公开(公告)号：US5514483A

公开(公告)日：1996-05-07

申请号：US107295

申请日：1993-08-16

申请人： Shigeko Sujita ,  Ryoichi Muko ,  Kyoko Hamahara ,  Kazuo Mochizuki ,  Nobuyuki Morito

发明人： Shigeko Sujita ,  Ryoichi Muko ,  Kyoko Hamahara ,  Kazuo Mochizuki ,  Nobuyuki Morito

IPC分类号： B05D7/00 ,  C09D5/08 ,  C23C22/83 ,  B32B15/08 ,  B32B15/18

CPC分类号： B05D7/51 ,  C09D5/08 ,  C23C22/83 ,  B05D2350/20 ,  Y10T428/12549 ,  Y10T428/12569 ,  Y10T428/12611

摘要： The improved organic composite coated steel plate includes a zinc or zinc alloy plated steel plate as a substrate that has on its surface a chromate film the Cr.sup.6+ content of which is no more than 70% of the total Cr content and which is deposited in an amount of 5-500 mg/m.sup.2 in terms of metallic chromium, the chromate film being overlaid with a resin layer that is deposited in an amount of 0.1-3 g/m.sup.2 on a dry weight basis and which is formed primarily of water-dispersed silica and one organic resin member as selected from the group consisting of an anionic aqueous resin, a nonionic aqueous resin and an anionic aqueous urethane resin. This steel plate is adapted for not contaminating the environment of the earth in the process of its manufacture.

摘要翻译： 改进的有机复合涂层钢板包括锌或锌合金镀覆钢板作为基材，其表面上具有Cr6 +含量不超过总Cr含量的70％并以一定量沉积的铬酸盐膜 以金属铬计为5-500mg / m 2，铬酸盐膜覆盖有以干重计为0.1-3g / m 2的量沉积的树脂层，主要由水分散二氧化硅 和一种选自阴离子水性树脂，非离子水性树脂和阴离子水性聚氨酯树脂的有机树脂构件。 该钢板适用于在制造过程中不污染地球的环境。

公开(公告)号：US5482787A

公开(公告)日：1996-01-09

申请号：US135311

申请日：1993-10-12

申请人： Shigeko Sujita ,  Nobuyuki Morito

发明人： Shigeko Sujita ,  Nobuyuki Morito

IPC分类号： B32B7/02 ,  B05D7/00 ,  B05D7/14 ,  B32B15/08 ,  B32B27/20 ,  C09D163/00 ,  C23C22/24 ,  C23C22/83 ,  C23C28/00

CPC分类号： B05D7/51 ,  B05D7/14 ,  C09D163/00 ,  C23C22/83 ,  C23C28/00 ,  C23C28/3225 ,  C23C28/345 ,  B05D2301/20 ,  B05D2601/22 ,  B05D2701/00 ,  Y10T428/12549 ,  Y10T428/12569 ,  Y10T428/12611 ,  Y10T428/12799

摘要： An organic composite coated steel strip having well-balanced corrosion resistance, coating properties including adaptability to electrophoretic coating and water resistant secondary coating adherence, and spot weldability is provided. The organic composite coated strip comprises a zinc or zinc base alloy plated steel substrate; a chromate later on the substrate containing up to 70% by weight of Cr.sup.6+ based on the total chromium quantity, the chromate layer being coated in a weight of 5 to 500 mg/m.sup.2 in terms of elemental chromium; and an organic composite layer on the chromate layer mainly comprising silica and an organic high molecular weight resin. In the organic composite coated steel strip, (a) silica has an average primary particle diameter of 5 to 30 nm; (b) silica is agglomerated into agglomerates of an average thickness of 0.2 to 2 .mu.m and an average apparent diameter of 5 to 300 .mu.m; and (c) the organic composite layer has been coated to a dry weight of 0.1 to 3 g/m.sup.2. The organic composite coated steel strip of the invention has various uses including automobile bodies.

