公开(公告)号：US20240254310A1

公开(公告)日：2024-08-01

申请号：US18576403

申请日：2022-06-28

Applicant: SHPP GLOBAL TECHNOLOGIES B.V.

Inventor： Peter Vollenberg ,  Ranjan Dash ,  Shubashree Swaminathan

IPC: C08K3/30 ,  C08G63/183 ,  C08G63/695 ,  C08G63/91 ,  C08K3/22

CPC classification number: C08K3/30 ,  C08G63/183 ,  C08G63/6956 ,  C08G63/916 ,  C08K3/22 ,  C08K2003/2241 ,  C08K2003/3036

Abstract: Thermoplastic compositions include: a copolyester elastomer including a polybutylene terephthalate (PBT) moiety and an elastomer moiety: and from greater than 0.1 wt % to 9 wt % of at least one brightening agent. The copolyester elastomer is formed according to a process including (1) forming the PBT moiety from a high purity terephthalic moiety: and (2) polymerizing the PBT moiety with the elastomer moiety to form the copolyester elastomer, wherein the high purity terephthalic moiety is derived from post-consumer, pre-consumer or post-industrial recycled (PCR) polyethylene terephthalate (PET). The PBT moiety includes PBT derived from post-consumer, pre-consumer or post-industrial recycled (PCR) polyethylene terephthalate (PET), the high purity terephthalic moiety has a purity of at least about 95%, and the thermoplastic composition has an L* color value of at least 80 as determined according to a CIELab color space standard. Methods for forming the copolymer elastomer and compositions including it are also described.

公开(公告)号：US20240150573A1

公开(公告)日：2024-05-09

申请号：US18277329

申请日：2022-02-24

Applicant: SHPP Global Technologies B.V.

Inventor： Yuntao Li ,  Hao Zhou ,  Franklin Ehrensbeck ,  Laura Mely Ramirez ,  Peter Vollenberg ,  Sarah E. Grieshaber

IPC: C08L69/00 ,  B29C39/00 ,  B29C48/00 ,  C08K9/12

CPC classification number: C08L69/00 ,  B29C39/003 ,  B29C48/022 ,  C08K9/12 ,  B29K2069/00 ,  C08K2201/003 ,  C08L2205/025

Abstract: An composition comprising: a homopolycarbonate; a poly(carbonate-siloxane) having a siloxane content of 30-70 wt %, preferably 35-65 wt %, based on the total weight of the poly(carbonate-siloxane) present in an amount effective to provide 2-10 wt % total siloxane, based on the total weight of the composition; an antimicrobial agent, wherein the antimicrobial agent is a silver zinc zeolite powder, wherein the antimicrobial agent is present in amount effective to provide up to 1000 parts per million of elemental silver based on the total weight of the composition and optionally, an additive composition.

公开(公告)号：US20230174738A1

公开(公告)日：2023-06-08

申请号：US17924487

申请日：2021-05-11

Applicant: SHPP GLOBAL TECHNOLOGIES B.V.

Inventor： Lohith Kenchaiah ,  Peter Vollenberg ,  Kaushal Gandhi ,  Ranjith CHOORIKKAT ,  Vinod KN

IPC: C08J11/24 ,  C08L67/02 ,  C08G63/183 ,  C08G63/83 ,  C08G63/84 ,  C08G63/19 ,  C08G63/199

CPC classification number: C08J11/24 ,  C08L67/02 ,  C08G63/183 ,  C08G63/83 ,  C08G63/84 ,  C08G63/19 ,  C08G63/199 ,  C08J2367/02 ,  C08L2207/20

Abstract: A method includes depolymerizing post-consumer or post-industrial recycled polyethylene terephthalate (rPET) to form bis(2-hydroxyethyl) terephthalate (BHET), and reacting at least a portion of the BHET with a catalyst to form an alcohol. The alcohol includes cyclohexanedimethanol (CHDM) or 1,4-phenylenedimethanol (PDM). Further steps of the method include polymerizing the alcohol in the presence of additional BHET to form a polyester. The polyester may include poly(cyclohexylenedimethylene terephthalate (PCT), polyethylene terephthalate glycol (PETG) copolyester, polycyclohexylene dimethylene terephthalate glycol (PCTG) copolyester, polycyclohexylene dimethylene terephthalate acid (PCTA), or a monomer having repeating units with the structure (I), wherein n is an integer having a value of at least 20.

公开(公告)号：US20230062944A1

公开(公告)日：2023-03-02

申请号：US17796783

申请日：2021-02-10

Applicant: SHPP GLOBAL TECHNOLOGIES B.V.

