公开(公告)号：US5851372A

公开(公告)日：1998-12-22

申请号：US732216

申请日：1996-10-24

申请人： Roland Noel

发明人： Roland Noel

IPC分类号： A23C9/144 ,  A23C9/146 ,  B01D61/42 ,  B01D61/58 ,  B01J39/04 ,  B01J49/00 ,  C02F1/42 ,  C02F1/469 ,  B01D61/44

CPC分类号： C02F1/4693 ,  A23C9/144 ,  A23C9/146 ,  B01J39/043 ,  B01J49/0069 ,  C02F1/42 ,  C02F2201/46115

摘要： A process of demineralizing a liquid containing organic matter and inorganic salts in solution, in which the treatment of the liquid comprises the following steps: the liquid is percolated over a strong cationic ion exchange resin for monovalent ions; both a batch of liquid from the preceding step and a brine for receiving ions from that liquid are caused to circulate in loops through at least one "two-compartment" electrodialyzer comprising a plurality of anionic membranes interposed between a plurality of cationic membranes; and the brine whose salt concentration lies in the range 90 grams per liter (g/l) to 110 g/l is used to regenerate the ion exchange resin.

摘要翻译： PCT No.PCT / FR95 / 00595 Sec。 371日期：1996年10月24日 102（e）日期1996年10月24日PCT提交1995年5月9日PCT公布。 WO95 / 30482 PCT出版物 日期：1995年11月16日一种将含有机物的液体和溶液中的无机盐脱矿质的方法，其中处理液体包括以下步骤：将液体渗透在强阳离子交换树脂上用于一价离子; 使来自前述步骤的一批液体和用于从该液体接收离子的盐水通过至少一个“两室”电渗析器循环循环，所述“双室”电渗析器包括插入在多个阳离子膜之间的多个阴离子膜; 并且使用盐浓度在90克/升（g / l）至110g / l范围内的盐水来再生离子交换树脂。

公开(公告)号：US4666776A

公开(公告)日：1987-05-19

申请号：US786263

申请日：1985-10-10

申请人： Peter M. Lange ,  Erich Rauenbusch

发明人： Peter M. Lange ,  Erich Rauenbusch

IPC分类号： C08F8/00 ,  B01J20/281 ,  B01J20/285 ,  B01J39/16 ,  B01J39/18 ,  B01J39/20 ,  B01J49/06 ,  B01J49/53 ,  C07H1/06 ,  C07H5/06 ,  C07H15/203 ,  C08F8/36 ,  G01N30/88 ,  B32B5/16

CPC分类号： C07H15/203 ,  B01J39/20 ,  B01J39/26 ,  B01J49/0008 ,  B01J49/0069 ,  C08F8/36 ,  C08F2800/20 ,  Y10T428/2982

摘要： In the purification of acarbose by contacting an acarbose-containing solution with a cation exchanger to adsorb the acarbose, eluting the ion exchanger and collecting an eluate fraction enriched in purified acarbose, the improvement wherein the cation exchanger is a polymer obtained by polymerizing an aromatic compound possessing at least one vinyl group and at least one hydrophilic monomer in the presence of a solvent for the monomer which is a precipitant for the crosslinked polymer formed, isolating the resistant polymer, and sulphonating the polymer in the presence of a swelling agent for the polymer. The invention gives shapr separation and other processing advantages.

摘要翻译： 在通过使含有阿卡波糖的溶液与阳离子交换剂接触以吸附阿卡波糖以洗脱离子交换剂并收集富集纯化的阿卡波糖的洗脱液级分的阿卡波糖的纯化中，其中阳离子交换剂是通过使芳族化合物聚合而获得的聚合物 在用于形成的交联聚合物的沉淀剂的溶剂的溶剂存在下，具有至少一个乙烯基和至少一个亲水性单体，分离耐药聚合物，并在聚合物溶胀剂存在下磺化聚合物 。 本发明提供了切割分离等加工优点。

