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公开(公告)号：US20110045725A1
公开(公告)日：2011-02-24
申请号：US12545889
申请日：2009-08-24
IPC分类号： B32B5/02 , C08L83/00 , C08L63/00 , C08L67/00 , B32B21/08 , B32B15/092 , B32B17/10 , B32B27/06 , B05D1/36
CPC分类号： C08G59/306 , C08G59/3254 , C08L63/00 , C09D163/00 , Y10T428/249991 , Y10T428/31511 , Y10T428/31525 , Y10T428/31529 , Y10T442/20 , C08L2666/22
摘要： Film-forming coating compositions are disclosed. The composition comprises a) an epoxy-containing polymer system; and b) a polyacid curing agent comprising two acid functional groups per molecule; wherein the epoxy-containing polymer system comprises: (i) an epoxy resin comprising at least two epoxy functional groups per molecule and which is different from (ii); and (ii) an epoxy functional silsesquioxane. Also disclosed are processes for applying the film-forming composition to a basecoat, and substrates coated in part by a coating deposited from the film-forming compositions.
摘要翻译： 公开了成膜涂料组合物。 该组合物包含a）含环氧基的聚合物体系; 和b）每分子含有两个酸官能团的多元酸固化剂; 其中所述含环氧基的聚合物体系包括：（i）每分子包含至少两个环氧官能团并且不同于（ⅱ）的环氧树脂; 和（ii）环氧官能硅倍半氧烷。 还公开了将成膜组合物施用于底涂层的方法，以及通过由成膜组合物沉积的涂层部分涂覆的基材。
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公开(公告)号：US20090062453A1
公开(公告)日：2009-03-05
申请号：US11846070
申请日：2007-08-28
申请人： Lyle L. Foringer , Constantine A. Kondos , Richard J. Sadvary , Kurt G. Olson , Dennis A. Simpson
发明人： Lyle L. Foringer , Constantine A. Kondos , Richard J. Sadvary , Kurt G. Olson , Dennis A. Simpson
CPC分类号： C08G18/637 , B05D5/005 , C08G18/4063 , C08G18/423 , C08G18/6254 , C08G18/792 , C08K3/36 , C08L33/08 , C08L67/00 , C09D133/08 , C09D175/16 , C08L2666/18
摘要： The present invention is directed to curable film-forming compositions comprising: (a) a polymeric binder comprising a polyester having hydroxyl functional groups; and (b) a curing agent comprising a polyisocyanate having at least three isocyanate functional groups. In certain embodiments, after application to a substrate as a coating and after curing, the compositions demonstrate a Fisher microhardness of at least 120 at ambient temperatures of 15 to 25° C. and a softening point greater than or equal to 35° C. Additionally, in certain embodiments, after application to a substrate as a coating and after curing, the compositions demonstrate a 20° gloss recovery of at least 75% when subjected to the DRY ABRASION TEST METHOD.
摘要翻译： 本发明涉及可固化成膜组合物，其包含：（a）包含具有羟基官能团的聚酯的聚合物粘合剂; 和（b）包含具有至少三个异氰酸酯官能团的多异氰酸酯的固化剂。 在某些实施方案中，作为涂层施用于基材并且在固化后，组合物在15至25℃的环境温度和大于或等于35℃的软化点下显示出至少120的Fisher显微硬度。另外 在某些实施方案中，在作为涂层施加到基材上并且在固化之后，当进行干磨试验方法时，组合物显示出至少75％的20°光泽恢复。
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3.发明授权Coating compositions having improved scratch resistance, coated substrates and methods related thereto 有权涂层组合物具有改进的耐刮擦性，涂覆的基材和与其有关的方法公开(公告)号：US06803408B2
公开(公告)日：2004-10-12
申请号：US10456854
申请日：2003-06-09
