公开(公告)号：US06387997B1

公开(公告)日：2002-05-14

申请号：US09437617

申请日：1999-11-10

申请人： Mary E. Grolemund ,  Masayuki Nakajima ,  Thomas R. Hockswender ,  Kurt G. Olson

发明人： Mary E. Grolemund ,  Masayuki Nakajima ,  Thomas R. Hockswender ,  Kurt G. Olson

IPC分类号： C08F28312

CPC分类号： C09D183/10 ,  C08F283/12 ,  C08G77/442 ,  C09D151/08

摘要： An aqueous dispersion including polymeric microparticles which are prepared in a medium substantially free of organic solvent from a mixture of one or more reaction products of polymerizable, ethylenically unsaturated monomers, and one or more reactive organopolysiloxanes is provided. Pigmented film-forming compositions, curable compositions and topcoats of multi-component composite coating composition containing the above-described dispersions also are provided. The substantially solvent-free film-forming compositions of the invention are storage stable at room temperature and provide coatings with excellent application properties such as sag resistance and tack-free overspray, and excellent performance properties such as hardness and scratch resistance. The film-forming compositions are suitable for wet-on-wet application over a base coat with little or no mudcracking.

摘要翻译： 提供了包含聚合物微粒的水分散体，其在基本上不含有机溶剂的介质中由可聚合的烯属不饱和单体和一种或多种反应性有机聚硅氧烷的一种或多种反应产物的混合物制备。 还提供了含有上述分散体的着色成膜组合物，可固化组合物和多组分复合涂料组合物的面漆。 本发明的基本上无溶剂的成膜组合物在室温下保存稳定，并提供具有优异应用性能的涂料，例如耐下落性和无粘性的过喷，以及优异的性能如硬度和耐刮擦性。 成膜组合物适用于湿法湿法施涂于基底涂层上，很少或没有泥浆破裂。

公开(公告)号：US06657001B1

公开(公告)日：2003-12-02

申请号：US09629444

申请日：2000-07-31

申请人： Lawrence G. Anderson ,  Karen A. Barkac ,  Shawn A. DeSaw ,  Marvis E. Hartman ,  Deborah E. Hayes ,  Thomas R. Hockswender ,  Kymarie L. Kuster ,  Masayuki Nakajima ,  Kurt G. Olson ,  Richard J. Sadvary ,  Dennis A. Simpson ,  Shiryn Tyebjee ,  Truman F. Wilt

发明人： Lawrence G. Anderson ,  Karen A. Barkac ,  Shawn A. DeSaw ,  Marvis E. Hartman ,  Deborah E. Hayes ,  Thomas R. Hockswender ,  Kymarie L. Kuster ,  Masayuki Nakajima ,  Kurt G. Olson ,  Richard J. Sadvary ,  Dennis A. Simpson ,  Shiryn Tyebjee ,  Truman F. Wilt

IPC分类号： C08L8304

CPC分类号： B82Y30/00 ,  C08J3/20 ,  C08K3/01 ,  C08K3/22 ,  C08K3/36 ,  C08K2201/011 ,  C09D7/00 ,  C09D7/61 ,  C09D7/67 ,  C09D7/68 ,  C09D7/69 ,  C09D183/04 ,  C08L2666/14 ,  C08L2666/54 ,  C08L2666/04

摘要： Compositions are provided which contain (a) one or more polysiloxanes comprising at least one reactive functional group; a plurality of particles; and, optionally, one or more curing agents comprising at least one functional group that is reactive with any reactive functional group of polysiloxane (a). Additionally, a process for applying the multi-component composite coatings described above to a substrate and coated substrates are provided. A process for preparing the coating compositions also is provided. The multi-component composite coating compositions of the invention provide highly scratch resistant color-plus-clearcoatings capable of retaining scratch resistance after weathering.