公开(公告)号：US4083782A

公开(公告)日：1978-04-11

申请号：US520322

申请日：1974-11-04

申请人： Robert Kunin

发明人： Robert Kunin

IPC分类号： B01J39/04 ,  B01J47/14 ,  B01J49/00 ,  C02B1/76

CPC分类号： B01J47/145 ,  B01J39/04 ,  B01J49/0069

摘要： Water is conditioned by contacting it with a weak acid cation exchange resin based upon a crosslinked methacrylic acid copolymer structure in the alkali metal (or ammonium) form. The resin when exhausted may be regenerated by either a two-step acid/alkali technique or by a one-step technique using a citric or fumaric acid solution or a poly or hexamethaphosphate solution. Water by this method is substantially free of hardness ion, dissolved heavy metal ions and has a corrected pH between 7 and 9.5, preferably between 8 and 8.5.

摘要翻译： 基于碱金属（或铵）形式的交联的甲基丙烯酸共聚物结构使其与弱酸性阳离子交换树脂接触来调节水分。 当排出的树脂可以通过两步酸/碱技术或通过使用柠檬酸或富马酸溶液或聚六氢磷酸盐溶液的一步技术再生。 通过该方法的水基本上不含硬度离子，溶解的重金属离子，并且校正pH在7和9.5之间，优选在8和8.5之间。

公开(公告)号：US4493907A

公开(公告)日：1985-01-15

申请号：US478167

申请日：1983-03-23

申请人： Harold N. Hedrick ,  Solon G. Whitney

发明人： Harold N. Hedrick ,  Solon G. Whitney

IPC分类号： B01J49/00 ,  C01F5/40

CPC分类号： C01F5/40 ,  B01J49/003 ,  B01J49/0069 ,  C22B3/42 ,  Y02P10/234

摘要： This invention relates to the regeneration of cation exchanger resin containing adsorbed magnesium ions, and the recovery of the magnesium as a crystalline precipitate. The regeneration uses moderate to high concentration aqueous H.sub.2 SO.sub.4, and the recovered precipitate comprises one or more co-crystallization compounds of MgSO.sub.4 and H.sub.2 SO.sub.4.

摘要翻译： 本发明涉及含有吸附的镁离子的阳离子交换树脂的再生以及作为结晶沉淀物的镁的回收。 再生使用中等至高浓度的H 2 SO 4水溶液，回收的沉淀物包含一种或多种MgSO 4和H 2 SO 4的共结晶化合物。

公开(公告)号：US4363880A

公开(公告)日：1982-12-14

申请号：US275648

申请日：1981-06-22

申请人： Solon G. Whitney ,  William R. Erickson

发明人： Solon G. Whitney ,  William R. Erickson

IPC分类号： B01D15/08 ,  B01D15/04 ,  B01J49/00 ,  C01B25/238 ,  C01F5/40 ,  C01F11/46

CPC分类号： C01F11/46 ,  B01J49/003 ,  B01J49/0069 ,  C01F5/40 ,  C22B3/24 ,  C22B3/42 ,  Y02P10/234

摘要： Adsorbed calcium is selectively removed from cation exchange resins in the presence of adsorbed magnesium by eluting the resin with aqueous sulfuric acid saturated with CaSO.sub.4 and undersaturated with MgSO.sub.4 to obtain a solution supersaturated with CaSO.sub.4 from which the CaSO.sub.4 can be readily precipitated. The magnesium is subsequently removed from the resin by eluting with aqueous sulfuric acid, such as 20-70% H.sub.2 SO.sub.4. The method is advantageously used in the regeneration of cation exchange resins, such as the loaded resins used for treatment of phosphate rock-derived phosphoric acid.

