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1.发明公开公开(公告)号：US20240093102A1
公开(公告)日：2024-03-21
申请号：US18452388
申请日：2023-08-18
Applicant: ExxonMobil Chemical Patents Inc.
Inventor： Bryan A. Patel , Brenda A. Raich , Steven M. Slack , Derrick B. Callander , Eric M. Yucha , Fritz A. Bernatz , Rainer Kolb , Alex S. Kolb
CPC classification number: C10G65/10 , C10B49/22 , C10G2300/1007 , C10G2400/20
Abstract: Systems and methods are provided for integration of polymeric waste co-processing in cokers to produce circular chemical products from coker gas oil, including a method of producing circular chemical products comprising: providing a coker gas oil that is at least partially derived from polymeric waste, wherein the coker gas oil has a paraffin content of about 5 wt % to about 50 wt %, a sulfur content of about 0.1 wt % to about 7 wt %, and a halide content of about 0.1 wppm to about 5 wppm; and converting the coker gas oil into at least a polymer.
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公开(公告)号：US10105668B2
公开(公告)日：2018-10-23
申请号：US15577030
申请日：2016-06-03
Applicant: ExxonMobil Chemical Patents Inc.
Inventor： Yesim Igci , Bryan A. Patel , Min Chang
IPC: C07C407/00 , C07C409/14 , B01J8/00 , B01J8/22 , B01J4/00
Abstract: Systems, methods, and apparatus for distribution of oxygen-containing gas within a gas-liquid oxidation reaction are provided herein. The invention is particularly suited for oxidation of liquid-phase organic reactants with oxidizing gas, such as the oxidation of cyclohexylbenzene to cyclohexylbenzene hydroperoxide using an oxygen-containing gas. The oxygen-containing gas is distributed through a gas distributor and into a liquid-phase reaction medium within an oxidation reactor. In some aspects, this achieves a high degree of uniformity of oxygen concentration within the liquid-phase reaction medium. The gas distributor is disposed within a lower portion of the reactor, and may comprise a network of conduits in fluid communication with each other, which are arranged within a plane that is substantially parallel to a bottom surface of the reactor. A plurality of orifices are disposed on the conduits, such that oxygen-containing gas flows through the conduits and into the liquid-phase reaction medium via the orifices.
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公开(公告)号：US20160122298A1
公开(公告)日：2016-05-05
申请号：US14893003
申请日：2014-06-06
Applicant: EXXONMOBIL CHEMICAL PATENTS INC.
Inventor： Jason D. Davis , Christopher L. Becker , Travis A. Reine , Bryan A. Patel
IPC: C07C407/00 , C07C29/132 , C07C45/53
CPC classification number: C07C407/00 , C07C29/132 , C07C37/08 , C07C45/53 , C07C407/003 , C07C2601/14 , C07C409/14 , C07C39/04 , C07C49/403 , C07C409/02
Abstract: Method for concentrating an organic hydroperoxide mixture comprising a hydrocarbon and a hydroperoxide corresponding thereto comprises evaporating a first liquid mixture in a thin-film evaporation device followed by separation in a separation zone. Both the evaporation device and the separation zone operate at a low absolute pressure at a temperature lower than the thermal degradation temperature of the hydroperoxide to prevent thermal decomposition thereof. The process is particularly useful for concentrating an oxidation product made from the oxidation of cyclohexylbenzene.
Abstract translation: 用于浓缩包含对应于其的烃和氢过氧化物的有机氢过氧化物混合物的方法包括在薄膜蒸发装置中蒸发第一液体混合物，然后在分离区中分离。 蒸发装置和分离区都在低于氢过氧化物的热降解温度的温度下在低绝对压力下操作，以防止其热分解。 该方法对于浓缩由环己基苯氧化制得的氧化产物特别有用。
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公开(公告)号：US09047439B2
公开(公告)日：2015-06-02
申请号：US13957488
申请日：2013-08-02
Applicant: ExxonMobil Chemical Patents Inc.
Inventor： Frank Hershkowitz , Richard John Basile , Jeffrey William Frederick , John William Fulton , Paul F. Keusenkothen , Bryan A. Patel , Andrew Richard Szafran
IPC: G05B15/02 , G06F19/00 , B01J8/04 , C01B3/46 , C10G9/26 , G05B15/00 , G05B19/00 , G05B19/02 , G05B19/04 , G05B19/042 , G05D3/00 , G05D7/00 , G05D7/06 , G05D27/00 , G05D27/02 , B01J8/00 , B01J19/00
CPC classification number: G06F19/709 , B01J8/0453 , B01J8/048 , B01J8/0484 , B01J8/0492 , C01B3/46 , C01B2203/0216 , C01B2203/0233 , C01B2203/0238 , C01B2203/0266 , C10G9/26
Abstract: A reactor with minimal dead volume especially suited to reverse-flow applications comprises: a) a reactor body; b) a first head engaged with said reactor body; c) a first conduit extending from outside said head to at least partially through said head; and d) a first valve in flow communication with said first conduit controlling fluid flow along a flow path extending from the first valve and through the reactor body. The reactor is especially suited for use in a process for rapid stream-switching of at least two streams in a reverse-flow reactor.
