公开(公告)号：US20170095797A1

公开(公告)日：2017-04-06

申请号：US15370705

申请日：2016-12-06

Applicant: IFP Energies Nouvelles

Inventor： Amandine CABIAC ,  Vincent ZOZAYA ,  Alexandre CHAMBARD ,  Cecile THOMAZEAU

IPC: B01J23/50 ,  B01J35/10 ,  B01J37/00 ,  B01J37/08 ,  B01J37/16 ,  B01J35/00 ,  B01J37/02

CPC classification number: B01J23/50 ,  B01J23/58 ,  B01J23/66 ,  B01J35/0006 ,  B01J35/006 ,  B01J35/0073 ,  B01J35/008 ,  B01J35/1014 ,  B01J35/1019 ,  B01J37/009 ,  B01J37/0236 ,  B01J37/024 ,  B01J37/0242 ,  B01J37/08 ,  B01J37/10 ,  B01J37/16 ,  C07C7/163 ,  C07C7/167 ,  C10G45/40 ,  Y02P20/52 ,  C07C11/06

Abstract: Disclosed are a catalyst, its preparation and use in selective hydrogenation, which catalyst has a porous support grain on which are deposited palladium and silver, and at least one alkali and/or alkaline earth metal; the porous support contains a refractory silica, alumina and/or silica-alumina oxide, where at least 80 wt. % of the palladium is distributed in a crust at the periphery of the support, and at least 80 wt. % of the silver is distributed in a crust at the periphery of the support, the local content of palladium at each point along the diameter of the grain follows the same course as the local content of silver.

公开(公告)号：US20160264882A1

公开(公告)日：2016-09-15

申请号：US15028451

申请日：2014-09-19

Applicant: IFP ENERGIES NOUVELLES

Inventor： Fabien CORVAISIER ,  Antoine FECANT ,  Cecile THOMAZEAU ,  Pascal RAYBAUD ,  Yves SCHUURMAN ,  David FARRUSSENG

IPC: C10G45/36 ,  B01J35/00 ,  B01J21/04 ,  B01J23/755 ,  B01J23/75

CPC classification number: C10G45/36 ,  B01J21/04 ,  B01J23/75 ,  B01J23/755 ,  B01J35/0006 ,  B01J35/08 ,  B01J35/1019 ,  B01J35/1042 ,  B01J37/0201

Abstract: The invention relates to a method for selective hydrogenation of a hydrocarbon feedstock that contains at least 2 carbon atoms per molecule and that has a final boiling point that is less than or equal to 250° C. and that comprises at least one polyunsaturated compound, in which in the presence of hydrogen, said feedstock is brought into contact with at least one catalyst that comprises a substrate and an active metal phase deposited on said substrate; said active metal phase comprises copper and at least one metal that is selected from between nickel and cobalt in a molar ratio of Cu:(Ni and/or Co) of greater than 1.

Abstract translation: 本发明涉及一种选择性氢化烃原料的方法，所述烃原料每分子含有至少2个碳原子，并且具有小于或等于250℃的最终沸点，并且其包含至少一种多不饱和化合物 在氢的存在下，所述原料与包含沉积在所述衬底上的衬底和活性金属相的至少一种催化剂接触; 所述活性金属相包含铜和选自镍和钴之中的至少一种金属，其中Cu：（Ni和/或Co）的摩尔比大于1。

公开(公告)号：US20170120224A1

公开(公告)日：2017-05-04

申请号：US15318611

申请日：2015-06-09

Applicant: IFP Energies nouvelles

Inventor： Malika BOUALLEG ,  Anne-Claire DUBREUIL ,  Emily MAILLE ,  Cecile THOMAZEAU

IPC: B01J23/755 ,  C07C5/10 ,  B01J21/04 ,  B01J35/10 ,  B01J37/16 ,  B01J37/00 ,  B01J37/02 ,  B01J37/08 ,  B01J37/04 ,  C07C5/03 ,  B01J37/03

CPC classification number: B01J23/755 ,  B01J21/04 ,  B01J33/00 ,  B01J35/006 ,  B01J35/1014 ,  B01J35/1019 ,  B01J35/1038 ,  B01J35/1042 ,  B01J35/1057 ,  B01J35/1061 ,  B01J35/1066 ,  B01J35/1071 ,  B01J35/108 ,  B01J37/009 ,  B01J37/0236 ,  B01J37/03 ,  B01J37/036 ,  B01J37/04 ,  B01J37/08 ,  B01J37/16 ,  B01J37/20 ,  C07C5/03 ,  C07C5/05 ,  C07C5/10 ,  C07C2521/04 ,  C07C2523/755 ,  C07C2601/14 ,  C10G45/36 ,  C10G45/40 ,  C10G45/48 ,  C10G45/52 ,  C10G2300/1096 ,  C10G2300/705 ,  C07C13/18 ,  C07C15/073 ,  C07C11/10 ,  C07C9/18

