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1.
公开(公告)号:US12053738B2
公开(公告)日:2024-08-06
申请号:US17537654
申请日:2021-11-30
Applicant: ExxonMobil Technology and Engineering Company , BASF
Inventor: Carla S. Pereira , Michael Siskin , Thomas Ingram , Gerald Vorberg , Martin Ernst
CPC classification number: B01D53/1493 , B01D53/1425 , B01D53/1468 , B01D53/18 , C10L3/10 , C10L3/103 , B01D2252/204 , B01D2252/20431 , B01D2252/20478 , B01D2252/20489 , B01D2257/304 , B01D2257/504 , C10L2290/542 , Y02C20/40
Abstract: A process for selectively separating H2S from a gas mixture which also comprises CO2 is disclosed. A stream of the gas mixture is contacted with an absorbent solution comprising one or more amines, alkanolamines, hindered alkanolamines, capped alkanolamines, or mixtures thereof. The H2S/CO2 selectivity of the absorbent solution is preferably greater than about 4.0 for an acid gas loading [mol(CO2+H2S)/mol(amine)] between about 0.2 and about 0.6, and is achieved by reducing pH of the absorbent solution.
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2.
公开(公告)号:US20230226483A1
公开(公告)日:2023-07-20
申请号:US18002519
申请日:2021-07-06
Inventor: Carla S. Pereira , Jenny P. Seagraves , P. Scott Northrop , Michael Siskin , Thomas Ingram , Gerald Vorberg , Martin Ernst , Georg K. Sieder
CPC classification number: B01D53/1425 , B01D53/1468 , B01D53/1493 , B01D53/1475 , B01D53/52 , B01D53/62 , B01D53/78 , B01D53/96 , B01D2257/304 , B01D2257/504 , B01D2252/2041 , B01D2252/20405 , B01D2252/20426 , B01D2252/20452 , B01D2252/20468 , B01D2252/20484 , B01D2252/60
Abstract: Capture of hydrogen sulfide from a gas mixture may be accomplished using an aqueous solution comprising an amine. Certain sterically hindered amines may selectively form a reaction product with hydrogen sulfide under kinetically controlled contacting conditions and afford a light phase and a heavy phase above a critical solution temperature, wherein the hydrogen sulfide may be present in either phase. Upon separation of the light phase from the heavy phase, processing of one of the phases may take place to remove hydrogen sulfide therefrom. Recycling of the amine to an absorber tower may then take place to promote capture of additional hydrogen sulfide.
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公开(公告)号:US11512040B2
公开(公告)日:2022-11-29
申请号:US17257080
申请日:2019-07-02
Applicant: BASF SE , BASF CORPORATION , THE REGENTS OF THE UNIVERSITY OF CALIFORNIA
Inventor: Martin Ernst , Stephan Zuend , Bo Su , Ala Bunescu , John F. Hartwig
IPC: C07C213/00
Abstract: A process for the preparation of amino alcohols includes condensing a compound of Formula (II), a stereoisomer, a tautomer, or a salt thereof with a compound of Formula (IIIa) or Formula (IIIb), a stereoisomer, a tautomer, or a salt thereof to form a condensation product; hydroxylating or acyloxylating the condensation product in the presence of an oxidant to obtain a hydroxylation or acyloxylation product; and subjecting the hydroxylation or acyloxylation product to one or more subsequent reactions comprising a hydrolysis reaction, alcohol deprotection, an amino lysis reaction, or a combination of two or more thereof to obtain an amino alcohol of Formula (I).
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公开(公告)号:US12275019B2
公开(公告)日:2025-04-15
申请号:US17606997
申请日:2020-04-27
Applicant: BASF SE
Inventor: Alexej Michailovski , Alexander Panchenko , Hannes Ferdinand Zipfel , Martin Ernst , Gabriela Budemberg , Stefanov Nedko Drebov , Sylvia von Krog , Tamara Kuelzer , Long Phan
IPC: B03D1/01 , C07C215/18
Abstract: The invention relates to a method for manufacturing a concentrate enriched in iron mineral content from an ore, which contains an iron mineral and silicate, by reverse flotation, which method comprises the step of (c) adding a compound of formula I wherein R1 is C9-C22 alkyl or alkenyl, which is linear or branched, R2 is H, C1-C4 alkyl, which is linear or branched, R3 is —X—NH2, H or C1-C4 alkyl, which is linear or branched, and X is C2-C4 alkylene, which is linear or branched, or a salt of a protonated compound of formula I and an anion, to a prepared aqueous pulp of the ore and optionally one or more flotation auxiliaries to obtain an aqueous mixture. Furthermore, a method for manufacturing a specific group of compounds of formula I, i.e. compounds of formula 1-X wherein R1 is C9-C15 alkyl, which is linear or branched, R2 is H, R3 is —X—NH2 and X is C2-C4 alkylene, which is linear or branched, is disclosed.
