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    Catalyst for aromatization of lower hydrocarbons and process for production of aromatic compounds
    5.
    发明授权
    Catalyst for aromatization of lower hydrocarbons and process for production of aromatic compounds 有权
    用于低级烃芳构化的催化剂和用于生产芳族化合物的方法

    公开(公告)号：US08278237B2

    公开(公告)日：2012-10-02

    申请号：US12524029

    申请日：2008-02-13

    Applicant: Shinichi Yamada ,  Tomohiro Yamada ,  Yuji Ogawa ,  Hirokazu Akiyama ,  Takuya Hatagishi

    Inventor： Shinichi Yamada ,  Tomohiro Yamada ,  Yuji Ogawa ,  Hirokazu Akiyama ,  Takuya Hatagishi

    IPC: B01J29/06 ,  C07C2/52 ,  C07C15/00

    CPC classification number: C10G45/68 ,  B01J21/16 ,  B01J23/885 ,  B01J29/0308 ,  B01J29/041 ,  B01J29/076 ,  B01J29/40 ,  B01J29/48 ,  B01J29/7876 ,  B01J35/023 ,  B01J37/0201 ,  B01J37/088 ,  B01J37/18 ,  B01J2229/12 ,  B01J2229/123 ,  B01J2229/32 ,  B01J2229/40 ,  C01B3/40 ,  C01B2203/02 ,  C01B2203/1241 ,  C07C2/76 ,  C10G2400/30 ,  Y02P20/52 ,  C07C15/02

    Abstract: A catalyst for producing aromatic compounds from lower hydrocarbons while improving activity life stability of methane conversion rate; benzene formation rate; naphthalene formation rate; and total formation rate of benzene, toluene and xylene is formed by loading molybdenum and copper on metallo-silicate serving as a substrate and then calcining the metallo-silicate. When the catalyst is reacted with a reaction gas containing lower hydrocarbons and carbonic acid gas, aromatic compounds are produced. In order to obtain the catalyst, it is preferable that molybdenum and copper are loaded on zeolite formed of metallo-silicate after the zeolite is treated with a silane compound larger than a pore of the zeolite in diameter and having an amino group and a straight-chain hydrocarbon group, the amino group being able to selectively react with the zeolite at a Bronsted acid point of the zeolite. It is preferable that a loaded amount of molybdenum is within a range of from 2 to 12 wt. % based on total amount of the calcined catalyst while copper is loaded at a copper to molybdenum molar ratio of 0.01 to 0.8.

    Abstract translation: 一种用于从低级烃生产芳族化合物的催化剂，同时提高甲烷转化率的活性寿命稳定性; 苯形成率; 萘形成率; 苯，甲苯和二甲苯的总形成速率是通过将钼和铜负载在作为基底的金属硅酸盐上，然后煅烧金属硅酸盐而形成的。 当催化剂与含有低级烃和碳酸气体的反应气体反应时，产生芳族化合物。 为了得到催化剂，优选在沸石用直径大于沸石孔的硅烷化合物进行处理并具有氨基和直链状烷基的情况下，将钼和铜负载在由金属硅酸盐形成的沸石上， 链烷烃基，该氨基能够在沸石的布朗斯台德酸点处与沸石选择性反应。 钼的负载量优选在2〜12重量％的范围内。 基于煅烧催化剂的总量的％，而铜以铜与钼的摩尔比为0.01至0.8。

    PROCESS FOR PRODUCING AROMATIC HYDROCARBON
    7.
    发明申请
    PROCESS FOR PRODUCING AROMATIC HYDROCARBON 审中-公开
    生产芳香烃的方法

    公开(公告)号：US20100185034A1

    公开(公告)日：2010-07-22

    申请号：US12452990

    申请日：2008-07-31

    Applicant: Toru Nishimura ,  Shinobu Aoki ,  Yan Liu

    Inventor： Toru Nishimura ,  Shinobu Aoki ,  Yan Liu

    IPC: C07C2/52

    CPC classification number: B01J29/7876 ,  B01J29/48 ,  B01J37/0201 ,  B01J37/08 ,  B01J37/18 ,  C07C2/76 ,  C07C2529/78 ,  C10G2400/30 ,  C07C15/00