Abstract: The invention concerns a catalyst comprising a calcined oxide matrix which is mainly alumina and an active phase comprising nickel, said active phase being at least partially co-mixed within said calcined oxide matrix which is mainly alumina, the nickel content being in the range 5% to 65% by weight of said element with respect to the total mass of catalyst, said active phase not comprising metal from group VIB, the nickel particles having a diameter of less than 15 nm, said catalyst having a median mesopore diameter in the range 8 nm to 25 nm, a median macropore diameter of more than 300 nm, a mesopore volume, measured by mercury porosimetry, of 0.30 mL/g or more and a total pore volume, measured by mercury porosimetry, of 0.34 mL/g or more. The invention also concerns the process for the preparation of said catalyst, and its use in a hydrogenation process.

公开(公告)号：US20180154340A1

公开(公告)日：2018-06-07

申请号：US15317839

申请日：2015-06-09

Applicant: IFP Energies nouvelles

Inventor： Malika BOUALLEG ,  Anne-Claire DUBREUIL ,  Emily MAILLE ,  Cecile THOMAZEAU

IPC: B01J23/755 ,  C07C5/03 ,  C07C5/10 ,  C07C5/05 ,  C10G45/36 ,  C10G45/48 ,  B01J21/04 ,  B01J35/10 ,  B01J35/02 ,  B01J37/08 ,  B01J37/03 ,  B01J37/00 ,  B01J37/02 ,  B01J37/04

CPC classification number: B01J23/755 ,  B01J21/04 ,  B01J23/835 ,  B01J23/892 ,  B01J27/1853 ,  B01J33/00 ,  B01J35/006 ,  B01J35/023 ,  B01J35/026 ,  B01J35/1014 ,  B01J35/1019 ,  B01J35/1038 ,  B01J35/1042 ,  B01J35/1047 ,  B01J35/1061 ,  B01J35/1066 ,  B01J35/109 ,  B01J35/1095 ,  B01J37/0009 ,  B01J37/0045 ,  B01J37/009 ,  B01J37/0236 ,  B01J37/03 ,  B01J37/036 ,  B01J37/038 ,  B01J37/04 ,  B01J37/08 ,  B01J37/20 ,  B01J2523/00 ,  C07C5/03 ,  C07C5/05 ,  C07C5/10 ,  C07C2521/04 ,  C07C2523/755 ,  C07C2601/14 ,  C10G45/36 ,  C10G45/48 ,  C07C9/18 ,  C07C15/073 ,  C07C11/10 ,  C07C13/18 ,  B01J2523/31 ,  B01J2523/847

Abstract: A catalyst comprising a calcined oxide matrix which is mainly alumina and an active phase comprising nickel, said active phase being at least partially co-mixed within said calcined oxide matrix which is mainly alumina, the nickel content being in the range 5% to 65% by weight of said element with respect to the total mass of catalyst, said active phase not comprising any metal from group VIB, the nickel particles having a diameter of less than 15 nm, said catalyst having a median mesopore diameter in the range 12 nm to 25 nm, a median macropore diameter in the range 50 to 300 nm, a mesopore volume, measured by mercury porosimetry, of 0.40 mL/g or more and a total pore volume, measured by mercury porosimetry, of 0.45 mL/g or more. The process for the preparation of said catalyst, and its use in a hydrogenation process.

公开(公告)号：US20170259249A1

公开(公告)日：2017-09-14

申请号：US15509873

申请日：2015-08-21

Applicant: IFP Energies Nouvelles

Inventor： Malika BOUALLEG ,  Anne-Claire DUBREUIL ,  Emily MAILLE ,  Cecile THOMAZEAU

IPC: B01J23/755 ,  B01J35/00 ,  B01J35/10 ,  B01J35/02 ,  B01J37/03 ,  C10G45/48 ,  B01J37/02 ,  B01J37/08 ,  B01J37/16 ,  C07C7/163 ,  C10G45/36 ,  B01J21/04 ,  B01J37/00