摘要翻译： 在吸附的镁的存在下，从阳离子交换树脂中选择性地除去吸附的钙，通过用CaSO 4饱和的硫酸水溶液洗脱树脂并用MgSO 4饱和，得到用CaSO 4过饱和的溶液，其中CaSO 4可容易地沉淀。 随后用硫酸水溶液（如20-70％H 2 SO 4）洗脱，从树脂中除去镁。 该方法有利地用于阳离子交换树脂的再生，例如用于处理磷酸盐岩衍生的磷酸的负载树脂。

公开(公告)号：US4298477A

公开(公告)日：1981-11-03

申请号：US204596

申请日：1980-11-06

申请人： Jack L. Cole

发明人： Jack L. Cole

IPC分类号： B01J49/00 ,  C02F1/42

CPC分类号： B01J49/0069

摘要： High-pressure boiler feedwater is polished and softened with a cation ion-exchange resin, and the resin is regenerated with a readily ionizable salt of an amine-type corrosion inhibitor.

摘要翻译： 高压锅炉给水用阳离子交换树脂进行抛光和软化，树脂用胺类腐蚀抑制剂的容易电离的盐再生。

公开(公告)号：US3939071A

公开(公告)日：1976-02-17

申请号：US496482

申请日：1974-08-12

申请人： Arthur Katzakian, Jr. ,  David O. DePree

发明人： Arthur Katzakian, Jr. ,  David O. DePree

IPC分类号： B01J49/00 ,  B01D15/06

CPC分类号： B01J49/0069

摘要： An improved, closed-cycle process for regeneration of weakly acidic spent cation resins and for the recovery and recycle of the regenerants is disclosed. The improvement resides in the use of hydroxy or alkoxy substituted carboxylic acids as the cation resin regenerant. These acids and their metal salts are soluble and are high boiling and do not form azeotropes. When the spent cation regenerant is combined with the spent anion regenerant such as an amine salt, a weak, dissociable complex of the regenerants is formed and the metal salt is reconstituted. The complex is dissociated, preferably by distillation, into the separate regenerants which are recycled and the salt is recovered.

摘要翻译： 公开了一种用于弱酸性废阳离子树脂的再生的改进的闭环方法以及再生剂的回收和再循环。 改进在于使用羟基或烷氧基取代的羧酸作为阳离子树脂再生剂。 这些酸及其金属盐是可溶的并且是高沸点并且不形成共沸物。 当废阳离子再生剂与废阴离子再生剂如胺盐结合时，形成再生剂的弱的可离解的络合物，并重新构成金属盐。 络合物优选通过蒸馏分离成分离的再生剂，其再循环并回收盐。

公开(公告)号：US08864999B2

公开(公告)日：2014-10-21

申请号：US12646327

申请日：2009-12-23

申请人： Timothy A. Brandvold ,  Stanley J. Frey ,  Vasken Abrahamian ,  Thomas Traynor

发明人： Timothy A. Brandvold ,  Stanley J. Frey ,  Vasken Abrahamian ,  Thomas Traynor

IPC分类号： B01D15/36 ,  G01N30/50 ,  B01J49/00 ,  B01D15/20 ,  C10L1/02 ,  B01D41/02 ,  G01N30/96

CPC分类号： B01J49/0069 ,  B01D15/20 ,  B01D15/203 ,  B01D15/362 ,  B01J49/06 ,  B01J49/53 ,  C10G2300/1011 ,  C10L1/02 ,  G01N30/50 ,  G01N30/96 ,  Y02P30/20

摘要： Methods for regenerating acidic ion-exchange resins and reusing regenerants in such methods are provided. A spent ion-exchange resin is contacted with an alcohol ion-exchange regenerant. The spent ion-exchange resin is thereafter contacted with an acidic ion-exchange regenerant to recharge the acidic ion-exchange resin to produce a regenerated acidic ion-exchange resin. Metal- and water-containing biomass-derived pyrolysis oil is then contacted with the regenerated acidic ion-exchange resin to produce low metal, water-containing biomass-derived pyrolysis oil. The regenerated acidic ion-exchange resin may be recycled. The spent alcohol and acid ion-exchange regenerants may be recovered and recycled.