申请人： Lawrence G. Anderson , Karen A. Barkac , Shawn A. DeSaw , Marvis E. Hartman , Deborah E. Hayes , Thomas R. Hockswender , Kymarie L. Kuster , Masayuki Nakajima , Kurt G. Olson , Richard J. Sadvary , Dennis A. Simpson , Shiryn Tyebjee , Truman F. Wilt
发明人： Lawrence G. Anderson , Karen A. Barkac , Shawn A. DeSaw , Marvis E. Hartman , Deborah E. Hayes , Thomas R. Hockswender , Kymarie L. Kuster , Masayuki Nakajima , Kurt G. Olson , Richard J. Sadvary , Dennis A. Simpson , Shiryn Tyebjee , Truman F. Wilt
IPC分类号： C08L8304
CPC分类号： B82Y30/00 , C08J3/20 , C08K3/01 , C08K3/22 , C08K3/36 , C08K2201/011 , C09D7/00 , C09D7/61 , C09D7/67 , C09D7/68 , C09D7/69 , C09D183/04 , C08L2666/14 , C08L2666/54 , C08L2666/04
摘要： Compositions are provided which contain (a) one or more polysiloxanes comprising at least one reactive functional group; a plurality of particles; and, optionally, one or more curing agents comprising at least one functional group that is reactive with any reactive functional group of polysiloxane (a). Additionally, a process for applying the multi-component composite coatings described above to a substrate and coated substrates are provided. A process for preparing the coating compositions also is provided. The multi-component composite coating compositions of the invention provide highly scratch resistant color-plus-clearcoatings capable of retaining scratch resistance after weathering.
摘要翻译： 提供了包含（a）一种或多种包含至少一个反应性官能团的聚硅氧烷的组合物; 多个颗粒; 和任选的一种或多种固化剂，其包含与聚硅氧烷（a）的任何反应性官能团反应的至少一个官能团。 另外，提供了将上述多组分复合涂层施加到基底和涂覆的基底上的方法。 还提供了制备涂料组合物的方法。 本发明的多组分复合涂料组合物提供了耐风化后能够保持耐刮擦性的高耐划伤性的彩色 - 透明涂层。
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4.发明授权Liquid coating of film-forming resin and particles chemically modified to lower surface tension 有权化学改性的成膜树脂和颗粒的液体涂层降低表面张力公开(公告)号：US06790904B2
公开(公告)日：2004-09-14
申请号：US10160888
申请日：2002-06-03
申请人： Daniela White , James B. O'Dwyer , Michael A. Mayo , Laura E. Poindexter , John R. Schneider , Michael L. White , Richard J. Sadvary , Shiryn Tyebjee , Joseph M. Carney , Lawrence G. Anderson , Dennis A. Simpson , Thomas R. Hockswender
发明人： Daniela White , James B. O'Dwyer , Michael A. Mayo , Laura E. Poindexter , John R. Schneider , Michael L. White , Richard J. Sadvary , Shiryn Tyebjee , Joseph M. Carney , Lawrence G. Anderson , Dennis A. Simpson , Thomas R. Hockswender
IPC分类号： C08K322
CPC分类号： C09D7/69 , C08K3/22 , C08K3/28 , C08K3/36 , C08K9/06 , C09D7/62 , C09D7/67 , C09D7/68 , Y10T428/31511
摘要： Liquid coating compositions having improved mar and scratch resistance are disclosed. The coatings generally comprise one or more particles that have been modified to render the particles more surface active. The improved resistance is achieved without affecting the appearance or mechanical performance of the coatings. Methods for using the coatings, and the substrates coated therewith, are also disclosed.