CPC classification number: B01J23/755 ,  B01J21/04 ,  B01J23/835 ,  B01J23/892 ,  B01J35/0006 ,  B01J35/0013 ,  B01J35/006 ,  B01J35/026 ,  B01J35/10 ,  B01J35/1019 ,  B01J35/1038 ,  B01J35/1042 ,  B01J35/1061 ,  B01J35/108 ,  B01J37/0009 ,  B01J37/009 ,  B01J37/0201 ,  B01J37/0205 ,  B01J37/0207 ,  B01J37/0213 ,  B01J37/0236 ,  B01J37/031 ,  B01J37/035 ,  B01J37/036 ,  B01J37/08 ,  B01J37/16 ,  B01J37/18 ,  C01F7/141 ,  C01F7/34 ,  C01F7/441 ,  C01P2006/12 ,  C01P2006/14 ,  C01P2006/16 ,  C07C7/163 ,  C10G45/36 ,  C10G45/48 ,  C10G2300/705 ,  C07C9/15

Abstract: A supported catalyst having a calcined, predominantly aluminium, oxide support and an active phase of 5 to 65% by weight nickel with respect to the total mass of the catalyst, said active phase having no group VIB metal, the nickel particles having a diameter less than or equal to 20 nm, said catalyst having a mesopore median diameter greater than or equal to 14 nm, a mesopore volume measured by mercury porosimetry greater than or equal to 0.45 mL/g, a total pore volume measured by mercury porosimetry greater than or equal to 0.45 mL/g, a macropore volume less than 5% of the total pore volume, said catalyst being in the form of grains having an average diameter comprised between 0.5 and 10 mm. The invention also relates to the process for the preparation of said catalyst and the use thereof in a hydrogenation process.

公开(公告)号：US20130303813A1

公开(公告)日：2013-11-14

申请号：US13906567

申请日：2013-05-31

Applicant: IFP Energies nouvelles

Inventor： Amandine CABIAC ,  Vincent ZOZAYA ,  Alexandre CHAMBARD ,  Cecile THOMAZEAU

IPC: B01J23/66

CPC classification number: B01J23/50 ,  B01J23/58 ,  B01J23/66 ,  B01J35/0006 ,  B01J35/006 ,  B01J35/0073 ,  B01J35/008 ,  B01J35/1014 ,  B01J35/1019 ,  B01J37/009 ,  B01J37/0236 ,  B01J37/024 ,  B01J37/0242 ,  B01J37/08 ,  B01J37/10 ,  B01J37/16 ,  C07C7/163 ,  C07C7/167 ,  C10G45/40 ,  Y02P20/52 ,  C07C11/06

Abstract: Disclosed are a catalyst, its preparation and use in selective hydrogenation, which catalyst has a porous support grain on which are deposited palladium and silver, and at least one alkali and/or alkaline earth metal; the porous support contains a refractory silica, alumina and/or silica-alumina oxide, where at least 80 wt. % of the palladium is distributed in a crust at the periphery of the support, and at least 80 wt. % of the silver is distributed in a crust at the periphery of the support, the local content of palladium at each point along the diameter of the grain follows the same course as the local content of silver.

Abstract translation: 公开了一种催化剂，其制备和在选择性氢化中的用途，该催化剂具有多孔载体颗粒，其上沉积有钯和银，以及至少一种碱金属和/或碱土金属; 多孔载体包含耐火二氧化硅，氧化铝和/或二氧化硅 - 氧化铝氧化物，其中至少80wt。 钯的百分比分布在载体周边的外壳中，并且至少80wt。 银的百分比分布在支撑体周边的外壳中，沿着晶粒直径的每个点处的钯的局部含量与银的局部含量相同。

公开(公告)号：US20180207622A1

公开(公告)日：2018-07-26

申请号：US15317995

申请日：2015-06-09

Applicant: IFP Energies Nouvelles

Inventor： Malika BOUALLEG ,  Anne Claire DUBREUIL ,  Emily MAILLE ,  Cecile THOMAZEAU

IPC: B01J23/755 ,  C07C5/10 ,  B01J21/04 ,  B01J32/00

Abstract: Disclosed are a supported catalyst, its method of preparation and use in hydrogenation methods, which catalyst contains an oxide substrate that is for the most part calcined aluminum and an active phase that contains nickel, with the nickel content between 5 and 65% by weight in relation to the total mass of the catalyst, with the active phase not containing a metal from group VIB, the nickel particles having a diameter that is less than or equal to 20 nm, the catalyst having a median mesopore diameter of between 14 nm and 30 nm, a median macropore diameter of between 50 and 200 nm, a mesopore volume that is measured by mercury porosimetry that is greater than or equal to 0.40 mL/g, and a total pore volume that is measured by mercury porosimetry that is greater than or equal to 0.42 mL/g.

