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1.
公开(公告)号:US20210121850A1
公开(公告)日:2021-04-29
申请号:US16635790
申请日:2018-08-01
Applicant: Research Triangle institute
Inventor: Jian-Ping Shen , Jason S. Norman , Brian S. Turk , Ragbubir Gupta
Abstract: Zinc oxide-based sorbents, and processes for preparing and using them are provided, wherein the sorbents are preferably used to remove one or more reduced sulfur species from gas streams. The sorbents contain an active zinc component, optionally in combination with one or more promoter components and/or one or more substantially inert components. The active zinc component is a two-phase material, consisting essentially of a zinc oxide (ZnO) phase and a zinc aluminate (ZnAl2O4) phase. Each of the two phases is characterized by a relatively small crystallite size of typically less than about 50 nm (500 Angstroms). Preferably the sorbents are prepared by using an alkali metal base to convert a precursor mixture, containing a precipitated zinc oxide precursor and a precipitated aluminum oxide precursor, to the two-phase, active zinc oxide containing component, with the resulting sorbent having a sodium level within a desired range.
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公开(公告)号:US20180065114A1
公开(公告)日:2018-03-08
申请号:US15808514
申请日:2017-11-09
Applicant: Research Triangle Institute
Inventor: Jian-ping Shen , Marty Lail , Brian Turk , Paul D. Mobley , Jason S. Norman , Laura DOUGLAS , Jonathan PETERS
IPC: B01J23/835 , C01B3/40 , C10G27/00 , C07C29/156 , B01J35/00 , B01J23/89 , B01J23/83 , B01J23/80 , B01J23/78 , B01J23/00 , B01J23/889
CPC classification number: B01J23/835 , B01J23/002 , B01J23/74 , B01J23/76 , B01J23/78 , B01J23/80 , B01J23/83 , B01J23/8892 , B01J23/8906 , B01J35/002 , B01J37/03 , B01J37/14 , B01J37/18 , B01J2523/00 , B01J2523/821 , C01B3/40 , C01B32/40 , C01B2203/0238 , C01B2203/1047 , C01B2203/1064 , C01B2203/1088 , C01B2203/1235 , C07C2/84 , C07C5/42 , C07C9/06 , C07C11/02 , C07C11/04 , C07C11/06 , C07C11/22 , C07C13/20 , C07C15/46 , C07C29/156 , C07C31/04 , C07C2521/04 , C07C2521/06 , C07C2521/08 , C07C2523/46 , C07C2523/74 , C07C2523/78 , C07C2523/80 , C07C2523/83 , C07C2523/835 , C07C2523/889 , C07C2523/89 , C07C2601/16 , C07D301/03 , C10G27/00 , C10G2400/22 , C10G2400/30 , C10J3/463 , C10J3/725 , C10J2300/0969 , C10J2300/0986 , C10J2300/1653 , Y02E20/18 , Y02P20/52 , B01J2523/31 , B01J2523/43 , B01J2523/842 , B01J2523/24 , B01J2523/3706 , B01J2523/845 , B01J2523/72 , B01J2523/13 , B01J2523/17 , B01J2523/22 , B01J2523/27
Abstract: This invention is directed to novel mixed transition metal iron (II/III) catalysts for the extraction of oxygen from CO2 and the selective reaction with organic compounds.
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公开(公告)号:US10286383B2
公开(公告)日:2019-05-14
申请号:US15808514
申请日:2017-11-09
Applicant: Research Triangle Institute
Inventor: Jian-ping Shen , Marty Lail , Brian Turk , Paul D. Mobley , Jason S. Norman , Laura Douglas , Jonathan Peters
IPC: B01J23/04 , B01J23/78 , B01J23/835 , B01J23/89 , C01B3/40 , C07C29/156 , B01J23/74 , B01J23/76 , B01J23/889 , B01J23/00 , B01J23/80 , B01J23/83 , B01J35/00 , C07C2/84 , C07C5/42 , C07D301/03 , C10G27/00 , C10J3/72 , C01B32/40 , C07C9/06 , C07C11/02 , C07C11/04 , C07C11/06 , C07C11/22 , C07C13/20 , C07C15/46 , C07C31/04 , C10J3/46 , B01J37/03 , B01J37/14 , B01J37/18
Abstract: This invention is directed to novel mixed transition metal iron (II/III) catalysts for the extraction of oxygen from CO2 and the selective reaction with organic compounds.
