公开(公告)号：US5360834A

公开(公告)日：1994-11-01

申请号：US188746

申请日：1994-01-31

申请人： Michael Popall ,  Jochen Schulz ,  Helmut Schmidt

发明人： Michael Popall ,  Jochen Schulz ,  Helmut Schmidt

IPC分类号： B01J13/00 ,  B01J19/12 ,  C03C1/00 ,  C03C17/02 ,  C03C17/25 ,  C08G4/00 ,  C08G77/02 ,  C08J3/28 ,  C08K3/18

CPC分类号： B01J13/0039 ,  B01J19/123 ,  C03C1/008 ,  C03C17/02 ,  C03C17/25

摘要： A process is described for photoinitiated control of inorganic network fotion in the sol-gel process, which comprises eitherA) subjecting one or more hydrolytically polycondensable compounds of constituent elements of glass or ceramic, excluding silicon compounds containing polymerizable organic groups, to hydrolytic polycondensation in a liquid reaction medium to form a sol and irradiating the resulting sol in a structured or unstructured manner in the presence of a photoinitiator which can change the pH of the reaction medium on irradiation, using radiation of a wavelength range in which the photoinitiator absorbs;orB) liberating water in an anhydrous reaction medium which contains an alcohol, one or more hydrolytically polycondensable compounds of constituent elements of glass or ceramic and a photoinitiator which can liberate water by a photochemical reaction or a secondary reaction when irradiated, by structured or non-structured irradiation using radiation of a wavelength range in which the photoinitiator absorbs, and in this way effecting the hydrolytic polycondensation.

摘要翻译： 描述了在溶胶 - 凝胶法中对无机网络形成进行光引发控制的方法，其包括A）将除了含有可聚合有机基团的硅化合物之外的玻璃或陶瓷的一种或多种水解可缩聚化合物的化合物水解缩聚 液体反应介质以形成溶胶，并且在光引发剂存在下以结构或非结构化方式照射所得溶胶，所述光引发剂可使用光引发剂吸收的波长范围的辐射在照射时改变反应介质的pH值; 或B）在含有醇，一种或多种水解可缩聚的玻璃或陶瓷组成元素的化合物和光引发剂的无水反应介质中释放水，其可以通过结构化或非结构化的光化学反应或二次反应释放水 使用光引发剂吸收的波长范围的辐射的结构化照射，并且以这种方式进行水解缩聚。

公开(公告)号：US5668237A

公开(公告)日：1997-09-16

申请号：US347472

申请日：1995-02-15

申请人： Michael Popall ,  Jochen Schulz ,  Birke Olsowski ,  Monika Pilz

发明人： Michael Popall ,  Jochen Schulz ,  Birke Olsowski ,  Monika Pilz

IPC分类号： B05D7/26 ,  C08G77/20 ,  C08G77/22 ,  C08G77/58 ,  C08G79/00 ,  C09D183/04 ,  C09D183/07 ,  C09D183/14 ,  C09D185/00 ,  H01B3/46 ,  H01G4/33 ,  H01L23/29 ,  H05K3/28

CPC分类号： C09D183/14 ,  C08G77/58 ,  H01B3/46 ,  H01L23/29 ,  H01L23/296 ,  H05K3/285 ,  H01L2924/0002

摘要： The present invention relates to a lacquer obtained by the process comprising the steps of: (i) precondensation of: a) 1 to 10 mol % of at least one zirconium compound of the formula ZrR.sub.4 ; b) 20 to 94 mol % of at least one organic silane of the formula R".sub.m (R'"Y).sub.n SiX.sub.(4-m-n) ; c) 5 to 30 mol % of at least one organic silane of the formula R".sub.p SiX.sub.4-p ; d) optionally 0 to 10 mol % of at least one low-volatility metal oxide; and (ii) hydrolysis condensation of the precondensate of step (i) in the presence of 0 to 50% of the stoichiometric amount of water. The invention also relates to a process for the obtention of a coating on substrate which comprises the steps of applying the lacquer and curing same. The invention also relates to the thus-coated substrates.

