公开(公告)号：US20240301191A1

公开(公告)日：2024-09-12

申请号：US17768134

申请日：2020-10-13

Applicant: INEOS STYROLUTION GROUP GMBH

Inventor： Christian RUTHARD

IPC: C08L25/12 ,  C08J3/20 ,  C08K3/04 ,  C08K5/3435 ,  C08L25/16 ,  C08L33/12 ,  C08L51/04

CPC classification number: C08L25/12 ,  C08J3/203 ,  C08K3/04 ,  C08K5/3435 ,  C08L25/16 ,  C08L33/12 ,  C08L51/04 ,  C08J2325/12 ,  C08J2433/12 ,  C08L2201/08 ,  C08L2205/035

Abstract: The invention relates to a thermoplastic molding composition (P) comprising: (A) thermoplastic polymer composition (A) comprising: (A-1) 10 to 50 wt.-% of graft copolymer (A-1), (A-2) 1 to 50 wt.-%, of thermoplastic polymer matrix (A-2) based on one or more vinylaromatic copolymers, (A-3) 20 to 50 wt.-%, of polymerized alkyl methacrylate component (A-3), and (A-4) 0 to 45 wt.-% of comonomer which is copolymerized with the at least one polymerized alkyl methacrylate component (A-3), where the sum of (A-1), (A-2), (A-3) and optional comonomers (A-4) is 83.2 to 99.8 wt.-%; (B) a hindered amine light stabilizer composition (B), comprising at least two of substances (B-1) to (B-3): (B-1) 0 to 0.9 wt.-%, of at least one hindered amine light stabilizer having a dipiperidine structure with at least one alkyl group at each of the 2 and 6 positions of the dipiperidine structure (B-2) 0 to 0.9 wt.-%, of a hindered amine light stabilizer mixture having a monopiperidine structure with at least one alkyl group at each of the 2 and 6 positions of the monopiperidine structure, and (B-3) 0 to 2 wt.-%, of at least one hindered amine light stabilizer having a polymeric structure comprising piperidine groups with at least one alkyl group at each of the 2 and 6 positions of the piperidine groups (C) 0 to 5 wt.-%, of one or more further additives (C), different from (B); and (D) 0 to 10 wt.-%, of colorants, dyes and/or pigments (D), different from (C); wherein the constituents (A) to (D) sum up to 100 wt.-% of the molding composition (P).

公开(公告)号：US20240093018A1

公开(公告)日：2024-03-21

申请号：US17766877

申请日：2020-10-13

Applicant: INEOS STYROLUTION GROUP GMBH

Inventor： Christian RUTHARD ,  Oliver CARSTENSEN ,  Eric CHAMBOST

IPC: C08L25/12 ,  C08J3/20 ,  C08K13/02

CPC classification number: C08L25/12 ,  C08J3/203 ,  C08K13/02 ,  C08K5/3435 ,  C08L2201/08 ,  C08L2203/30 ,  C08L2205/025 ,  C08L2205/035 ,  C08L2205/06

Abstract: The invention relates to a thermoplastic molding composition (P) comprising: (A) 81.1 to 99.7 wt. -% of at thermoplastic polymer composition (A) comprising: (A-1) graft copolymer (A-1), and (A-2) thermoplastic matrix (A-2) based on vinylaromatic copolymers; (B) at least one hindered amine light stabilizing composition (B) comprising: (B-1) 0.2 to 0.9 wt.-%, of at least one hindered amine light stabilizer having a dipiperidine structure with at least one alkyl group at each of the 2 and 6 positions of the dipiperidine structure and (B-2) 0.1 to 0.9 wt.-%, of a hindered amine light stabilizer mixture having a monopiperidine structure with at least one alkyl group at each of the 2 and 6 positions of the monopiperidine structure and (B-3) 0 to 2 wt.-%, of at least one hindered amine light stabilizer having a polymeric structure comprising piperidine groups with at least one alkyl group at each of the 2 and 6 positions of the piperidine groups, (C) 0 to 10 wt.-%, of colorants, dyes and/or pigments (C); and (D) 0 to 5 wt.-%, of further additives (D) different from (B) and (C); provided that the thermoplastic molding composition (P) further comprises 0.001 wt.-% to 0.1 wt.-%, based on the total weight of the molding composition (P), of oligomers and/or polymers comprising ethylene and/or propylene repeating units or provided that the thermoplastic molding composition (P) further comprises 0 wt.-%, based on the total weight of the molding composition (P), of oligomers and/or polymers comprising ethylene and/or propylene repeating units (as component E), wherein the constituents (A) to (E) sum up to 100 wt.-% of the molding composition (P).

