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1.发明授权Method for providing a co-feed in the coupling of toluene with a carbon source 有权在甲苯与碳源的偶合中提供共进料的方法公开(公告)号：US08969642B2
公开(公告)日：2015-03-03
申请号：US14105381
申请日：2013-12-13
Applicant: Fina Technology, Inc.
Inventor： Joseph E. Pelati , James R. Butler , Sivadinarayana Chinta
Abstract: A process for making styrene is disclosed that includes reacting toluene with a C1 source and a co-feed in the presence of a catalyst in a reactor to form a first product stream comprising styrene, ethylbenzene, carbon monoxide, and hydrogen; separating the hydrogen and carbon monoxide from the first product stream to form a second stream; separating the hydrogen from the second stream to form a third stream comprising hydrogen and a fourth stream comprising carbon monoxide; wherein the fourth stream is recycled to the reactor and forms at least a portion of the co-feed.
Abstract translation: 公开了一种制备苯乙烯的方法，其包括在反应器中在催化剂存在下使甲苯与C1源和共进料反应以形成包含苯乙烯，乙苯，一氧化碳和氢的第一产物流; 将氢和一氧化碳与第一产物流分离以形成第二流; 从第二流分离氢气以形成包含氢的第三料流和包含一氧化碳的第四料流; 其中第四料流被再循环到反应器中并形成共进料的至少一部分。
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公开(公告)号：US08796498B2
公开(公告)日：2014-08-05
申请号：US14093667
申请日：2013-12-02
Applicant: Fina Technology, Inc.
Inventor： James R. Butler , Joseph E. Pelati
CPC classification number: C07C2/867 , C07C1/2076 , C07C15/46 , C07C45/002 , C07C45/32 , C07C45/38 , C07C2521/04 , C07C2521/06 , C07C2521/08 , C07C2523/02 , C07C2523/04 , C07C2523/06 , C07C2523/10 , C07C2523/20 , C07C2523/22 , C07C2523/24 , C07C2523/34 , C07C2523/42 , C07C2523/44 , C07C2523/46 , C07C2523/72 , C07C2523/75 , C07C2523/755 , C07C2523/80 , C07C2523/86 , C07C2527/047 , C07C2527/049 , C07C2527/051 , C07C2529/06 , C07C2529/40 , Y02P30/42 , C07C47/04
Abstract: A process is disclosed for making styrene by converting methanol to formaldehyde in a reactor then reacting the formaldehyde with toluene to form styrene in a separate reactor.
Abstract translation: 公开了一种通过在反应器中将甲醇转化成甲醛来制造苯乙烯的方法，然后使甲醛与甲苯反应，在单独的反应器中形成苯乙烯。
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公开(公告)号：US20140094631A1
公开(公告)日：2014-04-03
申请号：US14093667
申请日：2013-12-02
Applicant: FINA TECHNOLOGY, INC.
Inventor： James R. Butler , Joseph E. Pelati
IPC: C07C1/207
CPC classification number: C07C2/867 , C07C1/2076 , C07C15/46 , C07C45/002 , C07C45/32 , C07C45/38 , C07C2521/04 , C07C2521/06 , C07C2521/08 , C07C2523/02 , C07C2523/04 , C07C2523/06 , C07C2523/10 , C07C2523/20 , C07C2523/22 , C07C2523/24 , C07C2523/34 , C07C2523/42 , C07C2523/44 , C07C2523/46 , C07C2523/72 , C07C2523/75 , C07C2523/755 , C07C2523/80 , C07C2523/86 , C07C2527/047 , C07C2527/049 , C07C2527/051 , C07C2529/06 , C07C2529/40 , Y02P30/42 , C07C47/04
Abstract: A process is disclosed for making styrene by converting methanol to formaldehyde in a reactor then reacting the formaldehyde with toluene to form styrene in a separate reactor.
Abstract translation: 公开了一种通过在反应器中将甲醇转化成甲醛来制造苯乙烯的方法，然后使甲醛与甲苯反应，在单独的反应器中形成苯乙烯。
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公开(公告)号：US20210146342A1
公开(公告)日：2021-05-20
申请号：US16687820
申请日：2019-11-19
Applicant: Fina Technology, Inc.