摘要翻译： 提供了包含（a）一种或多种包含至少一个反应性官能团的聚硅氧烷的组合物; 多个颗粒; 和任选的一种或多种固化剂，其包含与聚硅氧烷（a）的任何反应性官能团反应的至少一个官能团。 另外，提供了将上述多组分复合涂层施加到基底和涂覆的基底上的方法。 还提供了制备涂料组合物的方法。 本发明的多组分复合涂料组合物提供了耐风化后能够保持耐刮擦性的高耐划伤性的彩色 - 透明涂层。

公开(公告)号：US06803408B2

公开(公告)日：2004-10-12

申请号：US10456854

申请日：2003-06-09

申请人： Lawrence G. Anderson ,  Karen A. Barkac ,  Shawn A. DeSaw ,  Marvis E. Hartman ,  Deborah E. Hayes ,  Thomas R. Hockswender ,  Kymarie L. Kuster ,  Masayuki Nakajima ,  Kurt G. Olson ,  Richard J. Sadvary ,  Dennis A. Simpson ,  Shiryn Tyebjee ,  Truman F. Wilt

发明人： Lawrence G. Anderson ,  Karen A. Barkac ,  Shawn A. DeSaw ,  Marvis E. Hartman ,  Deborah E. Hayes ,  Thomas R. Hockswender ,  Kymarie L. Kuster ,  Masayuki Nakajima ,  Kurt G. Olson ,  Richard J. Sadvary ,  Dennis A. Simpson ,  Shiryn Tyebjee ,  Truman F. Wilt

IPC分类号： C08L8304

CPC分类号： B82Y30/00 ,  C08J3/20 ,  C08K3/01 ,  C08K3/22 ,  C08K3/36 ,  C08K2201/011 ,  C09D7/00 ,  C09D7/61 ,  C09D7/67 ,  C09D7/68 ,  C09D7/69 ,  C09D183/04 ,  C08L2666/14 ,  C08L2666/54 ,  C08L2666/04

摘要： Compositions are provided which contain (a) one or more polysiloxanes comprising at least one reactive functional group; a plurality of particles; and, optionally, one or more curing agents comprising at least one functional group that is reactive with any reactive functional group of polysiloxane (a). Additionally, a process for applying the multi-component composite coatings described above to a substrate and coated substrates are provided. A process for preparing the coating compositions also is provided. The multi-component composite coating compositions of the invention provide highly scratch resistant color-plus-clearcoatings capable of retaining scratch resistance after weathering.

摘要翻译： 提供了包含（a）一种或多种包含至少一个反应性官能团的聚硅氧烷的组合物; 多个颗粒; 和任选的一种或多种固化剂，其包含与聚硅氧烷（a）的任何反应性官能团反应的至少一个官能团。 另外，提供了将上述多组分复合涂层施加到基底和涂覆的基底上的方法。 还提供了制备涂料组合物的方法。 本发明的多组分复合涂料组合物提供了耐风化后能够保持耐刮擦性的高耐划伤性的彩色 - 透明涂层。

公开(公告)号：US06759478B2

公开(公告)日：2004-07-06

申请号：US10456552

申请日：2003-06-09

申请人： Lawrence G. Anderson ,  Karen A. Barkac ,  Shawn A. DeSaw ,  Marvis E. Hartman ,  Deborah E. Hayes ,  Thomas R. Hockswender ,  Kymarie L. Kuster ,  Gregory J. McCollum ,  Masayuki Nakajima ,  Kurt G. Olson ,  Richard J. Sadvary ,  Dennis A. Simpson ,  Shiryn Tyebjee ,  Truman F. Wilt

发明人： Lawrence G. Anderson ,  Karen A. Barkac ,  Shawn A. DeSaw ,  Marvis E. Hartman ,  Deborah E. Hayes ,  Thomas R. Hockswender ,  Kymarie L. Kuster ,  Gregory J. McCollum ,  Masayuki Nakajima ,  Kurt G. Olson ,  Richard J. Sadvary ,  Dennis A. Simpson ,  Shiryn Tyebjee ,  Truman F. Wilt

IPC分类号： C08L8304

CPC分类号： B82Y30/00 ,  C08J3/20 ,  C08K3/01 ,  C08K3/013 ,  C08K3/22 ,  C08K3/36 ,  C08K2201/011 ,  C09D7/00 ,  C09D7/61 ,  C09D7/67 ,  C09D7/68 ,  C09D7/69 ,  C09D183/04 ,  C08L2666/28 ,  C08L2666/54 ,  C08L2666/14 ,  C08L2666/04

