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    Liquid detergent with fabric softening properties
    3.
    发明授权
    Liquid detergent with fabric softening properties 失效
    液体洗涤剂具有织物软化性能

    公开(公告)号：US4717507A

    公开(公告)日：1988-01-05

    申请号：US860275

    申请日：1986-05-05

    申请人： Karl Schwadtke ,  Eduard Smulders ,  Hans Andree

    发明人： Karl Schwadtke ,  Eduard Smulders ,  Hans Andree

    IPC分类号： C11D1/22 ,  C11D1/14 ,  C11D1/52 ,  C11D1/72 ,  C11D3/00 ,  C11D3/20 ,  C11D3/32 ,  C11D3/34 ,  C11D9/02 ,  C11D10/00 ,  C11D10/04

    CPC分类号： C11D10/04 ,  C11D3/0015 ,  C11D1/14 ,  C11D1/523 ,  C11D1/72

    摘要： A liquid, readily pourable detergent concentrate having fabric-softening properties is free from builder salts and contains the following constituents: (a) from about 5 to about 15% by weight of sodium alkylbenzene sulfonate, (b) from about 7 to about 20% by weight of ethoxylated alcohols containing from 12 to 18 carbon atoms in the alcohol residue and from 5 to 10 glycol ether groups, (c) from about 6 to about 16% by weight, based on the weight of the fatty acids used to form the soap, of saturated or monounsaturated fatty acids containing from 12 to 18 C-atoms, present as a water-soluble soap, (d) from about 7 to about 15% by weight of a fatty acid diethanolamide derived from C.sub.16 -C.sub.18 fatty acids of which at least 50% are monounsaturated, (e) from about 0.2 to about 3% by weight of sequestering agents, (f) from about 5 to about 15% by weight of low molecular weight alcohols and from about 25 to about 45% by weight of water. The ratio by weight of (a) to (b) to (c) to (d) is in the range of 1:(1-2):(1-2):(1.5-2.5).

    摘要翻译： 具有织物软化性质的液体容易倾倒的洗涤剂浓缩物不含助洗剂盐，并且含有以下组分：（a）约5至约15重量％的烷基苯磺酸钠，（b）约7至约20重量％ 的醇残基中含有12至18个碳原子的乙氧基化醇和5至10个二醇醚基团，（c）约6至约16重量％，基于用于形成 肥皂，含有12至18个碳原子的饱和或单不饱和脂肪酸，作为水溶性皂存在，（d）约7至约15重量％的衍生自C16-C18脂肪酸的脂肪酸二乙醇酰胺 其至少50％是单不饱和的，（e）约0.2-约3重量％的螯合剂，（f）约5至约15重量％的低分子量醇和约25至约45重量％ 水的重量。 （a）至（b）至（c）至（d）的重量比在1：（1-2）：（1-2）：（1.5-2.5）的范围内。

    Process for the preparation of a storage-stable liquid detergent composition
    4.
    发明授权
    Process for the preparation of a storage-stable liquid detergent composition 失效
    用于制备储存稳定的液体洗涤剂组合物的方法

    公开(公告)号：US4929380A

    公开(公告)日：1990-05-29

    申请号：US262204

    申请日：1988-10-19

    申请人： Paul Schulz ,  Karl Schwadtke ,  Eduard Smulders

    发明人： Paul Schulz ,  Karl Schwadtke ,  Eduard Smulders

    IPC分类号： C11D1/22 ,  C11D1/72 ,  C11D1/83 ,  C11D1/831 ,  C11D10/04 ,  C11D17/00 ,  C11D17/04 ,  C11D17/08

    CPC分类号： C11D17/0004 ,  C11D1/83 ,  C11D1/831 ,  C11D10/045 ,  C11D17/043 ,  C11D1/22 ,  C11D1/72

    摘要： The invention provides a substantially anhydrous gas-free liquid detergent based on non-ionic surfactants containing a liquid surfactant component comprising adducts of from 2 to 8 moles ethylene oxide with 1 mole C.sub.10-20 - fatty alcohol, anionic surfactant, and low molecular weight polyethylene glycol. The liquid surfactant component makes up at least 20% by weight of the detergent as a whole; the ratio of fatty alcohol ethoxylate to anionic surfactant is from 1:1 to 2:1; and the detergent has a density of from 1.4 to 1.8. Typically, the detergent includes a particulate solids component which is incorporated with the liquid components as separate component fractions of differing particle size.

