公开(公告)号：US06352678B1

公开(公告)日：2002-03-05

申请号：US09671530

申请日：2000-09-27

Applicant: Denis Huguenin ,  Pierre Macaudiere ,  Rachid Mahiou

Inventor： Denis Huguenin ,  Pierre Macaudiere ,  Rachid Mahiou

IPC: C01F1700

CPC classification number: C09K11/7712 ,  C01B35/12

Abstract: The present invention provides a process for preparing a rare earth borate by reacting together at least one rare earth salt, boric acid and a base. The process is characterized in that the reaction is carried out using an excess of acid with respect to the stoichiometry and under conditions such that the pH of the reaction medium at the end of the reaction is in the range of 6 to 8. The precipitate formed is then recovered and calcined. The phase purity of the borate obtained is good and it can be used as a luminophore.

Abstract translation: 本发明提供了通过使至少一种稀土盐，硼酸和碱反应而制备稀土硼酸盐的方法。 该方法的特征在于，使用相对于化学计量的过量的酸进行反应，并且在使反应结束时反应介质的pH在6至8范围内的条件下进行。形成沉淀 然后回收并煅烧。 获得的硼酸盐的相纯度良好，可用作发光体。

公开(公告)号：US06284033B1

公开(公告)日：2001-09-04

申请号：US08600150

申请日：1996-02-12

Applicant: Thierry Chopin ,  Pierre Macaudiere

Inventor： Thierry Chopin ,  Pierre Macaudiere

IPC: C01F1700

CPC classification number: C01G3/00 ,  C01B13/363 ,  C01G3/006 ,  C01P2002/72 ,  C01P2004/50 ,  C01P2004/61 ,  C01P2006/37 ,  C01P2006/60 ,  C01P2006/62 ,  C01P2006/63 ,  C01P2006/64 ,  C09C1/00 ,  C09C1/04

Abstract: Thermally/chemically stable and nontoxic inorganic pigments/colorants, characteristically green and well suited for the coloration of a wide variety of materials and substrates, for example, plastics, ceramics, etc., comprise at least one mixed oxide of the formula: R2MxM′yO5 in which R is at least one element selected from among yttrium and a rare earth having an atomic number ranging from 62 to 71, inclusive, M and M′, which may be identical or different, are each at least one metallic element exhibiting at least one valence state of +2, and x and y are numbers, the sum x+y of which is equal to 2.

Abstract translation: 热/化学稳定和无毒的无机颜料/着色剂，特征为绿色，非常适合各种材料和基材的着色，例如塑料，陶瓷等，包含至少一种下式的混合氧化物：其中 R是选自钇和原子序数范围为62〜71的稀土元素中的至少一种元素，M和M'可相同或不同，各自为至少一种呈现至少一价的金属元素 状态为+2，x和y为数字，其和x + y等于2。

公开(公告)号：US06210451B1

公开(公告)日：2001-04-03

申请号：US09401966

申请日：1999-09-22

Applicant: Thierry Chopin ,  Pierre Macaudiere ,  Olivier Touret

Inventor： Thierry Chopin ,  Pierre Macaudiere ,  Olivier Touret

IPC: B01F312

CPC classification number: C10L10/02 ,  B01J13/0047 ,  C10L1/10 ,  C10L10/06

Abstract: Storage-stable colloidal organic sols comprise suspended tetravalent metal oxide particulates in an organic diluent medium, notably cerium dioxide particulates, the tetravalent metal oxide particulates having a particle size d90 no greater than 200 nanometers and being complexed with at least one amphiphilic organic acid, and either said tetravalent metal oxide particulates comprising agglomerates of crystallites, the d80 of which being no greater than 5 nanometers and at least 90% of said agglomerates comprising from 1 to 5 crystallites, and/or said at least one amphiphilic organic acid has from 11 to 50 carbon atoms and is branched in at least one of the &agr;-, &bgr;-, &ggr;- or &dgr;-positions relative to the atom bearing the acidic hydrogen.

