Clad optic fiber, and process for production thereof
    1.
    发明授权
    Clad optic fiber, and process for production thereof 失效
    包层光纤及其制造方法

    公开(公告)号:US5966490A

    公开(公告)日:1999-10-12

    申请号:US823005

    申请日:1997-03-21

    IPC分类号: G02B6/02 G02B6/42 G02B6/44

    摘要: In a double-clad optical fiber comprising a core having an index of refraction n.sub.1, an inner cladding surrounding the core and having an index of refraction n.sub.2, and a first outer cladding surrounding the inner cladding and having an index of refraction n.sub.3 (wherein n.sub.1 >n.sub.2 >n.sub.3), the softness of the first outer cladding often renders it difficult to perform polishing or other mechanical operations on the end of the fiber. To reduce such difficulties it is advantageous to remove the first outer cladding from a limited end portion of the fiber, replacing it with a second outer cladding having an index of refraction n.sub.4 (wherein n.sub.2 >n.sub.4) and a hardness which is greater than that of the first outer cladding.

    摘要翻译: 在包括具有折射率n1的芯的双包层光纤中,围绕芯并具有折射率n2的内包层和围绕内包层并具有折射率n3的第一外包层(其中n1 > n2> n3),第一外包层的柔软度常常使得难以对纤维的端部进行抛光或其它机械操作。 为了减少这种困难,有利的是从纤维的受限端部移除第一外包层,用具有折射率n4(其中n2> n4)的第二外包层和大于 第一个外包层。

    Sensitizer dyes for photoacid generating systems
    3.
    发明申请
    Sensitizer dyes for photoacid generating systems 失效
    用于光致酸产生系统的敏化剂染料

    公开(公告)号:US20090042105A1

    公开(公告)日:2009-02-12

    申请号:US12070913

    申请日:2008-02-21

    摘要: Photosensitizing dyes are often used in conjunction with a photoacid generator in holographic recording media. Conventional photosensitizing dyes typically are limited by having an appreciable absorption of light when used in a sufficient concentration, such that the intensity of light decreases significantly with penetration into a recording medium. The present invention discloses a number of new 5-alkynyl substituted napthacene photosensitizing dyes that have low extinction coefficients coupled with good sensitizing properties, such that the problems associated with the photosensitizing dyes absorbing light are significantly reduced.

    摘要翻译: 光敏染料通常与全息记录介质中的光致酸发生器结合使用。 常规的光敏染料通常在以足够的浓度使用时具有明显的光吸收来限制,使得光的强度随着渗入记录介质而显着降低。 本发明公开了许多具有低消光系数和良好的敏化性能的新的5-炔基取代的萘并茂光敏染料,使得与吸收光的光敏染料相关的问题显着降低。

    Process and composition for generation of acid

    公开(公告)号:US06242154B1

    公开(公告)日:2001-06-05

    申请号:US09210101

    申请日:1998-12-11

    IPC分类号: G03C1492

    CPC分类号: G03C1/73 B41M5/30 G03F7/0045

    摘要: A process for generation of acid uses a medium comprising a first acid-generating component capable of generating a first acid, and a secondary acid generator, this secondary acid generator being capable of thermal decomposition to form a secondary acid, the thermal decomposition of the secondary acid generator being catalyzed by the first acid. At least part of the medium is exposed to so as to cause formation of the first acid from the first acid-generating component; and the medium is then heated to cause, in the exposed part of the medium, acid-catalyzed thermal decomposition of the secondary acid generator and formation of the secondary acid. The secondary acid generator has a first site bearing a first leaving group and a second site bearing a second leaving group, the first leaving group being capable of protonation by the first acid, with expulsion of the first leaving group to form a cation which electrophilically adds to an unsaturated reagent bearing a proton at the site of addition and a proton-containing nucleophilic grouping at an adjacent site, following which said proton on the reagent is lost and the second leaving group is displaced by said nucleophilic grouping, the second leaving group, in combination with a proton, forming the secondary acid. Preferred variants of the process are of the types described in U.S. Pat. Nos. 5,286,612; 5,334,489; 5,395,736; 5,441,850 and 5,453,345.

    Process and composition for cladding optic fibers
    5.
    发明授权
    Process and composition for cladding optic fibers 失效
    包覆光纤的工艺和组成

    公开(公告)号:US5484822A

    公开(公告)日:1996-01-16

    申请号:US720233

    申请日:1991-06-24

    申请人: Richard A. Minns

    发明人: Richard A. Minns

    摘要: In a process for cladding an optical fiber, a photoinitiator monomer having both a photoinitiating group and an ethylenically unsaturated group is reacted with a fluorosubstituted monomer having an ethylenically unsaturated group, thereby preparing a copolymer having pendant photoinitiating groups. This copolymer is then mixed with a fluorosubstituted diacrylate, thereby forming a photopolymerizable composition, which is coated on to the optical fiber and exposed to ultraviolet light, thereby curing the photopolymerizable composition to produce a cladding on the optical fiber. Preferred claddings can have refractive indices below 1.35.

