Light sensitive composition and products thereof
    1.
    发明授权
    Light sensitive composition and products thereof 失效
    光敏组合物及其制品

    公开(公告)号:US4077806A

    公开(公告)日:1978-03-07

    申请号:US618990

    申请日:1975-10-02

    摘要: A light-sensitive composition comprising novel arylglyoxyalkyl acrylates that exhibits useful light sensitivity. The basic structure of the new compositions, which may also themselves be polymerized are as follows: ##STR1## wherein Ar represents an aromatic structure selected from the group consisting of benzene, naphthalene and substituted products of each, R.sub.1 represents an alkyl group having from one to ten carbon atoms, R.sub.2 represents a grouping selected from the group consisting of hydrogen, or a lower alkyl group having from one to five carbon atoms and R.sub.3 represents an alkenyl group having from one to ten carbon atoms and singular unsaturation. The light-sensitive compositions may themselves be utilized in photochemistry as photopolymers, they may be combined with suitable solvents and additives or polymerized with suitable backbone polymers to provide substances which can be used as light-sensitive coatings. These coatings may be placed on substrates and in one instance as presensitized lithographic plates.

    Device for use in photochemical and photomechanical processes
    2.
    发明授权
    Device for use in photochemical and photomechanical processes 失效
    用于光化学和光机械过程的设备

    公开(公告)号:US4268608A

    公开(公告)日:1981-05-19

    申请号:US042434

    申请日:1979-05-25

    CPC分类号: G03F7/032 C08F2/50

    摘要: A photoreactive composition containing an effective amount of a polymer which includes as a recurring structure: ##STR1## wherein Ar is a bivalent aromatic radical, and M is selected from the class consisting of hydrogen, alkali metal, ammonium, and substituted ammonium. These compositions are useful in a wide variety of photochemical and photomechanical processes and are particularly suited for use as photopolymers, photoinitiators and photosensitizers in light sensitive coatings of presensitized lithographic plates.

    摘要翻译: 包含有效量的聚合物的光反应性组合物,其包含作为重复结构的:其中Ar是二价芳族基团,M选自氢,碱金属,铵和取代的铵。 这些组合物可用于各种光化学和光机械方法中,并且特别适合用作预敏平版印刷版的光敏涂层中的光聚合物,光引发剂和光敏剂。

    Photopolymerizable latex systems
    3.
    发明授权
    Photopolymerizable latex systems 失效
    可光聚合胶乳系统

    公开(公告)号:US4186069A

    公开(公告)日:1980-01-29

    申请号:US873383

    申请日:1978-01-30

    摘要: A photopolymerizable system is provided as a latex system that is an oil-in-water polymer emulsion including particulates of water-insoluble polymers in combination with a water-soluble or water-dispersible, light-sensitive polymer having multiple light-sensitive moieties. Prior to coating onto a substrate, the system is a three-phase precursor emulsion of the emulsion particulates, the water phase, and the light-sensitive polymer. After coating, the bulk of the water phase is evaporated off, leaving a two-phase system of the emulsion particulates surrounded by the light-sensitive polymer. When selected areas are subjected to actinic radiation, a water-insoluble matrix is formed, the matrix containing cross-linked light-sensitive polymer having dispersed therethrough and/or included therein the water-insoluble polymer particulates, thus forming oleophilic image areas. Those portions of the system that were not subjected to actinic radiation are then readily washed from the coated item to form the hydrophilic, non-image areas.

    摘要翻译: 提供可光聚合体系作为胶乳系统,其是水包油聚合物乳液,其包括水不溶性聚合物的微粒与具有多个光敏部分的水溶性或水分散性光敏聚合物的组合。 在涂布到基材上之前,该体系是乳液颗粒,水相和光敏聚合物的三相前体乳液。 涂布后,将大部分水相蒸发掉,留下由光敏聚合物包围的乳液颗粒的两相体系。 当选择的区域经受光化辐射时,形成水不溶性基质,含有交联光敏聚合物的基质分散在其中并/或包含在其中的水不溶性聚合物微粒,从而形成亲油图像区域。 然后系统中不经过光化辐射的部分容易地从涂覆的物品洗涤以形成亲水的非图像区域。

