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1.发明授权Low metal, low water biomass-derived pyrolysis oils and methods for producing the same 有权低金属，低水生物质衍生的裂解油及其制备方法公开(公告)号：US08524087B2
公开(公告)日：2013-09-03
申请号：US12646288
申请日：2009-12-23
申请人： Stanley J. Frey , Richard Marinangeli , Timothy A. Brandvold , Mark Koch , Vasken Abrahamian , Jeffrey A. Noga , Thomas Traynor
发明人： Stanley J. Frey , Richard Marinangeli , Timothy A. Brandvold , Mark Koch , Vasken Abrahamian , Jeffrey A. Noga , Thomas Traynor
摘要： Low metal, low water biomass-derived pyrolysis oils and methods for producing the same are provided. Metal- and water-containing biomass-derived pyrolysis oil is contacted with an acidic ion-exchange resin having sulfonic acid groups to produce a low metal, water-containing biomass-derived pyrolysis oil. The low metal, water-containing biomass-derived pyrolysis oil is removed from the spent ion-exchange resin after ion-exchange. The low metal, water-containing biomass-derived pyrolysis oil is distilled to produce a low metal, low water biomass-derived pyrolysis oil and a distillation product. The distillation product comprises one or both of an alcohol ion-exchange regenerant and an acidic ion-exchange regenerant which may be used to regenerate the spent ion-exchange resin. The regenerated acidic ion-exchange resin may be recycled. The spent alcohol and acid ion-exchange regenerants may be recovered and recycled.
摘要翻译： 提供了低金属，低水生物质的热解油及其制备方法。 含金属和含水生物质的热解油与具有磺酸基团的酸性离子交换树脂接触以产生低含金属的含水生物质衍生的热解油。 离子交换后从废离子交换树脂中除去低金属含水生物质的热解油。 蒸馏低金属含水生物质的热解油，生成低金属，低水生物质的热解油和蒸馏产物。 蒸馏产物包括醇离子交换再生剂和酸性离子交换再生剂中的一种或两种，其可用于再生废离子交换树脂。 再生的酸性离子交换树脂可以再循环。 废乙醇和酸离子交换再生剂可以回收和再循环。
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2.发明申请LOW METAL, LOW WATER BIOMASS-DERIVED PYROLYSIS OILS AND METHODS FOR PRODUCING THE SAME 有权低金属，低水生物质衍生的热解油及其生产方法公开(公告)号：US20110146141A1
公开(公告)日：2011-06-23
申请号：US12646288
申请日：2009-12-23
申请人： Stanley J. Frey , Richard Marinangeli , Timothy A. Brandvold , Mark Koch , Vasken Abrahamian , Jeffrey M. Noga , Thomas Traynor
发明人： Stanley J. Frey , Richard Marinangeli , Timothy A. Brandvold , Mark Koch , Vasken Abrahamian , Jeffrey M. Noga , Thomas Traynor
IPC分类号： C10L1/18
摘要： Low metal, low water biomass-derived pyrolysis oils and methods for producing the same are provided. Metal- and water-containing biomass-derived pyrolysis oil is contacted with an acidic ion-exchange resin having sulfonic acid groups to produce a low metal, water-containing biomass-derived pyrolysis oil. The low metal, water-containing biomass-derived pyrolysis oil is removed from the spent ion-exchange resin after ion-exchange. The low metal, water-containing biomass-derived pyrolysis oil is distilled to produce a low metal, low water biomass-derived pyrolysis oil and a distillation product. The distillation product comprises one or both of an alcohol ion-exchange regenerant and an acidic ion-exchange regenerant which may be used to regenerate the spent ion-exchange resin. The regenerated acidic ion-exchange resin may be recycled. The spent alcohol and acid ion-exchange regenerants may be recovered and recycled.