公开(公告)号：US20170128912A1

公开(公告)日：2017-05-11

申请号：US15318615

申请日：2015-06-09

Applicant: IFP Energies nouvelles

Inventor： Malika BOUALLEG ,  Anne-Claire DUBREUIL ,  Emily MAILLE ,  Cecile THOMAZEAU

IPC: B01J21/04 ,  C07C5/10 ,  B01J23/755 ,  B01J35/02 ,  B01J37/16 ,  B01J37/03 ,  B01J37/00 ,  B01J37/02 ,  B01J37/08 ,  C07C5/03 ,  B01J35/10

CPC classification number: B01J21/04 ,  B01J23/755 ,  B01J23/835 ,  B01J23/892 ,  B01J27/1853 ,  B01J33/00 ,  B01J35/006 ,  B01J35/023 ,  B01J35/026 ,  B01J35/1014 ,  B01J35/1019 ,  B01J35/1038 ,  B01J35/1042 ,  B01J35/1061 ,  B01J35/1066 ,  B01J35/1071 ,  B01J35/1076 ,  B01J35/108 ,  B01J35/109 ,  B01J37/0009 ,  B01J37/0045 ,  B01J37/009 ,  B01J37/0201 ,  B01J37/0207 ,  B01J37/0236 ,  B01J37/03 ,  B01J37/031 ,  B01J37/036 ,  B01J37/08 ,  B01J37/16 ,  B01J37/18 ,  B01J37/20 ,  C07C5/03 ,  C07C5/05 ,  C07C5/10 ,  C07C2521/04 ,  C07C2523/755 ,  C07C2601/14 ,  C10G45/36 ,  C10G45/48 ,  C07C15/073 ,  C07C13/18 ,  C07C11/08 ,  C07C9/18

Abstract: The invention relates to a supported catalyst that comprises an oxide substrate that is for the most part calcined aluminum and an active phase that comprises nickel, with the nickel content being between 5 and 65% by weight of said element in relation to the total mass of the catalyst, with said active phase not comprising a metal from group VIB, the nickel particles having a diameter that is less than or equal to 20 nm, said catalyst having a median mesopore diameter of between 8 nm and 25 nm, a median macropore diameter of greater than 200 nm, a mesopore volume that is measured by mercury porosimetry that is greater than or equal to 0.30 mL/g, and a total pore volume that is measured by mercury porosimetry that is greater than or equal to 0.34 mL/g. The invention also relates to the method for preparation of said catalyst and its use in a hydrogenation method.

公开(公告)号：US20160264881A1

公开(公告)日：2016-09-15

申请号：US15029966

申请日：2014-09-19

Applicant: IFP ENERGIES NOUVELLES

Inventor： Fabien CORVAISIER ,  Antoine FECANT ,  Cecile THOMAZEAU ,  Pascal RAYBAUD ,  Yves SCHUURMAN ,  David FARRUSSENG

IPC: C10G45/34 ,  B01J35/00 ,  B01J21/04 ,  B01J23/745 ,  B01J23/80

CPC classification number: C10G45/34 ,  B01J21/04 ,  B01J23/745 ,  B01J23/80 ,  B01J35/0006

Abstract: The invention concerns a method for selectively hydrogenating a hydrocarbon charge containing at least two carbon atoms per molecule, having a final boiling point which is less than or equal to 250° C., and comprising at least one polyunsaturated compound, wherein the charge, in the presence of hydrogen, is brought into contact with at least one catalyst comprising a carrier and an active metal phase deposited on the carrier, the active metal phase comprising iron and at least one metal selected from zinc and copper in a molar ratio of Fe:(Zn and/or Cu) of between 0.35 and 0.99.

Abstract translation: 本发明涉及一种选择性氢化每分子含有至少两个碳原子的烃电荷的方法，其终沸点小于或等于250℃，并且包含至少一种多不饱和化合物，其中电荷在 使氢的存在与至少一种催化剂接触，所述催化剂包含沉积在载体上的载体和活性金属相，活性金属相包含铁和至少一种选自锌和铜的金属，摩尔比为Fe： （Zn和/或Cu）为0.35〜0.99。