摘要翻译： 提供了在这种方法中再生酸性离子交换树脂和再利用再生剂的方法。 将废弃的离子交换树脂与醇离子交换再生剂接触。 然后将废弃的离子交换树脂与酸性离子交换再生剂接触以对酸性离子交换树脂再充电以产生再生的酸性离子交换树脂。 然后将含金属和含水的生物质衍生的热解油与再生的酸性离子交换树脂接触以产生低金属，含水生物质的热解油。 再生的酸性离子交换树脂可以再循环。 废乙醇和酸离子交换再生剂可以回收和再循环。

公开(公告)号：US20140166582A1

公开(公告)日：2014-06-19

申请号：US14104496

申请日：2013-12-12

申请人： Peter Strain

发明人： Peter Strain

IPC分类号： B01J49/00 ,  C02F1/00 ,  C02F1/42 ,  C02F1/68

CPC分类号： B01J49/0069 ,  B01J49/53 ,  B01J49/75 ,  C02F1/008 ,  C02F1/42 ,  C02F1/68 ,  C02F1/78 ,  C02F2001/425 ,  C02F2201/782 ,  C02F2201/784 ,  C02F2303/04 ,  C02F2303/16

摘要： Embodiments of a water treatment system, a water treatment method, and an ozone kit for a water treatment system are provided. The water treatment system includes an ozone gas source; a regenerating fluid source; a water tank; a manifold having a first port in fluid communication with the regenerating fluid source, a second port in fluid communication with an outlet of the ozone gas source, and a third port in fluid communication with the water tank via a venturi nozzle; and a control system configured to: cause regenerating fluid to be drawn through the venturi nozzle into the water tank; and cause ozone gas to be drawn through the venturi nozzle into the water tank.

摘要翻译： 提供了水处理系统，水处理方法和用于水处理系统的臭氧套件的实施例。 水处理系统包括臭氧气源; 再生流体源; 水箱 歧管，其具有与再生流体源流体连通的第一端口，与臭氧气体源的出口流体连通的第二端口和通过文丘里管嘴与水箱流体连通的第三端口; 以及控制系统，其被配置为：使再生流体通过所述文丘里管喷嘴进入所述水箱; 并使臭氧气体通过文氏管喷嘴进入水箱。

公开(公告)号：US4753736A

公开(公告)日：1988-06-28

申请号：US20791

申请日：1987-03-02

申请人： David W. Reichgott

发明人： David W. Reichgott

IPC分类号： B01J49/00 ,  C02F1/42

CPC分类号： B01J49/0069

摘要： A method for treating boiler water condensate to remove undesirable cations which comprises providing a bed of cation-exchange resin, passing water to be treated through said resin bed, and regenerating said resin with an aqueous solution of a salt comprising a volatile amine and an anion selected from anions which do not form precipitates with any cation present in the water to be treated under operational conditions, and wherein the volatile amine is optionally not the same as that employed as the corrosion inhibitor in the boiler water system. The preferred salts include cyclohexylamine citrate, methoxypropylamine citrate, diethanolamine citrate and monoethanolamine citrate. The proposed method is particularly advantageous since the anion of the regenerant salt is selected to avoid the formation of insoluble calcium salts.

摘要翻译： 一种用于处理锅炉水冷凝物以除去不期望的阳离子的方法，其包括提供阳离子交换树脂床，使待处理的水通过所述树脂床，并用包含挥发性胺和阴离子的盐的水溶液再生所述树脂 选自不在操作条件下待处理水中存在的任何阳离子形成沉淀的阴离子，其中挥发性胺与锅炉水系统中的缓蚀剂所用的任选不同。 优选的盐包括环己胺柠檬酸盐，甲氧基丙胺柠檬酸盐，二乙醇胺柠檬酸盐和单乙醇胺柠檬酸盐。 所提出的方法是特别有利的，因为选择再生盐的阴离子以避免形成不溶性钙盐。