公开(公告)号：US20180179138A1

公开(公告)日：2018-06-28

申请号：US15829060

申请日：2017-12-01

Applicant: ExxonMobil Research and Engineering Company

Inventor： Michael P. LANCI ,  Joshua W. ALLEN ,  Jarid M. METZ ,  Victor DeFLORIO ,  Jihad M. DAKKA ,  Bryan A. PATEL ,  Michael SALCICCIOLI ,  Michael W. WEBER ,  Stephen ZUSHMA

IPC: C07C57/30 ,  C07C67/05 ,  C07C51/265 ,  C07C47/23 ,  B01J31/04 ,  C07C25/13

CPC classification number: C07C57/30 ,  B01J31/04 ,  C07C25/13 ,  C07C47/23 ,  C07C51/16 ,  C07C51/265 ,  C07C67/05 ,  C07C67/08 ,  C07C63/331 ,  C07C63/333

Abstract: A process for selective oxidation of dimethyl-1,1′-biphenyl to form methyl-1,1′-biphenyl mono-carboxylic acid(s), comprising contacting a solution of dimethyl-1,1′-biphenyl in acetic acid solvent in the presence of a Co(II) acetate catalyst and air, and optionally adding a co-solvent, or adding sodium or potassium acetate, and oxidizing the dimethyl-1,1′-biphenyl under time and temperature conditions sufficient to form one or more methyl-1,1′-biphenyl mono-carboxylic acid(s). The mono-carboxylic acids are advantageously isolated and esterified to form biphenyl mono-esters for use as plasticizers.

公开(公告)号：US20180162786A1

公开(公告)日：2018-06-14

申请号：US15839926

申请日：2017-12-13

Applicant: ExxonMobil Research and Engineering Company

Inventor： Jihad M. DAKKA ,  Guang CAO ,  Patrick L. HANKS ,  James R. BIELENBERG ,  Cynthia F. OMILIAN ,  Jessica M. WITTMANN

IPC: C07C2/86 ,  C07C2/62 ,  C07C31/12 ,  C07C31/125 ,  C07C29/50

Abstract: Systems and methods are provided for forming alkylate from an isoparaffin-containing feed. Olefins for the alkylation reaction can be generated from a portion of the isoparaffin-containing feed. This can be achieved, for example, by using selective oxidation to convert a portion of isoparaffins into alcohol, such as conversion of isobutane to t-butyl alcohol. The alcohol can then be converted to an alkene, such as conversion of t-butyl alcohol to isobutene, in the alkylation reaction environment in the presence of a solid acid catalyst. The solid acid catalyst can then facilitate alkylation of isoparaffin using the in-situ formed alkenes. A catalyst having an MWW framework is an example of a suitable solid acid catalyst.

公开(公告)号：US20170368540A1

公开(公告)日：2017-12-28

申请号：US15610700

申请日：2017-06-01

Applicant: ExxonMobil Research and Engineering Company

Inventor： Matthew S. METTLER ,  Jihad M. DAKKA ,  Ivy D. JOHNSON ,  Stefani PRIGOZHINA ,  Charles M. SMITH ,  William W. LONERGAN ,  Brett LOVELESS ,  Christine N. ELIA ,  Wenyih F. LAI

IPC: B01J29/70 ,  C07C2/62 ,  B01J29/035 ,  B01J29/18

CPC classification number: B01J29/7038 ,  B01J29/035 ,  B01J29/18 ,  B01J35/026 ,  B01J37/0018 ,  B01J37/06 ,  B01J37/08 ,  B01J2229/42 ,  C07C2/58 ,  C07C2/62 ,  C07C2521/04 ,  C07C2521/06 ,  C07C2521/08 ,  C07C2529/035 ,  C07C2529/18 ,  C07C2529/70 ,  C07C9/16

Abstract: In a process for the catalytic alkylation of an olefin with an isoparaffi, an olefin-containing feed is contacted with an isoparaffin-containing feed under alkylation conditions in the presence of a solid acid catalyst comprising a crystalline microporous material of at least one of the MWW and MOR framework types, wherein the solid acid catalyst is substantially free of amorphous alumina.

