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公开(公告)号：US08324334B2
公开(公告)日：2012-12-04
申请号：US13060058
申请日：2009-08-21
CPC分类号： C08G61/08 , C08G2261/3322 , C08G2261/418
摘要： Olefin metathesis polymerization reactions are disclosed, and more particularly ring-opening metathesis polymerization of cyclic olefins with olefinic compounds, such as are derived from seed oils and the like, to form telechelic polymers. In one aspect, a method is provided for carrying out a catalytic ring-opening metathesis polymerization reaction, comprising contacting at least one olefinic compound with at least one cyclic olefin, in the presence of a ruthenium alkylidene olefin metathesis catalyst under conditions effective to allow ring-opening metathesis polymerization of the cyclic olefin, whereby the cyclic olefin polymer formed is terminated with the olefinic compound. The invention has utility in the fields of catalysis, organic synthesis, polymer chemistry, and industrial chemistry.
摘要翻译： 公开了烯烃易位聚合反应，更具体地说，环烯烃与烯烃化合物如来自种子油等的开环易位聚合反应形成遥爪聚合物。 在一个方面，提供了一种用于进行催化开环易位聚合反应的方法，包括在钌亚烷基烯烃复分解催化剂存在下使至少一种烯烃化合物与至少一种环烯烃接触，所述条件有效地允许环 开环环烯烃的易位聚合，由此所形成的环烯烃聚合物用烯烃化合物终止。 本发明可用于催化，有机合成，聚合物化学和工业化学领域。
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公开(公告)号：US20110294971A1
公开(公告)日：2011-12-01
申请号：US13060058
申请日：2009-08-21
IPC分类号： C08F216/04 , C08F232/06 , C08F232/04 , C08F4/80 , C08F222/20 , C08F220/68 , C08F216/10
CPC分类号： C08G61/08 , C08G2261/3322 , C08G2261/418
摘要： Olefin metathesis polymerization reactions are disclosed, and more particularly ring-opening metathesis polymerization of cyclic olefins with olefinic compounds, such as are derived from seed oils and the like, to form telechelic polymers. In one aspect, a method is provided for carrying out a catalytic ring-opening metathesis polymerization reaction, comprising contacting at least one olefinic compound with at least one cyclic olefin, in the presence of a ruthenium alkylidene olefin metathesis catalyst under conditions effective to allow ring-opening metathesis polymerization of the cyclic olefin, whereby the cyclic olefin polymer formed is terminated with the olefinic compound. The invention has utility in the fields of catalysis, organic synthesis, polymer chemistry, and industrial chemistry.
摘要翻译： 公开了烯烃易位聚合反应，更具体地说，环烯烃与烯烃化合物如来自种子油等的开环易位聚合反应形成遥爪聚合物。 在一个方面，提供了一种用于进行催化开环易位聚合反应的方法，包括在钌亚烷基烯烃复分解催化剂存在下使至少一种烯烃化合物与至少一种环烯烃接触，所述条件有效地允许环 开环环烯烃的易位聚合，由此所形成的环烯烃聚合物用烯烃化合物终止。 本发明可用于催化，有机合成，聚合物化学和工业化学领域。
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公开(公告)号：US10457597B2
公开(公告)日：2019-10-29
申请号：US14125837
申请日：2012-06-17
申请人： Li-Sheng Wang , Anthony R. Stephen , Paul W. Boothe , Tessa Schulze , Michael A. Giardello , Mark S. Trimmer , Christopher J. Cruce , Farshad J. Motamedi , Brian Edgecombe
发明人： Li-Sheng Wang , Anthony R. Stephen , Paul W. Boothe , Tessa Schulze , Michael A. Giardello , Mark S. Trimmer , Christopher J. Cruce , Farshad J. Motamedi , Brian Edgecombe
摘要： This invention relates to compositions and methods for improving the adhesion of resin compositions to substrate materials, pre-treating substrate materials to improve the adhesion of resin compositions to the substrate materials, and/or controlling gel formation of resin compositions. More particularly, the invention relates to compositions and methods for improving the adhesion of ring opening metathesis polymerization (ROMP) compositions to substrate materials using adhesion promoters containing isocyariate groups in a resin composition. The invention also relates to methods for improving the adhesion of resin compositions to substrate materials by pre-treating substrate materials with adhesion promoters containing isocyanate groups. The invention further relates to a method of providing a gel-modified ROMP composition, in which a hydroperoxide is added to a ROMP polymerizable resin composition in order to control gel formation of the polymerizing resin. An improved ROMP composition is further disclosed, comprising a cyclic olefin, a ROMP metathesis catalyst, an adhesion promoter, and an added hydroperoxide gel modifier. The polymer products produced via ROMP reactions of the invention may be utilized for a wide range of materials and composite applications. The invention has utility in the fields of catalysis, organic synthesis, and polymer and materials chemistry and manufacture.
