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公开(公告)号:US20200181525A1
公开(公告)日:2020-06-11
申请号:US16708793
申请日:2019-12-10
Applicant: ExxonMobil Research and Engineering Company
Inventor: Douglas E. Deckman , Andrew E. Taggi , Mark P. Hagemeister , Andrew D. Satterfield
IPC: C10M169/02 , C10M101/00 , C10M105/04 , C10M105/32 , C10M107/10 , C10M119/12
Abstract: Provided is a method for improving oxidation resistance and deposit resistance of a lubricating oil for use in lubricating a mechanical component. The method includes the step of providing the lubricating oil to the mechanical component and measuring the improved oxidation and deposit resistance. The lubricating oil includes a lubricating oil base stock at from 0 to 80 wt %, at least one branched isoparaffin having a mole % of epsilon carbon as measured by C13 NMR of less than or equal to 10% at from 20 to 80 wt %, at least one viscosity modifier at from 5 to 20 wt %, and one or more other lubricating oil additives. The oxidation resistance in the CEC L-109 oxidation resistance test is improved to greater than 310 hours to achieve a 100% viscosity increase and the deposit resistance in the TEOST 33C is improve to total deposits of less than 45 mg as compared to oxidation resistance and deposit resistance achieved using a lubricating oil not containing the at least one branched isoparaffin.
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公开(公告)号:US10233403B2
公开(公告)日:2019-03-19
申请号:US15384443
申请日:2016-12-20
Applicant: ExxonMobil Research and Engineering Company
Inventor: Abhimanyu O. Patil , Satish Bodige , Stephen Zushma , Kyle G. Lewis , Mark P. Hagemeister
IPC: C10M129/70 , C10M105/34
Abstract: A composition including one or more monomethyl ester compounds represented by the formula: R1 is a monomethyl branched C15 to C19 alkyl group and R2 is an unsubstituted C2 to C30 linear alkyl group. The composition has a viscosity (Kv100) from 1 cSt to 10 cSt at 100° C. as determined by ASTM D445, a viscosity index (VI) from −100 to 300 as determined by ASTM D2270, a pour point from 0° C. to −50° C. as determined by ASTM D97, and a Noack volatility of no greater than 50 percent as determined by ASTM D5800. A process for producing the composition, a lubricating oil base stock and lubricating oil containing the composition, and a method for improving one or more of cold flow properties, thermal and oxidative stability, solubility and dispersancy of polar additives, deposit control and traction control in a lubricating oil by using as the lubricating oil a formulated oil containing the composition.
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3.
公开(公告)号:US09422498B2
公开(公告)日:2016-08-23
申请号:US14630065
申请日:2015-02-24
Applicant: ExxonMobil Research and Engineering Company
Inventor: Abhimanyu O. Patil , Satish Bodige , Mark P. Hagemeister
IPC: C08K5/01 , C10M135/24 , C07F7/04 , C07C321/00 , C10M105/72
CPC classification number: C10M105/72 , C10M2205/0285 , C10M2219/022 , C10M2219/024 , C10M2219/081 , C10M2219/082 , C10M2219/085 , C10M2219/086 , C10M2219/09 , C10N2220/022 , C10N2230/02 , C10N2230/08 , C10N2230/70 , C10N2230/74
Abstract: A composition containing one or more sulfur-containing compounds represented by the formula (R1)a(X)(R2)b wherein R1 and R2 are the same or different and are the residue of an olefin (e.g., vinyl ether, acrylate, methacrylate, or vinyl ester) having from 4 to 40 carbon atoms, X is the residue of a thiol or polythiol, a is a value from 1 to 6, and b is a value from 0 to 6. The composition has a kinematic viscosity at 100° C. (Kv100) from 2 to 300 cst, a kinematic viscosity at 40° C. (Kv40) from 5 to 4000 cst, a viscosity index (VI) from −100 to 300, and a Noack volatility of no greater than 90 percent. A process for producing the composition, a lubricating oil base stock and lubricating oil containing the composition, and a method for improving one or more of solubility and dispersancy of polar additives in a lubricating oil containing the composition.
