公开(公告)号：US20180179131A1

公开(公告)日：2018-06-28

申请号：US15739921

申请日：2016-04-21

申请人： IFP Energies Nouvelles

发明人： Emilie BRULE ,  Etienne GIRARD ,  Amandine CABIAC ,  Damien DELCROIX ,  Marc JACQUIN

IPC分类号： C07C31/18 ,  C07C27/00 ,  C07H3/06 ,  C07H3/02 ,  C01G25/02 ,  C01G45/12 ,  C01G23/00 ,  B01J21/06 ,  B01J23/34

CPC分类号： C07C27/00 ,  B01J21/063 ,  B01J21/066 ,  B01J23/34 ,  C01G23/006 ,  C01G25/02 ,  C01G45/125 ,  C01P2002/34 ,  C07B41/06 ,  C07B41/08 ,  C07B41/12 ,  C07C29/00 ,  C07C29/132 ,  C07C29/60 ,  C07C31/18 ,  C07H3/02 ,  C07H3/06 ,  Y02P20/52 ,  C07C31/02 ,  C07C31/202 ,  C07C31/205

摘要： The invention concerns a method for converting a feedstock selected from sugars or sugar alcohols, alone or in a mixture, into mono- or polyoxygenated compounds, wherein the feedstock is contacted with at least one heterogeneous catalyst comprising a support selected from perovskites of formula ABO3, in which A is selected from the elements Mg, Ca, Sr and Ba and B is selected from the elements Fe, Mn, Ti and Zr, and the oxides of elements selected from lanthanum, neodymium, yttrium and cerium, alone or in a mixture, which oxides can be doped with at least one element selected from alkali metals, alkaline earths and rare earths, in a reducing atmosphere, at a temperature of 100° C. to 300° C. and at a pressure of 0.1 MPa to 50 MPa.

公开(公告)号：US20180043337A1

公开(公告)日：2018-02-15

申请号：US15555658

申请日：2016-02-09

申请人： IFP Energies Nouvelles

发明人： Amandine CABIAC ,  Antoine HUGON

IPC分类号： B01J23/52 ,  B01J35/00 ,  C10G45/40 ,  B01J37/06 ,  B01J37/18 ,  B01J21/04 ,  B01J37/02

CPC分类号： B01J23/52 ,  B01J21/04 ,  B01J23/66 ,  B01J35/0006 ,  B01J35/0013 ,  B01J35/006 ,  B01J35/0066 ,  B01J35/0093 ,  B01J35/023 ,  B01J35/08 ,  B01J35/1009 ,  B01J35/1014 ,  B01J35/1019 ,  B01J35/1038 ,  B01J35/1042 ,  B01J35/1047 ,  B01J37/0201 ,  B01J37/0213 ,  B01J37/0236 ,  B01J37/06 ,  B01J37/10 ,  B01J37/18 ,  C07C5/05 ,  C07C7/163 ,  C07C2521/04 ,  C07C2523/52 ,  C10G45/40 ,  C07C11/08

摘要： A catalyst comprising gold and a porous support containing at least one refractory oxide, in which the gold content is in the range 0.01% to 5% by weight with respect to the total weight of catalyst, and in which the particles of gold are distributed homogeneously through said porous support and have a dimension, measured by transmission electron microscopy, in the range 0.5 to 5 nm.

公开(公告)号：US20210171839A1

公开(公告)日：2021-06-10

申请号：US16769736

申请日：2018-11-26

申请人： IFP Energies Nouvelles

发明人： Amandine CABIAC ,  Alexandra CHAUMONNOT ,  Etienne GIREL ,  Audrey BONDUELLE-SKRZYPCZAK