Abstract translation: 储存稳定的胶体有机溶胶在有机稀释剂介质中包括悬浮的四价金属氧化物颗粒，特别是二氧化铈颗粒，颗粒尺寸d90不大于200纳米并与至少一种两亲性有机酸络合的四价金属氧化物颗粒，以及 所述四价金属氧化物颗粒包含微晶聚集体，其d80不大于5纳米，所述至少90％的所述附聚物包含1至5个微晶，和/或所述至少一种两亲性有机酸具有11至 50个碳原子，并且相对于带有酸性氢原子的α，β，γ或δ-位置中的至少一个分支。

公开(公告)号：US5968247A

公开(公告)日：1999-10-19

申请号：US30594

申请日：1998-02-25

Applicant: Pierre Macaudiere

Inventor： Pierre Macaudiere

IPC: A61K8/00 ,  A61K8/23 ,  A61Q1/00 ,  A61Q1/02 ,  C01F17/00 ,  C03C1/02 ,  C04B33/14 ,  C08K3/30 ,  C08K9/02 ,  C08L21/00 ,  C08L101/00 ,  C09C1/00 ,  C09C3/06 ,  C09D7/12 ,  C09D11/00 ,  C09D201/00 ,  D21H21/28 ,  C09C1/02

CPC classification number: C09D7/1283 ,  A61K8/23 ,  A61Q1/02 ,  C01F17/0037 ,  C09D7/1216 ,  C09D7/1225 ,  C09D7/1275 ,  A61K2800/412 ,  A61K2800/43 ,  C01P2002/01 ,  C01P2002/52 ,  C01P2002/54 ,  C01P2002/72 ,  C01P2002/82 ,  C01P2004/61 ,  C01P2004/62 ,  C01P2006/60 ,  C08K3/30 ,  C08K9/02

Abstract: Unique colorant compositions, well suited for the pigmentation of a wide variety of coatings and substrates, e.g., cosmetics, plastics, paints and rubbers, comprise (1) at least one crystalline rare earth metal sulfide or sesquisulfide, for example cubic cerium sesquisulfide Ce.sub.2 S.sub.3, and (2) a dopant amount of at least one alkali metal, and wherein the at least one rare earth metal sulfide or sesquisulfide comprises whole (unground) monocrystalline grains thereof having a mean particle size of at most 1.5 .mu.m.

Abstract translation: 独特的着色剂组合物，非常适合各种涂料和基材（例如化妆品，塑料，油漆和橡胶）的着色，包括（1）至少一种结晶稀土金属硫化物或倍半硫化物，例如立方三硫化铈Ce 2 S 3， 和（2）至少一种碱金属的掺杂剂量，并且其中所述至少一种稀土金属硫化物或倍半硫化物包含平均粒度至多为1.5μm的全（未研磨）单晶晶粒。

公开(公告)号：US5888291A

公开(公告)日：1999-03-30

申请号：US693238

申请日：1996-11-07

Applicant: Thierry Chopin ,  Pierre Macaudiere

Inventor： Thierry Chopin ,  Pierre Macaudiere

IPC: A61K8/30 ,  A61K8/19 ,  A61K8/25 ,  A61K8/27 ,  A61Q1/00 ,  A61Q1/02 ,  B32B9/00 ,  C01B33/20 ,  C01B33/24 ,  C04B35/16 ,  C08K3/34 ,  C09C1/28 ,  C09D1/00 ,  C09D7/12 ,  C09D11/00 ,  D21H19/38 ,  C09C1/02

CPC classification number: A61K8/25 ,  A61Q1/02 ,  C01B33/20 ,  C09C1/28 ,  A61K2800/412 ,  A61K2800/43 ,  C01P2002/70 ,  C01P2004/61 ,  C01P2006/60

Abstract: Alkaline-earth metal- and copper- and optionally titanium-based silicates in the form of agglomerates consisting either of monocrystalline grains or of aggregates themselves consisting of monocrystalline particles.These silicates are prepared by a process including the following stages: a silica sol or a silicate and optionally a titanium sol is mixed with salts of the other constituent elements of the silicate with the exception of oxygen; the mixture thus obtained is dried, preferably by spraying, and the product obtained is calcined. The silicates may be employed as colored pigments in plastics, paints, varnishes, rubbers, ceramics, glazes, papers, inks, cosmetic products, dyes and laminated coatings.

Abstract translation: PCT No.PCT / FR95 / 00140 Sec。 371日期：1996年11月7日 102（e）日期1996年11月7日PCT提交1995年2月6日PCT公布。 WO95 / 21791 PCT公开号 日期1995年8月17日碱土金属 - 和铜 - 和任选的钛基硅酸盐，其形式为由单晶颗粒或由单晶颗粒组成的聚集体本身。 这些硅酸盐通过包括以下步骤的方法制备：除了氧之外，二氧化硅溶胶或硅酸盐和任选的钛溶胶与硅酸盐的其它构成元素的盐混合; 将如此获得的混合物干燥，优选通过喷雾干燥，并将所得产物煅烧。 硅酸盐可以用作塑料，油漆，清漆，橡胶，陶瓷，釉料，纸，油墨，化妆品，染料和层压涂料中的有色颜料。