摘要翻译： 公开了具有改善的耐擦伤和耐划伤性的液体涂料组合物。 涂料通常包含一种或多种已被改性以使颗粒更具表面活性的颗粒。 在不影响涂层的外观或机械性能的情况下实现改进的电阻。 还公开了使用涂层的方法及其涂覆的基材。
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5.发明授权Coating compositions having improved scratch resistance, coated substrates and methods related thereto 有权涂层组合物具有改进的耐刮擦性，涂覆的基材和与其有关的方法公开(公告)号：US06759478B2
公开(公告)日：2004-07-06
申请号：US10456552
申请日：2003-06-09
申请人： Lawrence G. Anderson , Karen A. Barkac , Shawn A. DeSaw , Marvis E. Hartman , Deborah E. Hayes , Thomas R. Hockswender , Kymarie L. Kuster , Gregory J. McCollum , Masayuki Nakajima , Kurt G. Olson , Richard J. Sadvary , Dennis A. Simpson , Shiryn Tyebjee , Truman F. Wilt
发明人： Lawrence G. Anderson , Karen A. Barkac , Shawn A. DeSaw , Marvis E. Hartman , Deborah E. Hayes , Thomas R. Hockswender , Kymarie L. Kuster , Gregory J. McCollum , Masayuki Nakajima , Kurt G. Olson , Richard J. Sadvary , Dennis A. Simpson , Shiryn Tyebjee , Truman F. Wilt
IPC分类号： C08L8304
CPC分类号： B82Y30/00 , C08J3/20 , C08K3/01 , C08K3/013 , C08K3/22 , C08K3/36 , C08K2201/011 , C09D7/00 , C09D7/61 , C09D7/67 , C09D7/68 , C09D7/69 , C09D183/04 , C08L2666/28 , C08L2666/54 , C08L2666/14 , C08L2666/04
摘要： Coating compositions are provided which are formed from components comprising (a) at least one polysiloxane comprising at least one reactive functional group; (b) at least one reactant comprising at least one functional group that is reactive with at least one functional group selected from the at least one reactive functional group of the at least one polysiloxane and at least one functional group of at least one reactant; and (c) a plurality of particles, wherein each component is different, and wherein the at least one reactive functional group of the at least one polysiloxane and the at least one functional group of the at least one reactant are substantially nonreactive with the particles. A multi-component composite coating composition formed from a basecoat and a topcoat deposited from the curable coating composition also is provided. The multi-component composite coating compositions of the invention provide highly scratch resistant color-plus-clearcoatings capable of retaining scratch resistance after weathering.
摘要翻译： 提供涂料组合物，其由包含（a）至少一种包含至少一个反应性官能团的聚硅氧烷的组分形成; （b）至少一种包含至少一种与至少一种选自至少一种聚硅氧烷的至少一种反应性官能团和至少一种反应物官能团的官能团反应的官能团的官能团; 和（c）多个颗粒，其中每个组分是不同的，并且其中所述至少一种聚硅氧烷的至少一种反应性官能团和所述至少一种反应物的至少一种官能团基本上与颗粒不反应。 还提供了由底涂层和从可固化涂料组合物沉积的面涂层形成的多组分复合涂料组合物。 本发明的多组分复合涂料组合物提供了耐风化后能够保持耐刮擦性的高耐划伤性的彩色 - 透明涂层。
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6.发明授权Flexible coating compositions having improved scratch resistance, coated substrates and methods related thereto 失效柔性涂料组合物具有改善的耐刮擦性，涂布的基材和与其有关的方法公开(公告)号：US06610777B1
公开(公告)日：2003-08-26
申请号：US09629420
申请日：2000-07-31
申请人： Lawrence G. Anderson , Shawn A. De Saw , Marvis E. Hartman , Deborah E. Hayes , Thomas R. Hockswender , Kymarie L. Kuster , Michael Allen Mayo , Masayuki Nakajima , Kurt G. Olson , Richard J. Sadvary , Laura E. Schilling , Dennis A. Simpson , Shiryn Tyebjee , Truman F. Wilt
发明人： Lawrence G. Anderson , Shawn A. De Saw , Marvis E. Hartman , Deborah E. Hayes , Thomas R. Hockswender , Kymarie L. Kuster , Michael Allen Mayo , Masayuki Nakajima , Kurt G. Olson , Richard J. Sadvary , Laura E. Schilling , Dennis A. Simpson , Shiryn Tyebjee , Truman F. Wilt
IPC分类号： C08L8304
CPC分类号： B82Y30/00 , C08J3/20 , C08K3/01 , C08K3/013 , C08K2201/011 , C09D7/00 , C09D7/61 , C09D7/62 , C09D7/69 , C09D183/04 , C08L2666/14 , C08L2666/54 , C08L2666/04 , C08L2666/28
摘要： Coating compositions are provided which include a polysiloxane comprising at least one reactive functional group and at least one material comprising at least one reactive functional group. Also provided are multi-layer composite coatings formed from a basecoat deposited from a pigmented coating composition and a topcoat applied over the basecoat, the topcoat deposited from the aforementioned coating composition. A method for improving the scratch resistance of a coated substrate, as well as coated substrates also are provided. The compositions of the invention provide highly scratch resistant coatings, particularly highly scratch resistant color-plus-clearcoatings.