IPC分类号： C10G45/04 ,  C10G45/50 ,  C10G45/54 ,  B01J37/02 ,  B01J23/883 ,  B01J27/188 ,  B01J37/20 ,  B01J37/08

摘要： The invention relates to a method for hydroprocessing a hydrocarbon feed, operated at a temperature of between 180° C. and 450° C., in the presence of a catalyst comprising i) a composite material comprising a compound based on at least one crystalline aluminium solid and carbon, the deposited carbon content being between 1 and 25 wt. % of the total mass of the composite material, and ii) at least one element of group VIB and at least one element of group VIII, in the sulfide form thereof, said catalyst being produced by a method comprising at least: a) a step of bringing a carbon precursor into contact with a compound based on at least one crystalline aluminium solid, b) a step of thermally treating the solid produced by step a), c) repeating steps a) and b) until the desired deposited carbon content is reached, d) depositing at least one element of group VIB and at least one element of group VIII on the surface of the solid produced by step c), and e) a step of sulfidisation of the solid produced in step d).

公开(公告)号：US20160060194A1

公开(公告)日：2016-03-03

申请号：US14783148

申请日：2014-04-07

申请人： IFP ENERGIES NOUVELLES

发明人： Damien DELCROIX ,  Christophe VALLEE ,  Amandine CABIAC ,  Emmanuelle GUILLON

IPC分类号： C07C29/00

CPC分类号： C07C29/00 ,  C07G1/00 ,  C08B15/00 ,  C08H6/00 ,  C08H8/00

摘要： The invention concerns a process for the transformation of lignocellulosic biomass or cellulose into mono- or poly-oxygenated compounds, in which the lignocellulosic biomass or the cellulose is brought into simultaneous contact with a catalytic system comprising a combination of one or more homogeneous catalysts and one or more heterogeneous catalysts, in the same reaction chamber, in the presence of at least one solvent, said solvent being water alone or as a mixture with at least one other solvent, in a reducing atmosphere, and at a temperature in the range 80° C. to 250° C. and at a pressure in the range 0.5 MPa to 20 MPa.

摘要翻译： 本发明涉及将木质纤维素生物质或纤维素转化为单氧化或多氧化化合物的方法，其中木质纤维素生物质或纤维素与包含一种或多种均相催化剂和一种或多种均相催化剂的组合的催化体系同时接触 或更多的非均相催化剂，在相同的反应室中，在至少一种溶剂的存在下，所述溶剂是单独的水或与至少一种其它溶剂的混合物，在还原气氛中，在80℃的温度 在250℃，压力为0.5MPa至20MPa的范围内。

公开(公告)号：US20130303813A1

公开(公告)日：2013-11-14

申请号：US13906567

申请日：2013-05-31

申请人： IFP Energies nouvelles

发明人： Amandine CABIAC ,  Vincent ZOZAYA ,  Alexandre CHAMBARD ,  Cecile THOMAZEAU

IPC分类号： B01J23/66

CPC分类号： B01J23/50 ,  B01J23/58 ,  B01J23/66 ,  B01J35/0006 ,  B01J35/006 ,  B01J35/0073 ,  B01J35/008 ,  B01J35/1014 ,  B01J35/1019 ,  B01J37/009 ,  B01J37/0236 ,  B01J37/024 ,  B01J37/0242 ,  B01J37/08 ,  B01J37/10 ,  B01J37/16 ,  C07C7/163 ,  C07C7/167 ,  C10G45/40 ,  Y02P20/52 ,  C07C11/06

摘要： Disclosed are a catalyst, its preparation and use in selective hydrogenation, which catalyst has a porous support grain on which are deposited palladium and silver, and at least one alkali and/or alkaline earth metal; the porous support contains a refractory silica, alumina and/or silica-alumina oxide, where at least 80 wt. % of the palladium is distributed in a crust at the periphery of the support, and at least 80 wt. % of the silver is distributed in a crust at the periphery of the support, the local content of palladium at each point along the diameter of the grain follows the same course as the local content of silver.

