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    Negative electrode for nonaqueous secondary battery
    5.
    发明授权
    Negative electrode for nonaqueous secondary battery 失效
    非水二次电池用负极

    公开(公告)号：US07838154B2

    公开(公告)日：2010-11-23

    申请号：US11174645

    申请日：2005-07-06

    申请人： Tomoyoshi Matsushima ,  Hitohiko Honda ,  Yoshiki Sakaguchi ,  Masahiro Hyakutake ,  Kiyotaka Yasuda

    发明人： Tomoyoshi Matsushima ,  Hitohiko Honda ,  Yoshiki Sakaguchi ,  Masahiro Hyakutake ,  Kiyotaka Yasuda

    IPC分类号： H01M4/80

    CPC分类号： H01M4/1395 ,  C25D3/38 ,  C25D17/10 ,  H01M4/02 ,  H01M4/0438 ,  H01M4/134 ,  H01M4/70 ,  H01M2004/027

    摘要： A negative electrode 10 for a nonaqueous secondary battery, has an active material layer 2 containing active material particles 2a. The active material layer 2 has a metallic material 4 deposited among the particles by electroplating. The negative electrode 10 has a large number of holes 5 open on at least one side thereof and extending through the thickness of the active material layer. The negative electrode 10 further has a pair of current collecting layers 3a and 3b adapted to be brought into contact with an electrolyte. The active material layer 2 is between the current collecting layers 3a and 3b. The holes 5 open on the negative electrode 10 preferably have an opening area ratio of 0.3% to 30%. At least one of the pair of the current collecting layers 3a and 3b preferably has a thickness of 0.3 to 10 μm.

    摘要翻译： 非水系二次电池用负极10具有含有活性物质粒子2a的活性物质层2。 活性物质层2具有通过电镀沉积在颗粒之间的金属材料4。 负极10具有在其至少一个侧面上开口并且延伸穿过活性材料层的厚度的大量孔5。 负极10还具有适于与电解液接触的一对集流层3a和3b。 活性物质层2位于集流层3a和3b之间。 在负极10上打开的孔5的开口面积比优选为0.3％〜30％。 一对集电层3a和3b中的至少一个优选具有0.3至10μm的厚度。

    Negative electrode for nonaqueous secondary battery
    6.
    发明授权
    Negative electrode for nonaqueous secondary battery 有权
    非水二次电池用负极

    公开(公告)号：US08197966B2

    公开(公告)日：2012-06-12

    申请号：US12306973

    申请日：2007-04-18

    申请人： Akihiro Modeki ,  Tomoyoshi Matsushima ,  Masahiro Hyakutake ,  Kiyotaka Yasuda ,  Kayoko Shinzawa ,  Yoshiki Sakaguchi

    发明人： Akihiro Modeki ,  Tomoyoshi Matsushima ,  Masahiro Hyakutake ,  Kiyotaka Yasuda ,  Kayoko Shinzawa ,  Yoshiki Sakaguchi

    IPC分类号： H01M2/16

    CPC分类号： H01M10/0525 ,  H01M4/134 ,  H01M4/386 ,  H01M4/625 ,  H01M2004/021

    摘要： A negative electrode 10 for a nonaqueous secondary battery has an active material layer 12 containing active material particles 12a. The particles 12a are coated at least partially with a metallic material 13 having low capability of lithium compound formation. The active material layer 12 has voids located between the metallic material-coated particles 12a with a void fraction of 15% to 45%. The metallic material 13 on the surface of the particles is preferably present throughout the thickness of the active material layer. The active material particles 12a are preferably of a silicon-based material. The active material layer 12 preferably contains 1% to 3% by weight of an electroconductive carbon material based on the weight of the active material particles 12a.

    摘要翻译： 非水系二次电池用负极10具有含有活性物质粒子12a的活性物质层12。 颗粒12a至少部分地被具有低的锂化合物形成能力的金属材料13涂覆。 活性物质层12具有位于金属材料涂覆颗粒12a之间的空隙，空隙率为15％至45％。 颗粒表面上的金属材料13优选存在于活性材料层的整个厚度上。 活性物质粒子12a优选为硅系材料。 基于活性物质颗粒12a的重量，活性物质层12优选含有1重量％至3重量％的导电碳材料。

    NEGATIVE ELECTRODE FOR NONAQUEOUS SECONDARY BATTERY
    7.
    发明申请
    NEGATIVE ELECTRODE FOR NONAQUEOUS SECONDARY BATTERY 有权
    用于非正常二次电池的负极