摘要： Coating compositions are provided which are formed from components comprising (a) at least one polysiloxane comprising at least one reactive functional group; (b) at least one reactant comprising at least one functional group that is reactive with at least one functional group selected from the at least one reactive functional group of the at least one polysiloxane and at least one functional group of at least one reactant; and (c) a plurality of particles, wherein each component is different, and wherein the at least one reactive functional group of the at least one polysiloxane and the at least one functional group of the at least one reactant are substantially nonreactive with the particles. A multi-component composite coating composition formed from a basecoat and a topcoat deposited from the curable coating composition also is provided. The multi-component composite coating compositions of the invention provide highly scratch resistant color-plus-clearcoatings capable of retaining scratch resistance after weathering.

摘要翻译： 提供涂料组合物，其由包含（a）至少一种包含至少一个反应性官能团的聚硅氧烷的组分形成; （b）至少一种包含至少一种与至少一种选自至少一种聚硅氧烷的至少一种反应性官能团和至少一种反应物官能团的官能团反应的官能团的官能团; 和（c）多个颗粒，其中每个组分是不同的，并且其中所述至少一种聚硅氧烷的至少一种反应性官能团和所述至少一种反应物的至少一种官能团基本上与颗粒不反应。 还提供了由底涂层和从可固化涂料组合物沉积的面涂层形成的多组分复合涂料组合物。 本发明的多组分复合涂料组合物提供了耐风化后能够保持耐刮擦性的高耐划伤性的彩色 - 透明涂层。

公开(公告)号：US06610777B1

公开(公告)日：2003-08-26

申请号：US09629420

申请日：2000-07-31

申请人： Lawrence G. Anderson ,  Shawn A. De Saw ,  Marvis E. Hartman ,  Deborah E. Hayes ,  Thomas R. Hockswender ,  Kymarie L. Kuster ,  Michael Allen Mayo ,  Masayuki Nakajima ,  Kurt G. Olson ,  Richard J. Sadvary ,  Laura E. Schilling ,  Dennis A. Simpson ,  Shiryn Tyebjee ,  Truman F. Wilt

发明人： Lawrence G. Anderson ,  Shawn A. De Saw ,  Marvis E. Hartman ,  Deborah E. Hayes ,  Thomas R. Hockswender ,  Kymarie L. Kuster ,  Michael Allen Mayo ,  Masayuki Nakajima ,  Kurt G. Olson ,  Richard J. Sadvary ,  Laura E. Schilling ,  Dennis A. Simpson ,  Shiryn Tyebjee ,  Truman F. Wilt

IPC分类号： C08L8304

CPC分类号： B82Y30/00 ,  C08J3/20 ,  C08K3/01 ,  C08K3/013 ,  C08K2201/011 ,  C09D7/00 ,  C09D7/61 ,  C09D7/62 ,  C09D7/69 ,  C09D183/04 ,  C08L2666/14 ,  C08L2666/54 ,  C08L2666/04 ,  C08L2666/28

摘要： Coating compositions are provided which include a polysiloxane comprising at least one reactive functional group and at least one material comprising at least one reactive functional group. Also provided are multi-layer composite coatings formed from a basecoat deposited from a pigmented coating composition and a topcoat applied over the basecoat, the topcoat deposited from the aforementioned coating composition. A method for improving the scratch resistance of a coated substrate, as well as coated substrates also are provided. The compositions of the invention provide highly scratch resistant coatings, particularly highly scratch resistant color-plus-clearcoatings.