Inventor： Joseph E. Pelati
Abstract: An oxidation catalyst for the oxidation of styrene to benzaldehyde and acetophenone, the oxidation catalyst comprising: a porous support; and an active phase comprising an oxygen activation metal comprising cobalt (Co), manganese (Mn), iron (Fe), molybdenum (Mo), or a combination thereof. A method of forming the oxidation catalyst, a method of forming an oxidation product comprising benzaldehyde and acetophenone by contacting the oxidation catalyst with styrene and air in an oxidation reactor, and a system and method for reducing the fouling in a process for the production of styrene by introducing an additive stream comprising at least a portion of the oxidation product into a stream comprising styrene and byproduct divinyl benzene (DVB) are also disclosed.
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公开(公告)号：US09272962B2
公开(公告)日：2016-03-01
申请号：US14626746
申请日：2015-02-19
Applicant: FINA TECHNOLOGY, INC.
Inventor： James R. Butler , Joseph E. Pelati
CPC classification number: C07C2/867 , C07C1/2076 , C07C15/46 , C07C45/002 , C07C45/32 , C07C45/38 , C07C2521/04 , C07C2521/06 , C07C2521/08 , C07C2523/02 , C07C2523/04 , C07C2523/06 , C07C2523/10 , C07C2523/20 , C07C2523/22 , C07C2523/24 , C07C2523/34 , C07C2523/42 , C07C2523/44 , C07C2523/46 , C07C2523/72 , C07C2523/75 , C07C2523/755 , C07C2523/80 , C07C2523/86 , C07C2527/047 , C07C2527/049 , C07C2527/051 , C07C2529/06 , C07C2529/40 , Y02P30/42 , C07C47/04
Abstract: A process is disclosed for making styrene by converting methanol to formaldehyde in a reactor then reacting the formaldehyde with toluene to form styrene in a separate reactor.
Abstract translation: 公开了一种通过在反应器中将甲醇转化成甲醛来制造苯乙烯的方法，然后使甲醛与甲苯反应，在单独的反应器中形成苯乙烯。
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Patent Agency Ranking
公开(公告)号：US20140288340A1
公开(公告)日：2014-09-25
申请号：US14299395
申请日：2014-06-09
Applicant: FINA TECHNOLOGY, INC.
Inventor： James R. Butler , Joseph E. Pelati
IPC: C07C2/86
CPC classification number: C07C2/867 , C07C1/2076 , C07C15/46 , C07C45/002 , C07C45/32 , C07C45/38 , C07C2521/04 , C07C2521/06 , C07C2521/08 , C07C2523/02 , C07C2523/04 , C07C2523/06 , C07C2523/10 , C07C2523/20 , C07C2523/22 , C07C2523/24 , C07C2523/34 , C07C2523/42 , C07C2523/44 , C07C2523/46 , C07C2523/72 , C07C2523/75 , C07C2523/755 , C07C2523/80 , C07C2523/86 , C07C2527/047 , C07C2527/049 , C07C2527/051 , C07C2529/06 , C07C2529/40 , Y02P30/42 , C07C47/04
Abstract: A process is disclosed for making styrene by converting methanol to formaldehyde in a reactor then reacting the formaldehyde with toluene to form styrene in a separate reactor.
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公开(公告)号：US11179702B2
公开(公告)日：2021-11-23
申请号：US16687820
申请日：2019-11-19
Applicant: Fina Technology, Inc.
Inventor： Joseph E. Pelati
IPC: B01J23/75 , B01J23/28 , B01J23/34 , B01J23/745 , B01J35/10 , B01J37/02 , C07C45/28 , B01J21/12 , C07C47/54 , C07C49/78
Abstract: An oxidation catalyst for the oxidation of styrene to benzaldehyde and acetophenone, the oxidation catalyst comprising: a porous support; and an active phase comprising an oxygen activation metal comprising cobalt (Co), manganese (Mn), iron (Fe), molybdenum (Mo), or a combination thereof. A method of forming the oxidation catalyst, a method of forming an oxidation product comprising benzaldehyde and acetophenone by contacting the oxidation catalyst with styrene and air in an oxidation reactor, and a system and method for reducing the fouling in a process for the production of styrene by introducing an additive stream comprising at least a portion of the oxidation product into a stream comprising styrene and byproduct divinyl benzene (DVB) are also disclosed.
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8.发明申请公开(公告)号：US20150328609A1
公开(公告)日：2015-11-19
申请号：US14812184
申请日：2015-07-29
Applicant: FINA TECHNOLOGY, INC.