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公开(公告)号:US20220212204A1
公开(公告)日:2022-07-07
申请号:US17606997
申请日:2020-04-27
Applicant: BASF SE
Inventor: Alexej Michailovski , Alexander Panchenko , Hannes Ferdinand Zipfel , Martin Ernst , Gabriela Budemberg , Stefanov Nedko Drebov , Sylvia von Krog , Tamara Kuelzer , Long Phan
IPC: B03D1/01 , C07C215/18
Abstract: The invention relates to a method for manufacturing a concentrate enriched in iron mineral content from an ore, which contains an iron mineral and silicate, by reverse flotation, which method comprises the step of (c) adding a compound of formula I wherein R1 is C9-C22 alkyl or alkenyl, which is linear or branched, R2 is H, C1-C4 alkyl, which is linear or branched, R3 is —X—NH2, H or C1-C4 alkyl, which is linear or branched, and X is C2-C4 alkylene, which is linear or branched, or a salt of a protonated compound of formula I and an anion, to a prepared aqueous pulp of the ore and optionally one or more flotation auxiliaries to obtain an aqueous mixture. Furthermore, a method for manufacturing a specific group of compounds of formula I, i.e. compounds of formula 1-X wherein R1 is C9-C15 alkyl, which is linear or branched, R2 is H, R3 is —X—NH2 and X is C2-C4 alkylene, which is linear or branched, is disclosed.
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公开(公告)号:US10889683B2
公开(公告)日:2021-01-12
申请号:US16463186
申请日:2017-12-04
Applicant: BASF SE
Inventor: Christian Gruenanger , Alexander Panchenko , Irene Gorman , Veit Stegmann , Johann-Peter Melder , Norbert Gutfrucht , Martin Ernst , Marc Hofmann
IPC: C08G59/50 , C07C209/26 , C07C209/84 , C07C211/36
Abstract: The present invention relates to the polyamines N,N′-diaminopropyl-2-methyl-cyclohexane-1,3-diamine and N,N′-diaminopropyl-4-methyl-cyclohexane-1,3-diamine and mixtures thereof, to the use thereof as curing agents for epoxy resin and to a curable composition comprising epoxy resin and these polyamines. Even at low temperatures this curing agent/the corresponding curable composition cures rapidly and is early-stage water resistant and is thus especially suitable for floor coatings. The invention further relates to the curing of this composition and the cured epoxy resin obtained by curing of this composition.
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公开(公告)号:US12162842B2
公开(公告)日:2024-12-10
申请号:US17617335
申请日:2020-06-02
Applicant: BASF SE
Inventor: Martin Ernst , Tatjana Huber , Johann-Peter Melder , Stephanie Jaegli , Thomas Krug
IPC: C07C29/154 , C07C209/16 , C07C209/26 , C07C209/62 , C07C209/84 , C07C213/02 , C07C213/04 , C07C213/08 , C07C213/10 , C07D251/04
Abstract: A process for the conversion of glycolaldehyde with an aminating agent in the presence of hydrogen and of a catalyst in a glycolaldehyde conversion reactor, wherein one or more organic carboxylic acids are fed into the glycolaldehyde conversion reactor.
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公开(公告)号:US12138583B2
公开(公告)日:2024-11-12
申请号:US17431872
申请日:2020-02-14
Applicant: BASF SE
Inventor: Martin Ernst , Thomas Ingram , Gerald Vorberg , Georg Sieder
IPC: B01D53/14 , C07D295/13 , C10L3/10
Abstract: A process for removal of acid gases from fluid stream, wherein the fluid stream is brought into contact with an absorbent to obtain a treated fluid stream and a laden absorbent, the absorbent comprising a diluent and a compound of the general formula (I) wherein R1 is selected from C1-C8-alkyl and C2-C8-hydroxyalkyl; R2 is selected from hydrogen and C1-C8-alkyl; R3 is selected from hydrogen and C1-C8-alkyl; R4 is selected from hydrogen and C1-C8-alkyl; R5 is C1-C8-alkyl; with the proviso that at least one of the following conditions (i) and (ii) is met: (i) R5 is C3-C8-alkyl bound to the nitrogen atom via a secondary or tertiary carbon atom; (ii) when R4 is hydrogen, R3 is C1-C8-alkyl; or when R4 is C1-C8-alkyl, at least one of R2 and R3 is C1-C8-alkyl; and n is an integer from 0 to 6. Further provided is an absorbent for the absorption of acid gases from a fluid stream, comprising a diluent and a compound of the general formula (I) as defined above, as well as the use of a compound of the general formula (I) as defined above for removal of acid gases from a fluid stream. The absorbents are useful for the selective removal of hydrogen sulfide from fluid streams and have high acid gas loading capacity, high stability, and low volatility.
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公开(公告)号:US20220402871A1
公开(公告)日:2022-12-22
申请号:US17819695
申请日:2022-08-15
Applicant: BASF SE
Inventor: Thomas SCHAUB , Martin Ernst , Pilar Calleja , A. Stephen K. Hashmi
IPC: C07D211/58 , C07C213/02 , C07C231/12 , C07C253/30
Abstract: A process for producing a compound of the formula (I) involves at least reacting a compound of the formula (II) with hydrogen and water in the presence of at least one homogeneous transition metal catalyst TMC 1.
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公开(公告)号:US11173446B2
公开(公告)日:2021-11-16
申请号:US16484860
申请日:2018-02-09
Applicant: BASF SE , ExxonMobil Research and Engineering Company
Inventor: Thomas Ingram , Martin Ernst , Gerald Vorberg , Alexander Panchenko , Sophia Ebert , Thomas Wesley Holcombe , Michael Siskin , Carla Pereira , Georg Sieder
Abstract: In a process for removal of acid gases from a fluid stream the fluid stream is contacted with an absorbent to obtain a treated fluid stream and a laden absorbent. The absorbent comprises a diluent and a compound of the general formula (I) wherein R1 is C1-C3-alkyl; R2 is C1-C3-alkyl; R3 is selected from hydrogen and C1-C3-alkyl; and R4 is selected from hydrogen and C1-C3-alkyl.
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