    摘要翻译： 本发明提供了基于非离子表面活性剂的基本上无水的无气体液体洗涤剂，其含有液体表面活性剂组分，其包含2-8摩尔环氧乙烷与1摩尔C10-20-脂肪醇，阴离子表面活性剂和低分子量聚乙烯 乙二醇 液体表面活性剂组分占整个洗涤剂的至少20重量％; 脂肪醇乙氧基化物与阴离子表面活性剂的比例为1:1至2:1; 洗涤剂的密度为1.4〜1.8。 通常，洗涤剂包括颗粒状固体组分，其与作为不同粒径的分离组分部分的液体组分结合。

    Process for the preparation of a stable, readily soluble granulate with a content of bleach activators
    5.
    发明授权
    Process for the preparation of a stable, readily soluble granulate with a content of bleach activators 失效
    用于制备具有漂白活化剂含量的稳定，易溶的颗粒的方法

    公开(公告)号：US4372868A

    公开(公告)日：1983-02-08

    申请号：US246097

    申请日：1981-03-20

    申请人： Herbert Saran ,  Martin Witthaus ,  Eduard Smulders ,  Karl Schwadtke

    发明人： Herbert Saran ,  Martin Witthaus ,  Eduard Smulders ,  Karl Schwadtke

    IPC分类号： C11D7/54 ,  C11D3/39 ,  C11D17/00 ,  C11D3/30 ,  C11D3/395 ,  C11D11/00 ,  C11D17/06

    CPC分类号： C11D3/3935 ,  C11D17/0039

    摘要： This invention relates to a process for preparing bleach activator granulates comprising from about 90 to 98 percent by weight of bleach activator and from about 10 to 2 percent by weight of granulating adjuvant, based on the weight of the anhydrous components, which comprises the steps of:(a) mixing powdered bleach activator which has a mean particle size of from about 0.01 to 0.8 mm with from about 50 to 100 percent by weight of the total granulating adjuvant to be used, which granulating adjuvant comprises a water-soluble cellulose ether, starch, or starch ether in the form of a free-flowing powder having a mean particle size of from about 0.01 to 0.8 mm;(b) moistening the mixture from step (a) with water or an aqueous solution containing the remainder of the granulating adjuvant in a solution of from about 0.1 to 10 percent by weight, based on the weight of the total solution;(c) granulating the moist mixture from step (b); and(d) drying the moist granulate from step (c) until the moisture content is less than 2 percent by weight, preferably less than 1 percent by weight. Additionally, during steps (a) or (b), a polysiloxane defoaming agent can be added.

    摘要翻译： 本发明涉及一种制备漂白活化剂颗粒的方法，其包含基于无水组分重量的约90至98重量％的漂白活化剂和约10至2重量％的造粒助剂，其包括以下步骤： ：（a）将平均粒度为约0.01至0.8mm的粉末状漂白活化剂与所使用的总造粒助剂的约50至100重量％混合，该造粒助剂包含水溶性纤维素醚， 淀粉或淀粉醚，其形式为平均粒度为约0.01至0.8mm的自由流动的粉末; （b）基于总溶液的重量，将来自步骤（a）的混合物与含有剩余造粒助剂的水或含水溶液一起溶于约0.1至10重量％的溶液中; （c）将来自步骤（b）的湿混合物制粒; 和（d）将来自步骤（c）的潮湿颗粒干燥直到水分含量小于2重量％，优选小于1重量％。 另外，在步骤（a）或（b）中，可以加入聚硅氧烷消泡剂。

    Zeolite-based phosphate-free detergent builder composition
    7.
    发明授权
    Zeolite-based phosphate-free detergent builder composition 失效
    基于沸石的无磷酸盐洗涤剂助洗剂组合物

    公开(公告)号：US5393455A

    公开(公告)日：1995-02-28

    申请号：US39328

    申请日：1993-04-26

    申请人： Joerg Poethkow ,  Horst Upadek ,  Eduard Smulders

    发明人： Joerg Poethkow ,  Horst Upadek ,  Eduard Smulders

    IPC分类号： C11D3/12 ,  C11D3/37 ,  C11D3/60 ,  C11D3/08 ,  C11D7/60

    CPC分类号： C11D3/3757 ,  C11D3/1273 ,  C11D3/128

    摘要： Phosphate-free builder combinations containing zeolite, crystalline layer silicates corresponding to formula (I) NaMSi.sub.x O.sub.2x+1..sub.y H.sub.2 O, in which M is sodium or hydrogen, x is a number of 1.9 to 4 and y is a number of 0 to 20, and polymeric polycarboxylates may be used separately as water softeners or in detergents. Their primary and secondary detergent properties are so favorable that there is little or no need to use phosphonates.

