30
Applicant: DSM IP Assets B.V.
Inventor： Rudy RULKENS , Renier Henricus Maria KIERKELS , Geert Adelina Rudolf VANDEN POEL , Theo Joseph CUYPERS , Eric GROLMAN
IPC: C08G69/32 , C07C209/68 , C08G69/26 , C07C51/41
CPC classification number: C08G69/32 , C07C51/41 , C07C51/412 , C07C209/68 , C07C211/09 , C07C211/12 , C08G69/26 , C08G69/265 , C08G69/28 , C07C63/28 , C07C63/38 , C07C63/333
Abstract: The invention relates to a process for preparing a salt from diamine and dicarboxylic acid, the process comprising contacting a diamine gas, having a gas temperature T-gas, with a dicarboxylic acid, thereby forming a reaction mixture comprising diamine/dicarboxylic acid salt, wherein the dicarboxylic acid and the reaction mixture are kept at a temperature T-mixture of at least 10° C. below the lowest of the melting temperature of the dicarboxylic acid (Tm-acid) and the melting temperature of the resulting diamine/dicarboxylic acid salt (Tm-salt). The invention also relates to a process for preparing a polyamide comprising preparing a salt from diamine and dicarboxylic acid.
Abstract translation: 本发明涉及一种由二胺和二羧酸制备盐的方法，该方法包括使具有气体温度T气体的二胺气体与二羧酸接触，从而形成包含二胺/二羧酸盐的反应混合物，其中 将二羧酸和反应混合物保持在低于二羧酸的熔融温度（Tm-酸）的最低温度和所得二胺/二羧酸盐的熔融温度至少10℃的温度T混合物 （Tm-盐）。 本发明还涉及一种制备聚酰胺的方法，包括由二胺和二羧酸制备盐。
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公开(公告)号：US20150368399A1
公开(公告)日：2015-12-24
申请号：US14763601
申请日：2014-01-30
Applicant: DSM IP ASSETS B.V.
Inventor： Rudy RULKENS , Theo Joseph CUYPERS , Geert Adelina Rudolf VANDEN POEL , Eric GROLMAN , Renier Henricus Maria KIERKELS
CPC classification number: C08G69/30 , C08G69/265 , C08G69/28 , C08L77/06
Abstract: The invention related to a process for the production of a PA-MXDT/ZT polyamide copolymer comprising the following steps: •i. providing a solid MXDT/ZT salt, wherein MXD is meta-xylylenediamine, T is terephthalic acid, Z is a linear aliphatic diamine having from 2 to 12 carbon atoms and wherein amount of Z is from 5 to 40 mole % with respect to the total amount of MXD and Z units in the copolymer and wherein the MXDT/ZT salt is provided by dosing of liquid diamines MXD and Z to a powder of terephthalic acid; •ii. heating the solid MXDT/ZT salt to a first condensation temperature (Tc1) thereby condensing the salt in solid state to produce a solid polyamide copolymer, wherein Tc1 is below the melting temperature (Tm-salt) of said salt. The invention further relates to a PA-MXDT/ZT polyamide copolymer, wherein MXD is meta-xylylenediamine, T is terephthalic acid, Z is a linear aliphatic diamine having from 2 to 12 carbon atom, Z is from 5 to 40 mole % with respect to the total of MXD and Z units in the copolymer.
Abstract translation: 本发明涉及一种生产PA-MXDT / ZT聚酰胺共聚物的方法，包括以下步骤：i。 提供固体MXDT / ZT盐，其中MXD是间二甲苯二胺，T是对苯二甲酸，Z是具有2至12个碳原子的直链脂族二胺，其中Z的量相对于总量为5〜40摩尔％ 共聚物中MXD和Z单元的量，其中MXDT / ZT盐通过将液体二胺MXD和Z加入到对苯二甲酸的粉末中而提供; •ii。 将固体MXDT / ZT盐加热至第一冷凝温度（Tc1），由此使固体状态的盐浓缩，生成固体聚酰胺共聚物，其中Tc1低于所述盐的熔融温度（Tm-盐）。 本发明还涉及一种PA-MXDT / ZT聚酰胺共聚物，其中MXD为间苯二甲胺，T为对苯二甲酸，Z为具有2至12个碳原子的直链脂族二胺，Z为5至40摩尔％，相对于 共聚物中的MXD和Z单元总数。
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Patent Agency Ranking
公开(公告)号：US20150361216A1
公开(公告)日：2015-12-17
申请号：US14763642
申请日：2014-01-30
Applicant: DSM IP ASSETS B.V.
Inventor： Eric GROLMAN , Rudy RULKENS , Konraad Albert Louise Hector DULLAERT , Renier Henricus Maria KIERKELS , Geert Adelina Rudolf VANDEN POEL
IPC: C08G69/32
CPC classification number: C08G69/32 , C07C51/412 , C07C209/68 , C08G69/26 , C08G69/265 , C08G69/30 , C08L77/06 , C08L77/10 , C07C63/333 , C07C63/38 , C07C63/28 , C07C211/12 , C07C211/09
Abstract: The invention relates to a process for preparing a semi-aromatic polyamide from diamine and dicarboxylic acid, comprising steps of •(i) dosing a liquid diamine to an agitated powder comprising an aromatic dicarboxylic acid thereby forming a powder comprising a diamine/dicarboxylic acid salt (DD-salt), and •(ii) solid-state polymerizing the DD-salt to obtain the polyamide.