摘要翻译： 提供了具有良好平衡的耐腐蚀性，包括对电泳涂层的适应性和耐水二次涂层粘附性的涂层性能和点焊性的有机复合涂层钢带。 有机复合涂层带材包括锌或锌基合金镀钢基材; 铬酸盐层以基于铬的总铬含量高达70重量％的Cr 6+，铬酸盐层以元素铬计为5至500mg / m 2的重量; 以及主要包含二氧化硅和有机高分子量树脂的铬酸盐层上的有机复合层。 在有机复合涂层钢带中，（a）二氧化硅的平均一次粒径为5〜30nm; （b）将二氧化硅凝聚成平均厚度为0.2〜2μm，平均视野直径为5〜300μm的团块; 和（c）有机复合层已被涂覆至干燥重量为0.1至3g / m 2。 本发明的有机复合涂层钢带具有各种用途，包括汽车车身。

公开(公告)号：US5403468A

公开(公告)日：1995-04-04

申请号：US850454

申请日：1992-03-10

申请人： Hisatada Nakakoji ,  Seiji Nakajima ,  Shuji Gomi ,  Nobuyuki Morito

发明人： Hisatada Nakakoji ,  Seiji Nakajima ,  Shuji Gomi ,  Nobuyuki Morito

IPC分类号： C25D3/66 ,  C25D7/06

CPC分类号： C25D3/66

摘要： A process for the manufacture of tinplates comprising electroplating a substrate in a fused-chloride tin plating bath at a temperature of about 150.degree. to 350.degree. C., a current density of about 100 to 500 A/dm.sup.2 in an atmosphere of a non-oxidizing gas. This process may be converted to a process for the manufacture of reflow type tinplates by only changing the bath temperature, and vice versa. For the manufacture of no-reflow type tinplates, the bath is kept at 150.degree. to 232.degree. C., while for the manufacture of reflow type tinplates, the bath is kept at 233.degree. to 350.degree. C. In these cases, the bath includes SnCl.sub.2 and at least one member selected from the group consisting of KCl, NaCl, LiCl and AlCl.sub.3, and may preferably be operated while flowing the bath at a flow rate of about 0.1 m/sec higher. There is provided equipment for the manufacture of tin-plated steel strip comprising a pretreating apparatus for cold rolling steel strip, an annealing apparatus, a skin pass rolling apparatus, a fused-salt tin-electroplating apparatus with the above bath including chlorides, and an aftertreating apparatus, these apparatus being continuously integrated into the equipment by use of a fused-salt bath.

摘要翻译： 一种用于制造镀锡板的方法，包括在熔融氯化锡镀浴中在约150℃至350℃的温度下电镀底物，在非气溶胶的气氛中电流密度为约100至500A / dm 2， 氧化气体。 该方法可以通过仅改变浴温度而转化为制造回流型锡板的方法，反之亦然。 对于无回流型锡板的制造，将浴保持在150℃至232℃，而为了制造回流型锡板，将浴保持在233℃至350℃。在这些情况下，浴 包括SnCl 2和选自KCl，NaCl，LiCl和AlCl 3中的至少一种，并且优选在以约0.1m /秒的流速流动浴的情况下操作。 提供了一种用于制造镀锡钢带的设备，其包括用于冷轧钢带的预处理装置，退火装置，皮肤通过轧制装置，具有上述浴的熔融盐电镀装置，包括氯化物，以及 后处理装置，这些装置通过使用熔盐浴连续地集成到设备中。

公开(公告)号：US5326648A

公开(公告)日：1994-07-05

申请号：US658084

申请日：1991-02-20

申请人： Chiaki Kato ,  Yasuji Uesugi ,  Nobuyuki Morito ,  Akira Yasuda ,  Kouichi Yasuda ,  Hajime Kimura

发明人： Chiaki Kato ,  Yasuji Uesugi ,  Nobuyuki Morito ,  Akira Yasuda ,  Kouichi Yasuda ,  Hajime Kimura