摘要翻译： PCT No.PCT / EP93 / 01427 Sec。 371日期1995年2月15日 102（e）日期1995年2月15日PCT提交1993年6月5日PCT公布。 出版物WO93 / 25605 日本公开日1993年12月23日本发明涉及通过该方法获得的漆，其包括以下步骤：（i）预缩合：a）1至10mol％的至少一种式ZrR 4的锆化合物; b）20-94摩尔％的至少一种式R''m（R“'）nSiX（4-m-n）的有机硅烷; c）5至30mol％的至少一种式R''pSiX4-p的有机硅烷; d）任选的0至10摩尔％的至少一种低挥发性金属氧化物; 和（ii）步骤（i）的预缩合物在0至50％化学计量的水存在下的水解缩合。 本发明还涉及一种用于获得基材上的涂层的方法，该方法包括施加该漆并固化其的步骤。 本发明还涉及如此涂覆的基底。

公开(公告)号：US06312085B1

公开(公告)日：2001-11-06

申请号：US09029350

申请日：1998-07-13

申请人： J{overscore (u)}rgen Kappel ,  Michael Popall ,  Jochen Schulz ,  Adelheid Martin ,  Birke-E. Olsowski ,  Karl Bühler

发明人： J{overscore (u)}rgen Kappel ,  Michael Popall ,  Jochen Schulz ,  Adelheid Martin ,  Birke-E. Olsowski ,  Karl Bühler

IPC分类号： B41J2015

CPC分类号： B41J2/164 ,  B41J2/1604 ,  B41J2/1631

摘要： The invention provides inkjet print heads, which have one or more components of a polymer material, which is produced, substantially, or with the use of, at least one Compound (I) XaRbSiR1(4−a−b) with X=hydrolyzable group, R=eventually substituted Alkyl, Aryl, Alkenyl, Alkylaryl or Arylalkyl, R1=organic remainder with at least one polymerizable group, a= to 3, b=0 to 2. In addition, the invention provides a process for the manufacture of the heads and for the utilization, for said purpose, of a polymer material.

摘要翻译： 本发明提供喷墨打印头，其具有聚合物材料的一种或多种组分，其基本上或使用至少一种具有X =可水解基团的化合物（I）XaRbSiR1（4-ab），R =最终取代的烷基，芳基，烯基，烷基芳基或芳基烷基，R1 =具有至少一个可聚合基团的有机残余物，a = 3，b = 0至2.另外，本发明提供了制造头部的方法， 用于所述目的的聚合物材料的利用。

公开(公告)号：US06283578B1

公开(公告)日：2001-09-04

申请号：US09029127

申请日：1998-06-11

申请人： Michael Popall ,  Jochen Schulz ,  Birke-E. Olsowski ,  Adelheid Martin ,  Karl Bühler

发明人： Michael Popall ,  Jochen Schulz ,  Birke-E. Olsowski ,  Adelheid Martin ,  Karl Bühler

IPC分类号： B41J2135

CPC分类号： B41J2/1606 ,  C09D183/04 ,  C09D183/06

摘要： The invention provides inkjet print head which has an Anti-wetting Coating of a polymer material, which is produced with the utilization of at least one Compound (I) XaRbSiR1(4-a-b) with X=hydrolyzable group, R=possibly substituted Alkyl, Aryl, Alkenyl, Alkylaryl or Arylalkyl, R1=organic remainder with at least one polymerizable group, a=to 3, b=0 to 2. In addition, a Process for the Manufacture of the Print Heads is made available, as well as a Means for the Coating of same.

摘要翻译： 本发明提供喷墨打印头，其具有使用至少一种化合物（I）XaRbSiR1（4-ab）与X =可水解基团，R =可能被取代的烷基取代的聚合物材料的抗潮湿涂层， 芳基，烯基，烷基芳基或芳基烷基，R1 =具有至少一个可聚合基团的有机残基，a = 3，b = 0至2.此外，制造印刷头的方法可用，以及 用于涂层的方法。

公开(公告)号：US5734000A

公开(公告)日：1998-03-31

申请号：US351357

申请日：1995-02-13

申请人： Michael Popall ,  Jochen Schulz ,  Birke Olsowski ,  Monika Pilz

发明人： Michael Popall ,  Jochen Schulz ,  Birke Olsowski ,  Monika Pilz

IPC分类号： B05D7/26 ,  C08G77/06 ,  C08G77/20 ,  C08G77/22 ,  C09D183/04 ,  C09D183/07 ,  H01G2/12 ,  H01G4/33 ,  H05K3/28 ,  C08G77/04

CPC分类号： H01G2/12 ,  C08G77/06 ,  C08G77/22 ,  C09D183/04 ,  H05K3/285 ,  Y10T428/31663

摘要： A silicon-based lacquer is obtained by precondensation of a silicon compound and organic silanes followed by hydrolysis of the precondensate.

