公开(公告)号：US20170141388A1

公开(公告)日：2017-05-18

申请号：US15353250

申请日：2016-11-16

Applicant: Hutchinson ,  Centre National de la Recherche Scientifique ,  Université De Montpellier

Inventor： David Ayme-Perrot ,  Philippe Sonntag ,  Philippe Antitomaso ,  Laure Monconduit ,  Francoise Morato-Lallemand ,  Philippe Girard

IPC: H01M4/38 ,  H01M4/62 ,  H01M4/04 ,  H05B6/64 ,  C22C12/00 ,  C22C1/02 ,  H05B6/80 ,  H01M10/0525 ,  C22C13/02

CPC classification number: H01M4/387 ,  B22F1/0003 ,  B22F1/0059 ,  B22F2003/1054 ,  B22F2998/10 ,  C22C1/02 ,  C22C1/0483 ,  C22C1/0491 ,  C22C12/00 ,  C22C13/02 ,  H01M4/0404 ,  H01M4/622 ,  H01M4/625 ,  H01M10/0525 ,  H05B6/6491 ,  H05B6/80

Abstract: Method for preparing an intermetallic material SnSb, said method comprising at least the following steps: a/mixing the precursors Sn and Sb, b/treating the mixture from step a/with microwaves. The intermetallic phase obtained may be used for the manufacture of electrodes.

公开(公告)号：US09666855B2

公开(公告)日：2017-05-30

申请号：US14813637

申请日：2015-07-30

Applicant: Hutchinson

Inventor： Baptiste Voillequin ,  David Ayme-Perrot ,  Bruno Dufour ,  Philippe Sonntag

IPC: H01M4/04 ,  B29C47/00 ,  H01M4/133 ,  H01M4/136 ,  H01M4/1391 ,  H01M4/1393 ,  H01M4/1397 ,  H01M4/1399 ,  H01M4/62 ,  H01M10/0525 ,  H01M4/38 ,  H01M4/485 ,  H01M4/02 ,  B29L31/34

CPC classification number: H01M4/0483 ,  B29C47/0004 ,  B29L2031/3468 ,  H01M4/0409 ,  H01M4/0485 ,  H01M4/133 ,  H01M4/136 ,  H01M4/1391 ,  H01M4/1393 ,  H01M4/1397 ,  H01M4/1399 ,  H01M4/38 ,  H01M4/485 ,  H01M4/622 ,  H01M10/0525 ,  H01M2004/027 ,  Y02E60/122 ,  Y02P70/54

Abstract: An anode usable in a cell of a lithium-ion battery comprising an electrolyte based on a lithium salt and a non-aqueous solvent, to a process for manufacturing this anode and to a lithium-ion battery having one or more cells incorporating this anode. This anode is based on a polymer composition, obtained by melt processing and without solvent evaporation, that is the product of a hot compounding reaction between an active material and additives having a polymer binder and an electrically conductive filler. The binder is based on at least one crosslinked elastomer and the additives furthermore include at least one non-volatile organic compound usable in the electrolyte solvent, the composition advantageously includes the active material in a mass fraction greater than or equal to 85%.

公开(公告)号：US20170025673A1

公开(公告)日：2017-01-26

申请号：US15288325

申请日：2016-10-07

Applicant: Hutchinson

Inventor： Baptiste Voillequin ,  David Ayme-Perrot ,  Bruno Dufour ,  Philippe Sonntag

IPC: H01M4/04 ,  H01M4/36 ,  H01M10/0525 ,  H01M4/583 ,  H01M4/62 ,  H01M4/66 ,  H01M4/136 ,  H01M4/58

CPC classification number: H01M4/0483 ,  H01M4/0404 ,  H01M4/0409 ,  H01M4/0411 ,  H01M4/043 ,  H01M4/08 ,  H01M4/136 ,  H01M4/1397 ,  H01M4/366 ,  H01M4/5825 ,  H01M4/583 ,  H01M4/621 ,  H01M4/622 ,  H01M4/625 ,  H01M4/661 ,  H01M10/0525 ,  H01M2004/028 ,  Y02E60/122

Abstract: The invention relates to a cathode that is usable in a cell of a lithium-ion battery comprising an electrolyte based on a lithium salt and on a non-aqueous solvent, to a process for manufacturing this cathode and to a lithium-ion battery having one or more cells incorporating this cathode. This cathode is based on a polymer composition, obtained by melt processing and without solvent evaporation, that is the product of a hot compounding reaction between an active material and additives including a polymer binder and an electrically conductive filler. According to the invention, the binder is based on at least one crosslinked elastomer and the additives furthermore comprise at least one non-volatile organic compound usable in the electrolyte solvent, the composition advantageously includes the active material in a mass fraction greater than or equal to 90%.