IPC分类号： C23C2/06 ,  C23C2/02 ,  C25D5/10 ,  C25D5/26 ,  C25D5/50 ,  B32B5/14 ,  B32B15/18

CPC分类号： C25D5/50 ,  C23C2/02 ,  C25D5/10 ,  Y10S205/917 ,  Y10T428/12458 ,  Y10T428/12799

摘要： A zinc or zinc-alloy plated steel sheet having an improved weldability and plating properties, as well as a method for making the same is provided. Even when the substrate steel sheet is the one which is difficult to deposit a zinc or zinc-alloy layer by conventional methods, such as an extra low carbon steel sheet, the present invention enable a reliable production of a galvanized steel sheet suffering from no plating failure or insufficient adhesion as well as a reliable production of a galvannealed steel sheet suffering from no plating failure or streaking of the alloyed layer.The zinc or zinc-alloy plated steel sheet having improved weldability comprises an extra low carbon steel sheet, an iron-carbon plated layer or a carbon-rich layer generated by diffusion of the iron-carbon plated layer on at least one major surface of the extra low carbon steel sheet, and a zinc or zinc-alloy plated layer on the iron-carbon plated layer or the carbon-rich layer.The zinc or zinc-alloy plated steel sheet having improved weldability and/or plating properties is produced by depositing on the steel sheet an iron-carbon plated layer having a carbon content of from 0.01% by weight to 10% by weight to a coating weight of from 0 01 g/m.sup.2 to 10 g/m.sup.2, optionally annealing the iron-carbon plated steel sheet, and depositing a zinc or zinc-alloy plated layer, preferably by galvanizing or galvannealing, on the annealed steel sheet.

摘要翻译： 提供具有改进的焊接性和电镀性能的锌或锌合金镀覆钢板及其制造方法。 即使基板钢板是通过常规方法难以沉积锌或锌合金层的钢板，例如超低碳钢板，本发明能够可靠地生产没有电镀的镀锌钢板 失效或不充分的粘合性，以及可靠地生产没有电镀失效或合金化层的条纹的合金化热镀锌钢板。 具有改善的焊接性的锌或锌合金镀覆钢板包括通过铁碳镀层在至少一个主表面上扩散而产生的超低碳钢板，铁碳镀层或富碳层 铁碳镀层或富碳层上的锌或锌合金镀层。 通过在碳钢板上沉积碳含量为0.01重量％〜10重量％的铁碳镀层，涂布量为1重量％以上，制成具有改善的焊接性和/或电镀性能的锌或锌合金镀覆钢板 为0.01g / m 2至10g / m 2，可选择地对含铁碳素钢板进行退火，并且优选通过镀锌或合金化退火将锌或锌合金镀层沉积在退火钢板上。

公开(公告)号：US5207777A

公开(公告)日：1993-05-04

申请号：US886305

申请日：1992-05-21

申请人： Kiyoshi Shibuya ,  Toru Sato ,  Nobuyuki Morito ,  Seiko Nara ,  Teruo Hiramatsu

发明人： Kiyoshi Shibuya ,  Toru Sato ,  Nobuyuki Morito ,  Seiko Nara ,  Teruo Hiramatsu

IPC分类号： B22D11/06

CPC分类号： B22D11/0694

摘要： A method of guiding and transferring a rapidly quenched metallic tape includes steps of peeling the rapidly quenched metallic tape produced by solidification through rapid quenching on a circumferential surface of a single cooling roll rotating at a high speed, introducing the metallic tape into a cylindrical transfer guide to a pinch roll unit arranged at a terminal end of the transfer guide to catch the metallic tape by the pinch roll unit, and moving the pinch roll unit to a winder for the metal tape. The metallic tape is fed in the transfer guide substantially without being in contact with the transfer guide. An apparatus for guiding and transferring a rapidly quenched metallic tape includes a cylindrical transfer guide arranged on a normal line of a single cooling roll for introducing and guiding the metallic tape, a pinch roll unit arranged at a terminal end of the transfer guide for catching the metallic tape, and a transfer trolley for transferring the pinch roll unit to a winder for the metallic tape.