    公开(公告)号：US20090202915A1

    公开(公告)日：2009-08-13

    申请号：US12306973

    申请日：2007-04-18

    申请人： Akihiro Modeki ,  Tomoyoshi Matsushima ,  Masahiro Hyakutake ,  Kiyotaka Yasuda ,  Kayoko Shinzawa ,  Yoshiki Sakaguchi

    发明人： Akihiro Modeki ,  Tomoyoshi Matsushima ,  Masahiro Hyakutake ,  Kiyotaka Yasuda ,  Kayoko Shinzawa ,  Yoshiki Sakaguchi

    IPC分类号： H01M2/16 ,  H01M4/02

    CPC分类号： H01M10/0525 ,  H01M4/134 ,  H01M4/386 ,  H01M4/625 ,  H01M2004/021

    摘要： A negative electrode (10) for use in a non-aqueous electrolyte secondary battery comprises an active material layer (12) containing a particle (12a) of an active material. At least a part of the surface of the particle (12a) is coated with a metal material (13) having a poor ability of forming a lithium compound. A void is formed between the particles (12a) that are coated with the metal material (13). The active material layer has a void ratio of 15 to 45%. Preferably, the metal material (13) is present over the entire area of such a part of the surface of the particle that extends in the thickness-wise direction of the active material layer. Also preferably, the particle (12a) of the active material is composed of a silicone material, and the active material layer (12) contains a conductive carbon material in an amount of 1 to 3% by weight relative to the weight amount of the particle (12a) of the active material.

    摘要翻译： 用于非水电解质二次电池的负极（10）包括含有活性物质的粒子（12a）的活性物质层（12）。 颗粒（12a）的表面的至少一部分涂覆有形成锂化合物的能力差的金属材料（13）。 在被金属材料（13）涂覆的颗粒（12a）之间形成空隙。 活性物质层的空隙率为15〜45％。 优选地，金属材料（13）存在于在活性材料层的厚度方向上延伸的颗粒表面的这种部分的整个区域上。 还优选地，活性物质的粒子（12a）由硅酮材料构成，活性物质层（12）相对于粒子的重量为1〜3重量％的导电性碳材料 （12a）的活性物质。

    Negative electrode for nonaqueous secondary battery
    8.
    发明申请
    Negative electrode for nonaqueous secondary battery 失效
    非水二次电池用负极

    公开(公告)号：US20060051677A1

    公开(公告)日：2006-03-09

    申请号：US11174645

    申请日：2005-07-06

    申请人： Tomoyoshi Matsushima ,  Hitohiko Honda ,  Yoshiki Sakaguchi ,  Masahiro Hyakutake ,  Kiyotaka Yasuda

    发明人： Tomoyoshi Matsushima ,  Hitohiko Honda ,  Yoshiki Sakaguchi ,  Masahiro Hyakutake ,  Kiyotaka Yasuda

    IPC分类号： H01M4/80 ,  H01M4/40

    CPC分类号： H01M4/1395 ,  C25D3/38 ,  C25D17/10 ,  H01M4/02 ,  H01M4/0438 ,  H01M4/134 ,  H01M4/70 ,  H01M2004/027

    摘要： A negative electrode 10 for a nonaqueous secondary battery, has an active material layer 2 containing active material particles 2a. The active material layer 2 has a metallic material 4 deposited among the particles by electroplating. The negative electrode 10 has a large number of holes 5 open on at least one side thereof and extending through the thickness of the active material layer. The negative electrode 10 further has a pair of current collecting layers 3a and 3b adapted to be brought into contact with an electrolyte. The active material layer 2 is between the current collecting layers 3a and 3b. The holes 5 open on the negative electrode 10 preferably have an opening area ratio of 0.3% to 30%. At least one of the pair of the current collecting layers 3a and 3b preferably has a thickness of 0.3 to 10 μm.

    摘要翻译： 非水系二次电池用负极10具有包含活性物质粒子2a的活性物质层2。 活性物质层2具有通过电镀沉积在颗粒之间的金属材料4。 负极10具有在其至少一个侧面上开口并且延伸穿过活性材料层的厚度的大量孔5。 负极10还具有适于与电解质接触的一对集流层3a和3b。 活性物质层2位于集流层3a和3b之间。 在负极10上打开的孔5的开口面积比优选为0.3％〜30％。 一对集电层3a和3b中的至少一个优选具有0.3至10μm的厚度。