摘要翻译： 提供了低金属，低水生物质的热解油及其制备方法。 含金属和含水生物质的热解油与具有磺酸基团的酸性离子交换树脂接触以产生低含金属的含水生物质衍生的热解油。 离子交换后从废离子交换树脂中除去低金属含水生物质的热解油。 蒸馏低金属含水生物质的热解油，生成低金属，低水生物质的热解油和蒸馏产物。 蒸馏产物包括醇离子交换再生剂和酸性离子交换再生剂中的一种或两种，其可用于再生废离子交换树脂。 再生的酸性离子交换树脂可以再循环。 废乙醇和酸离子交换再生剂可以回收和再循环。
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3.发明申请公开(公告)号：US20110146145A1
公开(公告)日：2011-06-23
申请号：US12646327
申请日：2009-12-23
IPC分类号： C10L1/12
CPC分类号： B01J49/0069 , B01D15/20 , B01D15/203 , B01D15/362 , B01J49/06 , B01J49/53 , C10G2300/1011 , C10L1/02 , G01N30/50 , G01N30/96 , Y02P30/20
摘要： Methods for regenerating acidic ion-exchange resins and reusing regenerants in such methods are provided. A spent ion-exchange resin is contacted with an alcohol ion-exchange regenerant. The spent ion-exchange resin is thereafter contacted with an acidic ion-exchange regenerant to recharge the acidic ion-exchange resin to produce a regenerated acidic ion-exchange resin. Metal- and water-containing biomass-derived pyrolysis oil is then contacted with the regenerated acidic ion-exchange resin to produce low metal, water-containing biomass-derived pyrolysis oil. The regenerated acidic ion-exchange resin may be recycled. The spent alcohol and acid ion-exchange regenerants may be recovered and recycled.
摘要翻译： 提供了在这种方法中再生酸性离子交换树脂和再利用再生剂的方法。 将废弃的离子交换树脂与醇离子交换再生剂接触。 然后将废弃的离子交换树脂与酸性离子交换再生剂接触以对酸性离子交换树脂再充电以产生再生的酸性离子交换树脂。 然后将含金属和含水的生物质衍生的热解油与再生的酸性离子交换树脂接触以产生低金属，含水生物质的热解油。 再生的酸性离子交换树脂可以再循环。 废乙醇和酸离子交换再生剂可以回收和再循环。
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4.发明授权Methods for regenerating acidic ion-exchange resins and reusing regenerants in such methods 有权在这种方法中再生酸性离子交换树脂和再利用再生剂的方法公开(公告)号：US08864999B2
公开(公告)日：2014-10-21
申请号：US12646327
申请日：2009-12-23
CPC分类号： B01J49/0069 , B01D15/20 , B01D15/203 , B01D15/362 , B01J49/06 , B01J49/53 , C10G2300/1011 , C10L1/02 , G01N30/50 , G01N30/96 , Y02P30/20
摘要： Methods for regenerating acidic ion-exchange resins and reusing regenerants in such methods are provided. A spent ion-exchange resin is contacted with an alcohol ion-exchange regenerant. The spent ion-exchange resin is thereafter contacted with an acidic ion-exchange regenerant to recharge the acidic ion-exchange resin to produce a regenerated acidic ion-exchange resin. Metal- and water-containing biomass-derived pyrolysis oil is then contacted with the regenerated acidic ion-exchange resin to produce low metal, water-containing biomass-derived pyrolysis oil. The regenerated acidic ion-exchange resin may be recycled. The spent alcohol and acid ion-exchange regenerants may be recovered and recycled.
摘要翻译： 提供了在这种方法中再生酸性离子交换树脂和再利用再生剂的方法。 将废弃的离子交换树脂与醇离子交换再生剂接触。 然后将废弃的离子交换树脂与酸性离子交换再生剂接触以对酸性离子交换树脂再充电以产生再生的酸性离子交换树脂。 然后将含金属和含水的生物质衍生的热解油与再生的酸性离子交换树脂接触以产生低金属，含水生物质的热解油。 再生的酸性离子交换树脂可以再循环。 废乙醇和酸离子交换再生剂可以回收和再循环。
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5.发明授权公开(公告)号：US08519203B2
公开(公告)日：2013-08-27
申请号：US12707433
申请日：2010-02-17
IPC分类号： C01C1/00
摘要： Low oxygen biomass-derived pyrolysis oils and methods for producing them from carbonaceous biomass feedstock are provided. The carbonaceous biomass feedstock is pyrolyzed in the presence of a catalyst comprising base metal-based catalysts, noble metal-based catalysts, treated zeolitic catalysts, or combinations thereof to produce pyrolysis gases. During pyrolysis, the catalyst catalyzes a deoxygenation reaction whereby at least a portion of the oxygenated hydrocarbons in the pyrolysis gases are converted into hydrocarbons. The oxygen is removed as carbon oxides and water. A condensable portion (the vapors) of the pyrolysis gases is condensed to low oxygen biomass-derived pyrolysis oil.
