摘要:
Disclosed is a negative electrode for a nonaqueous secondary battery included of a current collector and an active material structure containing an electro-conductive material having low capability of forming a lithium compound on at least one side of the current collector, the active material structure containing 5 to 80% by weight of active material particles containing a material having high capability of forming a lithium compound. The active material structure preferably has an active material layer containing the active material particles and a surface coating layer formed on the active material layer.
摘要:
A negative electrode 1 for nonaqueous secondary batteries characterized by having an active material layer 5 and a metallic lithium layer 3 both between a pair of current collecting surface layers 4. The negative electrode 1 has two negative electrode precursors 2 each composed of the current collecting surface layer 4 and the active material layer 5 on one side of the surface layer 4. The two negative electrode precursors 2 are united with their active material layers 5 facing each other and with the metallic lithium layer 3 sandwiched therebetween. A metallic material having low capability of forming a lithium compound penetrates through the whole thickness of the active material layer 5.
摘要:
A negative electrode 10 for a nonaqueous secondary battery, has an active material layer 2 containing active material particles 2a. The active material layer 2 has a metallic material 4 deposited among the particles by electroplating. The negative electrode 10 has a large number of holes 5 open on at least one side thereof and extending through the thickness of the active material layer. The negative electrode 10 further has a pair of current collecting layers 3a and 3b adapted to be brought into contact with an electrolyte. The active material layer 2 is between the current collecting layers 3a and 3b. The holes 5 open on the negative electrode 10 preferably have an opening area ratio of 0.3% to 30%. At least one of the pair of the current collecting layers 3a and 3b preferably has a thickness of 0.3 to 10 μm.
摘要:
A process of producing a nonaqueous secondary battery comprising the steps of disposing a separator between a member containing a silicon-based material and a positive electrode, together with interposing a metallic lithium layer between the separator and the member to obtain an assembly, and aging the resulting assembly for a prescribed period of time to alloy lithium with the silicon-based material. Lithium alloying is preferably performed to a degree such that the amount of lithium in the silicon-based material is 5% to 50% based on the theoretical initial charge capacity of silicon. When the positive electrode has a lithium-containing active material for positive electrode, lithium alloying is preferably performed to a degree satisfying formula (1): 4.4A−B≧C, where A is the number of moles of silicon in the member containing the silicon-based material; B is the number of moles of lithium in the lithium-containing active material for positive electrode; and C is the number of moles of lithium to be alloyed.
摘要:
Disclosed is a negative electrode for a nonaqueous secondary battery comprised of a current collector and an active material structure containing an electro-conductive material having low capability of forming a lithium compound on at least one side of the current collector, the active material structure containing 5 to 80% by weight of active material particles containing a material having high capability of forming a lithium compound. The active material structure preferably has an active material layer containing the active material particles and a surface coating layer formed on the active material layer.
摘要:
A negative electrode 1 for nonaqueous secondary batteries characterized by having an active material layer 5 and a metallic lithium layer 3 both between a pair of current collecting surface layers 4. The negative electrode 1 has two negative electrode precursors 2 each composed of the current collecting surface layer 4 and the active material layer 5 on one side of the surface layer 4. The two negative electrode precursors 2 are united with their active material layers 5 facing each other and with the metallic lithium layer 3 sandwiched therebetween. A metallic material having low capability of forming a lithium compound penetrates through the whole thickness of the active material layer 5.
摘要:
A negative electrode for nonaqueous secondary batteries is disclosed. The negative electrode has a pair of current collecting surface layers of which the surfaces are adapted to be brought into contact with an electrolyte and at least one active material layer interposed between the surface layers. The active material layer contains particles of an active material having high capability of forming a lithium compound. The material constituting the surfaces is preferably present over the whole thickness of the active material layer to electrically connect the surfaces so that the electrode exhibits a current collecting function as a whole. The surface layers each preferably have a thickness of 0.3 to 10 μm.
摘要:
An anode for nonaqueous secondary batteries is disclosed. The anode has a pair of current collecting surface layers of which the surfaces are adapted to be brought into contact with an electrolytic solution and at least one active material layer interposed between the surface layers. The active material layer contains particles of an active material having high capability of forming a lithium compound. The material constituting the surfaces is preferably present over the whole thickness of the active material layer to electrically connect the surfaces so that the electrode exhibits a current collecting function as a whole. The surface layers each preferably have a thickness of 0.3 to 10 μm.
摘要:
A negative electrode 10 for a nonaqueous secondary battery, has an active material layer 2 containing active material particles 2a. The active material layer 2 has a metallic material 4 deposited among the particles by electroplating. The negative electrode 10 has a large number of holes 5 open on at least one side thereof and extending through the thickness of the active material layer. The negative electrode 10 further has a pair of current collecting layers 3a and 3b adapted to be brought into contact with an electrolyte. The active material layer 2 is between the current collecting layers 3a and 3b. The holes 5 open on the negative electrode 10 preferably have an opening area ratio of 0.3% to 30%. At least one of the pair of the current collecting layers 3a and 3b preferably has a thickness of 0.3 to 10 μm.
摘要:
A negative electrode for a non-aqueous electrolyte secondary cell includes a current collector an, formed on a surface or both surfaces thereof, an active material structure containing an electroconductive material with a low capability of forming a compound with lithium, and the active material structure includes 5% to 80% by weight of active material particles containing a material having a high capability for forming a compound with lithium. The active material structure can include an active material layer containing the active material particles and a surface-covering layer on the active material layer.