Abstract translation: 含有一种或多种式(R1)a(X)(R2)b表示的含硫化合物的组合物,其中R 1和R 2相同或不同,为烯烃的残基(例如乙烯基醚,丙烯酸酯,甲基丙烯酸酯 或乙烯基酯),X是硫醇或多硫醇的残基,a是1至6的值,b是0至6的值。该组合物的运动粘度为100 ℃(Kv100)为2〜300cst,40℃下的运动粘度(Kv40)为5〜4000cst,粘度指数(VI)为-100〜300,Noack挥发度为90以下 百分。 一种制备该组合物的方法,含有该组合物的润滑油基础油和润滑油,以及一种改善极性添加剂在含有该组合物的润滑油中的溶解度和分散性中的一种或多种的方法。
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公开(公告)号:US20180273870A1
公开(公告)日:2018-09-27
申请号:US15928996
申请日:2018-03-22
Applicant: ExxonMobil Research and Engineering Company
Inventor: Raymond G. Burns, III , Smruti A. Dance , Douglas E. Deckman , Mark P. Hagemeister
IPC: C10M105/36 , C10M101/02 , C10M105/34 , C10M105/04 , C10M107/10
Abstract: A method for improving fuel efficiency and energy efficiency, while maintaining or improving deposit control and cleanliness performance, in an engine lubricated with a lubricating oil by using as the lubricating oil a formulated oil. The formulated oil includes a base oil mixture. The base oil mixture includes a lubricating oil base stock as a major component, and at least one cobase stock, as a minor component. The at least one cobase stock is present in an amount sufficient to reduce kinematic viscosity (Kv100) of the base oil mixture as determined by ASTM D445, while maintaining or controlling cold cranking simulator viscosity (CCSV) of the lubricating oil as determined by ASTM D5293-15, such that the lubricating oil meets both kinematic viscosity (Kv100) and cold cranking simulator viscosity (CCSV) requirements for a SAE engine oil grade as determined by SAE J300 viscosity grade classification system. A lubricating oil having a composition including a lubricating oil base stock as a major component, and at least one cobase stock, as a minor component.
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公开(公告)号:US10077409B2
公开(公告)日:2018-09-18
申请号:US15384421
申请日:2016-12-20
Applicant: ExxonMobil Research and Engineering Company
Inventor: Man Kit Ng , Halou Oumar-Mahamat , Hong Cheng , David A. Blain , Kathleen K. Cooper , James T. Carey , Michael R. Douglass , Percy R. Kanga , Abhimanyu O. Patil , Satish Bodige , Kyle G. Lewis , Mark P. Hagemeister
IPC: C10M105/34 , C07C69/26
CPC classification number: C10M105/34 , C07C69/24 , C07C69/26 , C07C69/28 , C07C69/708 , C10M111/02 , C10M129/70 , C10M129/95 , C10M2203/024 , C10M2207/281 , C10M2207/2815 , C10M2207/284 , C10M2207/2845 , C10M2207/34 , C10M2207/345 , C10N2230/02 , C10N2230/04 , C10N2230/06 , C10N2230/10 , C10N2230/12 , C10N2230/14 , C10N2230/18 , C10N2230/36 , C10N2230/54 , C10N2230/74 , C10N2240/10
Abstract: A lubricating oil base stock including one or more monoesters represented by the formula (I), (II), (III) and (IV) as defined herein. The lubricating oil base stock has a high temperature high shear (HTHS) viscosity of less than about 1.7 cP as determined by ASTM D4683, and a Noack volatility from about 15 to about 90 percent as determined by ASTM D5800. A lubricating oil containing the lubricating oil base stock including one or more monoesters represented by the formula (I), (II), (III) and (IV) as defined herein. A method for improving one or more of thermal and oxidative stability, solubility and dispersancy of polar additives, deposit control and traction control in a lubricating oil by using as the lubricating oil a formulated oil containing the lubricating oil base stock including one or more monoesters represented by the formula (I), (II), (III) and (IV) as defined herein.