摘要翻译： 提供涂料组合物，其包括包含至少一个反应性官能团的聚硅氧烷和至少一种包含至少一个反应性官能团的材料。 还提供了由从着色涂料组合物沉积的底涂层和涂覆在底涂层上的顶涂层，由上述涂料组合物沉积的面漆形成的多层复合涂层。 还提供了一种用于改善涂覆基材的耐擦伤性的方法以及涂覆的基材。 本发明的组合物提供高度耐刮擦的涂层，特别是高度耐刮擦的彩色 - 透明涂层。
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7.发明授权Coating compositions having improved scratch resistance, coated substrates and methods related thereto 失效涂层组合物具有改进的耐刮擦性，涂覆的基材和与其有关的方法公开(公告)号：US06593417B1
公开(公告)日：2003-07-15
申请号：US09629443
申请日：2000-07-31
申请人： Lawrence G. Anderson , Karen A. Barkac , Shawn A. DeSaw , Marvis E. Hartman , Deborah E. Hayes , Thomas R. Hockswender , Kymarie L. Kuster , Gregory J. McCollum , Masayuki Nakajima , Kurt G. Olson , Richard J. Sadvary , Dennis A. Simpson , Shiryn Tyebjee , Truman F. Wilt
发明人： Lawrence G. Anderson , Karen A. Barkac , Shawn A. DeSaw , Marvis E. Hartman , Deborah E. Hayes , Thomas R. Hockswender , Kymarie L. Kuster , Gregory J. McCollum , Masayuki Nakajima , Kurt G. Olson , Richard J. Sadvary , Dennis A. Simpson , Shiryn Tyebjee , Truman F. Wilt
IPC分类号： C08L8304
CPC分类号： B82Y30/00 , C08J3/20 , C08K3/01 , C08K3/013 , C08K3/22 , C08K3/36 , C08K2201/011 , C09D7/00 , C09D7/61 , C09D7/67 , C09D7/68 , C09D7/69 , C09D183/04 , C08L2666/28 , C08L2666/54 , C08L2666/14 , C08L2666/04
摘要： Coating compositions are provided which are formed from components comprising (a) at least one polysiloxane comprising at least one reactive functional group; (b) at least one reactant comprising at least one functional group that is reactive with at least one functional group selected from the at least one reactive functional group of the at least one polysiloxane and at least one functional group of at least one reactant; and (c) a plurality of particles, wherein each component is different, and wherein the at least one reactive functional group of the at least one polysiloxane and the at least one functional group of the at least one reactant are substantially nonreactive with the particles. A multi-component composite coating composition formed from a basecoat and a topcoat deposited from the curable coating composition also is provided. The multi-component composite coating compositions of the invention provide highly scratch resistant color-plus-clearcoatings capable of retaining scratch resistance after weathering.
摘要翻译： 提供涂料组合物，其由包含（a）至少一种包含至少一个反应性官能团的聚硅氧烷的组分形成; （b）至少一种包含至少一种与至少一种选自至少一种聚硅氧烷的至少一种反应性官能团和至少一种反应物官能团的官能团反应的官能团的官能团; 和（c）多个颗粒，其中每个组分是不同的，并且其中所述至少一种聚硅氧烷的至少一种反应性官能团和所述至少一种反应物的至少一种官能团基本上与颗粒不反应。 还提供了由底涂层和从可固化涂料组合物沉积的面涂层形成的多组分复合涂料组合物。 本发明的多组分复合涂料组合物提供了耐风化后能够保持耐刮擦性的高耐划伤性的彩色 - 透明涂层。
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公开(公告)号：US06541119B2
公开(公告)日：2003-04-01
申请号：US09844535
申请日：2001-04-27
申请人： Richard J. Sadvary , Lawrence G. Anderson , Dennis A. Simpson , Thomas R. Hockswender , Masayuki Nakajima , Truman F. Wilt
发明人： Richard J. Sadvary , Lawrence G. Anderson , Dennis A. Simpson , Thomas R. Hockswender , Masayuki Nakajima , Truman F. Wilt
IPC分类号： B32B2728
CPC分类号： C09D183/08 , C08G77/388 , C08L63/00 , C08L67/02 , C08L83/04 , C09D5/448 , C09D133/066 , C09D183/06 , Y10T428/31663 , C08L2666/14 , C08L2666/04 , C08L2666/36 , C08L2666/34
摘要： Multi-component composite coating compositions are provided which comprise a base coat deposited from a pigmented film-forming composition and a transparent top coat applied over the base coat in which the transparent top coat is deposited from a film-forming composition comprising one ore more ungelled chain-extended organic polysiloxanes having reactive functional groups, and one or more curing agents having functional groups reactive with the functional groups of the polysiloxane. Additionally provided is a process for applying the multi-component composite coatings described above to a substrate. Substrates coated with the above-described multi-component composite coating compositions are also provided.