    摘要翻译： PCT No.PCT / EP91 / 01976 Sec。 371日期：1993年4月26日 102（e）日期1993年4月26日PCT 1991年10月17日PCT公布。 出版物WO92 / 07928 日期：1992年5月14日。含有沸石的无磷酸盐助洗剂组合物，对应于式（I）NaMSixO 2 x + 1.yH 2 O的结晶层硅酸盐，其中M为钠或氢，x为数为1.9至4，y为数 为0至20，聚合多羧酸盐可单独用作软水剂或洗涤剂。 它们的主要和次要洗涤剂性质如此有利，因此很少或不需要使用膦酸盐。

    Production of compacted granules for detergents
    8.
    发明授权
    Production of compacted granules for detergents 失效
    生产用于洗涤剂的压实颗粒

    公开(公告)号：US5318733A

    公开(公告)日：1994-06-07

    申请号：US834251

    申请日：1992-04-09

    申请人： Franz-Josef Carduck ,  Hubert Pawelczyk ,  Wilfried Raehse ,  Jochen Jacobs ,  Eduard Smulders ,  Guenther Vogt

    发明人： Franz-Josef Carduck ,  Hubert Pawelczyk ,  Wilfried Raehse ,  Jochen Jacobs ,  Eduard Smulders ,  Guenther Vogt

    IPC分类号： C11D11/00 ,  C11D17/00 ,  C11D17/06 ,  B29C59/00

    CPC分类号： C11D17/0047 ,  C11D11/0082 ,  C11D17/0073 ,  C11D17/065

    摘要： A process for the production of compacted granules for use in a detergent composition by providing a homogeneous, solid, free-flowing premix to which a plasticizer or lubricant is added, and extruding the mixture through a perforated die under a pressure of from about 25 bar to about 200 bar to form strands of the mixture. The perforated die has an opening width corresponding to a predetermined size of the granules. After emerging from the perforated die, the strands are cut to the predetermined size of the granules by means of a cutting unit. The process enables the preparation of detergent compositions containing increased contents of surfactant components.

    摘要翻译： PCT No.PCT / EP90 / 01247 Sec。 371日期：1992年4月9日 102（e）日期1992年4月9日PCT提交1990年7月31日PCT公布。 第WO91 / 02047号公报 日本1991年2月21日。一种用于生产用于洗涤剂组合物的压实颗粒的方法，其通过提供均匀，固体，自由流动的预混物，其中加入增塑剂或润滑剂，并通过穿孔模具将混合物挤出 约25巴至约200巴的压力以形成混合物的股线。 穿孔模具具有对应于预定尺寸的颗粒的开口宽度。 在从穿孔模具出来之后，通过切割单元将股线切割成预定尺寸的颗粒。 该方法能够制备含有增加的表面活性剂组分含量的洗涤剂组合物。

    Process and device for washing
    10.
    发明授权
    Process and device for washing 失效
    洗涤方法和装置

    公开(公告)号：US5404606A

    公开(公告)日：1995-04-11

    申请号：US133207

    申请日：1993-12-13

    申请人： Thomas Mueller-Kirschbaum ,  Eduard Smulders ,  Wolfgang Hoefer

    发明人： Thomas Mueller-Kirschbaum ,  Eduard Smulders ,  Wolfgang Hoefer

    IPC分类号： B08B3/10 ,  D06F33/02 ,  D06F39/00 ,  D06F39/02 ,  G01N13/02

    CPC分类号： D06F39/004 ,  G01N13/02 ,  G01N2013/0275 ,  Y02B40/56

    摘要： The invention concerns a process for washing fibrous materials, skins, textile materials or the like using an aqueous, surfactant containing washing liquid obtained by adding washing agents to water. The minimal dispensed amounts as determined in subsequent washing tests are always obtained automatically, without the cleaning power and the cleaning efficiency being reduced to unacceptable levels. To this end, the surface tension of the washing liquid is measured during the washing process using a tensiometer. The actual washing agent concentration is derived from these measured values and an initial concentration is derived from the quantity of washing agent added. The detergency is calculated from this initial concentration. The addition of a washing agent is discontinued when no further increase occurs in the detergency. The invention also concerns a device for carrying out the process. The device has capillaries connected to constant gas flow sources and immersed to the same depth in the washing liquid. The capillaries are connected to a device for determining the pressure or the frequency of pressure variations which controls a dispensing unit via an evaluation unit.

    摘要翻译： PCT No.PCT / EP92 / 00785 Sec。 371日期：1993年12月13日 102（e）日期1993年12月13日PCT提交1992年4月7日PCT公布。 公开号WO92 / 18680 PCT 日本1992年10月29日。本发明涉及使用通过向水中添加洗涤剂而获得的含水洗涤液的表面活性剂洗涤纤维材料，表皮，纺织材料等的方法。 在随后的洗涤测试中确定的最小分配量总是自动获得，而清洁能力和清洁效率降低到不可接受的水平。 为此，使用张力计在洗涤过程中测量洗涤液的表面张力。 实际洗涤剂浓度来源于这些测定值，初始浓度来源于加入的洗涤剂的量。 洗涤力由该初始浓度计算。 当洗涤剂没有进一步增加时，停止加入洗涤剂。 本发明还涉及用于执行该过程的装置。 该装置具有连接到恒定气体流动源并且浸入洗涤液体中相同深度的毛细管。 毛细管连接到用于确定通过评估单元控制分配单元的压力变化的压力或频率的装置。