摘要翻译： 公开了一种催化剂，其制备和在选择性氢化中的用途，该催化剂具有多孔载体颗粒，其上沉积有钯和银，以及至少一种碱金属和/或碱土金属; 多孔载体包含耐火二氧化硅，氧化铝和/或二氧化硅 - 氧化铝氧化物，其中至少80wt。 钯的百分比分布在载体周边的外壳中，并且至少80wt。 银的百分比分布在支撑体周边的外壳中，沿着晶粒直径的每个点处的钯的局部含量与银的局部含量相同。

公开(公告)号：US20180036717A1

公开(公告)日：2018-02-08

申请号：US15555096

申请日：2016-02-09

申请人： IFP Energies nouvelles

发明人： Amandine CABIAC ,  Antoine HUGON

IPC分类号： B01J23/52 ,  B01J35/00 ,  C10G45/40 ,  B01J37/02 ,  C07C5/09 ,  B01J23/44 ,  B01J35/02

CPC分类号： B01J23/52 ,  B01J23/44 ,  B01J23/66 ,  B01J35/006 ,  B01J35/0066 ,  B01J35/008 ,  B01J35/0093 ,  B01J35/023 ,  B01J35/08 ,  B01J35/1009 ,  B01J35/1014 ,  B01J35/1019 ,  B01J35/1038 ,  B01J35/1042 ,  B01J35/1047 ,  B01J37/0201 ,  B01J37/0211 ,  B01J37/024 ,  B01J37/031 ,  B01J37/06 ,  B01J37/10 ,  B01J37/14 ,  B01J37/18 ,  C07C5/09 ,  C07C7/167 ,  C07C2521/04 ,  C07C2523/44 ,  C07C2523/52 ,  C10G45/40 ,  C10G2400/20 ,  Y02P20/52 ,  C07C11/04

摘要： A catalyst comprising gold, palladium, and a porous support, in the form of at least one grain, in which: the gold content in the catalyst is in the range 0.5% to 3% by weight with respect to the total weight of catalyst; the mean particle size of the gold, estimated by transmission electron microscopy (TEM), is in the range 0.5 nm to 5 nm; the gold is distributed homogeneously in said porous support; at least 80% by weight of the palladium is distributed in an eggshell at the periphery of said porous support; the gold/palladium molar ratio is more than 2.

公开(公告)号：US20170095797A1

公开(公告)日：2017-04-06

申请号：US15370705

申请日：2016-12-06

申请人： IFP Energies Nouvelles

发明人： Amandine CABIAC ,  Vincent ZOZAYA ,  Alexandre CHAMBARD ,  Cecile THOMAZEAU

IPC分类号： B01J23/50 ,  B01J35/10 ,  B01J37/00 ,  B01J37/08 ,  B01J37/16 ,  B01J35/00 ,  B01J37/02

CPC分类号： B01J23/50 ,  B01J23/58 ,  B01J23/66 ,  B01J35/0006 ,  B01J35/006 ,  B01J35/0073 ,  B01J35/008 ,  B01J35/1014 ,  B01J35/1019 ,  B01J37/009 ,  B01J37/0236 ,  B01J37/024 ,  B01J37/0242 ,  B01J37/08 ,  B01J37/10 ,  B01J37/16 ,  C07C7/163 ,  C07C7/167 ,  C10G45/40 ,  Y02P20/52 ,  C07C11/06

摘要： Disclosed are a catalyst, its preparation and use in selective hydrogenation, which catalyst has a porous support grain on which are deposited palladium and silver, and at least one alkali and/or alkaline earth metal; the porous support contains a refractory silica, alumina and/or silica-alumina oxide, where at least 80 wt. % of the palladium is distributed in a crust at the periphery of the support, and at least 80 wt. % of the silver is distributed in a crust at the periphery of the support, the local content of palladium at each point along the diameter of the grain follows the same course as the local content of silver.