公开(公告)号：US06596196B2

公开(公告)日：2003-07-22

申请号：US09742344

申请日：2000-12-22

Applicant: Denis Huguenin ,  Pierre Macaudiere

Inventor： Denis Huguenin ,  Pierre Macaudiere

IPC: C09K1163

CPC classification number: C09K11/7712 ,  C01B35/00 ,  C01B35/127 ,  C01B35/128 ,  C09K11/778 ,  C09K11/7797

Abstract: An improved material in the form of rare-earth borate, its precursor(s) and a luminophore made thereof is provided. The material is characterizable as comprising spherical, cubic or parallelepipedal particles having an average particle size not more than 10 &mgr;m, over a narrow particle size distribution (dispersion index not greater than 0.8). The material may comprise a rare earth element having that lacks luminescence in combination with a dopant.

Abstract translation: 提供了一种改进的稀土硼酸盐形式的材料，其前体和由其制成的发光体。 在窄的粒度分布（分散指数不大于0.8）下，该材料可表征为包含平均粒径不超过10μm的球形，立方体或平行六面体颗粒。 该材料可以包括与掺杂剂组合的缺少发光的稀土元素。

公开(公告)号：US06464953B1

公开(公告)日：2002-10-15

申请号：US09308538

申请日：1999-01-28

Applicant: Pierre Macaudiere ,  Thierry Seguelong

Inventor： Pierre Macaudiere ,  Thierry Seguelong

IPC: C01F1700

CPC classification number: G01N27/4073 ,  B01D71/024 ,  B01J4/04 ,  C01B13/0255 ,  C01F17/0025 ,  C01G15/00 ,  C01G15/006 ,  C01P2002/34 ,  C04B35/44 ,  H01M8/124 ,  Y02P70/56

Abstract: The present invention relates to a compound of the LaMO3 type, M being aluminum, gallium or indium, in the form of a powder or in sintered form, its process of preparation and its use as an oxygen conductor. The compound in powder form is capable of achieving, by pressureless sintering, a density of at least 93% of the theoretical density and of giving a sintered compound substantially free of any electrically active secondary phase of the grain boundaries. The compound in powder form is obtained by the reaction of the salts of lanthanum and of the element M with a base, and then the separation and calcining of the precipitate obtained. It may also be obtained by mixing, in a liquid medium, salts of lanthanum, and of the element M and, optionally, of a base, and then spray-drying and calcining the precipitate obtained. The sintered compound may be used in any application requiring an oxygen-conducting material in oxide form, such as solid-oxide fuel cells.

Abstract translation: 本发明涉及LaMO3型的化合物，M为铝，镓或铟，为粉末形式或烧结形式，其制备方法及其用作氧导体。 粉末形式的化合物能够通过无压烧结获得理论密度的至少93％的密度，并且给出基本上不含任何电活性的晶界二次相的烧结组合物。 粉末形式的化合物是通过镧和元素M与碱的反应而获得的，然后分离和煅烧沉淀物。 还可以通过在液体介质中混合镧，元素M和任选的碱的盐，然后将所得沉淀物喷雾干燥和煅烧来获得。 烧结的化合物可以用于需要氧化物形式的导电材料的任何应用，例如固体氧化物燃料电池。

公开(公告)号：US06419735B1

公开(公告)日：2002-07-16

申请号：US09485385

申请日：2000-05-19

Applicant: Sylvain Busnot ,  Pierre Macaudiere

Inventor： Sylvain Busnot ,  Pierre Macaudiere

IPC: C01F1700

CPC classification number: C01F17/0037 ,  C01P2004/61 ,  C01P2006/60 ,  C08K3/30 ,  C09C1/00 ,  C09C3/063

Abstract: The composition is based on a samarium sesquisulphide, it exhibits a samarium purity with respect to other rare earth metals of greater than 99% and it comprises at least one alkali metal or alkaline earth metal element, at least a portion of which is included in the crystal lattice of the said sesquisulphide. According to another embodiment, the composition is based on a sesquisulphide of samarium and of at least one rare earth metal which is solely trivalent and it comprises at least one alkali metal or alkaline earth metal element, at least a portion of which is included in the crystal lattice of the said sesquisulphide. According to a third embodiment, the composition exhibits a samarium purity such that the cerium content is less than 1%. The process consists in reacting samarium, trivalent rare earth metal and alkali metal or alkaline earth metal compounds with a gaseous mixture of hydrogen sulphide and of carbon disulphide.