摘要翻译： 提供涂料组合物，其包括包含至少一个反应性官能团的聚硅氧烷和至少一种包含至少一个反应性官能团的材料。 还提供了由从着色涂料组合物沉积的底涂层和涂覆在底涂层上的顶涂层，由上述涂料组合物沉积的面漆形成的多层复合涂层。 还提供了一种用于改善涂覆基材的耐擦伤性的方法以及涂覆的基材。 本发明的组合物提供高度耐刮擦的涂层，特别是高度耐刮擦的彩色 - 透明涂层。

公开(公告)号：US06593417B1

公开(公告)日：2003-07-15

申请号：US09629443

申请日：2000-07-31

申请人： Lawrence G. Anderson ,  Karen A. Barkac ,  Shawn A. DeSaw ,  Marvis E. Hartman ,  Deborah E. Hayes ,  Thomas R. Hockswender ,  Kymarie L. Kuster ,  Gregory J. McCollum ,  Masayuki Nakajima ,  Kurt G. Olson ,  Richard J. Sadvary ,  Dennis A. Simpson ,  Shiryn Tyebjee ,  Truman F. Wilt

发明人： Lawrence G. Anderson ,  Karen A. Barkac ,  Shawn A. DeSaw ,  Marvis E. Hartman ,  Deborah E. Hayes ,  Thomas R. Hockswender ,  Kymarie L. Kuster ,  Gregory J. McCollum ,  Masayuki Nakajima ,  Kurt G. Olson ,  Richard J. Sadvary ,  Dennis A. Simpson ,  Shiryn Tyebjee ,  Truman F. Wilt

IPC分类号： C08L8304

CPC分类号： B82Y30/00 ,  C08J3/20 ,  C08K3/01 ,  C08K3/013 ,  C08K3/22 ,  C08K3/36 ,  C08K2201/011 ,  C09D7/00 ,  C09D7/61 ,  C09D7/67 ,  C09D7/68 ,  C09D7/69 ,  C09D183/04 ,  C08L2666/28 ,  C08L2666/54 ,  C08L2666/14 ,  C08L2666/04

摘要： Coating compositions are provided which are formed from components comprising (a) at least one polysiloxane comprising at least one reactive functional group; (b) at least one reactant comprising at least one functional group that is reactive with at least one functional group selected from the at least one reactive functional group of the at least one polysiloxane and at least one functional group of at least one reactant; and (c) a plurality of particles, wherein each component is different, and wherein the at least one reactive functional group of the at least one polysiloxane and the at least one functional group of the at least one reactant are substantially nonreactive with the particles. A multi-component composite coating composition formed from a basecoat and a topcoat deposited from the curable coating composition also is provided. The multi-component composite coating compositions of the invention provide highly scratch resistant color-plus-clearcoatings capable of retaining scratch resistance after weathering.

摘要翻译： 提供涂料组合物，其由包含（a）至少一种包含至少一个反应性官能团的聚硅氧烷的组分形成; （b）至少一种包含至少一种与至少一种选自至少一种聚硅氧烷的至少一种反应性官能团和至少一种反应物官能团的官能团反应的官能团的官能团; 和（c）多个颗粒，其中每个组分是不同的，并且其中所述至少一种聚硅氧烷的至少一种反应性官能团和所述至少一种反应物的至少一种官能团基本上与颗粒不反应。 还提供了由底涂层和从可固化涂料组合物沉积的面涂层形成的多组分复合涂料组合物。 本发明的多组分复合涂料组合物提供了耐风化后能够保持耐刮擦性的高耐划伤性的彩色 - 透明涂层。

公开(公告)号：US07005472B2

公开(公告)日：2006-02-28

申请号：US10784830

申请日：2004-02-24

申请人： Lawrence G. Anderson ,  Karen A. Barkac ,  Shawn A. DeSaw ,  Marvis E. Hartman ,  Deborah E. Hayes ,  Thomas R. Hockswender ,  Kymarje L. Koster ,  Gregory J. McCollum ,  Masayuki Nakajima ,  Kurt G. Olson ,  Richard J. Sadvary ,  Dennis A. Simpson ,  Shiryn Tyebjee ,  Truman F. Wilt

发明人： Lawrence G. Anderson ,  Karen A. Barkac ,  Shawn A. DeSaw ,  Marvis E. Hartman ,  Deborah E. Hayes ,  Thomas R. Hockswender ,  Kymarje L. Koster ,  Gregory J. McCollum ,  Masayuki Nakajima ,  Kurt G. Olson ,  Richard J. Sadvary ,  Dennis A. Simpson ,  Shiryn Tyebjee ,  Truman F. Wilt