公开(公告)号：US20160376246A1

公开(公告)日：2016-12-29

申请号：US14903335

申请日：2014-07-03

申请人： IFP ENERGIES NOUVELLES

发明人： Damien DELCROIX ,  Christophe VALLEE ,  Amandine CABIAC ,  Emmanuelle GUILLON

IPC分类号： C07D309/06 ,  C07C29/132 ,  B01J37/18 ,  B01J23/652 ,  B01J37/08 ,  C07D307/32 ,  C07C51/00

CPC分类号： C07D309/06 ,  B01J23/6527 ,  B01J37/08 ,  B01J37/18 ,  C07C29/132 ,  C07C51/00 ,  C07D307/32 ,  C07G1/00

摘要： The invention relates to a process for transformation of lignocellulosic biomass or cellulose using in a simultaneous manner an original combination of at least two homogeneous catalysts and one or more heterogeneous catalyst(s). The use of these catalysts makes it possible to obtain mono-oxidized or poly-oxidized upgradable products directly and to limit the formation of non-upgradable products. Non-upgradable products are defined as soluble and non-soluble humins, i.e., products of high molecular weight obtained from undesirable condensation reactions of sugars and their derivatives.

摘要翻译： 本发明涉及使用至少两种均相催化剂和一种或多种非均相催化剂的原始组合的同时方式转化木质纤维素生物质或纤维素的方法。 使用这些催化剂使得可以直接获得单氧化或多氧化可升级产物并限制不可升级产品的形成。 不可升级的产品被定义为可溶性和不可溶性的腐殖质，即从糖和其衍生物的不期望的缩合反应获得的高分子量产物。

公开(公告)号：US20160090331A1

公开(公告)日：2016-03-31

申请号：US14862296

申请日：2015-09-23

申请人： IFP Energies Nouvelles

发明人： Etienne GIRARD ,  Amandine CABIAC ,  Damien DELCROIX

IPC分类号： C07B33/00 ,  B01J21/02 ,  B01J21/06 ,  B01J23/34 ,  B01J23/42 ,  B01J23/755

CPC分类号： C07B33/00 ,  B01J21/02 ,  B01J21/063 ,  B01J21/066 ,  B01J23/002 ,  B01J23/34 ,  B01J23/42 ,  B01J23/58 ,  B01J23/6562 ,  B01J23/755 ,  B01J23/78 ,  B01J23/8906 ,  B01J37/0201 ,  B01J37/0236 ,  B01J37/18 ,  C07C27/04 ,  C07C29/132 ,  C07C29/60 ,  Y02P20/52 ,  C07C31/202 ,  C07C31/205 ,  C07C31/10 ,  C07C31/207 ,  C07C31/20

摘要： Process for transformation of a feedstock of lignocellulosic biomass and/or the carbohydrates, into mono-oxidized or poly-oxidized compounds, wherein the feedstock is contacted, simultaneously, with a catalytic system that comprises one or more homogeneous catalysts selected from Brønsted acids and heterogeneous catalysts comprising at least one metal selected from groups 6 to 11 and 14 of the periodic table, and a substrate selected from perovskites of formula ABO3, in which A is Mg, Ca, Sr, Ba, and La, and B is selected from Fe, Mn, Ti and Zr, oxides of lanthanum, neodymium, yttrium, cerium, and niobium, or mixtures thereof, and mixed oxides of aluminates of zinc, copper, and cobalt, or mixtures thereof, in the same reaction chamber, with at least one solvent, being water or water with at least one other solvent, under reducing atmosphere, and temperature of 50° C. to 300° C., and pressure of 0.5 MPa to 20 MPa.

摘要翻译： 将木质纤维素生物质和/或碳水化合物的原料转化为单氧化或多氧化化合物的方法，其中原料同时与催化体系接触，所述催化体系包含一种或多种选自布朗斯台德酸和异构体的均相催化剂 包含选自元素周期表第6至11和14族中的至少一种金属的催化剂和选自式ABO3的钙钛矿的底物，其中A是Mg，Ca，Sr，Ba和La，B选自Fe ，Mn，Ti和Zr，镧，钕，钇，铈和铌的氧化物或其混合物，以及锌，铜和钴的铝酸盐或其混合物的混合氧化物或其混合物在至少相同的反应室中 一种溶剂，在还原气氛下，在50℃至300℃，压力为0.5MPa至20MPa的情况下，与水或水一起使用至少一种其它溶剂。