Inventor： Peter Vollenberg ,  Christopher Luke Hein ,  Laura Mely Ramirez

IPC: C08G64/18 ,  C08G64/06 ,  C08G77/448 ,  C08K3/04 ,  C08K3/30 ,  C08K3/22 ,  C08K5/00

Abstract: A poly(carbonate-siloxane) composition comprising: a poly(carbonate-siloxane) copolymer comprising carbonate units and siloxane units, wherein a siloxane content is greater than 25 wt % to less than 70 wt %, based on the total weight of the poly (carbonate-siloxane) copolymer and wherein the weight average molecular weight of the poly (carbonate-siloxane) copolymer is greater than 30,000 g/mol, as measured by gel permeation chromatography using a crosslinked styrene-divinyl benzene column, using polystyrene standards and calibrated for polycarbonate; a homopolycarbonate comprising a bisphenol A homopolycarbonate; a colorant composition comprising an organic colorant, an inorganic pigment, or a combination thereof, wherein the colorant composition optionally comprises titanium dioxide in an amount of 0.8 wt % or less; optionally, a flame retardant; optionally, an anti-drip agent; optionally, an additive composition, wherein an average siloxane domain size is less than 100 nanometers as determined by scanning electron microscopy, nd a molded sample of the poly(carbonate-siloxane) composition is substantially free of pearlescence.

公开(公告)号：US20220389223A1

公开(公告)日：2022-12-08

申请号：US17834471

申请日：2022-06-07

Applicant: SHPP Global Technologies B.V.

Inventor： Yunfei He ,  Yun Zheng ,  Wei Shan ,  Rui Gao ,  Yuntao Li ,  Hao Zhou ,  Franklin J. Ehrensbeck ,  Laura Mely Ramirez ,  Peter Vollenberg ,  Sarah E. Grieshaber

IPC: C08L83/06 ,  C08L69/00 ,  C08K3/32 ,  C08K3/34 ,  C08K3/08 ,  C08K3/22

Abstract: A thermoplastic composition comprising: a homopolycarbonate; a poly(carbonate siloxane) component present in an amount effective to provide 0.5-20 wt % total siloxane content; an antimicrobial agent comprising silver zirconium phosphate, silver phosphate glass, or a combination thereof; optionally, an additive composition; each based on the total weight of the composition which totals to 100 wt %.

公开(公告)号：US11834577B2

公开(公告)日：2023-12-05

申请号：US17280244

申请日：2019-04-25

Applicant: SHPP Global Technologies B.V.

Inventor： Eddie Kebin Geng ,  Rabeh Elleithy ,  Timothy Allessio ,  Peter Vollenberg ,  Walter R. Thompson ,  David Voorde

IPC: C08L69/00 ,  C08K7/06 ,  B29C64/165 ,  C08G64/12 ,  B33Y80/00 ,  B33Y70/10 ,  C08K7/02

CPC classification number: C08L69/00 ,  B29C64/165 ,  C08G64/12 ,  C08K7/06 ,  B33Y70/10 ,  B33Y80/00 ,  C08K7/02 ,  C08K2201/003 ,  C08L2201/08 ,  C08L2205/02 ,  C08L69/00 ,  C08L69/00 ,  C08K7/06 ,  C08K3/04

Abstract: A composition includes specific amounts of a reinforcing filler and a copolycarbonate containing bisphenol A carbonate units and second carbonate units of the formula wherein Ra, Rb, R3, R4, j, p, and q are defined herein. The composition is useful for fabricating articles that exhibit a desirable balance of heat resistance, printability in large format additive manufacturing, and good surface appearance in printed parts. Also described is a method of additive manufacturing utilizing the composition.

公开(公告)号：US11760878B2

公开(公告)日：2023-09-19

申请号：US17286873

申请日：2019-10-22

Applicant: SHPP GLOBAL TECHNOLOGIES B.V.

Inventor： Christopher Luke Hein ,  Hao Zhou ,  Bing Zhou ,  Manojkumar Chellamuthu ,  Peter Vollenberg

IPC: C08L83/10 ,  C08J5/18 ,  C08L33/12

CPC classification number: C08L83/10 ,  C08J5/18 ,  C08L33/12 ,  C08J2333/12 ,  C08J2383/10 ,  C08J2433/12 ,  C08J2483/10 ,  C08L2201/08 ,  C08L2203/16 ,  C08L2203/30

Abstract: A thermoplastic composition includes from about 30 wt % to about 95 wt % poly(methyl methacrylate) (PMMA), and from about 5 wt % to about 70 wt % of a poly(carbonate-siloxane) copolymer having a siloxane content of from about 25 wt % to about 45 wt %. A method of making a thermoplastic composition includes: (a) combining from about 30 wt % to about 95 wt % poly(methyl methacrylate) (PMMA) and from about 5 wt % to about 70 wt % of a poly(carbonate-siloxane) copolymer having a siloxane content of from about 25 wt % to about 45 wt % to form a mixture; and melt processing the mixture to polymerize it and form the thermoplastic composition.