摘要翻译： 提供了低氧生物质衍生的热解油及其从碳质生物质原料生产它们的方法。 在含有贱金属基催化剂，贵金属基催化剂，经处理的沸石催化剂或其组合的催化剂存在下，碳质生物质原料热解产生裂解气。 在热解期间，催化剂催化脱氧反应，由此将热解气体中的至少一部分氧化烃转化成烃。 作为碳氧化物和水除去氧气。 热解气体的可冷凝部分（蒸汽）被冷凝成低氧生物质衍生的裂解油。
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6.发明申请LOW WATER BIOMASS-DERIVED PYROLYSIS OIL AND PROCESSES FOR PREPARING THE SAME 审中-公开低水生物质衍生的热解油及其制备方法公开(公告)号：US20110146140A1
公开(公告)日：2011-06-23
申请号：US12646203
申请日：2009-12-23
IPC分类号： C10L1/18
摘要： Low water-containing biomass-derived pyrolysis oils and processes for preparing them are provided. Water-containing biomass-derived pyrolysis oil is distilled in the presence of an azeotrope-forming liquid to form an azeotrope. The azeotrope is removed at or above the boiling point of the azeotrope and low water biomass-derived pyrolysis oil is obtained.
摘要翻译： 提供了低含水生物质衍生的热解油及其制备方法。 在形成共沸物质的液体存在下蒸馏含水生物质的热解油，形成共沸物。 在共沸物的沸点以上沸腾除去共沸物，得到低水生物质衍生的热解油。
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7.发明申请公开(公告)号：US20110201855A1
公开(公告)日：2011-08-18
申请号：US12707433
申请日：2010-02-17
IPC分类号： C10G1/00
摘要： Low oxygen biomass-derived pyrolysis oils and methods for producing them from carbonaceous biomass feedstock are provided. The carbonaceous biomass feedstock is pyrolyzed in the presence of a catalyst comprising base metal-based catalysts, noble metal-based catalysts, treated zeolitic catalysts, or combinations thereof to produce pyrolysis gases. During pyrolysis, the catalyst catalyzes a deoxygenation reaction whereby at least a portion of the oxygenated hydrocarbons in the pyrolysis gases are converted into hydrocarbons. The oxygen is removed as carbon oxides and water. A condensable portion (the vapors) of the pyrolysis gases is condensed to low oxygen biomass-derived pyrolysis oil.
摘要翻译： 提供了低氧生物质衍生的热解油及其从碳质生物质原料生产它们的方法。 在含有贱金属基催化剂，贵金属基催化剂，经处理的沸石催化剂或其组合的催化剂存在下，碳质生物质原料热解产生裂解气。 在热解期间，催化剂催化脱氧反应，由此将热解气体中的至少一部分氧化烃转化成烃。 作为碳氧化物和水除去氧气。 热解气体的可冷凝部分（蒸汽）被冷凝成低氧生物质衍生的裂解油。
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公开(公告)号：US20150175896A1
公开(公告)日：2015-06-25
申请号：US14632585
申请日：2015-02-26
IPC分类号： C10G3/00
CPC分类号： C10G3/48 , B01J21/063 , B01J21/066 , B01J23/44 , B01J23/462 , B01J23/464 , B01J23/52 , B01J23/6484 , B01J23/682 , B01J23/882 , B01J23/883 , B01J23/8877 , B01J23/888 , B01J37/20 , C10G3/50 , C10L1/02 , C10L1/04 , Y02P30/20
摘要： Methods for deoxygenating treated biomass-derived pyrolysis oil are provided. The treated biomass-derived pyrolysis oil is exposed to a catalyst having a neutral catalyst support such as a non-alumina metal oxide support, a theta alumina support, or both. The non-alumina metal oxide support may be a titanium oxide (TiO2) support, a silicon oxide support, a zirconia oxide (ZrO2) support, a niobium oxide (Nb2O5) support, or a support having a mixture of non-alumina metal oxides. The catalyst may include a noble metal or a Group VIII non-noble metal and a Group VIB non-noble metal on the neutral catalyst support. The treated biomass-derived pyrolysis oil is introduced into a hydroprocessing reactor in the presence of the catalyst under hydroprocessing conditions to produce low oxygen biomass-derived pyrolysis oil.
