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1.发明授权Process for purification of methyl methacrylate using molecular sieve membranes 有权使用分子筛膜纯化甲基丙烯酸甲酯的方法公开(公告)号：US09487469B2
公开(公告)日：2016-11-08
申请号：US13963677
申请日：2013-08-09
申请人： Shiguang Li , Shaojun Zhou , Miao Yu
发明人： Shiguang Li , Shaojun Zhou , Miao Yu
IPC分类号： C07C67/56
摘要： A method for separating the components of a mixture containing methyl methacrylate, water, and methanol in which the mixture is dehydrated in a first stage membrane unit, producing a dehydrated mixture. Methanol in the dehydrated mixture is removed in a second stage membrane unit, producing a retentate stream containing methyl methacrylate and substantially no said methanol.
摘要翻译： 一种分离含有甲基丙烯酸甲酯，水和甲醇的混合物的组分的方法，其中混合物在第一级膜单元中脱水，产生脱水混合物。 脱水混合物中的甲醇在第二级膜单元中除去，产生含有甲基丙烯酸甲酯并基本上不含所述甲醇的滞留物流。
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公开(公告)号：US09249934B2
公开(公告)日：2016-02-02
申请号：US14262161
申请日：2014-04-25
申请人： Shiguang Li , Shaojun Zhou , Howard S. Meyer , Miao Yu , Moises A. Carreon
发明人： Shiguang Li , Shaojun Zhou , Howard S. Meyer , Miao Yu , Moises A. Carreon
CPC分类号： F17C11/007 , B01D2253/25 , B01J20/16 , B01J20/20 , B01J20/226 , B01J20/28016 , B01J20/28052 , B01J20/2808 , B01J20/28097 , Y02C10/08
摘要： Adsorbent pellets coated with an outer nano-porous layer can be loaded with gas at loading pressures of 250 bar or greater, enabling a much higher loading than can be achieved at low pressures. The nano-porous layer provides nano-valves which can be sealed with an adsorbate such as ethanol or a hydrocarbon to close the nano-valves. The closed nano-valves maintain the high loading pressure inside the adsorbent pellets, and thus maintain the gas loading, during storage of the loaded nano-valved adsorbent pellets at much lower pressure. To release the gas, the nano-porous layer can be heated to a temperature sufficient to vaporize the adsorbate and open the nano-valves.
摘要翻译： 涂覆有外部纳米多孔层的吸附颗粒可以在250巴或更大的负载压力下装载气体，使得能够在低压下实现高得多的载荷。 纳米多孔层提供纳米阀，可以用诸如乙醇或烃的吸附物密封以封闭纳米阀。 封闭的纳米阀门在吸附剂颗粒内部保持高的负载压力，从而在负载的纳米阀吸附剂颗粒在非常低的压力下储存期间保持气体负载。 为了释放气体，可以将纳米多孔层加热至足以蒸发被吸附物并打开纳米阀的温度。
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公开(公告)号：US09005345B2
公开(公告)日：2015-04-14
申请号：US13622434
申请日：2012-09-19
申请人： Shiguang Li , Shaojun Zhou , Miao Yu , Moises A Carreon
发明人： Shiguang Li , Shaojun Zhou , Miao Yu , Moises A Carreon
CPC分类号： B01D53/22 , B01D53/228 , B01D69/148 , B01D71/028 , B01D2257/504 , B01D2258/0283 , B01D2325/04 , B82Y30/00 , Y02C10/10 , Y10S977/778
摘要： An apparatus for gas separation a composite gas separation membrane having a gas separation layer disposed on a surface of a porous support. The gas separation layer has a plurality of gas permeable inorganic nano-particles embedded in a dense polymer forming substantially only discrete gas transport channels through the dense polymer layer, wherein direct fluid communication is provided from a feed side of the composite gas separator membrane to the porous support. Preferably, the inorganic nano-particles are porous molecular sieve particles, such as SAPO-34, ALPO-18, and Zeolite Y nano-particles.