Inventor： James R. Butler , Joseph E. Pelati
CPC classification number: B01J4/001 , B01J4/002 , B01J23/78 , B01J2219/00024 , F17D1/06 , Y10T29/49718 , Y10T29/4973 , Y10T137/4891
Abstract: An apparatus and method for adding an alkali metal promoter into steam and contacting the solution with a dehydrogenation catalyst during a dehydrogenation reaction is disclosed. The apparatus has a first conduit capable of transporting an alkali metal salt solution and a second conduit in fluid communication with the first conduit, the second conduit capable of transporting steam so that the alkali metal salt is dissipated into the steam prior to entry into a dehydrogenation reaction zone.
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公开(公告)号：US20150158793A1
公开(公告)日：2015-06-11
申请号：US14626746
申请日：2015-02-19
Applicant: FINA TECHNOLOGY, INC.
Inventor： James R. Butler , Joseph E. Pelati
CPC classification number: C07C2/867 , C07C1/2076 , C07C15/46 , C07C45/002 , C07C45/32 , C07C45/38 , C07C2521/04 , C07C2521/06 , C07C2521/08 , C07C2523/02 , C07C2523/04 , C07C2523/06 , C07C2523/10 , C07C2523/20 , C07C2523/22 , C07C2523/24 , C07C2523/34 , C07C2523/42 , C07C2523/44 , C07C2523/46 , C07C2523/72 , C07C2523/75 , C07C2523/755 , C07C2523/80 , C07C2523/86 , C07C2527/047 , C07C2527/049 , C07C2527/051 , C07C2529/06 , C07C2529/40 , Y02P30/42 , C07C47/04
Abstract: A process is disclosed for making styrene by converting methanol to formaldehyde in a reactor then reacting the formaldehyde with toluene to form styrene in a separate reactor.
Abstract translation: 公开了一种通过在反应器中将甲醇转化成甲醛来制造苯乙烯的方法，然后使甲醛与甲苯反应以在单独的反应器中形成苯乙烯。
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公开(公告)号：US20150051063A1
公开(公告)日：2015-02-19
申请号：US14525456
申请日：2014-10-28
Applicant: FINA TECHNOLOGY, INC.
Inventor： Sivadinarayana Chinta , Joseph E. Pelati
IPC: B01J29/06
CPC classification number: B01J29/061 , B01J29/06 , B01J29/064 , B01J29/068 , B01J29/072 , B01J29/076 , B01J29/087 , B01J29/088 , B01J29/143 , B01J29/146 , B01J29/16 , B01J29/163 , B01J29/166 , B01J29/185 , B01J29/24 , B01J29/26 , B01J29/405 , B01J29/46 , B01J29/48 , B01J29/505 , B01J29/56 , B01J29/58 , B01J29/605 , B01J29/63 , B01J29/64 , B01J29/7053 , B01J29/7057 , B01J29/7088 , B01J29/7607 , B01J29/7615 , B01J29/7676 , B01J29/7807 , B01J29/7815 , B01J29/7876 , B01J29/90 , B01J35/0006 , B01J37/0009 , B01J37/0018 , B01J2229/20 , B01J2229/24 , B01J2229/26 , B01J2229/42 , C07C2/66 , C07C2521/04 , C07C2521/08 , C07C2523/02 , C07C2523/06 , C07C2523/14 , C07C2523/18 , C07C2523/22 , C07C2523/34 , C07C2523/72 , C07C2523/745 , C07C2523/75 , Y02P20/584 , Y02P20/588 , C07C15/073
Abstract: An alkylation catalyst having a zeolite catalyst component and a binder component providing mechanical support for the zeolite catalyst component is disclosed. The binder component is an ion-modified binder that can include metal ions selected from the group consisting of Co, Mn, Ti, Zr, V, Nb, K, Cs, Ga, B, P, Rb, Ag, Na, Cu, Mg, Fe, Mo, Ce, and combinations thereof The metal ions reduce the number of acid sites on the zeolite catalyst component. The metal ions can range from 0.1 to 50 wt % based on the total weight of the ion-modified binder. Optionally, the ion-modified binder is present in amounts ranging from 1 to 80 wt % based on the total weight of the catalyst.
Abstract translation: 公开了具有沸石催化剂组分和为沸石催化剂组分提供机械载体的粘合剂组分的烷基化催化剂。 粘合剂组分是可以包括选自Co，Mn，Ti，Zr，V，Nb，K，Cs，Ga，B，P，Rb，Ag，Na，Cu中的金属离子的离子改性粘合剂， Mg，Fe，Mo，Ce及其组合金属离子减少沸石催化剂组分上的酸性位数。 基于离子改性粘合剂的总重量，金属离子可以为0.1-50wt％。 任选地，基于催化剂的总重量，离子改性粘合剂的存在量为1至80重量％。
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