摘要翻译： 提供了处理过的生物质衍生的热解油的脱氧方法。 将经处理的生物质衍生的热解油暴露于具有中性催化剂载体的催化剂，例如非氧化铝金属氧化物载体，θ氧化铝载体或两者。 非氧化铝金属氧化物载体可以是氧化钛（TiO 2）载体，氧化硅载体，氧化锆（ZrO 2）载体，氧化铌（Nb 2 O 5）载体或具有非氧化铝金属氧化物的混合物的载体 。 催化剂可以在中性催化剂载体上包括贵金属或VIII族非贵金属和VIB族非贵金属。 经处理的生物质衍生的热解油在加氢处理条件下在催化剂存在下引入加氢处理反应器，以产生低氧生物质衍生的裂解油。
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9.发明申请公开(公告)号：US20150166901A1
公开(公告)日：2015-06-18
申请号：US14628178
申请日：2015-02-20
CPC分类号： C10G3/50 , B01J23/883 , B01J23/8877 , B01J2523/00 , C10G3/46 , C10G65/04 , C10G2300/1011 , C10L1/02 , C10L2200/0469 , C10L2290/08 , C10L2290/10 , Y02P30/20 , B01J2523/47 , B01J2523/68 , B01J2523/845 , B01J2523/847 , B01J2523/48 , B01J2523/56 , B01J2523/31
摘要： Embodiments of methods and catalysts for deoxygenating a biomass-derived pyrolysis oil are provided. The method comprises the step of contacting the biomass-derived pyrolysis oil with a first deoxygenating catalyst in the presence of hydrogen at first predetermined hydroprocessing conditions to form a first low-oxygen biomass-derived pyrolysis oil effluent. The first deoxygenating catalyst comprises a neutral catalyst support, nickel, cobalt, and molybdenum. The first deoxygenating catalyst comprises nickel in an amount calculated as an oxide of from about 0.1 to about 1.5 wt. %.
摘要翻译： 提供了用于脱氧生物质衍生的热解油的方法和催化剂的实施方案。 该方法包括在第一预定加氢处理条件下，在氢存在下使生物质衍生的热解油与第一脱氧催化剂接触的步骤，以形成第一低氧生物质衍生的热解油流出物。 第一脱氧催化剂包括中性催化剂载体，镍，钴和钼。 第一脱氧催化剂包括以约0.1至约1.5重量％的氧化物计算的量的镍。 ％。
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10.发明申请公开(公告)号：US20120305836A1
公开(公告)日：2012-12-06
申请号：US13150844
申请日：2011-06-01
IPC分类号： B01J23/889 , C09K3/00
CPC分类号： B01J23/883 , C10G3/46 , C10G65/04 , C10G2300/1011 , Y02P30/20
摘要： Embodiments of methods and catalysts for deoxygenating a biomass-derived pyrolysis oil are provided. The method comprises the step of contacting the biomass-derived pyrolysis oil with a first deoxygenating catalyst in the presence of hydrogen at first predetermined hydroprocessing conditions to form a first low-oxygen biomass-derived pyrolysis oil effluent. The first deoxygenating catalyst comprises a neutral catalyst support, nickel, cobalt, and molybdenum. The first deoxygenating catalyst comprises nickel in an amount calculated as an oxide of from about 0.1 to about 1.5 wt. %.
摘要翻译： 提供了用于脱氧生物质衍生的热解油的方法和催化剂的实施方案。 该方法包括在第一预定加氢处理条件下，在氢存在下使生物质衍生的热解油与第一脱氧催化剂接触的步骤，以形成第一低氧生物质衍生的热解油流出物。 第一脱氧催化剂包括中性催化剂载体，镍，钴和钼。 第一脱氧催化剂包括以约0.1至约1.5重量％的氧化物计算的量的镍。 ％。
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