    Photoreactive compositions comprising polymers containing
alkoxyaromaticglyoxy groups
    4.
    发明授权
    Photoreactive compositions comprising polymers containing alkoxyaromaticglyoxy groups 失效
    包含含有烷氧基芳基乙氧基的聚合物的光反应性组合物

    公开(公告)号:US3969119A

    公开(公告)日:1976-07-13

    申请号:US585215

    申请日:1975-06-09

    IPC分类号: G03F7/031 G03F7/038 G03C1/68

    摘要: A photoreactive composition containing an effective amount of a compound having at least two alkoxyaromaticglyoxy substituents per molecule, which substituents have the following general formula: ##EQU1## wherein R is selected from the class consisting of H, aryl, alkyl, halo and arakyl having up to 10 carbon atoms, n is an integer from 1 to 18, Ar is an aromatic substituent, and M is selected from the class consisting of H, alkali metal, ammonium, and substituted ammonium. These compositions are useful in a wide variety of photochemical and photomechanical processes and are particularly suited for use as photopolymers, photoinitiators and photosensitizers in light sensitive coatings of presensitized lithographic plates.

    摘要翻译: 含有有效量的每分子具有至少两个烷氧基芳氧基取代基的化合物的光反应性组合物,该取代基具有以下通式:OO PARALLEL PARALLEL - [C(R)2] nO-Ar-CC-OM其中R选自 由具有至多10个碳原子的H,芳基,烷基,卤素和芳烷基组成的类别,n为1至18的整数,Ar为芳族取代基,M选自H,碱金属,铵 和取代的铵。 这些组合物可用于各种光化学和光机械方法中,并且特别适合用作预敏平版印刷版的光敏涂层中的光聚合物,光引发剂和光敏剂。

    Light sensitive arylglyoxyacrylate compositions
    5.
    发明授权
    Light sensitive arylglyoxyacrylate compositions 失效
    光敏ARYLGLYOXYACRYLATE组合物

    公开(公告)号:US3930868A

    公开(公告)日:1976-01-06

    申请号:US363018

    申请日:1973-05-23

    摘要: A light-sensitive composition comprising novel arylglyoxyalkyl acrylates that exhibits useful light sensitivity. The basic structure of the new compositions, which may also themselves be polymerized are as follows: ##EQU1## wherein Ar represents an aromatic structure selected from the group consisting of benzene, naphthalene and substituted products of each, R.sub.1 represents an alkyl group having from one to ten carbon atoms, R.sub.2 represents a grouping selected from the group consisting of hydrogen, or a lower alkyl group having from one to five carbon atoms and R.sub.3 represents an alkenyl group having from one to 10 carbon atoms and singular unsaturation. The light-sensitive compositions may themselves be utilized in photochemistry as photopolymers, they may be combined with suitable solvents and additives or polymerized with suitable backbone polymers to provide substances which can be used as light-sensitive coatings. These coatings may be placed on substrates and in one instance as presensitized lithographic plates.

    摘要翻译: 一种感光组合物,其包含显示有用的光敏感性的新型丙烯酸芳基乙氧基烷基酯。 本文也可以聚合的新组合物的基本结构如下:其中Ar表示选自苯,萘和各自的取代产物的芳族结构,R 1表示具有一个 至10个碳原子,R 2表示选自氢或具有1至5个碳原子的低级烷基,R 3表示具有1至10个碳原子和单数不饱和键的链烯基的基团。 光敏组合物本身可以作为光聚合物用于光化学,它们可以与合适的溶剂和添加剂组合,或者与合适的主链聚合物聚合以提供可用作光敏涂层的物质。 这些涂层可以放置在基底上,在一种情况下可以放置在平版印刷版上。

    Method of coating using photopolymerizable latex systems
    6.
    发明授权
    Method of coating using photopolymerizable latex systems 失效
    使用光聚合胶乳体系涂布方法

    公开(公告)号:US4273851A

    公开(公告)日:1981-06-16

    申请号:US134275

    申请日:1980-03-26

    IPC分类号: G03F7/038 B05D3/06 G03F7/08

    摘要: A photopolymerizable system is provided as a latex system that is an oil-in-water polymer emulsion including particulates of water-insoluble polymers in combination with a water-soluble or water-dispersible, light-sensitive polymer having multiple light-sensitive moieties. Prior to coating onto a substrate, the system is a three-phase precursor emulsion of the emulsion particulates, the water phase, and the light-sensitive polymer. After coating, the bulk of the water phase is evaporated off, leaving a two-phase system of the emulsion particulates surrounded by the light-sensitive polymer. When selected areas are subjected to actinic radiation, a water-insoluble matrix is formed, the matrix containing cross-linked light-sensitive polymer having dispersed therethrough and/or included therein the water-insoluble polymer particulates, thus forming oleophilic image areas. Those portions of the system that were not subjected to actinic radiation are then readily washed from the coated item to form the hydrophilic, non-image areas.