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4.发明申请公开(公告)号：US20140329017A1
公开(公告)日：2014-11-06
申请号：US14125837
申请日：2012-06-17
申请人： Li-Sheng Wang , Anthony R. Stephen , Paul W. Booth , Tessa Schulze , Michael A. Giardello , Mark S. Trimmer , Christopher J. Cruce , Farshad J. Motamedi , Brian Edgecombe
发明人： Li-Sheng Wang , Anthony R. Stephen , Paul W. Booth , Tessa Schulze , Michael A. Giardello , Mark S. Trimmer , Christopher J. Cruce , Farshad J. Motamedi , Brian Edgecombe
IPC分类号： C03C25/30
CPC分类号： C03C25/30 , C08F32/02 , C08G61/08 , C08G2261/3325 , C08G2261/418 , C08K5/0025 , C08K5/14 , C08K5/29 , C08K2201/014 , C08L65/00
摘要： This invention relates to compositions and methods for improving the adhesion of resin compositions to substrate materials, pre-treating substrate materials to improve the adhesion of resin compositions to the substrate materials, and/or controlling gel formation of resin compositions. More particularly, the invention relates to compositions and methods for improving the adhesion of ring opening metathesis polymerization (ROMP) compositions to substrate materials using adhesion promoters containing isocyariate groups in a resin composition. The invention also relates to methods for improving the adhesion of resin compositions to substrate materials by pre-treating substrate materials with adhesion promoters containing isocyanate groups. The invention further relates to a method of providing a gel-modified ROMP composition, in which a hydroperoxide is added to a ROMP polymerizable resin composition in order to control gel formation of the polymerizing resin. An improved ROMP composition is further disclosed, comprising a cyclic olefin, a ROMP metathesis catalyst, an adhesion promoter, and an added hydroperoxide gel modifier. The polymer products produced via ROMP reactions of the invention may be utilized for a wide range of materials and composite applications. The invention has utility in the fields of catalysis, organic synthesis, and polymer and materials chemistry and manufacture.
摘要翻译： 本发明涉及用于改善树脂组合物与基材的粘合性，预处理基材以改善树脂组合物与基材的粘合性和/或控制树脂组合物凝胶形成的组合物和方法。 更具体地，本发明涉及使用在树脂组合物中含有异质基团的粘合促进剂来改善开环易位聚合（ROMP）组合物与基材的粘合性的组合物和方法。 本发明还涉及通过用含有异氰酸酯基团的粘合促进剂预处理底物材料来改善树脂组合物对基材的粘附性的方法。 本发明还涉及一种提供凝胶改性的ROMP组合物的方法，其中将氢过氧化物加入到ROMP可聚合树脂组合物中以控制聚合树脂的凝胶形成。 进一步公开了改进的ROMP组合物，其包含环烯烃，ROMP复分解催化剂，粘合促进剂和加入的氢过氧化物凝胶改性剂。 通过本发明的ROMP反应生产的聚合物产品可用于广泛的材料和复合材料应用。 本发明可用于催化，有机合成，聚合物和材料的化学和制造领域。
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5.发明申请MICROFLUIDIC RADIOSYNTHESIS OF A RADIOLABELED COMPOUND USING ELECTROCHEMICAL TRAPPING AND RELEASE 审中-公开使用电化学捕获和释放的无定形化合物的微流体放射线公开(公告)号：US20090095635A1
公开(公告)日：2009-04-16
申请号：US12176296
申请日：2008-07-18
申请人： Arkadij M. Elizarov , Hartmuth C. Kolb , R. Michael van Dam , James R. Heath , Brian Edgecombe , Farshad Motamedi , Anthony Stephen , Michael A. Giardello
发明人： Arkadij M. Elizarov , Hartmuth C. Kolb , R. Michael van Dam , James R. Heath , Brian Edgecombe , Farshad Motamedi , Anthony Stephen , Michael A. Giardello
IPC分类号： C25B3/08
CPC分类号： C07B59/00
摘要： Methods and apparatus enable radiosynthesis of radiolabeled compounds using electrochemical trapping and release. The trapping and release of radioactive isotopes all occur inside a microreactor, a vial or similar device, thus eliminating the need for azeotropic drying and several dead-end filling steps, as well as the necessity to move concentrated radioisotopes from one compartment of the chip to another. These and other features allow radioisotope enrichment to be carried out internally within a radiochemical synthesis chip, providing faster and more robust operation, as well as producing very high radiochemical labeling yields.