公开(公告)号：US20170297986A1

公开(公告)日：2017-10-19

申请号：US15455181

申请日：2017-03-10

Applicant: ExxonMobil Research and Engineering Company

Inventor： Anita S. LEE ,  Jihad M. DAKKA ,  Arun K. SHARMA ,  Michel DAAGE ,  Preeti KAMAKOTI ,  Ronald SURYO ,  Chuansheng BAI ,  J. Timothy CULLINANE

IPC: C07C41/09 ,  C01B3/34 ,  C07C29/151

CPC classification number: C07C41/09 ,  C01B3/34 ,  C01B2203/0216 ,  C01B2203/0233 ,  C01B2203/06 ,  C01B2203/061 ,  C07C29/151 ,  C07C41/01 ,  C07C43/043

Abstract: Integrated methods and systems are disclosed for the production of dimethyl ether. The method may include reforming natural gas to syngas in a first reactor; contacting the syngas produced in the first reactor with a catalyst system in a second reactor to produce dimethyl ether and carbon dioxide; and supplying steam as a cofeed to at least one of the first reactor and the second reactor in an amount sufficient to achieve a Mm value of 1.4 to 1.8 or to improve the hydrocarbon or oxygenate selectivity.

公开(公告)号：US20180170838A1

公开(公告)日：2018-06-21

申请号：US15834183

申请日：2017-12-07

Applicant: ExxonMobil Research and Engineering Company

Inventor： Guang CAO ,  Jihad M. DAKKA

IPC: C07C5/48 ,  C07C2/58 ,  C07C2/24

CPC classification number: C07C5/48 ,  C07C2/12 ,  C07C2/24 ,  C07C2/58 ,  C07C2523/28 ,  C07C2523/30 ,  C07C2523/72 ,  C07C2523/755 ,  C07C2529/068 ,  C07C2529/072 ,  C07C2529/40 ,  C07C2529/48 ,  C10G50/00 ,  C10G2400/02 ,  Y02P20/52 ,  C07C11/04 ,  C07C11/02

Abstract: A process for upgrading an ethane-containing C5− paraffin stream comprises contacting the paraffin stream with an oxygen containing gas in the presence of a selective oxidation catalyst under conditions to selectively oxidize at least part of the ethane in the paraffin stream and produce a first product stream comprising ethylene. At least part of the first product stream may then be contacted with an isoparaffin-containing feed in the presence of a solid alkylation catalyst and under conditions to alkylate at least part of the isoparaffin with at least part of the ethylene and produce a second product stream comprising C6+ alkylate. Alternatively, at least part of the ethylene in the first product stream may be dimerized before the alkylation step.

公开(公告)号：US20180162787A1

公开(公告)日：2018-06-14

申请号：US15839937

申请日：2017-12-13

Applicant: ExxonMobil Research and Engineering Company

Inventor： Jihad M. DAKKA ,  Matthew S. IDE ,  David B. SPRY ,  Sumod KALAKKUNNATH ,  Guang CAO ,  Patrick L. HANKS ,  Cynthia F. OMILIAN

IPC: C07C2/86 ,  C07C2/62 ,  C07C31/12 ,  C07C31/125 ,  C07C29/50

Abstract: Systems and methods are provided for production of high octane hydrocarbon from an isoparaffin feed using oxidation acid catalysis chemistry.

公开(公告)号：US20170369394A1

公开(公告)日：2017-12-28

申请号：US15610729

申请日：2017-06-01

Applicant: ExxonMobil Research and Engineering Company

Inventor： Jihad M. DAKKA ,  Matthew S. METTLER ,  Charles M. SMITH ,  Ivy D. JOHNSON ,  Jeffrey M. FITT

IPC: C07C2/58 ,  B01J37/06 ,  C07C7/00 ,  C10L10/10 ,  C10L1/16 ,  B01J29/70 ,  B01J37/00 ,  B01J37/08

CPC classification number: C07C2/58 ,  B01J29/7038 ,  B01J35/026 ,  B01J37/0018 ,  B01J37/06 ,  B01J37/08 ,  B01J2229/42 ,  C07C7/00 ,  C07C2521/04 ,  C07C2521/08 ,  C07C2529/70 ,  C10L1/1608 ,  C10L10/10 ,  C10L2270/023 ,  C07C9/21 ,  C07C9/16

Abstract: A process for the catalytic alkylation of an olefin with an isoparaffin comprises contacting an olefin-containing feed with an isoparaffin-containing feed under alkylation conditions in a reaction zone containing a fixed bed of a solid acid catalyst comprising a crystalline microporous material of the MWW framework type, wherein the reaction zone contains at least 100 kg of the catalyst and the catalyst has a cycle length of at least 150 days.