摘要翻译： PCT No.PCT / EP93 / 01428 371日期1995年2月13日 102（e）日期1995年2月13日PCT提交1993年6月5日PCT公布。 出版物WO93 / 25604 日期1993年12月23日通过硅化合物和有机硅烷的预缩合，然后水解预缩合物获得硅基漆。

公开(公告)号：US20080194856A1

公开(公告)日：2008-08-14

申请号：US12029493

申请日：2008-02-12

申请人： Lothar Frohlich ,  Stephane Jacob ,  Michael Popall ,  Ruth Houbertz-Krauss

发明人： Lothar Frohlich ,  Stephane Jacob ,  Michael Popall ,  Ruth Houbertz-Krauss

IPC分类号： C07F7/02

CPC分类号： C08G77/14 ,  C08G77/20

摘要： A silane resin that can be structured photochemically and/or thermally is obtained by at least partial condensation of a mixture of a) at least one silane compound RaR2bSiX4-a-b wherein R is a group polymerizable photochemically and/or thermally via an organic group by radical or cationic polymerization; R2 is a straight-chain, branched, or cyclic C1-C12 alkyl group; X is identical or different and is a leaving group; a is 1 or 2; b is 0 or 1; a+b is not more than 2; and b) at least one silanediol R12Si(OH)2 wherein R1 is identical or different and is a straight-chain, branched, or cyclic C1-C12 alkyl group or a group polymerizable photochemically and/or thermally via an organic group by radical or cationic polymerization, provided the group does not contain aryl. The silane resins have dielectric properties useful in extremely high frequency applications.

摘要翻译： 可通过光化学和/或热结构的硅烷树脂通过a）至少一种硅烷化合物R 2的混合物的至少部分缩合获得， 其中R是通过自由基或阳离子聚合通过有机基团光化学和/或热可聚合的基团; R 2是直链，支链或环状C 1 -C 12烷基; X相同或不同，为离去组; a是1或2; b为0或1; a + b不大于2; 和b）至少一种硅烷二醇R 1 2 Si（OH）2 2其中R 1是相同或不同的 并且是直链，支链或环状C 1 -C 12烷基或通过自由基或阳离子聚合通过有机基团光学和/或热可聚合的基团 ，条件是该基团不含芳基。 硅烷树脂具有在极高频应用中有用的介电特性。

公开(公告)号：US07348393B2

公开(公告)日：2008-03-25

申请号：US10491588

申请日：2002-10-04

申请人： Lothar Fröhlich ,  Stéphane Jacob ,  Michael Popall ,  Ruth Houbertz-Krauss

发明人： Lothar Fröhlich ,  Stéphane Jacob ,  Michael Popall ,  Ruth Houbertz-Krauss

IPC分类号： C08G77/20

CPC分类号： C08G77/14 ,  C08G77/20

摘要： A silane resin that can be structured photochemically and/or thermally is obtained by at least partial condensation of a mixture of a) at least one silane compound RaR2bSiX4-a-b wherein R is a group polymerizable photochemically and/or thermally via an organic rest by radical or cationic polymerization; R2 is a straight-chain, branched, or cyclic C1-C12 alkyl group; X is identical or different and is a leaving group; a is 1 or 2; b is 0 or 1; a+b is not more than 2; and b) at least one silanediol R12Si(OH)2 wherein R1 is identical or different and is a straight-chain, branched, or cyclic C1-C12 alkyl group or a group polymerizable photochemically and/or thermally via an organic rest by radical or cationic polymerization, provided the group does not contain aryl. The silane resins have dielectric properties useful in extremely high frequency applications.