IPC分类号： C08L83/04 ,  C08L83/06 ,  C08L83/08

CPC分类号： B82Y30/00 ,  C08J3/20 ,  C08K3/01 ,  C08K3/013 ,  C08K3/22 ,  C08K3/36 ,  C08K2201/011 ,  C09D7/00 ,  C09D7/61 ,  C09D7/67 ,  C09D7/68 ,  C09D7/69 ,  C09D183/04 ,  C08L2666/28 ,  C08L2666/54 ,  C08L2666/14 ,  C08L2666/04

摘要： Coating compositions are provided which are formed from components comprising (a) at least one polysiloxane comprising at least one reactive functional group; (b) at least one reactant comprising at least one functional group that is reactive with at least one functional group selected from the at least one reactive functional group of the at least one polysiloxane and at least one functional group of at least one reactant; and (c) a plurality of particles, wherein each component is different, and wherein the at least one reactive functional group of the at least one polysiloxane and the at least one functional group of the at least one reactant are substantially nonreactive with the particles. A multi-component composite coating composition formed from a basecoat and a topcoat deposited from the curable coating composition also is provided. The multi-component composite coating compositions of the invention provide highly scratch resistant color-plus-clearcoatings capable of retaining scratch resistance after weathering.

公开(公告)号：US06987144B2

公开(公告)日：2006-01-17

申请号：US10456576

申请日：2003-06-09

申请人： Lawrence G. Anderson ,  Shawn A. De Saw ,  Marvis E. Hartman ,  Deborah E. Hayes ,  Thomas R. Hockswender ,  Kymarie L. Kuster ,  Michael Allen Mayo ,  Masayuki Nakajima ,  Kurt G. Olson ,  Richard J. Sadvary ,  Laura E. Schilling ,  Dennis A. Simpson ,  Shiryn Tyebjee ,  Truman F. Wilt

发明人： Lawrence G. Anderson ,  Shawn A. De Saw ,  Marvis E. Hartman ,  Deborah E. Hayes ,  Thomas R. Hockswender ,  Kymarie L. Kuster ,  Michael Allen Mayo ,  Masayuki Nakajima ,  Kurt G. Olson ,  Richard J. Sadvary ,  Laura E. Schilling ,  Dennis A. Simpson ,  Shiryn Tyebjee ,  Truman F. Wilt

IPC分类号： C08L83/04 ,  C08L83/06 ,  C08L83/08

CPC分类号： B82Y30/00 ,  C08J3/20 ,  C08K3/01 ,  C08K3/013 ,  C08K2201/011 ,  C09D7/00 ,  C09D7/61 ,  C09D7/62 ,  C09D7/69 ,  C09D183/04 ,  C08L2666/14 ,  C08L2666/54 ,  C08L2666/04 ,  C08L2666/28

摘要： Coating compositions are provided which include a polysiloxane comprising at least one reactive functional group and at least one material comprising at least one reactive functional group. Also provided are multi-layer composite coatings formed from a basecoat deposited from a pigmented coating composition and a topcoat applied over the basecoat, the topcoat deposited from the aforementioned coating composition. A method for improving the scratch resistance of a coated substrate, as well as coated substrates also are provided. The compositions of the invention provide highly scratch resistant coatings, particularly highly scratch resistant color-plus-clearcoatings.

公开(公告)号：US06387519B1

公开(公告)日：2002-05-14

申请号：US09629423

申请日：2000-07-31

申请人： Lawrence G. Anderson ,  Karen A. Barkac ,  Anthony M. Chasser ,  Shawn A. DeSaw ,  Marvis E. Hartman ,  Deborah E. Hayes ,  Thomas R. Hockswender ,  Kymarie L. Kuster ,  Robert A. Montague ,  Masayuki Nakajima ,  Kurt G. Olson ,  Jamel S. Richardson ,  Richard J. Sadvary ,  Dennis A. Simpson ,  Shiryn Tyebjee ,  Truman F. Wilt