公开(公告)号：US20170369396A1

公开(公告)日：2017-12-28

申请号：US15610745

申请日：2017-06-01

Applicant: ExxonMobil Research and Engineering Company

Inventor： Jihad M. DAKKA ,  Matthew S. METTLER ,  Jeffrey M. FITT ,  Ivy D. JOHNSON ,  Charles M. SMITH

IPC: C07C2/58 ,  B01J29/70 ,  C10L1/16 ,  C10L10/10 ,  B01J37/00 ,  B01J37/08

CPC classification number: C07C2/58 ,  B01J29/7038 ,  B01J35/026 ,  B01J37/0018 ,  B01J37/06 ,  B01J37/08 ,  B01J2229/42 ,  C07C2521/04 ,  C07C2521/08 ,  C07C2529/70 ,  C10L1/1608 ,  C10L10/10 ,  C10L2270/023 ,  Y02P20/588 ,  C07C9/16 ,  C07C9/21

Abstract: In a process for isoparaffin-olefin alkylation, a feed comprising at least one olefin and at least one isoparaffin is contacted under alkylation conditions in the presence of a solid acid catalyst comprising a crystalline microporous material of the MWW framework type to produce an alkylated product. The alkylated product comprises a C8− fraction, which is useful as a gasoline blending stock, and a C9+ fraction, which is separated from the alkylated product and at least partially recycled to the alkylation step.

公开(公告)号：US20170369393A1

公开(公告)日：2017-12-28

申请号：US15610717

申请日：2017-06-01

Applicant: ExxonMobil Research and Engineering Company

Inventor： Jihad M. DAKKA ,  Matthew S. METTLER ,  Charles M. SMITH ,  Ivy D. JOHNSON ,  Jeffrey M. FITT ,  Christopher M. DEAN

IPC: C07C2/58 ,  B01J37/00 ,  B01J29/70 ,  B01J37/08

CPC classification number: C07C2/58 ,  B01J29/7038 ,  B01J37/0018 ,  B01J37/08 ,  C07C2521/04 ,  C07C2529/70 ,  C07C9/16 ,  C07C9/21

Abstract: A process for the catalytic alkylation of an olefin with an isoparaffin comprises: contacting an olefin-containing feed with an isoparaffin-containing feed under alkylation conditions in the presence of a solid acid catalyst comprising a crystalline microporous material of the MWW framework type, wherein the olefin-containing feed comprises propylene and at least one other C4 to C12 olefin.

公开(公告)号：US20170369392A1

公开(公告)日：2017-12-28

申请号：US15610679

申请日：2017-06-01

Applicant: ExxonMobil Research and Engineering Company

Inventor： Vinit CHOUDHARY ,  Jihad M. DAKKA ,  Matthew S. METTLER ,  Ivy D. JOHNSON ,  Joshua W. ALLEN ,  Ajit B. DANDEKAR ,  Cynthia F. OMILIAN

IPC: C07C2/58 ,  B01J37/06 ,  B01J37/08 ,  C10L10/10 ,  B01J29/70 ,  B01J37/00 ,  C10L1/16

CPC classification number: C07C2/58 ,  B01J29/7038 ,  B01J37/0018 ,  B01J37/06 ,  B01J37/08 ,  C07C2/62 ,  C07C2521/04 ,  C07C2529/70 ,  C10L1/1608 ,  C10L10/10 ,  C10L2270/023 ,  C07C9/16 ,  C07C9/21

Abstract: In a process for the catalytic alkylation of an olefin with an isoparaffin, an olefin-containing feed is contacted with an isoparaffin-containing feed under alkylation conditions in the presence of a solid acid catalyst comprising a crystalline microporous material of the MWW framework types, wherein the olefin-containing feed consists essentially of pentenes.