Abstract translation: 具有最小死体积特别适合逆流应用的反应器包括：a）反应器体; b）与所述反应器主体接合的第一头部; c）从所述头部外部至少部分地穿过所述头部延伸的第一导管; 以及d）与所述第一管道流动连通的第一阀门，其沿着沿着从所述第一阀门延伸并通过所述反应器主体的流动路径控制流体流动。 该反应器尤其适用于在逆流反应器中快速流切换至少两股物流的方法。
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公开(公告)号：US20130317801A1
公开(公告)日：2013-11-28
申请号：US13957488
申请日：2013-08-02
Applicant: ExxonMobil Chemical Patents Inc.
Inventor： Frank Hershkowitz , Richard J. Basile , Jeffrey W. Frederick , John W. Fulton , Paul F. Keusenkothen , Bryan A. Patel , Andrew R. Szafran
IPC: G06F19/00
CPC classification number: G06F19/709 , B01J8/0453 , B01J8/048 , B01J8/0484 , B01J8/0492 , C01B3/46 , C01B2203/0216 , C01B2203/0233 , C01B2203/0238 , C01B2203/0266 , C10G9/26
Abstract: A reactor with minimal dead volume especially suited to reverse-flow applications comprises: a) a reactor body; b) a first head engaged with said reactor body; c) a first conduit extending from outside said head to at least partially through said head; and d) a first valve in flow communication with said first conduit controlling fluid flow along a flow path extending from the first valve and through the reactor body. The reactor is especially suited for use in a process for rapid stream-switching of at least two streams in a reverse-flow reactor.
Abstract translation: 具有最小死体积特别适合逆流应用的反应器包括：a）反应器体; b）与所述反应器主体接合的第一头部; c）从所述头部外部至少部分地穿过所述头部延伸的第一导管; 以及d）与所述第一管道流动连通的第一阀门，其沿着沿着从所述第一阀门延伸并通过所述反应器主体的流动路径控制流体流动。 该反应器尤其适用于在逆流反应器中快速流切换至少两股物流的方法。
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Patent Agency Ranking
6.发明公开公开(公告)号：US20240084199A1
公开(公告)日：2024-03-14
申请号：US18452328
申请日：2023-08-18
Applicant: ExxonMobil Chemical Patents Inc.
Inventor： Bryan A. Patel , Brenda A. Raich , Steven M. Slack , Derrick B. Callander , Eric M. Yucha , Fritz A. Bernatz , Rainer Kolb , Alex S. Kolb
CPC classification number: C10B57/04 , C10B57/005 , C10B57/02
Abstract: Systems and methods are provided for integration of polymeric waste co-processing in cokers to produce circular chemical products from coker gas, including a method of producing circular chemical products comprising: providing a coker gas that is at least partially derived from polymeric waste, wherein the coker gas has an olefin content of about 10 wt % to about 30 wt %, a sulfur content of about 0.5 wt % to about 5 wt %, and a total halide content of about 1 wppm to about 150 wppm; and oxygen-containing compounds in an amount of about 0.5 wt % to about 15 wt %; and converting the coker gas into at least a polymer.
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公开(公告)号：US20160075623A1
公开(公告)日：2016-03-17
申请号：US14787862
申请日：2014-04-09
Applicant: EXXONMOBIL CHEMICAL PATENTS INC.
Inventor： Bryan A. Patel , John S. Coleman
IPC: C07C37/50 , C07C407/00 , C07C2/74 , C07C45/53
CPC classification number: C07C37/50 , C07C2/74 , C07C37/08 , C07C45/53 , C07C407/00 , C07C409/14 , C07C2529/70 , C07C2601/14 , C07C39/04 , C07C49/403 , C07C13/28
Abstract: In a process for producing phenol and cyclohexanone, reaction components comprising cyclohexylbenzene hydroperoxide and an acid catalyst are supplied to a cleavage reaction zone, mixed under mixing conditions effective to combine the reaction components into a reaction mixture and at least part of the cyclohexylbenzene hydroperoxide in the reaction mixture is converted under cleavage conditions to into phenol and cyclohexanone; and a cleavage effluent is recovered from the cleavage reaction zone. The cleavage and mixing conditions are controlled such that the ratio tR/tM is at least 10, where tR is the half-life of cyclohexylbenzene hydroperoxide under the cleavage conditions and tM is the time required after injection of a tracer material into the reaction mixture under the mixing conditions for at least 95% by volume of the entire reaction mixture to attain at least 95% of the volume-averaged tracer material concentration.