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公开(公告)号:US10738258B2
公开(公告)日:2020-08-11
申请号:US15928996
申请日:2018-03-22
Applicant: ExxonMobil Research and Engineering Company
Inventor: Raymond G. Burns, III , Smruti A. Dance , Douglas E. Deckman , Mark P. Hagemeister
IPC: C10M105/36 , C10M101/02 , C10M105/34 , C10M105/04 , C10M107/10 , C10M169/04 , C10M171/02 , C10M111/02
Abstract: A method for improving fuel efficiency and energy efficiency, while maintaining or improving deposit control and cleanliness performance, in an engine lubricated with a lubricating oil by using as the lubricating oil a formulated oil. The formulated oil includes a base oil mixture. The base oil mixture includes a lubricating oil base stock as a major component, and at least one cobase stock, as a minor component. The at least one cobase stock is present in an amount sufficient to reduce kinematic viscosity (Kv100) of the base oil mixture as determined by ASTM D445, while maintaining or controlling cold cranking simulator viscosity (CCSV) of the lubricating oil as determined by ASTM D5293-15, such that the lubricating oil meets both kinematic viscosity (Kv100) and cold cranking simulator viscosity (CCSV) requirements for a SAE engine oil grade as determined by SAE J300 viscosity grade classification system. A lubricating oil having a composition including a lubricating oil base stock as a major component, and at least one cobase stock, as a minor component.
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7.
公开(公告)号:US09422499B2
公开(公告)日:2016-08-23
申请号:US14630022
申请日:2015-02-24
Applicant: ExxonMobil Research and Engineering Company
Inventor: Abhimanyu O. Patil , Satish Bodige , Mark P. Hagemeister
IPC: C07F7/08 , C07C69/34 , C08K5/01 , C10M135/22 , C07F7/04 , C07C319/00 , C10M105/76 , C10M105/72 , C07C321/20 , C07F7/18 , C10M135/04 , C10M135/24 , C10M135/26 , C10M135/28 , C10M135/30 , C10M139/04 , C10M159/12 , C10M177/00
CPC classification number: C10M105/76 , C07C321/20 , C07F7/1804 , C10M105/72 , C10M135/04 , C10M135/22 , C10M135/24 , C10M135/26 , C10M135/28 , C10M135/30 , C10M139/04 , C10M159/12 , C10M177/00 , C10M2219/02 , C10M2219/021 , C10M2219/022 , C10M2227/04 , C10M2227/045 , C10N2220/021 , C10N2220/022 , C10N2230/02 , C10N2230/04 , C10N2230/70 , C10N2230/74 , C10N2270/00
Abstract: A composition containing one or more sulfur-containing compounds represented by the formula (R1)a(X)(R2)b wherein R1 and R2 are the same or different and are the residue of an olefin (e.g., aliphatic, aromatic or cycloaliphatic olefin) having from 4 to 40 carbon atoms, X is the residue of a thiol or polythiol, a is a value from 1 to 6, and b is a value from 0 to 6. The composition has a kinematic viscosity at 100° C. (Kv100) from 2 to 300 cst, a kinematic viscosity at 40° C. (Kv40) from 5 to 4000 cst, a viscosity index (VI) from −100 to 300, and a Noack volatility of no greater than 90 percent. A process for producing the composition, a lubricating oil base stock and lubricating oil containing the composition, and a method for improving one or more of solubility and dispersancy of polar additives in a lubricating oil containing the composition.
Abstract translation: 含有一种或多种式(R1)a(X)(R2)b表示的含硫化合物的组合物,其中R 1和R 2相同或不同,并且是烯烃的残基(例如脂族,芳族或脂环族烯烃 ),X是硫醇或多硫醇的残基,a是1至6的值,b是0至6的值。该组合物在100℃下具有运动粘度( Kv100)为2〜300cst,40℃下的运动粘度(Kv40)为5〜4000cst,粘度指数(VI)为-100〜300,Noack挥发度为90%以下。 一种制备该组合物的方法,含有该组合物的润滑油基础油和润滑油,以及一种改善极性添加剂在含有该组合物的润滑油中的溶解度和分散性中的一种或多种的方法。
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8.