发明人： Lawrence G. Anderson ,  Karen A. Barkac ,  Anthony M. Chasser ,  Shawn A. DeSaw ,  Marvis E. Hartman ,  Deborah E. Hayes ,  Thomas R. Hockswender ,  Kymarie L. Kuster ,  Robert A. Montague ,  Masayuki Nakajima ,  Kurt G. Olson ,  Jamel S. Richardson ,  Richard J. Sadvary ,  Dennis A. Simpson ,  Shiryn Tyebjee ,  Truman F. Wilt

IPC分类号： B32B516

CPC分类号： B82Y30/00 ,  C08J3/20 ,  C08K3/01 ,  C08K3/013 ,  C08K2201/011 ,  C09D7/00 ,  C09D7/62 ,  C09D7/67 ,  C09D7/68 ,  C09D7/69 ,  C09D183/04 ,  Y10T428/25 ,  Y10T428/259 ,  Y10T428/31 ,  Y10T428/31551 ,  Y10T428/31663 ,  C08L2666/54 ,  C08L2666/14 ,  C08L2666/04

摘要： Cured coatings having particles at a surface region of the cured coating are provided. Also provided are multi-component composite coatings which include a cured basecoat deposited from a pigmented coating composition and a cured topcoat deposited from a topcoating composition. The multi-component composite coatings of the invention provide highly scratch resistant color-plus-clearcoatings capable of retaining scratch resistance after weathering.

摘要翻译： 提供了在固化涂层的表面区域具有颗粒的固化涂层。 还提供了多组分复合涂层，其包括由着色涂料组合物沉积的固化底涂层和从表面涂层组合物沉积的固化顶涂层。 本发明的多组分复合涂层提供了耐刮擦后能够保持耐划伤性的高耐划伤性的彩色 - 透明涂层。

公开(公告)号：US07053149B2

公开(公告)日：2006-05-30

申请号：US10795216

申请日：2004-03-09

申请人： Lawrence G. Anderson ,  Karen A. Barkac ,  Shawn A. DeSaw ,  Marvis E. Hartman ,  Deborah E. Hayes ,  Thomas R. Hockswender ,  Kymarie L. Kuster ,  Masayuki Nakajima ,  Kurt G. Olson ,  Richard J. Sadvary ,  Dennis A. Simpson ,  Shiryn Tyebjee ,  Truman F. Wilt

发明人： Lawrence G. Anderson ,  Karen A. Barkac ,  Shawn A. DeSaw ,  Marvis E. Hartman ,  Deborah E. Hayes ,  Thomas R. Hockswender ,  Kymarie L. Kuster ,  Masayuki Nakajima ,  Kurt G. Olson ,  Richard J. Sadvary ,  Dennis A. Simpson ,  Shiryn Tyebjee ,  Truman F. Wilt

IPC分类号： C08L83/04 ,  C08L83/06 ,  C08L83/08

CPC分类号： B82Y30/00 ,  C08J3/20 ,  C08K3/01 ,  C08K3/22 ,  C08K3/36 ,  C08K2201/011 ,  C09D7/00 ,  C09D7/61 ,  C09D7/67 ,  C09D7/68 ,  C09D7/69 ,  C09D183/04 ,  C08L2666/14 ,  C08L2666/54 ,  C08L2666/04

摘要： Compositions are provided which contain (a) one or more polysiloxanes comprising at least one reactive functional group; a plurality of particles; and optionally, one or more curing agents comprising at least one functional group that is reactive with any reactive functional group of polysiloxane (a). Additionally, a process for applying the multi-component composite coatings described above to a substrate and coated substrates are provided. A process for preparing the coating compositions also is provided. The multi-component composite coating compositions of the invention provide highly scratch resistant color-plus-clearcoatings capable of retaining scratch resistance after weathering.

摘要翻译： 提供了包含（a）一种或多种包含至少一个反应性官能团的聚硅氧烷的组合物; 多个颗粒; 和任选的一种或多种包含至少一种与聚硅氧烷（a）的任何反应性官能团反应的官能团的固化剂。 另外，提供了将上述多组分复合涂层施加到基底和涂覆的基底上的方法。 还提供了制备涂料组合物的方法。 本发明的多组分复合涂料组合物提供了耐风化后能够保持耐刮擦性的高耐划伤性的彩色 - 透明涂层。