Abstract translation: 本发明涉及一种可用于包含基于锂盐的电解质和非水溶剂的锂离子电池的电池的阴极，涉及制造阴极的方法和具有一个锂离子电池的锂离子电池 或更多的电池。 该阴极基于通过熔融加工而不用溶剂蒸发获得的聚合物组合物，其是活性材料与包括聚合物粘合剂和导电填料的添加剂之间的热复合反应的产物。 根据本发明，粘合剂基于至少一种交联弹性体，并且添加剂还包含可用于电解质溶剂中的至少一种非挥发性有机化合物，组合物有利地包括质量分数大于或等于 90％。

公开(公告)号：US20130183577A1

公开(公告)日：2013-07-18

申请号：US13742626

申请日：2013-01-16

Applicant: Hutchinson

Inventor： Baptiste Voillequin ,  David Ayme-Perrot ,  Bruno Dufour ,  Philippe Sonntag

IPC: H01M4/08

CPC classification number: H01M4/0483 ,  H01M4/0404 ,  H01M4/0409 ,  H01M4/0411 ,  H01M4/043 ,  H01M4/08 ,  H01M4/136 ,  H01M4/1397 ,  H01M4/366 ,  H01M4/5825 ,  H01M4/583 ,  H01M4/621 ,  H01M4/622 ,  H01M4/625 ,  H01M4/661 ,  H01M10/0525 ,  H01M2004/028 ,  Y02E60/122

Abstract: The invention relates to a cathode that is usable in a cell of a lithium-ion battery comprising an electrolyte based on a lithium salt and on a non-aqueous solvent, to a process for manufacturing this cathode and to a lithium-ion battery having one or more cells incorporating this cathode. This cathode is based on a polymer composition, obtained by melt processing and without solvent evaporation, that is the product of a hot compounding reaction between an active material and additives including a polymer binder and an electrically conductive filler. According to the invention, the binder is based on at least one crosslinked elastomer and the additives furthermore comprise at least one non-volatile organic compound usable in the electrolyte solvent, the composition advantageously includes the active material in a mass fraction greater than or equal to 90%.

Abstract translation: 本发明涉及一种可用于包含基于锂盐的电解质和非水溶剂的锂离子电池的电池的阴极，涉及制造阴极的方法和具有一个锂离子电池的锂离子电池 或更多的电池。 该阴极基于通过熔融加工而不用溶剂蒸发获得的聚合物组合物，其是活性材料与包括聚合物粘合剂和导电填料的添加剂之间的热复合反应的产物。 根据本发明，粘合剂基于至少一种交联弹性体，并且添加剂还包含可用于电解质溶剂中的至少一种非挥发性有机化合物，组合物有利地包括质量分数大于或等于 90％。

公开(公告)号：US10723846B2

公开(公告)日：2020-07-28

申请号：US15112990

申请日：2014-02-19

Applicant: HUTCHINSON

Inventor： Philippe Sonntag ,  David Ayme-Perrot ,  Bruno Dufour ,  Arnaud Prebe ,  Nicolas Garois

IPC: H01M10/054 ,  H01M10/0525 ,  H01M4/04 ,  H01M4/139 ,  H01M4/58 ,  H01M4/62 ,  H01M4/485 ,  C08J3/20 ,  H01M4/13 ,  H01G11/50 ,  H01G11/38 ,  H01G11/44 ,  C08J3/00 ,  C08J9/00 ,  C08J9/26 ,  C08L69/00 ,  H01F1/34 ,  H01M4/02

Abstract: A process for preparing a polymeric composition for forming a lithium-ion or sodium-ion battery electrode or a supercapacitor electrode or for exhibiting magnetic properties, to such a polymeric composition obtained by means of this process, to a mixture which is a precursor of the composition, obtained by means of a first mixing step of the process, and to this electrode.The process for preparing this composition comprises: a) hot-mixing, via the melt process and without solvent, at least one active material, a binder-forming polymeric phase and a sacrificial polymeric phase so as to obtain a mixture, and b) at least partially eliminating said sacrificial polymeric phase so as to obtain said composition which comprises the active material(s) according to a weight fraction greater than 80%. The sacrificial phase is used in step a) according to a weight fraction in the mixture being greater than or equal to 15%.