Abstract translation: 该组合物基于钐倍半硫化物，相对于大于99％的其它稀土金属显示钐纯度，并且其包含至少一种碱金属或碱土金属元素，其至少一部分包括在 所述倍半硫化物的晶格。 根据另一个实施方案，该组合物是基于钐的倍半硫化物和至少一种仅为三价的稀土金属，并且其包含至少一种碱金属或碱土金属元素，其至少一部分包括在 所述倍半硫化物的晶格。 根据第三实施方案，组合物显示钐纯度，使得铈含量小于1％。 该方法包括使钐，三价稀土金属和碱金属或碱土金属化合物与硫化氢和二硫化碳的气体混合物反应。

公开(公告)号：US5501733A

公开(公告)日：1996-03-26

申请号：US257823

申请日：1994-06-09

Applicant: Pierre Macaudiere ,  Jorge Morros ,  Jean-Michel Tourre ,  Alain Tressaud

Inventor： Pierre Macaudiere ,  Jorge Morros ,  Jean-Michel Tourre ,  Alain Tressaud

IPC: C09C1/62 ,  A61K8/18 ,  A61K8/21 ,  A61K8/23 ,  A61K8/26 ,  A61Q1/00 ,  A61Q1/02 ,  A61Q1/04 ,  A61Q1/06 ,  A61Q3/02 ,  C01F17/00 ,  C03C1/02 ,  C04B33/14 ,  C04B35/50 ,  C08K3/30 ,  C08K9/00 ,  C08L21/00 ,  C08L101/00 ,  C09C1/00 ,  C09C3/06 ,  C09C3/08 ,  C09D7/12 ,  C09D11/00 ,  C09D11/02 ,  C09D17/00 ,  C09D201/00 ,  D21H21/28 ,  C01F1/00

CPC classification number: A61Q1/02 ,  A61K8/21 ,  A61K8/23 ,  A61Q3/02 ,  C08K3/30 ,  C09C1/00 ,  C09D11/037 ,  C09D7/1225 ,  D21H21/285 ,  C01P2002/70 ,  C01P2004/80 ,  C08K3/0033 ,  C08K9/10

Abstract: Fluoridated particulates, especially external face surface-fluoridated particulates of the rare earth metal sesquisulfide pigments/colorants, advantageously encapsulated within a coating layer of at least one transparent oxide or hydrate thereof, e.g., silica, have improved chromatic properties and are well suited for the coloration/pigmentation of a wide variety of materials and substrates, for example paints, plastics, resins, varnishes, rubbers, ceramics, glazes, papers, inks, leathers, cosmetics, dyes, coatings, etc.

Abstract translation: 氟化颗粒，特别是稀土金属倍半硫系颜料/着色剂的外表面氟化颗粒，有利地包封在至少一种透明氧化物或其水合物（例如二氧化硅）的涂层内，具有改善的色性，并且非常适合于 各种材料和基材的着色/着色，例如油漆，塑料，树脂，清漆，橡胶，陶瓷，釉料，纸，油墨，皮革，化妆品，染料，涂料等。

公开(公告)号：US06491886B1

公开(公告)日：2002-12-10

申请号：US09446955

申请日：2000-04-19

Applicant: Catherine Hedouin ,  Pierre Macaudiere

Inventor： Catherine Hedouin ,  Pierre Macaudiere

IPC: B01J800

CPC classification number: B01J21/063 ,  B01D53/9418 ,  B01D2251/21 ,  B01D2255/1021 ,  B01D2255/2063 ,  B01D2255/20707 ,  B01J21/08 ,  B01J23/42 ,  B01J35/0013 ,  B01J37/0211 ,  Y02T10/24

Abstract: The present invention relates to a process for treating gases to reduce emissions of oxides of nitrogen. This process is of the type in which a catalytic composition is used which comprises a catalytic phase on a support and is characterized in that the support is based on silica and titanium oxide in an atomic proportion Ti/Ti+Si of between 0.1 and 15%. The process of the invention applies more particularly to the treatment of the exhaust gases from diesel engines or from lean burn engines.

Abstract translation: 本发明涉及一种处理气体以减少氮氧化物排放的方法。 该方法是其中使用催化组合物的类型，其在载体上包含催化相，其特征在于载体是以二氧化硅和Ti / Ti + Si原子比为0.1至15％的氧化钛， 。 本发明的方法更具体地适用于来自柴油发动机或稀薄燃烧发动机的废气的处理。