摘要翻译： 提供了多组分复合涂料组合物，其包含从着色成膜组合物沉积的底涂层和施加在底涂层上的透明顶涂层，其中透明顶涂层由成膜组合物沉积，所述成膜组合物包含一个或多个未凝胶 具有反应性官能团的链延伸的有机聚硅氧烷，以及具有与聚硅氧烷的官能团反应的官能团的一种或多种固化剂。 另外提供了将上述多组分复合涂层应用于基材的方法。 还提供了涂覆有上述多组分复合涂料组合物的基材。
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公开(公告)号：US09708504B2
公开(公告)日：2017-07-18
申请号：US12752570
申请日：2010-04-01
申请人： Debra L. Singer , Dennis A. Simpson , John M. Dudik , Anthony M. Chasser , Kam Lun Lock , Richard Woods , Nigel Francis Masters
发明人： Debra L. Singer , Dennis A. Simpson , John M. Dudik , Anthony M. Chasser , Kam Lun Lock , Richard Woods , Nigel Francis Masters
IPC分类号： C09D167/06 , C08F299/04
CPC分类号： C09D167/06 , C08F299/04 , Y10T428/1355 , Y10T428/31786
摘要： A polyester prepared by free radical polymerization of an unsaturated polyester prepolymer, wherein the polymerization occurs primarily by reaction of the unsaturation is disclosed. Coatings comprising the same are also disclosed, as are substrates coated at least in part with such coatings.
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10.发明授权Coating composition comprising an alkoxysilane, a polysiloxane, and a plurality of particles 有权包含烷氧基硅烷，聚硅氧烷和多个颗粒的涂料组合物公开(公告)号：US08563648B2
公开(公告)日：2013-10-22
申请号：US12607734
申请日：2009-10-28
申请人： Robert Schmeltzer , Susan Donaldson , Kevin C. Olson , Kurt G. Olson , John E. Schwendeman , Dennis A. Simpson , Frank C. Williams
发明人： Robert Schmeltzer , Susan Donaldson , Kevin C. Olson , Kurt G. Olson , John E. Schwendeman , Dennis A. Simpson , Frank C. Williams
IPC分类号： C08L83/04
CPC分类号： C09D183/04 , C08G18/792 , C08K3/22 , C08K3/36 , C09D183/06 , C09D183/08 , C09D201/10 , C08L2666/02
摘要： The present invention is directed to a coating composition, such as a substantially clear coating composition, which comprises (1) an alkoxysilane, (2) a polysiloxane, (3) a plurality of particles, and (4) curing agent that is reactive with the polysiloxane. The coating composition of the present invention can exhibit increased physical properties, such as scratch resistance, when compared to similar coating compositions that lack the components disclosed herein.
摘要翻译： 本发明涉及涂料组合物，例如基本上透明的涂料组合物，其包括（1）烷氧基硅烷，（2）聚硅氧烷，（3）多个颗粒，和（4）与 聚硅氧烷。 当与缺乏本文公开的组分的类似涂料组合物相比时，本发明的涂料组合物可以表现出增加的物理性能，例如耐刮擦性。
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