公开(公告)号：US20170133714A1

公开(公告)日：2017-05-11

申请号：US15343526

申请日：2016-11-04

Applicant: Hutchinson ,  Centre National de la Recherche Scientifique ,  Universite de Nantes

Inventor： David Ayme-Perrot ,  Philippe Sonntag ,  Philippe-Franck Girard ,  Carole Cerclier ,  Jean Le Bideau ,  Thierry Brousse

IPC: H01M10/0565 ,  H01M10/0525 ,  H01G11/56 ,  C08J3/09 ,  C08J5/18

CPC classification number: H01M10/0565 ,  B01J13/0065 ,  C08J3/09 ,  C08J3/11 ,  C08J5/18 ,  C08J2367/04 ,  C08K3/34 ,  H01B1/122 ,  H01G11/56 ,  H01M10/0525 ,  H01M2300/0085 ,  Y02E60/122 ,  Y02E60/13 ,  Y02P70/54

Abstract: The invention relates to an ionogel that may be used for making a self-supporting film forming a solid electrolyte of an electrochemical device, to such a device incorporating this ionogel and to a process for manufacturing this ionogel. The invention generally applies to all energy storage devices such as supercapacitors or storage batteries (e.g. lithium-ion).An ionogel according to the invention comprises: a polymeric confinement matrix which comprises at least one polylactic acid, and at least one ionic liquid confined in this matrix. According to the invention, this matrix also comprises a polycondensate of at least one sol-gel molecular precursor bearing hydrolysable group(s).

公开(公告)号：US11180625B2

公开(公告)日：2021-11-23

申请号：US15566238

申请日：2016-04-07

Applicant: HUTCHINSON

Inventor： Arnaud Prebe ,  Bruno Dufour ,  David Ayme-Perrot ,  Yannick Bureau ,  Philippe Sonntag

IPC: C08J9/26 ,  C08J9/00 ,  B29C67/20 ,  C08F20/44 ,  C08F36/06 ,  C09K5/14 ,  B29K33/20 ,  B29K105/04 ,  H01B1/24

Abstract: Porous polymeric materials having a very high content of thermally conductive and/or electrically conductive fillers. Process for the preparation of the porous composite material including at least one binder-forming polymeric phase and one or more fillers, this process including the stages of hot mixing, by the molten route, the polymeric phase, the fillers and a sacrificial polymeric phase, so as to obtain a mixture, of shaping the mixture and of removing the sacrificial polymeric phase.

公开(公告)号：US11139474B2

公开(公告)日：2021-10-05

申请号：US15353250

申请日：2016-11-16

Applicant: Hutchinson ,  Centre National de la Recherche Scientifique ,  Université De Montpellier

Inventor： David Ayme-Perrot ,  Philippe Sonntag ,  Philippe Antitomaso ,  Laure Monconduit ,  Francoise Morato-Lallemand ,  Philippe Girard

IPC: H01M4/38 ,  C22C1/04 ,  B22F9/04 ,  C22C1/02 ,  C22C12/00 ,  C22C13/02 ,  H01M4/04 ,  H01M4/62 ,  H01M10/0525 ,  H05B6/64 ,  H05B6/80 ,  B22F3/105

Abstract: A method for preparing a material having an Sn:Sb intermetallic phase includes at least the steps of mixing chemical elements Sn and Sb, and treating the mixture with microwaves. An electrode is manufactured by using the material having an Sn:Sb intermetallic phase; forming the material in a form of powder; mixing the powder with carbon, a binder and a solvent to form an ink; coating a current collector with the ink; and drying the electrode.

公开(公告)号：US09484571B2

公开(公告)日：2016-11-01

申请号：US13742626

申请日：2013-01-16

Applicant: Hutchinson

Inventor： Baptiste Voillequin ,  David Ayme-Perrot ,  Bruno Dufour ,  Philippe Sonntag

IPC: H01M4/04 ,  H01M4/62 ,  H01M4/08 ,  H01M4/136 ,  H01M4/1397 ,  H01M10/0525

CPC classification number: H01M4/0483 ,  H01M4/0404 ,  H01M4/0409 ,  H01M4/0411 ,  H01M4/043 ,  H01M4/08 ,  H01M4/136 ,  H01M4/1397 ,  H01M4/366 ,  H01M4/5825 ,  H01M4/583 ,  H01M4/621 ,  H01M4/622 ,  H01M4/625 ,  H01M4/661 ,  H01M10/0525 ,  H01M2004/028 ,  Y02E60/122