Abstract translation: 在生产酚和环己酮的方法中，将包含环己基苯氢过氧化物和酸催化剂的反应组分供应至裂解反应区，在有效将反应组分混合成反应混合物和至少部分环己基苯氢过氧化物的混合条件下混合， 在裂解条件下将反应混合物转化成苯酚和环己酮; 并从裂解反应区回收裂解流出物。 控制裂解和混合条件使得tR / tM的比例至少为10，其中t R是在切割条件下环己基苯氢过氧化物的半衰期，tM是将示踪材料注入反应混合物中所需的时间 整个反应混合物的至少95体积％的混合条件达到体积平均示踪剂材料浓度的至少95％。
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公开(公告)号：US20160046550A1
公开(公告)日：2016-02-18
申请号：US14779131
申请日：2014-03-24
Applicant: EXXONMOBIL CHEMICAL PATENTS INC.
Inventor： Jason D. Davis , Christopher L. Becker , Bryan A. Patel , John S. Coleman , Hari Nair
IPC: C07C37/08 , C07C407/00 , B01J19/24 , C07C45/53
CPC classification number: C07C37/08 , B01J19/0013 , B01J19/1862 , B01J19/245 , B01J2219/00076 , B01J2219/00103 , B01J2219/00159 , B01J2219/24 , C07C45/53 , C07C407/00 , C07C2601/14 , C07C39/04 , C07C49/403
Abstract: A process for producing phenol and/or cyclohexanone by cleaving cyclohexylbenzene hydroperoxide in a loop cleavage reactor comprising multiple reaction zones connected in series. In desirable embodiments, fresh cyclohexylbenzene hydroperoxide feed(s) are supplied to reaction zones the final reaction zone, and fresh acid catalyst is supplied only to the final reaction zone. In desirable embodiments, a portion of the effluent exiting the final reaction zone is recycled to the first reaction zone. Each reaction zone is equipped with a heat exchanger downstream of the feed port to extract heat generated from the cleavage reaction.
Abstract translation: 一种通过在环切割反应器中裂解环己基苯氢过氧化物来制备苯酚和/或环己酮的方法，其包括串联连接的多个反应区。 在理想的实施方案中，将新鲜的环己基苯氢过氧化物进料提供给最终反应区的反应区，而新鲜酸催化剂仅供应至最终反应区。 在理想的实施方案中，离开最终反应区的一部分流出物再循环到第一反应区。 每个反应区在进料口的下游配备有热交换器，以提取由裂解反应产生的热量。
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公开(公告)号：US09238605B2
公开(公告)日：2016-01-19
申请号：US14421232
申请日：2013-09-05
Applicant: ExxonMobil Chemical Patents Inc.
Inventor： Bryan A. Patel , Travis A. Reine
IPC: C07C45/53 , C07C37/08 , C07C2/66 , C07C407/00
CPC classification number: C07C37/08 , C07C45/53 , C07C407/00 , C07C2601/14 , C07C409/14 , C07C49/403 , C07C39/04
Abstract: A process for oxidizing a first hydrocarbon to a corresponding first oxygenate by feeding a first feedstock comprising the first hydrocarbon into an oxidation reactor, contacting the reaction medium with a gas stream comprising O2 in the oxidation reactor, and supplying a hydroperoxide additive to the oxidation reactor. By including the hydroperoxide additive in the reaction medium, foaming at and/or close to the beginning of the oxidation reaction can be significantly reduced.
Abstract translation: 通过将包含第一烃的第一原料进料到氧化反应器中将第一烃氧化成相应的第一含氧化合物的方法，使反应介质与氧化反应器中包含O 2的气流接触，并向氢氧化反应器供应氢过氧化物添加剂 。 通过将氢过氧化物添加剂包括在反应介质中，可以显着降低在氧化反应开始时和/或接近氧化反应开始的发泡。
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公开(公告)号：US12065616B2
公开(公告)日：2024-08-20
申请号：US17595344
申请日：2020-06-12
Applicant: ExxonMobil Chemical Patents Inc.
Inventor： Sundararajan Uppili , Bryan A. Patel , Randolph J. Smiley , Lawrence R. Gros , Anthony Go , Saurabh S. Maduskar , Melissa D. Foster , Philippe Laurent
Abstract: Systems and methods are provided for integration of a reactor for polyolefin pyrolysis with the effluent processing train for a steam cracker. The polyolefins can correspond to, for example, polyolefins in plastic waste. Integrating a process for polyolefin pyrolysis with a steam cracker processing train can allow a mixture of polymers to be converted to monomer units while reducing or minimizing costs and/or equipment footprint. This can allow for direct conversion of polyolefins to the light olefin monomers in high yield while significantly lowering capital and energy usage due to integration with a steam cracking process train. The integration can be enabled in part by selecting feeds with appropriate mixtures of various polymer types and/or by limiting the volume of the plastic waste pyrolysis product relative to the volume from the steam cracker(s) in the steam cracking process train. By selecting plastic waste and/or other polyolefin sources with an appropriate mixture of polyolefins as the feedstock, the resulting polyolefin pyrolysis product can be separated in a steam cracking process train to produce separate fractions for various polymer grade small olefin products.
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