摘要翻译： 方法和装置能够使用电化学捕获和释放来放射性标记化合物的放射合成。 放射性同位素的捕获和释放都发生在微反应器，小瓶或类似装置内，因此不需要共沸干燥和几个死端填充步骤，以及将浓缩放射性同位素从芯片的一个室移动到 另一个。 这些和其他特征允许放射性同位素富集在放射化学合成芯片内部进行，提供更快和更强的操作，以及产生非常高的放射化学标记产率。
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6.发明申请METATHESIS-ACTIVE ADHESION AGENTS AND METHODS FOR ENHANCING POLYMER ADHESION TO SURFACES 有权METATHESIS-ACTIVE粘合剂和增强聚合物粘附于表面的方法公开(公告)号：US20090048405A1
公开(公告)日：2009-02-19
申请号：US12042236
申请日：2008-03-04
IPC分类号： C08F255/00
CPC分类号： C09J4/00 , C08F263/04 , C08G61/08 , C08L2666/02 , C09J151/003 , C09J151/06 , C09J151/10 , Y10T428/31536 , Y10T428/31855
摘要： The invention discloses an adhesion agent composition comprising at least one C3-C200 olefin compound having at least one metathesis active double bond, wherein the olefin is substituted or unsubstituted; and at least one compatibilizing functionality for interacting with a substrate surface. The substrate surface can be any surface, for example, silicate glasses, silicate minerals, metals, metal alloys, ceramics, natural stones, plastics, carbon, silicon, and semiconductors. The invention also discloses articles of manufacture utilizing these adhesion agents as well as methods for adhering a polyolefin to a substrate surface.
摘要翻译： 本发明公开了一种粘合剂组合物，其包含至少一种具有至少一个复分解活性双键的C 3 -C 20烯烃化合物，其中所述烯烃是取代或未取代的; 以及用于与衬底表面相互作用的至少一种相容性功能。 衬底表面可以是任何表面，例如硅酸盐玻璃，硅酸盐矿物，金属，金属合金，陶瓷，天然石，塑料，碳，硅和半导体。 本发明还公开了利用这些粘合剂的制品以及将聚烯烃粘附到基材表面的方法。
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7.发明授权Metathesis-active adhesion agents and methods for enhancing polymer adhesion to surfaces 有权复分解活性粘合剂和增强聚合物与表面粘附的方法公开(公告)号：US06409875B1
公开(公告)日：2002-06-25
申请号：US09497741
申请日：2000-02-04
IPC分类号： C09J400
CPC分类号： C09J4/00 , C08F263/04 , C08G61/08 , C08L2666/02 , C09J151/003 , C09J151/06 , C09J151/10 , Y10T428/31536 , Y10T428/31855
摘要： The invention discloses an adhesion agent composition comprising at least one C3-C200 olefin compound having at least one metathesis active double bond, wherein the olefin is substituted or unsubstituted; and at least one compatibilizing functionality for interacting with a substrate surface. The substrate surface can be any surface, for example, silicate glasses, silicate minerals, metals, metal alloys, ceramics, natural stones, plastics, carbon, silicon, and semiconductors. The invention also discloses articles of manufacture utilizing these adhesion agents as well as methods for adhering a polyolefin to a substrate surface.