公开(公告)号:US20200024538A1
公开(公告)日:2020-01-23
申请号:US16519039
申请日:2019-07-23
Applicant: ExxonMobil Research and Engineering Company
Inventor: Douglas E. Deckman , Smruti A. Dance , Mark P. Hagemeister , Luca Salvi , Nicole Wallace
IPC: C10M105/68 , C10M105/38 , C10M105/06
Abstract: A method for improving oxidative stability of a lubricating oil in a diesel engine, in which biodiesel fuel is used with diesel fuel in the diesel engine, by using as the lubricating oil a formulated oil. The formulated oil has a composition including at least one Group V lubricating oil base stock. The at least one Group V lubricating oil base stock is present in an amount from 1 to 75 weight percent, based on the total weight of the lubricating oil. Oxidative stability is improved in a diesel engine lubricated with the lubricating oil, as compared to oxidative stability achieved in a diesel engine lubricated with a lubricating oil not having the at least one Group V lubricating oil base stock, as determined by a CEC L-109-16 Bio-Diesel Oxidation Bench test. The lubricating oils are useful as passenger vehicle engine oil (PVEO) products or commercial vehicle engine oil (CVEO) products.
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9.
公开(公告)号:US20180119045A1
公开(公告)日:2018-05-03
申请号:US15384443
申请日:2016-12-20
Applicant: ExxonMobil Research and Engineering Company
Inventor: Abhimanyu O. Patil , Satish Bodige , Stephen Zushma , Kyle G. Lewis , Mark P. Hagemeister
IPC: C10M129/70
CPC classification number: C10M129/70 , C10M105/34 , C10M2203/024 , C10M2203/1006 , C10M2203/1025 , C10M2205/0285 , C10M2205/173 , C10M2207/281 , C10M2207/2815 , C10M2207/2845 , C10N2220/022 , C10N2220/028 , C10N2230/02 , C10N2230/04 , C10N2230/10 , C10N2230/70 , C10N2230/74 , C10N2240/04 , C10N2240/10
Abstract: A composition including one or more monomethyl ester compounds represented by the formula: R1 is a monomethyl branched C15 to C19 alkyl group and R2 is an unsubstituted C2 to C30 linear alkyl group. The composition has a viscosity (Kv100) from 1 cSt to 10 cSt at 100° C. as determined by ASTM D445, a viscosity index (VI) from −100 to 300 as determined by ASTM D2270, a pour point from 0° C. to −50° C. as determined by ASTM D97, and a Noack volatility of no greater than 50 percent as determined by ASTM D5800. A process for producing the composition, a lubricating oil base stock and lubricating oil containing the composition, and a method for improving one or more of cold flow properties, thermal and oxidative stability, solubility and dispersancy of polar additives, deposit control and traction control in a lubricating oil by using as the lubricating oil a formulated oil containing the composition.
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公开(公告)号:US20210230653A1
公开(公告)日:2021-07-29
申请号:US17142771
申请日:2021-01-06
Applicant: ExxonMobil Research and Engineering Company
Inventor: Christopher M. Flynn , Mark P. Hagemeister
IPC: C12P7/64 , C12N9/10 , C12N9/06 , C07C69/34 , C10M105/34
Abstract: The present disclosure provides processes for producing alkylated fatty acids and derivatives thereof. In at least one embodiment, a process includes introducing a terminal alkyl transferase and a fatty acid into a bioreactor. The process includes introducing an internal methyl transferase and internal methyl reductase into the bioreactor or a second bioreactor. The process includes obtaining an alkylated fatty acid having a methyl substituent located at an internal carbon atom of the fatty acid and a methyl substituent or ethyl substituent located at a carbon atom alpha to the terminal carbon atom of the fatty acid.
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