摘要翻译： 一种用于气体分离的装置，其具有设置在多孔载体的表面上的气体分离层的复合气体分离膜。 气体分离层具有多个气体可渗透的无机纳米颗粒，其嵌入致密聚合物中，基本上仅形成通过致密聚合物层的不连续的气体输送通道，其中从复合气体分离器膜的进料侧提供直接流体连通 多孔支撑。 优选地，无机纳米颗粒是多孔分子筛颗粒，例如SAPO-34，ALPO-18和沸石Y纳米颗粒。
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公开(公告)号：US09901846B2
公开(公告)日：2018-02-27
申请号：US14549954
申请日：2014-11-21
申请人： Shaojun Zhou , Howard S. Meyer , Shiguang Li
发明人： Shaojun Zhou , Howard S. Meyer , Shiguang Li
CPC分类号： B01D19/0036 , B01D53/1425 , B01D53/1475 , B01D2252/10 , B01D2252/102 , B01D2252/204 , B01D2257/504 , Y02A50/2342 , Y02C10/04 , Y02C10/06
摘要： A process for removing carbon dioxide from a carbon dioxide-loaded solvent uses two stages of flash apparatus. Carbon dioxide is flashed from the solvent at a higher temperature and pressure in the first stage, and a lower temperature and pressure in the second stage, and is fed to a multi-stage compression train for high pressure liquefaction. Because some of the carbon dioxide fed to the compression train is already under pressure, less energy is required to further compress the carbon dioxide to a liquid state, compared to conventional processes.
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5.发明授权Method and apparatus for desorption using a microporous membrane operated in wetted mode 有权使用在湿润模式下操作的微孔膜解吸的方法和装置公开(公告)号：US09072987B2
公开(公告)日：2015-07-07
申请号：US13837671
申请日：2013-03-15
申请人： Shiguang Li , Dennis Rocha , Shaojun Zhou , Howard Meyer , Benjamin Bikson , Yong Ding
发明人： Shiguang Li , Dennis Rocha , Shaojun Zhou , Howard Meyer , Benjamin Bikson , Yong Ding
CPC分类号： B01D19/0031 , B01D53/1425 , B01D53/1475 , B01D69/08 , B01D71/52 , B01D2257/504 , Y02C10/06 , Y02C10/10
摘要： A method for desorption of one or more gases from a liquid stream in which a liquid stream containing at least one gas is provided to the feed side of a porous membrane and a trans-membrane pressure drop from the feed side to the opposite gas side of the membrane is created, resulting in a portion of the liquid stream filling at least a portion of the pores of the porous membrane and desorption of at least a portion of the at least one gas from the liquid stream to the gas side of the porous membrane.
摘要翻译： 一种从液体流中解吸一种或多种气体的方法，其中将含有至少一种气体的液体流提供到多孔膜的进料侧和从进料侧到相对气体侧的跨膜压降 产生膜，导致一部分液体流填充多孔膜的孔的至少一部分，并且至少一部分气体从液体流解吸到多孔膜的气体侧 。
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公开(公告)号：US20130277615A1
公开(公告)日：2013-10-24
申请号：US13512018
申请日：2012-04-23
CPC分类号： C01B3/32 , B01J19/00 , B01J19/0006 , C01B2203/025 , C01B2203/0877 , C10J3/485 , C10J2300/0903 , C10J2300/0959 , C10J2300/0973 , C10J2300/0983 , C10J2300/0993 , C10J2300/0996 , Y02E20/16 , Y02E20/18
摘要： A system includes a slag additive slurry feed system configured to combine a slurrying agent, a mineral slag additive, and a liquid slurrying medium to generate a stabilized mineral slurry. The slurrying agent is configured to increase a viscosity of the stabilized mineral slurry. The system also includes a partial oxidation system configured to receive the stabilized mineral slurry, a feedstock, and oxygen into a gasifier reaction chamber. The partial oxidation system is configured to partially oxidize the feedstock to produce a gaseous product and a solid product.
摘要翻译： 系统包括炉渣添加剂浆料进料系统，其被配置为组合制浆剂，矿渣添加剂和液体制浆介质以产生稳定的矿物浆料。 配制剂被配置成增加稳定的矿物浆料的粘度。 该系统还包括构造成将稳定的矿物浆料，原料和氧气接收到气化器反应室中的部分氧化系统。 部分氧化系统被配置为部分氧化原料以产生气态产物和固体产物。
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7.发明授权公开(公告)号：US08302782B2
公开(公告)日：2012-11-06
申请号：US12044116
申请日：2008-03-07
CPC分类号： B01D67/0051 , B01D53/228 , B01D67/0058 , B01D71/028 , B01D2256/24 , B01D2257/504 , B01D2323/18 , Y02C10/10 , Y10T428/24999
摘要： SAPO-34 membranes and methods for their preparation and use are described. The SAPO-34 membranes are prepared by contacting at least one surface of a porous membrane support with a synthesis gel comprising a first and a second templating agent. SAPO-34 crystals having a narrow size distribution were applied to the surface of the support prior to synthesis. A layer of SAPO-34 crystals is formed on at least one surface of the support. SAPO-34 membranes of the invention can have improved selectivity for certain gas mixtures, including mixtures of carbon dioxide and methane.