摘要翻译： 本发明公开了一种粘合剂组合物，其包含至少一种具有至少一个复分解活性双键的C 3 -C 20烯烃化合物，其中所述烯烃是取代或未取代的; 以及用于与衬底表面相互作用的至少一种相容性功能。 衬底表面可以是任何表面，例如硅酸盐玻璃，硅酸盐矿物，金属，金属合金，陶瓷，天然石，塑料，碳，硅和半导体。 本发明还公开了利用这些粘合剂的制品以及将聚烯烃粘附到基材表面的方法。
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8.发明授权Metathesis polymerized olefin composites including sized reinforcement material 有权复分解聚合烯烃复合材料，包括尺寸增强材料公开(公告)号：US06323296B1
公开(公告)日：2001-11-27
申请号：US09514481
申请日：2000-02-28
IPC分类号： C08F480
摘要： A reinforced polyolefin article is provided which includes a sized reinforcement material incorporated in the article. The article may be prepared by polymerizing a cyclic olefin monomer in the presence of the sizing agent and a metathesis polymerization catalyst which includes ruthenium or osmium.
摘要翻译： 提供了一种增强聚烯烃制品，其包括结合在制品中的尺寸增强材料。 该制品可以通过在施胶剂和包含钌或锇的易位聚合催化剂存在下聚合环烯烃单体来制备。
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9.发明申请ELECTROLYTIC CELL COVERS COMPRISING A RESIN COMPOSITION POLYMERIZED WITH A GROUP 8 OLEFIN METATHESIS CATALYST 审中-公开含有8个烯烃METATHESIS催化剂聚合的树脂组合物的电解槽公开(公告)号：US20150165652A1
公开(公告)日：2015-06-18
申请号：US14343513
申请日：2012-09-14
申请人： Michael A. Giardello , Mark S. Trimmer , Christopher J. Cruce , Anthony R. Stephen , Stuart A. M. Toner , Albert E. Pappano
发明人： Michael A. Giardello , Mark S. Trimmer , Christopher J. Cruce , Anthony R. Stephen , Stuart A. M. Toner , Albert E. Pappano
CPC分类号： C25B9/00 , B29C39/003 , B29C67/246 , B29K2023/00 , B29K2023/38 , B29K2105/0014 , B29K2995/0029 , B29L2031/7146 , C08G61/02 , C08G2120/00 , C08G2261/3325 , C08G2261/418 , C08G2261/58 , C25B1/34
摘要： Articles of manufacture possessing corrosion resistance characteristics are described, in particular for use in the chlor-alkali and other industries. The articles are formed from a resin composition, e.g., a cyclic olefin composition, polymerized with a Group 8 olefin metathesis catalyst. In particular aspects, an electrolytic cell component, such as a cell cover for use in the electrolysis of brine, may be formed from the resin composition. Among other benefits, such articles provide improved corrosion resistance compared to articles molded from other resin compositions, such as Fiberglass reinforced polyesters and vinyl esters, and two-component dicyclopentadiene (DCPD) resins comprising molybdenum or tungsten pre-catalysts.
摘要翻译： 描述了具有耐腐蚀特性的制品，特别是用于氯碱等行业。 制品由用8族烯烃复分解催化剂聚合的树脂组合物形成，例如环烯烃组合物。 在特定方面，可以由树脂组合物形成用于电解盐水的电解池组件，例如电池盖。 除了其它益处之外，与由其它树脂组合物（例如玻璃纤维增强聚酯和乙烯基酯）和包含钼或钨预催化剂的双组分二环戊二烯（DCPD）树脂模制的制品相比，这些制品提供了改进的耐腐蚀性。
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10.发明授权公开(公告)号：US08597794B2
公开(公告)日：2013-12-03
申请号：US13165515
申请日：2011-06-21
IPC分类号： B32B27/00
CPC分类号： C09J4/00 , C08F263/04 , C08G61/08 , C08L2666/02 , C09J151/003 , C09J151/06 , C09J151/10 , Y10T428/31536 , Y10T428/31855
摘要： The invention discloses an adhesion agent composition comprising at least one C3-C200 olefin compound having at least one metathesis active double bond, wherein the olefin is substituted or unsubstituted; and at least one compatibilizing functionality for interacting with a substrate surface. The substrate surface can be any surface, for example, silicate glasses, silicate minerals, metals, metal alloys, ceramics, natural stones, plastics, carbon, silicon, and semiconductors. The invention also discloses articles of manufacture utilizing these adhesion agents as well as methods for adhering a polyolefin to a substrate surface.
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