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公开(公告)号:US09884313B2
公开(公告)日:2018-02-06
申请号:US14908852
申请日:2014-07-31
Applicant: Research Triangle Institute
Inventor: Jian-ping Shen , Marty Lail , Brian Turk , Paul D. Mobley , Jason S. Norman , Laura Douglas , Jonathan Peters
IPC: C07C29/156 , C07C2/84 , C07C5/42 , B01J23/835 , B01J23/78 , B01J23/80 , B01J23/83 , B01J23/00 , B01J23/889 , B01J23/89 , C10G27/00 , B01J23/74 , B01J23/76 , B01J35/00 , C01B31/18 , C07D301/03 , C10J3/72 , C01B3/40 , B01J37/03 , B01J37/14 , B01J37/18
CPC classification number: B01J23/835 , B01J23/002 , B01J23/74 , B01J23/76 , B01J23/78 , B01J23/80 , B01J23/83 , B01J23/8892 , B01J23/8906 , B01J35/002 , B01J37/03 , B01J37/14 , B01J37/18 , B01J2523/00 , B01J2523/821 , C01B3/40 , C01B32/40 , C01B2203/0238 , C01B2203/1047 , C01B2203/1064 , C01B2203/1088 , C01B2203/1235 , C07C2/84 , C07C5/42 , C07C9/06 , C07C11/02 , C07C11/04 , C07C11/06 , C07C11/22 , C07C13/20 , C07C15/46 , C07C29/156 , C07C31/04 , C07C2521/04 , C07C2521/06 , C07C2521/08 , C07C2523/46 , C07C2523/74 , C07C2523/78 , C07C2523/80 , C07C2523/83 , C07C2523/835 , C07C2523/889 , C07C2523/89 , C07C2601/16 , C07D301/03 , C10G27/00 , C10G2400/22 , C10G2400/30 , C10J3/463 , C10J3/725 , C10J2300/0969 , C10J2300/0986 , C10J2300/1653 , Y02E20/18 , Y02P20/52 , B01J2523/31 , B01J2523/43 , B01J2523/842 , B01J2523/24 , B01J2523/3706 , B01J2523/845 , B01J2523/72 , B01J2523/13 , B01J2523/17 , B01J2523/22 , B01J2523/27
Abstract: This invention is directed to novel mixed transition metal iron (II/III) catalysts for the extraction of oxygen from CO2 and the selective reaction with organic compounds.
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公开(公告)号:US11491457B2
公开(公告)日:2022-11-08
申请号:US16635790
申请日:2018-08-01
Applicant: Research Triangle Institute
Inventor: Jian-Ping Shen , Jason S. Norman , Brian S. Turk , Raghubir Gupta
Abstract: Zinc oxide-based sorbents, and processes for preparing and using them are provided, wherein the sorbents are preferably used to remove one or more reduced sulfur species from gas streams. The sorbents contain an active zinc component, optionally in combination with one or more promoter components and/or one or more substantially inert components. The active zinc component is a two-phase material, consisting essentially of a zinc oxide (ZnO) phase and a zinc aluminate (ZnAl2O4) phase. Each of the two phases is characterized by a relatively small crystallite size of typically less than about 50 nm (500 Angstroms). Preferably the sorbents are prepared by using an alkali metal base to convert a precursor mixture, containing a precipitated zinc oxide precursor and a precipitated aluminum oxide precursor, to the two-phase, active zinc oxide containing component, with the resulting sorbent having a sodium level within a desired range.
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公开(公告)号:US20190201877A1
公开(公告)日:2019-07-04
申请号:US16296746
申请日:2019-03-08
Applicant: Research Triangle Institute
Inventor: Jian-Ping Shen , Marty Lail , Brian Turk , Paul D. Mobley , Jason S. Norman , Laura Douglas , Jonathan Peters
IPC: B01J23/835 , C07C11/02 , B01J23/83 , B01J23/89 , C07C31/04 , C07C13/20 , C07C11/22 , C07C11/06 , C07C15/46 , C10J3/46 , B01J35/00 , C01B32/40 , C10J3/72 , C07C29/156 , C07C11/04 , B01J23/74 , B01J23/76 , C07C2/84 , C07C5/42 , C07D301/03 , C01B3/40 , C10G27/00 , B01J23/889 , B01J23/00 , B01J23/78 , B01J23/80 , C07C9/06
CPC classification number: B01J23/835 , B01J23/002 , B01J23/74 , B01J23/76 , B01J23/78 , B01J23/80 , B01J23/83 , B01J23/8892 , B01J23/8906 , B01J35/002 , B01J37/03 , B01J37/14 , B01J37/18 , B01J2523/00 , B01J2523/821 , C01B3/40 , C01B32/40 , C01B2203/0238 , C01B2203/1047 , C01B2203/1064 , C01B2203/1088 , C01B2203/1235 , C07C2/84 , C07C5/42 , C07C9/06 , C07C11/02 , C07C11/04 , C07C11/06 , C07C11/22 , C07C13/20 , C07C15/46 , C07C29/156 , C07C31/04 , C07C2521/04 , C07C2521/06 , C07C2521/08 , C07C2523/46 , C07C2523/74 , C07C2523/78 , C07C2523/80 , C07C2523/83 , C07C2523/835 , C07C2523/889 , C07C2523/89 , C07C2601/16 , C07D301/03 , C10G27/00 , C10G2400/22 , C10G2400/30 , C10J3/463 , C10J3/725 , C10J2300/0969 , C10J2300/0986 , C10J2300/1653 , Y02E20/18 , Y02P20/52 , B01J2523/31 , B01J2523/43 , B01J2523/842 , B01J2523/24 , B01J2523/3706 , B01J2523/845 , B01J2523/72 , B01J2523/13 , B01J2523/17 , B01J2523/22 , B01J2523/27
Abstract: This invention is directed to novel mixed transition metal iron (II/III) catalysts for the extraction of oxygen from CO2 and the selective reaction with organic compounds.
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