摘要翻译： 引导和转移快速淬火的金属带的方法包括以下步骤：通过快速淬火将快速淬火的金属带剥离在高速旋转的单个冷却辊的圆周表面上，将金属带引入圆柱形转移导向件 涉及一种夹送辊单元，其布置在转印导向件的终端处，以通过夹送辊单元捕获金属带，并将夹送辊单元移动到用于金属带的卷绕机。 金属带基本上不与转印引导件接触地供给到转印导向件中。 用于引导和传送快速淬火的金属带的装置包括：布置在单个冷却辊的法线上的圆柱形转移引导件，用于引导和引导金属带;压辊单元，布置在转移引导件的终端处，用于捕获 金属带和用于将夹送辊单元转移到用于金属带的卷绕机的转运手推车。

公开(公告)号：US5510196A

公开(公告)日：1996-04-23

申请号：US204298

申请日：1994-03-08

申请人： Hiroki Nakamaru ,  Tohru Fujimura ,  Hiroaki Ohnuma ,  Kazuo Mochizuki ,  Nobuyuki Morito ,  Michio Katayama

发明人： Hiroki Nakamaru ,  Tohru Fujimura ,  Hiroaki Ohnuma ,  Kazuo Mochizuki ,  Nobuyuki Morito ,  Michio Katayama

IPC分类号： C25D3/56 ,  B32B15/18

CPC分类号： C25D3/565 ,  Y10S428/935 ,  Y10T428/12799

摘要： Zn--Cr alloy plated steel sheets have excellent corrosion resistance. It has now been found that the phase structures of Zn--Cr alloy platings are such that they comprise yet to be known phases .eta.x, .delta.x and .GAMMA.x. Furthermore, these phases when taken either singly or with two or more phases being mixed together, exhibit the following characteristics (1)-(6). The characteristics of the respective phases are also identified below.______________________________________(1) .eta.x Resistance to cosmetic corrosion(2) .GAMMA.x Formability(3) .eta.x + .delta.x Chipping resistance(4) .eta.x + .GAMMA.x Corrosion resistance in the as-formed state(5) .delta.x + .GAMMA.x Water resistant secondary adherence of coating(6) .eta.x + .delta.x + .GAMMA.x Perforation corrosion resistance.eta.x: Hexagonal crystal a = 2.66-2.74 .ANG. c = 4.61-4.95 .ANG..delta.x: Hexagonal crystal a = 2.72-2.78 .ANG. c = 4.43-4.60 .ANG..GAMMA.x: Cubic crystal a = 3.00-3.06 .ANG.______________________________________

摘要翻译： PCT No.PCT / JP93 / 00956 Sec。 371日期：1994年3月8日 102（e）1994年3月8日PCT 1993年7月9日PCT公布。 第WO94 / 01602号公报 1994年1月20日.Zn-Cr合金镀层钢板具有优异的耐腐蚀性。 现在已经发现，Zn-Cr合金电镀的相结构使得它们还包括尚未知的相，ηx和GAMMA x。 此外，当单独或两相或更多相混合时，这些相具有以下特征（1） - （6）。 各个阶段的特征也在下面确定。 - （1）eta x耐化妆品腐蚀 - （2）GAMMA x成型性 - （3）eta x +δx抗剪切性 - （4）eta x + GAMMA x形成状态下的耐腐蚀性 - （5） δx + GAMMA x涂层的防水二次附着力（6）eta x + delta x + GAMMA x穿孔耐腐蚀性等级x：六方晶体a = 2.66-2.74 ANGSTROM - c = 4.61-4.95 ANGSTROM - δx ：六角晶体 - a = 2.72-2.78 ANGSTROM - c = 4.43-4.60 ANGSTROM - GAMMA x：立方晶体a = 3.00-3.06 ANGSTROM -