摘要翻译： 可通过光化学和/或热结构的硅烷树脂通过a）至少一种硅烷化合物R 2的混合物的至少部分缩合获得， 其中R是通过自由基或阳离子聚合通过有机残基可光化学和/或热可聚合的基团; R 2是直链，支链或环状C 1 -C 12烷基; X相同或不同，为离去组; a是1或2; b为0或1; a + b不大于2; 和b）至少一种硅烷二醇R 1 2 Si（OH）2 2其中R 1是相同或不同的 并且是直链，支链或环状C 1 -C 12烷基或通过自由基或阳离子聚合通过有机残基可光化和/或热可聚合的基团 ，条件是该基团不含芳基。 硅烷树脂具有在极高频应用中有用的介电特性。

公开(公告)号：US20080069964A1

公开(公告)日：2008-03-20

申请号：US11663726

申请日：2005-09-26

申请人： Pelagie Declerck ,  Birke Olsowski ,  Ruth Houbertz-Krauss ,  Michael Popall

发明人： Pelagie Declerck ,  Birke Olsowski ,  Ruth Houbertz-Krauss ,  Michael Popall

IPC分类号： B05D1/02 ,  B05D1/18 ,  C08G79/00

CPC分类号： G02B1/11 ,  C08G77/58 ,  C09D183/14 ,  G02B1/10

摘要： The invention relates to a method for the production of a transparent coating composition which is based essentially on a polycondensation reaction. The coating composition produced by this method is based on a completely through-condensed inorganic silicate network whilst the organic network is not yet formed. The invention also relates to a method for coating substrates with coating compositions of this type with formation of a coated substrate in which, in addition to the inorganic network, the organic network is also formed by the curing process. Coating compositions of this type and coated substrates are used widely in all optical fields of application.

摘要翻译： 本发明涉及一种基本上基于缩聚反应的透明涂料组合物的制备方法。 通过该方法制备的涂料组合物基于完全通过冷凝的无机硅酸盐网络，而有机网络尚未形成。 本发明还涉及一种用这种涂层组合物涂覆基材的方法，其形成了涂覆的基材，其中除了无机网络之外，还通过固化方法形成有机网络。 这种类型的涂层组合物和涂覆的基材广泛用于所有光学应用领域。

公开(公告)号：US5973176A

公开(公告)日：1999-10-26

申请号：US832283

申请日：1997-04-03

申请人： Christof Roscher ,  Michael Popall ,  Birke-E. Olsowski

发明人： Christof Roscher ,  Michael Popall ,  Birke-E. Olsowski

IPC分类号： C07F7/04 ,  C07F7/12 ,  C07F7/18 ,  C08G77/24 ,  C08G77/58 ,  C08J5/14 ,  C09C3/12 ,  C09D183/08 ,  C09K3/10 ,  G03F7/00 ,  C07F7/08 ,  C07F7/10

CPC分类号： C07F7/04 ,  C07F7/12 ,  C07F7/1836 ,  C07F7/184 ,  C07F7/1896 ,  C08G77/24 ,  C08G77/58 ,  C09C3/12 ,  C09D183/08 ,  C09K3/1018 ,  G03F7/00

摘要： The invention relates to hydrolyzable fluorinate silanes, methods of theirroduction and of their use for producing silicic acid polycondensates and hetero silicic acid polycondensats The silanes in accordance with the invention are of the general formula: {[R'-(Y).sub.e ].sub.c+1 (C.sub.6 F.sub.4-c) (C.sub.6 F.sub.4).sub.d }.sub.f SiR.sub.a X.sub.b (I) in which the groups and indices are identical or different and have the following meaning:R=alkyl, alkenyl, aryl, alkylaryl or arylalkyl, substituted if required, each with 1 to 15 carbon atoms, whereby the groups may be interrupted by oxygen or sulfur atoms, ester, carbonyl, amide or amino groups;R'=I, Br, Cl (if d.noteq.0), F (if d.noteq.0), H (if X.noteq.H or R.noteq.methyl or e=1) or an organic group with 1 to 50 carbon atoms;X=hydrogen, halogen except fluorine, hydroxy, alkoxy, acyloxy, alkylcarbonyl, alkoxycarbonyl or NR".sub.2, with R"=hydrogen, alkyl or aryl;Y=O, S, NH or NR', where R' is an organic group with 1 to 50 carbon atoms;a=0, 1 or 2;b=1, 2 or 3;c=0 or 1;d=0 to 9;e=0 or 1;f=1, 2 or 3, with a+b+f=4.