Abstract: The invention relates to a cathode that is usable in a cell of a lithium-ion battery comprising an electrolyte based on a lithium salt and on a non-aqueous solvent, to a process for manufacturing this cathode and to a lithium-ion battery having one or more cells incorporating this cathode. This cathode is based on a polymer composition, obtained by melt processing and without solvent evaporation, that is the product of a hot compounding reaction between an active material and additives including a polymer binder and an electrically conductive filler. According to the invention, the binder is based on at least one crosslinked elastomer and the additives furthermore comprise at least one non-volatile organic compound usable in the electrolyte solvent, the composition advantageously includes the active material in a mass fraction greater than or equal to 90%.

Abstract translation: 本发明涉及一种可用于包含基于锂盐的电解质和非水溶剂的锂离子电池的电池的阴极，涉及制造阴极的方法和具有一个锂离子电池的锂离子电池 或更多的电池。 该阴极基于通过熔融加工而不用溶剂蒸发获得的聚合物组合物，其是活性材料与包括聚合物粘合剂和导电填料的添加剂之间的热复合反应的产物。 根据本发明，粘合剂基于至少一种交联弹性体，并且添加剂还包含可用于电解质溶剂中的至少一种非挥发性有机化合物，组合物有利地包括质量分数大于或等于 90％。

公开(公告)号：US20160164139A1

公开(公告)日：2016-06-09

申请号：US14907521

申请日：2013-07-29

Applicant: HUTCHINSON ,  CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE ,  UNIVERSITE DE NANTES

Inventor： David Ayme-Perrot ,  Carole Cerclier ,  Jean Le Bideau ,  Nela Buchtova ,  Aurélie Guyomard-Lack ,  Philippe-Franck Girard

IPC: H01M10/0565

CPC classification number: H01M10/0565 ,  B32B17/10036 ,  B32B17/10174 ,  B32B17/10201 ,  B32B17/10431 ,  B32B17/10541 ,  B32B17/10669 ,  B32B17/10761 ,  C03C17/3435 ,  C03C2217/734 ,  G02B1/10 ,  G02B1/115 ,  G02B5/30 ,  G02B27/0018 ,  G02B27/0101 ,  G02B2027/012 ,  G02B2027/0196 ,  H01M8/1027 ,  H01M8/1037 ,  H01M8/1074 ,  H01M14/005 ,  H01M2300/0082 ,  H01M2300/0085 ,  Y02P70/56

Abstract: The invention relates to a monolithic ionogel with an organic confinement matrix for at least one ionic liquid, and a method for manufacturing same. An ionogel according to the invention comprises a biopolymer confinement matrix with a cross-linked polysaccharide base and an ionic liquid confined in a network formed by the matrix, and it is such that the polysaccharide has siloxane cross-linking bridges, the ionogel being a chemical gel able to constitute a self-supported solid electrolyte by itself. This ionogel is obtained using a method comprising silanisation of the polysaccharide in a basic aqueous solution by a silanisation agent, and polycondensation of the silanised polysaccharide. In a first embodiment, this method comprises preparing a hydrogel with a polysaccharide base that is silanised and cross-linked by sol-gel, then exchange reactions of solvents with increasing hydrophobicities. In a second preferred embodiment, it comprises mixing a first solution comprising the ionic liquid in an acid medium and a second solution containing the silanised and non-cross-linked polysaccharide, such that its cross-linking takes place through that mixing.

Abstract translation: 本发明涉及一种具有用于至少一种离子液体的有机约束基质的单片离子凝胶及其制造方法。 根据本发明的离子凝胶包含具有交联多糖碱的生物聚合物约束基质和限制在由基质形成的网络中的离子液体，并且使得多糖具有硅氧烷交联桥，离子凝胶是化学 凝胶本身可以构成自支撑的固体电解质。 该离子凝胶是通过使硅烷化剂在碱性水溶液中硅烷化多糖，以及硅烷化多糖的缩聚的方法得到的。 在第一实施方案中，该方法包括制备具有硅烷化并通过溶胶 - 凝胶交联的多糖碱的水凝胶，然后交换溶剂的增加的疏水性的反应。 在第二优选实施方案中，其包括在酸性介质中混合包含离子液体的第一溶液和含有硅烷化和非交联多糖的第二溶液，使得其通过该混合进行交联。