公开(公告)号：US5322741A

公开(公告)日：1994-06-21

申请号：US30412

申请日：1993-04-16

申请人： Yasuji Uesugi ,  Koichi Hashiguchi ,  Yoshihiro Matsumoto ,  Makoto Imanaka ,  Takaaki Hira ,  Nobuyuki Morito ,  Yoichi Tobiyama ,  Nobuo Totsuka ,  Motohiro Nabae

发明人： Yasuji Uesugi ,  Koichi Hashiguchi ,  Yoshihiro Matsumoto ,  Makoto Imanaka ,  Takaaki Hira ,  Nobuyuki Morito ,  Yoichi Tobiyama ,  Nobuo Totsuka ,  Motohiro Nabae

IPC分类号： C23C2/02 ,  C23C2/28 ,  C23C28/00 ,  C23C30/00 ,  C25D5/44 ,  B32B15/20 ,  C22F1/04

CPC分类号： C23C30/00 ,  C23C2/02 ,  C23C2/28 ,  C23C28/00 ,  C25D5/44 ,  Y10T428/12736 ,  Y10T428/12757

摘要： The invention provides an aluminum alloy sheet having improved formability, an elongation of at least 30%, a sliding frictional resistance of up to 0.13 and minimized surface pressure dependency of sliding frictional resistance, comprising an aluminum alloy substrate containing at least 4 wt % of Mg and a Fe rich plating layer on a surface thereof in a coating weight of 1 to 50 g/m.sup.2. Also provided is a bake hardenable, surface treated aluminum alloy sheet having improved formability, an elongation of at least 25%, a sliding frictional resistance of up to 0.13 and minimized surface pressure dependency of sliding frictional resistance, comprising a bake hardenable aluminum alloy substrate containing Mg and Si in an amount of at least 0.4 wt % calculated as Mg.sub.2 Si and a Fe rich plating layer on a surface thereof in coating weight of 1 to 50 g/m.sup.2. By forming a zincate layer as an undercoat below the Fe rich plating layer, the plating adhesion is further improved. The preferred Fe rich plating layer is a Fe-Zn alloy plating layer containing 20 to 80 wt % of Zn for corrosion resistance improvement. A Fe-Zn alloy plating layer containing 30 to 40 wt % of Zn meets both formability and corrosion resistance.

摘要翻译： PCT No.PCT / JP92 / 00931 Sec。 371日期：1993年04月16日 102（e）日期1993年4月16日PCT提交1992年7月22日PCT公布。 第WO93 / 02225号公报 日本公开1993年2月4日。本发明提供一种铝合金板，其具有改进的成形性，伸长率至少为30％，滑动摩擦阻力高达0.13，并且滑动摩擦阻力的表面压力依赖性最小化，包括含有 表面上含有至少4重量％的Mg和富Fe镀层，涂层重量为1〜50g / m 2。 还提供了具有改进的成型性，至少25％的伸长率，至多0.13的滑动摩擦阻力和最小化的滑动摩擦阻力的表面压力依赖性的烘烤可硬化的表面处理的铝合金板，其包括含有 Mg和Si的量为至少0.4重量％，其表面上的Mg 2 Si和Fe富镀层的涂层重量为1至50g / m 2。 通过在富Fe镀层下形成作为底涂层的锌酸盐层，进一步提高镀层附着力。 优选的富Fe镀层是含有20〜80重量％的Zn以提高耐腐蚀性的Fe-Zn合金镀层。 含有30〜40重量％Zn的Fe-Zn合金镀层满足成型性和耐腐蚀性。

公开(公告)号：US5273643A

公开(公告)日：1993-12-28

申请号：US46764

申请日：1993-04-13

申请人： Kazuhiro Hasegawa ,  Hiroki Nakamaru ,  Kazuo Mochizuki ,  Tomokatsu Katagiri ,  Nobuyuki Morito ,  Shigeo Kurokawa

发明人： Kazuhiro Hasegawa ,  Hiroki Nakamaru ,  Kazuo Mochizuki ,  Tomokatsu Katagiri ,  Nobuyuki Morito ,  Shigeo Kurokawa

