摘要:
Zeolites washed with aqueous solutions or water or exhibit pH in the range of 9.4 to 10.0 and preferably 9.6 to 10.0 which can be converted to reforming catalysts with enhanced activity, selectivity and activity maintenance. Also processes for washing the zeolite to the target pH range and processes for using catalysts made with the washed zeolite to reform naphtha feeds.
摘要:
A process for reforming a hydrocarbon fraction substantially free of dimethylbutanes. The hydrocarbon is separated into a fraction comprising the C.sub.5 - hydrocarbons and the dimethylbutanes, a light fraction excluding dimethyl butanes, and a heavy fraction. The light fraction is reformed in the presence of a monofunctional catalyst, and the heavy fraction is reformed in the presence of a bifunctional catalyst.
摘要:
Zeolites washed with aqueous solutions or water to exhibit pH in the range of 9.4 to 10.0 and preferably 9.6 to 10.0 which can be converted to reforming catalysts with enhanced activity, selectivity and activity maintenance. Also processes for washing the zeolite to the target pH range and processes for using catalysts made with the washed zeolite to reform naphtha feeds.
摘要:
A process for reforming a full boiling range naptha feed to enhance benzene yield is disclosed which first separates the feed into a .[.C.sub.6 .]. .Iadd.lighter .Iaddend.fraction .[.containing at least 10% by volume of C.sub.7+ hydrocarbons.]. .Iadd., comprising at least one member selected from the group consisting of C.sub.6, C.sub.7, and C.sub.8 hydrocarbons, .Iaddend.and a .[.C.sub.7 +.]. .Iadd.heavier .Iaddend.fraction, then subjecting the .[.C.sub.6 .]. .Iadd.lighter .Iaddend.fraction to a catalytic aromatization process .[.and subjecting the C.sub.7 + fraction to a catalytic reforming process, followed by recovering the aromatics produced.]..Iadd.in the presence of a non-acidic catalyst.Iaddend..
摘要:
A process for reforming a hydrocarbon fraction having a limited proportion of C.sub.9 + hydrocarbons. A hydrocarbon fraction is separated into a light fraction and a heavy fraction, the light fraction containing less than 10% by volume of C.sub.9 + hydrocarbon. The light fraction is reformed in the presence of a monofunctional catalyst, and the heavy fraction is reformed in the presence of a bifunctional catalyst.
摘要:
The present invention is directed to a process for treating hydrotreated naphtha which involves treating the naphtha over massive nickel catalyst followed by treating the naphtha over a metal oxide under conditions effective for removing impurities from said naphtha to result in substantially purified naphtha, wherein the metal oxide is selected from the group of metal oxides having a free energy of formation of sulfide which exceeds said free energy of formation of platinum sulfide, such as manganous oxide. In so doing, naphtha in the gas phase in the presence of hydrogen is passed over the manganous oxide at a temperature within the range of about 800.degree. F. and 1100.degree. F., a hydrogen to oil molar ratio between about 1:1 and 6:1, a whsv between about 2 and 8, and pressure between about 50 and 300 psig; and the naphtha in the liquid phase at a temperature between about 300.degree. F. and about 350.degree. F., and whsv less than about 5 is passed over the massive nickel.The naphtha in the liquid phase, at about ambient temperature, and at a whsv between 2 and 10, may also be passed over a Na Y mole sieve prior to treating over massive nickel and manganous oxide. In addition the naphtha be being passed over alumina after treating over massive nickel and prior to treating over manganous oxided in the liquid phase, at a temperature between 300.degree. F. and 350.degree. F., and a whsv between 2 and 10.The naphtha may also be passed over a mole sieve water trap in the liquid phase at ambient temperature and at a whsv between 2 and 10, prior to treating over massive nickel and manganous oxide.
摘要:
An integrated power generating plant includes a fuel cell for generating electrical energy directly, an auxiliary power generating plant that utilizes both the sensible heat and the heating value of effluents from the fuel cell by using working fluids in a closed cycle. The working fluid is vaporized by sensible heat and is superheated by combusting incompletely reacted fuels from the fuel cell.