    摘要翻译: 在光纤包层的方法中,将具有光引发性基团和烯键式不饱和基团的光引发剂单体与具有烯键式不饱和基团的氟取代单体反应,由此制备具有侧链光引发基团的共聚物。 然后将该共聚物与氟取代的二丙烯酸酯混合,从而形成光聚合组合物,其涂覆在光纤上并暴露于紫外光,从而固化可光聚合组合物以在光纤上产生包层。 优选的包层可以具有低于1.35的折射率。

    Fluoroarylsulfonium photoacid generators
    6.
    发明申请
    Fluoroarylsulfonium photoacid generators 审中-公开
    氟芳基锍光酸发生剂

    公开(公告)号:US20090182172A1

    公开(公告)日:2009-07-16

    申请号:US12221517

    申请日:2008-08-04

    IPC分类号: C07F5/02

    摘要: The present invention discloses a new class of triarylsulfonium salt photoacid generators (PAGs), which are thermally stable and can be activated by long wavelength UV or visible light. The sulfonium PAGs of the present invention are additionally soluble in monomers that can be polymerized by cationic polymerization chemistry, and mixtures of said sulfonium PAGs and monomers can be stored for long periods of time without undergoing polymerization. Furthermore, typical holographic recording media comprising one of these sulfonium PAGs, polymerizable monomer(s), a sensitizing dye, and a binder can be stored for long periods of time without exhibiting significant loss of recording sensitivity. Preferred sulfonium PAGs of the present invention are sulfonium PAGs substituted with one or more fluoro or fluoroalkyl groups.

    摘要翻译: 本发明公开了一类新的三芳基锍盐光致酸发生剂(PAG),它们是热稳定的并且可以通过长波长的紫外或可见光活化。 本发明的锍PAG还可溶于可通过阳离子聚合化学反应聚合的单体,并且所述锍PAG和单体的混合物可以长时间储存​​而不经历聚合。 此外,包含这些锍PAG,可聚合单体,敏化染料和粘合剂中的一种的典型全息记录介质可以长时间储存​​,而不会显着降低记录灵敏度。 本发明优选的锍PAG是被一个或多个氟代或氟烷基取代的锍PAG。

    Adhesive composition, and imaging medium comprising this adhesive
composition
    8.
    发明授权
    Adhesive composition, and imaging medium comprising this adhesive composition 失效
    粘合剂组合物和包含该粘合剂组合物的成像介质

    公开(公告)号:US5552259A

    公开(公告)日:1996-09-03

    申请号:US126087

    申请日:1993-09-23

    摘要: A laminar thermal imaging medium is prepared from a first element comprising a first sheet transparent to image-forming radiation and having at least a surface zone or layer of polymeric material heat-activatable upon subjection of the thermal imaging medium to brief and intense radiation, the first element carrying a layer of porous or particulate image-forming substance having cohesivity in excess of its adhesivity for the polymeric heat-activatable layer, and, on the opposed side of the layer of porous or particulate image-forming substance from the surface zone or layer, a first layer of adhesive, and a second element comprising a second sheet carrying a second layer of adhesive. The second layer of adhesive comprises a polymeric hardenable adhesive comprising a macromolecular organic binder having acidic groups, and a photopolymerizable monomer. The first and second elements are laminated together with the first and second layers of adhesive in contact with one another, so forming a unitary laminar medium in which the hardenable adhesive remains in its unhardened condition and serves to reduce the tendency for the unitary laminar medium to delaminate on application of stresses to the medium. Only a short lag time, typically about 10-90 seconds, is required between lamination and curing of the hardenable adhesive in order to provide a strong bond between the two elements following curing.

    摘要翻译: 层状热成像介质由第一元件制备,第一元件包括透明至图像形成辐射的第一片,并且具有至少一个在将热成像介质置于短暂和强烈辐射之后可热激活的聚合物材料的表面区或层。 第一元件承载一层多孔或颗粒成像物质,其具有超过其对于聚合物可热激活层的粘合性的内聚力,以及在表面区域的多孔或颗粒成像物质层的相对侧上,或 层,第一层粘合剂,以及包含承载第二层粘合剂的第二片的第二元件。 第二层粘合剂包括含有具有酸性基团的高分子有机粘合剂和可光聚合单体的聚合物可硬化粘合剂。 第一和第二元件与第一和第二粘合剂层彼此接触地层压在一起,从而形成整体层状介质,其中可硬化粘合剂保持在其未硬化状态,并且用于降低单一层状介质的倾向 在对介质施加应力时分层。 在可硬化粘合剂的层压和固化之间仅需要很短的滞后时间(通常为约10-90秒),以便在固化后在两个元件之间提供强结合。