公开(公告)号：US20210292460A1

公开(公告)日：2021-09-23

申请号：US17262026

申请日：2019-07-22

Applicant: INEOS STYROLUTION GROUP GMBH

Inventor： Tobias SCHULZ ,  Wolfgang FISCHER ,  Norbert NIESSNER ,  Christian RUTHARD ,  Hannes KERSCHBAUMER

IPC: C08F257/02 ,  C08K5/00

Abstract: Thermoplastic molding composition comprising a graft copolymer B with core-shell structure having a particle diameter dw of 280 to 450 nm, comprising a core B1 and three layers B2 to B4: B1: 6 to 19 wt.-% of a core B1 comprising crosslinked polystyrene; B2: 41 to 54 wt.-% of a first layer B2 of a crosslinked acrylate polymer; B3: 1 to 19 wt.-% of a second layer B3 of polystyrene; and B4: 21 to 39 wt.-% of a third layer B4 consisting of SAN copolymer.

公开(公告)号：US20210292459A1

公开(公告)日：2021-09-23

申请号：US17262018

申请日：2019-07-22

Applicant: INEOS STYROLUTION GROUP GMBH

Inventor： Tobias SCHULZ ,  Wolfgang FISCHER ,  Norbert NIESSNER ,  Christian RUTHARD ,  Hannes KERSCHBAUMER

IPC: C08F257/02 ,  C08L33/20

Abstract: Polyacrylate graft rubber copolymer B and an impact modified thermoplastic molding composition thereof, where the graft copolymer B is composed of: B1: 50 to 70 wt.-% crosslinked acrylate polymer graft base B1 B2: 30 to 50 wt.-% graft shell B2 comprising a first layer B21 of vinylaromatic monomers, and a second layer B22 of vinylaromatic monomers B21-1 and nitrile monomers B22-2; wherein the particle diameter dw of the graft base B1 is 255 to 290 nm; the fraction of B21 is 10 to 26 wt.-%; and the amount of B22-2, is 20 to 30 wt.-%.

公开(公告)号：US20240117171A1

公开(公告)日：2024-04-11

申请号：US17769005

申请日：2020-10-13

Applicant: INEOS STYROLUTION GROUP GMBH

Inventor： Christian RUTHARD

IPC: C08L25/12 ,  C08K3/04 ,  C08K5/3435 ,  C08L51/06

CPC classification number: C08L25/12 ,  C08K3/04 ,  C08K5/3435 ,  C08L51/06

Abstract: The invention relates to a molding composition (P) comprising: (A) 83.2 to 98.5 wt.-% of a thermoplastic polymer composition (A) comprising: (A-1) at least one graft copolymer (A-1), and (A-2) at least one thermoplastic matrix polymer (A-2) based on one or more vinylaromatic copolymers; (B) 1.5 to 3 wt.-% of carbon black (B) or a mixture of carbon blacks (B); (C) a hindered amine light stabilizer composition (C), comprising at least two of substances (C-1) to (C-3): (C-1) 0 to 0.9 wt.-%, based on the total weight of the molding composition (P), of at least one hindered amine light stabilizer having a dipiperidine structure with at least one alkyl group at each of the 2 and 6 positions of the dipiperidine structure, (C-2) 0 to 0.9 wt.-% of a hindered amine light stabilizer mixture having a monopiperidine structure with at least one alkyl group at each of the 2 and 6 positions of the monopiperidine structure and (C-3) 0 to 2 wt.-%, of at least one hindered amine light stabilizer having a polymeric structure comprising piperidine groups with at least one alkyl group at each of the 2 and 6 positions of the piperidine groups provided that the at least one hindered amine light stabilizer composition (C) is present in the molding composition (P) in an amount of at least 0.2 wt.-%; (D) 0 to 5 wt.-%, of one or more further additives (D), different from (B) and (C); and (E) 0 to 5 wt.-%, of one or more further colorants, dyes or pigments (E), different from (B) and (D); wherein the constituents (A) to (E) sum up to 100 wt.-% of the molding composition (P).