    Abstract: Provided is a process for producing an aromatic hydrocarbon using a molybdenum-containing solid catalyst, more specifically a process for producing an aromatic hydrocarbon efficiently from a lower hydrocarbon gas essentially containing methane by activating the molybdenum-containing solid catalyst with maintaining a high yield for a long period of time.The process comprises a pre-contacting step of allowing a molybdenum-containing solid catalyst to contact with a pre-contacting gas comprising at least one selected from a lower hydrocarbon and a hydrogen gas; and a reaction step of allowing the pre-contacted catalyst to contact with a raw material gas essentially containing methane, to generate an aromatic hydrocarbon, wherein the starting temperature in the pre-contacting step is lower than the reaction temperature, and the temperature during the pre-contacting step from the beginning to the end is not over the reaction temperature.

    Abstract translation: 本发明提供使用含钼固体催化剂制造芳族烃的方法，更具体地说，是从基本上含有甲烷的低级烃气体中有效地制备芳族烃的方法，其中通过使维持高收率的钼含量的固体催化剂活化 很长一段时间 该方法包括使含钼固体催化剂与包含选自低级烃和氢气中的至少一种的预接触气体接触的预接触步骤; 以及使预接触催化剂与基本上含甲烷的原料气体接触以产生芳族烃的反应步骤，其中预接触步骤中的起始温度低于反应温度，而在 从开始到结束的预接触步骤不超过反应温度。

    PROCESS FOR PRODUCTION OF AROMATIC HYDROCARBON
    8.
    发明申请
    PROCESS FOR PRODUCTION OF AROMATIC HYDROCARBON 审中-公开
    生产芳香烃的方法

    公开(公告)号：US20090076316A1

    公开(公告)日：2009-03-19

    申请号：US11816068

    申请日：2006-02-08

    Applicant: Masaru Ichikawa ,  Ryoichi Kojima ,  Satoshi Kikuchi

    Inventor： Masaru Ichikawa ,  Ryoichi Kojima ,  Satoshi Kikuchi

    IPC: C07C2/52

    CPC classification number: B01J29/076 ,  B01J29/48 ,  B01J29/7815 ,  B01J29/7876 ,  B01J2229/12 ,  B01J2229/18 ,  B01J2229/32 ,  C07C2/84 ,  C07C2529/48 ,  C07C2529/78 ,  C07C15/02

    Abstract: A process for producing an aromatic hydrocarbon, comprises heating the hydrocarbon in the presence of a catalyst carrying a molybdenum compound or a rhenium compound on a metallosilicate carrier modified with a silicon compound, a sodium compound or a calcium compound. The silicon compound is a silane compound having a basic group selected from amino, alkylamino and pyridyl groups and an organic group of a size equal to or greater than the pore size of the metallosilicate and selected from trialkoxy and triphenyl groups and the sodium compound or the calcium compound is a compound having an organic group of a size equal to or greater than the pore size of the metallosilicate and selected from crown ether, hexafluoropentanedione and acetylacetonate. The silane compound, the sodium compound or the calcium compound is modified so as to make an oxide thereof by impregnating the metallosilicate carrier with it and subsequently heat-treating it in an oxygen-containing atmosphere.

    Abstract translation: 一种制备芳族烃的方法，包括在载有钼化合物或铼化合物的催化剂存在下，在用硅化合物，钠化合物或钙化合物改性的金属硅酸盐载体上加热烃。 硅化合物是具有选自氨基，烷基氨基和吡啶基的碱性基团的硅烷化合物和等于或大于金属硅酸盐孔径的有机基团，选自三烷氧基和三苯基，并且钠化合物或 钙化合物是具有等于或大于金属硅酸盐孔径的有机基团并选自冠醚，六氟戊二酮和乙酰丙酮化物的化合物。 对硅烷化合物，钠化合物或钙化合物进行改性以通过用其浸渍金属硅酸盐载体并随后在含氧气氛中进行热处理来制备其氧化物。

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