摘要翻译： 本发明涉及可水解的氟化物硅烷，其制备方法及其用于生产硅酸缩聚物和异硅酸缩合物的用途根据本发明的硅烷具有以下通式：{[R' - （Y）e] c +1（C6F4-c）（C6F4）d} fSiRaXb（I）其中基团和指数相同或不同，具有以下含义：R =烷基，烯基，芳基，烷基芳基或芳烷基，如果需要， 1至15个碳原子，其中基团可被氧或硫原子间隔，酯，羰基，酰胺或氨基; R'= I，Br，Cl（如果d NOTEQUAL 0），F（如果d NOTEQUAL 0），H（如果X NOTEQUAL H或R NOTEQUAL甲基或e = 1）或具有1至50个碳原子的有机基团; X =氢，除氟以外的卤素，羟基，烷氧基，酰氧基，烷基羰基，烷氧基羰基或NR'2，其中R“=氢，烷基或芳基; Y = O，S，NH或NR'，其中R'是具有1至50个碳原子的有机基团; a = 0,1或2; b = 1,2或3; c = 0或1; d = 0〜9; e = 0或1; f = 1,2或3，a + b + f = 4。

公开(公告)号：US20140051821A1

公开(公告)日：2014-02-20

申请号：US13980501

申请日：2011-01-21

申请人： Michael Popall ,  Ruth Houbertz-Krauss ,  Sebastien Cochet ,  Herbert Wolter ,  Kentaro Ohmori ,  Tetsuo Sato

发明人： Michael Popall ,  Ruth Houbertz-Krauss ,  Sebastien Cochet ,  Herbert Wolter ,  Kentaro Ohmori ,  Tetsuo Sato

IPC分类号： C08G77/20

CPC分类号： C08G77/80 ,  C08F2/24 ,  C08F230/08 ,  C08G77/20 ,  C08L43/04 ,  C08L83/04 ,  C09D183/04 ,  C08L2666/28

摘要： [Problem] To provide a polymerizable composition having an excellent transparency in near-infrared wavelength and excellent heat resistance, and a method for producing the same.[Means of Solving the Problem] A polymerizable composition includes: a reactive silicone compound obtained by polycondensing a diaryl silicic acid compound of Formula [1] below with a silane compound, selected under compounds of Formula [2] and Formula [2b] below in the presence of an acid or a base; and (b) a compound having at least one polymerizable group selected from the group consisting of alkenyl group and (meth)acryl group, wherein Ar1 and Ar2 are independently a phenyl group optionally substituted with a C1-C6 alkyl group, and X is a group which can undergo a hydrolytic condensation reaction, and wherein Ar3 is naphthyl or anthracyl substituted with at least one group having a polymerizable double bond, or wherein Ar3 is phenyl substituted with at least one group having a polymerizable double bond other than vinyl, or is phenyl substituted with at least two groups having a polymerizable double bond.

摘要翻译： 本发明提供一种具有优异的近红外波长透明度和优异耐热性的聚合性组合物及其制造方法。 解决问题的手段可聚合组合物包括：通过将下式[1]的二芳基硅酸化合物与下式在式[2]和式[2b]的化合物下选择的硅烷化合物缩聚得到的反应性硅氧烷化合物 存在酸或碱; 和（b）具有至少一个选自烯基和（甲基）丙烯酰基的可聚合基团的化合物，其中Ar 1和Ar 2独立地是任选被C 1 -C 6烷基取代的苯基，X是 可以进行水解缩合反应的基团，其中Ar 3是被至少一个具有可聚合双键的基团取代的萘基或蒽基，或其中Ar3是被至少一个具有除了乙烯基以外的可聚合双键的基团取代的苯基，或者 被至少两个具有可聚合双键的基取代的苯基。