IPC分类号： B41J2/52 ,  C25D3/56 ,  G06T5/00 ,  H04N1/405 ,  C25D7/06

CPC分类号： C25D3/565

摘要： The present invention provides a method of producing a zinc-chromium alloy-plated steel sheet having excellent properties such as bare corrosion resistance, corrosion resistance after coating, plating adhesiveness and weldability.The method is characterized by plating the surface of the steel sheet using an acid plating bath containing zinc ion (Zn.sup.2+) and chromium ion (Cr.sup.3+) at a molar concentration ratio of about 0.1.ltoreq.Cr.sup.3+ /(Zn.sup.3+ +Cr.sup.3+).ltoreq.0.9 in a total amount of at least about 0.5 mol/1 within the dissolution range, and about 0.1 to 30 g/1 of at least one nonionic organic additive having at least a triple bond, at a bath temperature of about 25.degree. to 70.degree. C. and a pH of about 1.0 to 4.0 with a current density of about 50 to 200 A/dm.sup.2.

摘要翻译： 本发明提供一种具有耐腐蚀性，涂层耐蚀性，电镀粘合性和焊接性等优异性能的镀锌 - 铬合金镀覆钢板的方法。 该方法的特征在于，使用含有约0.1 Cr 3+ /（Zn 3+ ++ Cr 3+）摩尔浓度的锌离子（Zn 2+）和铬离子（Cr 3+）的酸性电镀电镀钢板的表面， 在溶解范围内的总量为至少约0.5mol / l的0.9，以及约0.1至30g / l的至少一种具有至少三重键的非离子有机添加剂，在浴温为约25℃至 70℃，pH为约1.0至4.0，电流密度为约50至200A / dm 2。

公开(公告)号：US4977949A

公开(公告)日：1990-12-18

申请号：US444030

申请日：1989-11-30

申请人： Kiyoshi Shibuya ,  Toru Sato ,  Nobuyuki Morito ,  Seiko Nara ,  Teruo Hiramatsu

发明人： Kiyoshi Shibuya ,  Toru Sato ,  Nobuyuki Morito ,  Seiko Nara ,  Teruo Hiramatsu

IPC分类号： B22D11/06 ,  B22F9/00

CPC分类号： B22F9/008 ,  B22D11/0611

摘要： An apparatus for transferring a rapidly quenched metallic tape, which is produced by solidification through rapid quenching on a circumferential surface of a single cooling roll rotating at a high speed, from the cooling roll into a winder, comprises a transfer means provided with a pinch roll unit for catching and feeding out the peeled metallic tape, a fan for breaking and discharging the metallic tape fed out from the pinch roll unit, and a dust device for recovering metallic pieces and powder generated in the breakage of the metallic tape by the fan.

公开(公告)号：US4809768A

公开(公告)日：1989-03-07

申请号：US089527

申请日：1987-08-26

申请人： Toru Sato ,  Nobuyuki Morito ,  Shinji Kobayashi

发明人： Toru Sato ,  Nobuyuki Morito ,  Shinji Kobayashi

IPC分类号： B22D11/06

CPC分类号： B22D11/0651

摘要： Cooling rolls which receive a falling stream of a metal melt, and rapidly cooling and solidifying it. Each of the cooling rolls comprises a roll base body and a sleeve which is fitted around a barrel periphery of the roll base body and forms a cooling water flow path between the roll base body and the sleeve. The sleeve is only partially tightly fixed to the roll base body. End portions of the sleeve are joined to the roll base body in such a soft structure that movement of the sleeve in the roll axial direction due to the thermal expansion is not interrupted at end portions of the sleeve.

摘要翻译： 冷却辊接收金属熔体的下降流，并迅速冷却并固化。 每个冷却辊包括辊基体和套筒，其围绕辊基体的圆筒周边安装，并在辊基体和套筒之间形成冷却水流路。 套筒仅部分地紧密地固定到辊基体上。 套筒的端部以如此柔软的结构连接到辊基体上，使得由于热膨胀而使套筒在辊轴向方向上的移动不会在套管的端部处中断。