摘要翻译： 描述了SAPO-34膜及其制备和使用的方法。 通过使多孔膜载体的至少一个表面与包含第一和第二模板剂的合成凝胶接触来制备SAPO-34膜。 在合成之前将具有窄尺寸分布的SAPO-34晶体施加到载体的表面。 在载体的至少一个表面上形成一层SAPO-34晶体。 本发明的SAPO-34膜可以对某些气体混合物（包括二氧化碳和甲烷的混合物）具有改进的选择性。
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公开(公告)号：US08221525B2
公开(公告)日：2012-07-17
申请号：US12837563
申请日：2010-07-16
申请人： Shiguang Li , Qinbai Fan
发明人： Shiguang Li , Qinbai Fan
CPC分类号： B01D67/0051 , B01D53/228 , B01D71/028 , B01D2256/12 , B01D2257/102 , B01D2323/12
摘要： A method of oxygen enrichment in which a gaseous mixture containing O2 molecules and N2 molecules is provided to a feed side of a SAPO molecular sieve, oxygen enrichment membrane having pore sizes suitable for discriminating between O2 molecules and N2 molecules, resulting in selective transport of the O2 molecules through the membrane to a permeate side of the membrane. Also disclosed is a method for producing the membrane.
摘要翻译： 一种富氧方法，其中将含有O 2分子和N 2分子的气态混合物提供给SAPO分子筛的进料侧，具有适于区分O 2分子和N 2分子的孔径的富氧膜，导致选择性运输 O2分子通过膜到膜的渗透侧。 还公开了一种膜的制造方法。
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公开(公告)号：US20120012001A1
公开(公告)日：2012-01-19
申请号：US12837563
申请日：2010-07-16
申请人： Shiguang Li , Qinbai Fan
发明人： Shiguang Li , Qinbai Fan
CPC分类号： B01D67/0051 , B01D53/228 , B01D71/028 , B01D2256/12 , B01D2257/102 , B01D2323/12
摘要： A method of oxygen enrichment in which a gaseous mixture containing O2 molecules and N2 molecules is provided to a feed side of a SAPO molecular sieve, oxygen enrichment membrane having pore sizes suitable for discriminating between O2 molecules and N2 molecules, resulting in selective transport of the O2 molecules through the membrane to a permeate side of the membrane. Also disclosed is a method for producing the membrane.
摘要翻译： 一种富氧方法，其中将含有O 2分子和N 2分子的气态混合物提供给SAPO分子筛的进料侧，具有适于区分O 2分子和N 2分子的孔径的富氧膜，导致选择性运输 O2分子通过膜到膜的渗透侧。 还公开了一种膜的制造方法。
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10.发明授权公开(公告)号：US08409326B2
公开(公告)日：2013-04-02
申请号：US11746191
申请日：2007-05-09
申请人： Shiguang Li , John L. Falconer , Richard D. Noble
发明人： Shiguang Li , John L. Falconer , Richard D. Noble
CPC分类号： B01D53/228 , B01D67/0048 , B01D71/02 , B01D2257/504 , B01D2323/08 , B01D2323/12 , B01D2323/14 , Y02C10/08 , Y02C10/10
摘要： SAPO-34 membranes and methods for their preparation and use are described. The SAPO-34 membranes are prepared by contacting at least one surface of a porous membrane support with a synthesis gel. The Si/Al ratio of the synthesis gel can be from 0.3 to 0.15. SAPO-34 crystals are optionally applied to the surface of the support prior to synthesis. A layer of SAPO-34 crystals is formed on at least one surface of the support. SAPO-34 crystals may also form in the pores of the support. SAPO-34 membranes of the invention can have improved selectivity for certain gas mixtures, including mixtures of carbon dioxide and methane.
摘要翻译： 描述了SAPO-34膜及其制备和使用的方法。 通过使多孔膜载体的至少一个表面与合成凝胶接触来制备SAPO-34膜。 合成凝胶的Si / Al比可以为0.3〜0.15。 在合成之前，SAPO-34晶体任选地施加到载体的表面。 在载体的至少一个表面上形成一层SAPO-34晶体。 SAPO-34晶体也可以形成在载体的孔中。 本发明的SAPO-34膜可以对某些气体混合物（包括二氧化碳和甲烷的混合物）具有改进的选择性。
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