公开(公告)号：US20190071540A1

公开(公告)日：2019-03-07

申请号：US16115738

申请日：2018-08-29

Applicant: Rohm and Haas Company

Inventor： James C. Bohling ,  Ibrahim Eryazici ,  Philip R. Harsh ,  Partha S. Majumdar ,  Edwin Nungesser

IPC: C08G65/22 ,  C08L71/02 ,  C09D7/40 ,  C09D7/65 ,  C09D7/42

Abstract: The present invention relates to composition comprising an aqueous dispersion of microspheres and a class of a nonionic polyalkylene oxide of a distyryl or tristyryl phenol or an anionic polyalkylene oxide salt of a distyryl or tristyryl phenol and a process for preparing the composition. The microspheres have an average particle size in the range of from 1 μm to 25 μm, as well as a low coefficient of variation and low gel concentration; the composition is useful in coatings applications, especially where a matte finish is desired.

公开(公告)号：US10087315B2

公开(公告)日：2018-10-02

申请号：US15304386

申请日：2015-04-15

Applicant: Dow Global Technologies LLC ,  Rohm and Haas Company

Inventor： Edward E. Lafleur ,  Claudia Hernandez ,  Edwin Nungesser ,  Xuming Chen

IPC: C08L23/02 ,  C08J5/18 ,  C08K7/16

Abstract: A polymeric composition suitable for blown film applications comprising a) 80 to 99.5 percent by weight of a continuous polymeric phase comprising a polyolefin, and b) 0.5 to 20 percent by weight of polymeric particles having i) an average particle diameter of 0.85 to 20 μm; ii) a refractive index from 1.46 to 1.61; iii) an average particle hardness from 1.2367E+10 N/m2 to 8.4617E+10 N/m2; and iv) at least 60% polymerized acrylic monomer units, is disclosed. The polymeric composition can be used to form blown film characterized by having a thickness in the range of from 5 to 350 μm, a modulus of elasticity in the range of from 5 to 133 MPa, a melt strength in the range of from 4 to 40 cN, an elongation at break in the range of from 100 to 1000%, a 45 degree gloss in the range of from 7 to 136 and a softness measured by human panel handfeel-ranking methodology, measured by ISO 8587 Sensory analysis that is higher than a film which does not contain the polymeric composition.

公开(公告)号：US11473156B2

公开(公告)日：2022-10-18

申请号：US15777358

申请日：2015-12-18

Applicant: Rohm and Haas Company

Inventor： Edwin Nungesser ,  Andrew Hejl ,  Caiyun Li ,  Pu Luo

IPC: C14C11/00 ,  C08K3/08 ,  C08K3/32 ,  C09D133/08 ,  C09D175/04 ,  C14C3/16 ,  C14C3/22 ,  C14C3/28 ,  C08G18/08 ,  C09D133/06 ,  C14C3/10 ,  C09D7/40

Abstract: A method for forming chrome-free retanned leather including: (a) contacting wet white (chrome-free tanned hide) with a retanning mixture comprising from 2% to 15%, by solids weight, based on the wet weight of the wet white, of an amphoteric polymer composition comprising amine functional units and acid functional units; and (b) applying a polymeric overcoat containing an acrylic copolymer with one or more metal transition elements, with a thickness of no greater than 100 microns, to the retanned wet white, is provided. The present invention also provides a chrome-free retanned leather formed by the method.

公开(公告)号：US10508213B2

公开(公告)日：2019-12-17

申请号：US15691839

申请日：2017-08-31

Applicant: Rohm and Haas Company

Inventor： David M. Conner ,  Joy A. Gallagher ,  Philip R. Harsh ,  Partha S. Majumdar ,  Edwin Nungesser

IPC: C09D133/12 ,  C09D5/02

Abstract: The present invention relates to a composition comprising an aqueous dispersion of polymer particles and crosslinked polymer beads that are each functionalized with keto groups, and a diamine or dihydrazide crosslinking agent. The dispersions of the present invention are useful in coatings applications.

公开(公告)号：US10479907B2

公开(公告)日：2019-11-19

申请号：US15329737

申请日：2014-07-30

Applicant: Dow Global Technologies LLC ,  Rohm and Haas Company

Inventor： James C. Bohling ,  Junyu Chen ,  Edwin Nungesser ,  Zhen Qian ,  Tao Wang

IPC: C09D131/04 ,  C09D143/02 ,  C09D141/00 ,  C08F218/08 ,  C08F230/02 ,  C08F228/02 ,  C08K3/22 ,  C09D133/14

Abstract: The present invention is an above-critical coating composition comprising an aqueous dispersion of polymer particles, pigment particles, and extender particles wherein the polymer particles comprise from 80 to 99.8 weight percent structural units of vinyl acetate and from 0.1 to 6 weight percent structural units of a phosphorus acid monomer. The composition shows surprisingly improved hiding with increased particle size of the polymer particles.