公开(公告)号：US11118052B2

公开(公告)日：2021-09-14

申请号：US17128435

申请日：2020-12-21

Applicant: SHPP GLOBAL TECHNOLOGIES B.V.

Inventor： Norberto Silvi ,  Edward Kung ,  Peter Vollenberg ,  Christopher Ziegler

IPC: C08L69/00 ,  C08K3/04 ,  C08L83/04

Abstract: Thermoplastic compositions include: (a) a thermoplastic polymer including a polycarbonate component; (b) a poly(carbonate-siloxane) copolymer; and (c) from 4 wt % to 25 wt % carbon black. The composition has a total siloxane content of from 2 wt % to 14 wt %. The thermoplastic compositions exhibit improved physical properties as compared to compositions that do not include the poly(carbonate-siloxane) copolymer, including volume resistivity, melt viscosity, impact strength, puncture impact energy and surface resistivity.

公开(公告)号：US11912864B2

公开(公告)日：2024-02-27

申请号：US17423213

申请日：2020-01-17

Applicant: SHPP GLOBAL TECHNOLOGIES B.V.

Inventor： Christopher Ryan Ziegler ,  Peter Vollenberg

IPC: C08L69/00 ,  C08K5/5399 ,  C08K7/14

CPC classification number: C08L69/00 ,  C08K5/5399 ,  C08K7/14 ,  C08L2205/025 ,  C08L2205/035 ,  C08L2207/20 ,  C08L69/00 ,  C08L69/00 ,  C08L69/00 ,  C08L83/04 ,  C08K7/14 ,  C08K5/5399

Abstract: Thermoplastic compositions include: (a) from about 20 wt % to about 50 wt % post-consumer recycled polycarbonate (PCR-PC); (b) from about 5 wt % to about 25 wt % of a filler component; (c) from about 4 wt % to about 7 wt % of a phosphazene component; (d) from about 20 wt % to about 65 wt % of a polycarbonate copolymer component; and (e) from about 1 wt % to about 20 wt % one or more additional components. The polycarbonate copolymer component includes bisphenol-A and a monomer comprising one or more of 3,3-Bis(4-hydroxyphenyl)-2-phenyl-2,3-dihydro-isoindol-1-one (PPPBP), 4-4-(3-3-5 trimethylcyclohexane-1-ldiyl)diphenol (BPI), 4,4′-(1-Methyl Ethyl) 1-3-cyclohexandiyl) Bis-Phenol (BHPM), 1,1-Bis(4-hydroxy-3-methyl phenyl) cyclohexane (DMBPC); 4-[1-(4-hydroxyphenyl)cyclododecyl]phenol (Red Cross), bisphenol based on cyclooctadiene, bisphenol based on isophorone nitrile, and combinations thereof. The thermoplastic composition exhibits improved heat properties, including but not limited to heat deflection temperature.

公开(公告)号：US20240018353A1

公开(公告)日：2024-01-18

申请号：US18037152

申请日：2021-11-18

Applicant: SHPP GLOBAL TECHNOLOGIES B.V.

Inventor： Anna Sangregorio ,  Mark Adrianus Johannes van der Mee ,  Tony Farrell ,  Peter Vollenberg ,  Rahul Patil

IPC: C08L69/00 ,  C08G77/448 ,  C08K5/524 ,  C08K5/11

CPC classification number: C08L69/00 ,  C08G77/448 ,  C08K5/524 ,  C08K5/11 ,  C08L2205/025 ,  C08L2205/03 ,  C08L2201/02 ,  C08L2207/20 ,  C08L2203/30

Abstract: A polycarbonate composition includes particular amounts of a bisphenol A polycarbonate homopolymer, a first poly-carbonate-siloxane copolymer having a siloxane content of 10 to 30 weight percent, based on the total weight of the first polycarbon-ate-siloxane copolymer, a second polycarbonate-siloxane copolymer having a siloxane content of greater than 30 to 55 weight percent, preferably 35 to 50 weight percent, based on the total weight of the second polycarbonate-siloxane copolymer, and an organophosphorus flame retardant. Methods of making the composition and articles including the composition ar also described.