公开(公告)号：US20210261740A1

公开(公告)日：2021-08-26

申请号：US17251324

申请日：2019-06-11

Applicant: INEOS STYROLUTION GROUP GMBH

Inventor： Tobias SCHULZ ,  Christian RUTHARD

IPC: C08J3/00 ,  C08J3/20 ,  C08L51/00 ,  C08L25/12 ,  C08L83/04 ,  C08L83/10 ,  C08F220/18 ,  C08K3/013 ,  C08K5/00

Abstract: The present invention relates to a method of improving UV resistance of a vinylaro-maticmolding mass by means of compounding a thermoplastic polymer composition which comprises at least one graft copolymer with an organopolysiloxane compound and optionally further components.

公开(公告)号：US20240287302A1

公开(公告)日：2024-08-29

申请号：US18573716

申请日：2022-06-20

Applicant: INEOS STYROLUTION GROUP GMBH

Inventor： Norbert NIESSNER ,  Christian RUTHARD ,  Shridhar MADHAV ,  Kirit GEVARIA ,  Manjula AK ,  Pankaj ROHIT ,  Saurabh MISHRA

IPC: C08L51/00 ,  C08L23/08 ,  C08L25/12

CPC classification number: C08L51/003 ,  C08L23/0853 ,  C08L25/12 ,  C08L2201/08 ,  C08L2203/30 ,  C08L2205/025 ,  C08L2205/035 ,  C08L2207/53

Abstract: Weather resistant thermoplastic ASA compositions comprising (A): 20 to 80 wt.-% of a polymer mixture (A) consisting of: 35 to 65 wt.-% graft copolymer GR1 (D50 of 55 to 170 nm), composed of: 40 to 80 wt.-% cross-linked C1 to C8 alkyl acrylate graft base G11 and 20 to 60 wt.-% SAN-copolymer graft shell G12; and 65 to 35 wt.-% SAN copolymer S1 (MVR 50 to 70 ml/10 min); (B): 5 to 35 wt.-% polymer mixture (B) consisting of: 35 to 65 wt.-% graft copolymer GR2 (D50 of 410 to 1000 nm), composed of: 40 to 80 wt.-% cross-linked C1 to C8 alkyl acrylate graft base G21 and 20 to 60 wt.-% SAN-copolymer graft shell G22; and 65 to 35 wt.-% SAN copolymer S2 (MVR 11 to 25 ml/10 min); (C): 10 to 40 wt.-% of at least one SAN copolymer (C) (MVR 11 to 70 ml/10 min); (D): 1 to 15 wt.-% EVA copolymer (D) (VA>25 wt.-%); are particularly useful e.g. in the automotive industry.

公开(公告)号：US20240026146A1

公开(公告)日：2024-01-25

申请号：US17768045

申请日：2020-10-13

Applicant: INEOS STYROLUTION GROUP GMBH

Inventor： Christian RUTHARD

IPC: C08L35/04

CPC classification number: C08L35/04 ,  C08L2205/03 ,  C08L2205/025 ,  C08L2201/08 ,  B60R13/00

Abstract: The invention relates to a molding composition (P) comprising: (A) 81.7 to 99.4 wt.-% of at least one thermoplastic polymer composition (A); (B) at least one hindered amine light stabilizing composition (B) comprising: (B-1) 0.1 to 0.9 wt.-% of a hindered amine light stabilizer mixture having a monopiperidine structure, (B-2) 0 to 0.4 wt.-% of at least one hindered amine light stabilizer having a dipiperidine structure with at least one alkyl group at each of the 2 and 6 positions of the dipiperidine structure and (B-3) 0.5 to 2 wt. -% of at least one hindered amine light stabilizer having a polymeric structure comprising piperidine groups (C) 0 to 10 wt.-% of one or more colorants, dyes and/or pigments (C); and (D) 0 to 5 wt.-%, based on the total weight of the molding composition (P), of one or more further additives (D); wherein constituents (A) to (D) sum up to 100 wt.-% of molding composition (P).