公开(公告)号：US20170058371A1

公开(公告)日：2017-03-02

申请号：US15246583

申请日：2016-08-25

Applicant: Rohm and Haas Company

Inventor： Ibrahim Eryazici ,  Bradley K. Hageman ,  Joseph M. Hoefler ,  Edwin Nungesser

IPC: C14C11/00 ,  C09D133/08

CPC classification number: C14C11/003 ,  C08F220/18 ,  C08F265/06 ,  C08G18/0823 ,  C08G18/6254 ,  C09D133/00 ,  C09D133/08 ,  C09D133/14 ,  C09D151/06 ,  C09D175/04 ,  C14C11/006 ,  C08F220/14 ,  C08L75/04 ,  C08L83/04 ,  C08F2220/1825 ,  C08F2220/1858 ,  C08F220/06 ,  C08F2220/281 ,  C09D175/06 ,  C08L51/06 ,  C09D175/08

Abstract: The present invention provides aqueous composition comprising a multi-stage acrylic emulsion polymer having a first stage polymer of from 0.5 to 4 wt. %, based on the total weight of monomers used to make the first stage polymer, of a copolymerized carboxylic acid or salt group containing monomer, and having 10 to 30 wt. %, on total solids of the multi-stage acrylic emulsion polymer, of a second stage polymer of from 3 to 15 wt. % of a copolymerized hydroxyl group containing monomer, the first stage polymer having a glass transition temperature (Tg) by dynamic mechanical analysis (DMA) of less than −10° C. and the second stage polymer having a Tg (DMA) of greater than 80° C.; and (ii) from 25 to 75 wt. %, based on the total solids weight of the multi-stage acrylic polymer, of a polyurethane.

Abstract translation: 本发明提供含水组合物，其包含多级丙烯酸乳液聚合物，其具有0.5至4wt。 基于用于制备第一阶段聚合物的单体的总重量，含有共聚羧酸或含盐单体的，并且具有10至30重量％ ％，多级丙烯酸乳液聚合物的总固体含量为3至15wt。％的第二级聚合物。 ％的共聚羟基单体，第一阶段聚合物通过动态力学分析（DMA）小于-10℃具有玻璃化转变温度（Tg），第二阶段聚合物的Tg（DMA）大于 80℃。 和（ii）25至75wt。 ％，基于多级丙烯酸类聚合物的总固体重量，聚氨酯。

公开(公告)号：US11845998B2

公开(公告)日：2023-12-19

申请号：US17573029

申请日：2022-01-11

Applicant: Rohm and Haas Company

Inventor： Joy A. Gallagher ,  Philip R. Harsh ,  Pu Luo ,  Edwin Nungesser

IPC: C14C11/00 ,  C09D4/06 ,  C09D133/06 ,  C09D5/00 ,  C09D133/12

CPC classification number: C14C11/003 ,  C09D4/06 ,  C09D5/00 ,  C09D133/06 ,  C09D133/12 ,  C09D133/06 ,  C08F230/02

Abstract: The present invention relates to a composition comprising an aqueous dispersion of submicron-sized polymer particles and micron-sized polymer beads, wherein the polymer particles or beads or both are functionalized with phosphorus acid groups. The composition of the present invention is useful for providing a matte finish on substrates, such as leather, textiles, wallboard, decorative coatings, concrete, and wood, with improved stain resistance. The present invention also relates to a leather substrate coated with a clear matte finish comprising an acrylic or styrene-acrylic polymer film and micron-sized polymer beads, wherein the film or the beads or both are functionalized with a phosphorus acid monomer.

公开(公告)号：US20220325134A1

公开(公告)日：2022-10-13

申请号：US17639378

申请日：2020-10-22

Applicant: Dow Silicones Corporation ,  Dow Global Technologies LLC ,  Rohm and Haas Company

Inventor： Bertrand Lenoble ,  Nancy Delys ,  Stephane Ugazio ,  Edwin Nungesser ,  Xiangyi Zhang ,  David Malotky

IPC: C09D175/04 ,  C09D7/65 ,  C14C11/00

Abstract: An aqueous coating composition comprising an aqueous dispersion of polyurethane and a siloxane-based polyamide.

公开(公告)号：US20220127686A1

公开(公告)日：2022-04-28

申请号：US17573029

申请日：2022-01-11

Applicant: Rohm and Haas Company

Inventor： Joy A. Gallagher ,  Philip R. Harsh ,  Pu Luo ,  Edwin Nungesser

IPC: C14C11/00 ,  C09D4/06 ,  C09D133/06 ,  C09D5/00 ,  C09D133/12

Abstract: The present invention relates to a composition comprising an aqueous dispersion of submicron-sized polymer particles and micron-sized polymer beads, wherein the polymer particles or beads or both are functionalized with phosphorus acid groups. The composition of the present invention is useful for providing a matte finish on substrates, such as leather, textiles, wallboard, decorative coatings, concrete, and wood, with improved stain resistance. The present invention also relates to a leather substrate coated with a clear matte finish comprising an acrylic or styrene-acrylic polymer film and micron-sized polymer beads, wherein the film or the beads or both are functionalized with a phosphorus acid monomer.

公开(公告)号：US10676580B2

公开(公告)日：2020-06-09

申请号：US15973930

申请日：2018-05-08

Applicant: Rohm and Haas Company

Inventor： Kebede Beshah ,  James C. Bohling ,  Ibrahim Eryazici ,  Philip R. Harsh ,  Partha S. Majumdar ,  Edwin Nungesser

IPC: C08F220/18 ,  C08F230/02 ,  C08J7/16 ,  C09D7/42 ,  C08F275/00 ,  C08F285/00

Abstract: The present invention relates to an aqueous dispersion of a class of organic phosphate functionalized microspheres having a particle size in the range of from 1 μm to 25 μm, and a process for preparing the dispersion. The microspheres, which have a low coefficient of variation and low gel concentration, are useful in coatings applications, especially where a matte finish is desired.