Abstract translation: 本发明涉及一种由二胺和二羧酸制备半芳族聚酰胺的方法，包括以下步骤：（i）将液体二胺加入到包含芳族二羧酸的搅拌粉末中，从而形成包含二胺/二羧酸盐的粉末 （DD-盐），和（ii）固态聚合DD盐以获得聚酰胺。
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公开(公告)号：US20190263965A1
公开(公告)日：2019-08-29
申请号：US16340781
申请日：2017-10-18
Applicant: DSM IP Assets B.V.
Inventor： Martin WOLFFS , Rudy RULKENS , Renier Henricus Maria KIERKELS
Abstract: The present invention relates to a semi-crystalline semi-aromatic polyamide consisting of 95-100 mole % of monomeric units derived from diamine comprising aliphatic diamine comprising 5-40 mole % of a cycloaliphatic diamine, and dicarboxylic acid comprising at least 50 mole % of naphthalene dicarboxylic acid (N), or biphenyl dicarboxylic acid (B), or a combination thereof.
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公开(公告)号：US20180297933A1
公开(公告)日：2018-10-18
申请号：US16016310
申请日：2018-06-22
Applicant: DSM IP ASSETS B.V.
Inventor： Eric GROLMAN , Rudy RULKENS
IPC: C07C209/68 , C08G69/26 , C07C63/28 , C07C55/14 , C07C55/20 , C08G69/04 , C07C211/09 , C07C211/12 , C07C51/41 , C07C63/24 , C07C63/26 , C07C63/36
Abstract: Processes are disclosed for preparing a diamine/dicarboxylic acid salt, wherein the dicarboxylic acid includes an aromatic dicarboxylic acid and is provided in a powder form. The diamine is provided in a liquid form gradually dosed to the dicarboxylic acid powder, while keeping the dicarboxylic acid powder in constant movement; the processing temperature is above 0° C. and below the boiling temperature of the diamine and the melting temperature of the acid and the salt, and the reaction mixture comprises at most 5 wt. % of water. An anhydrous diamine/dicarboxylic acid salts obtained by the process are also provided.
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公开(公告)号：US20160376220A1
公开(公告)日：2016-12-29
申请号：US15258835
申请日：2016-09-07
Applicant: DSM IP ASSETS B.V.
Inventor： Eric GROLMAN , Rudy RULKENS
CPC classification number: C07C209/68 , C07B2200/13 , C07C51/412 , C07C55/14 , C07C55/20 , C07C63/28 , C07C211/09 , C07C211/12 , C08G69/04 , C08G69/265 , C07C63/24 , C07C63/26 , C07C63/36
Abstract: The present invention also relates to a process for preparing a diamine/dicarboxylic acid salt wherein the dicarboxylic acid comprises an aromatic dicarboxylic acid and is provided in a powder form; the diamine is provided in a liquid form gradually dosed to the dicarboxylic acid powder, while keeping the dicarboxylic acid powder in constant movement; the processing temperature is above 0° C. and below the boiling temperature of the diamine and the melting temperature of the acid and the salt, and the reaction mixture comprises at most 5 wt. % of water. The present invention also relates to an anhydrous diamine/dicarboxylic acid salt obtainable by the process according to invention, or any embodiment thereof as described above.
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公开(公告)号：US20140135444A1
公开(公告)日：2014-05-15
申请号：US14160172
申请日：2014-01-21
Applicant: DSM IP ASSETS B.V.
Inventor： Alexander Antonius Maria STROEKS , Rudy RULKENS , Lee SANGHOON , Sidiki Tamim PETER
CPC classification number: C08G69/26 , B29C47/0021 , B29C47/0057 , B29C47/8845 , B29C47/887 , B29C47/8875 , B29C47/8895 , C08J5/18 , C08J2377/00 , C08L77/06
Abstract: The invention relates to an optically transparent polymer film or extrudate product made of a polymer composition comprising a semi-crystalline polyamide having a melting temperature of at least 270° C. or a blend of the semi-crystalline polyamide (A) and a second polymer (B), and optionally at least one additive, wherein the semi-crystalline polyamide (A) is present in an amount of more than 50 wt. %, relative to the total weight of the polymer composition, the polymer composition in the optically transparent polymer film or extrudate product has a melting temperature (Tm-C) in the range of 270-340° C., and wherein the film or a part of the extrudate product has a haze of less than 12% and a light transmittance, of at least 88% measured with the method according to ASTM D1003A.
Abstract translation: 本发明涉及由聚合物组合物制成的光学透明聚合物膜或挤出物产品，该聚合物组合物包含熔融温度至少为270℃的半结晶聚酰胺或半结晶聚酰胺（A）和第二聚合物 （B）和任选的至少一种添加剂，其中半结晶聚酰胺（A）的存在量大于50wt。 相对于聚合物组合物的总重量，光学透明聚合物膜或挤出物产品中的聚合物组合物的熔融温度（Tm-C）在270-340℃的范围内，并且其中所述膜或 挤出物产品的一部分具有小于12％的雾度和至少88％的透光率，使用根据ASTM D1003A的方法测量。
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