    摘要翻译: 提供可光聚合体系作为胶乳系统,其是水包油聚合物乳液,其包括水不溶性聚合物的微粒与具有多个光敏部分的水溶性或水分散性光敏聚合物的组合。 在涂布到基材上之前,该体系是乳液颗粒,水相和光敏聚合物的三相前体乳液。 涂布后,将大部分水相蒸发掉,留下由光敏聚合物包围的乳液颗粒的两相体系。 当选择的区域经受光化辐射时,形成水不溶性基质,含有交联光敏聚合物的基质分散在其中并/或包含在其中的水不溶性聚合物微粒,从而形成亲油图像区域。 然后系统中不经过光化辐射的部分容易地从涂覆的物品洗涤以形成亲水的非图像区域。

    Photoreactive coating compositions and photomechanical plates produced
therewith
    7.
    发明授权
    Photoreactive coating compositions and photomechanical plates produced therewith 失效
    光反应涂料组合物和由其制备的光机械板

    公开(公告)号:US4225661A

    公开(公告)日:1980-09-30

    申请号:US904378

    申请日:1978-05-10

    IPC分类号: G03F7/105 G03C1/52 G03F7/02

    CPC分类号: G03F7/105

    摘要: A photoreactive coating composition, particularly suited for use in a lithographic plate, is characterized by both reduced exposure time requirements and an intense visual image which is immediately produced upon exposure of the composition to light permitting visual inspection during imaging. The photoreactive composition has a diazo resin layer and an overlayer which includes a photochromic compound (e.g. an indolinobenzospiropyran compound) and a light sensitive polymer selected from the group cinnamoylated and acrylated photopolymer resins.

    摘要翻译: 特别适用于平版印刷版的光反应性涂料组合物的特征在于减少曝光时间要求,以及在将组合物暴露于允许成像期间目视检查的光时立即产生的强烈视觉图像。 光反应性组合物具有重氮树脂层和包含光致变色化合物(例如二氢吲哚基三苯并吡喃化合物)和选自肉桂酰化和丙烯酸酯化的光聚合物树脂的光敏聚合物的覆盖层。

    Method of making light sensitive polymerizable compositions
    9.
    发明授权
    Method of making light sensitive polymerizable compositions 失效
    制备光敏聚合性组合物的方法

    公开(公告)号:US4083724A

    公开(公告)日:1978-04-11

    申请号:US601677

    申请日:1975-08-04

    摘要: A light-sensitive composition comprising novel arylglyoxyalkyl acrylates that exhibits useful light sensitivity. The basic structure of the new compositions, which may also themselves be polymerized are as follows: ##STR1## wherein Ar represents an aromatic structure selected from the group consisting of benzene, naphthalene and substituted products of each, R.sub.1 represents an alkyl group having from one to ten carbon atoms, R.sub.2 represents a grouping selected from the group consisting of hydrogen, or a lower alkyl group having from one to five carbon atoms and R.sub.3 represents an alkenyl group having from one to ten carbon atoms and singular unsaturation. The light-sensitive compositions may themselves be utilized in photochemistry as photopolymers, they may be combined with suitable solvents and additives or polymerized with suitable backbone polymers to provide substances which can be used as light-sensitive coatings. These coatings may be placed on substrates and in one instance as presensitized lithographic plates.

    摘要翻译: 一种感光组合物,其包含显示有用的光敏感性的新型丙烯酸芳基乙氧基烷基酯。 本文也可以聚合的新组合物的基本结构如下:其中Ar表示选自苯,萘和各自的取代产物的芳族结构,R 1表示具有一个 至10个碳原子,R 2表示选自氢或具有1至5个碳原子的低级烷基,R 3表示具有1至10个碳原子和单数不饱和键的链烯基的基团。 光敏组合物本身可以作为光聚合物用于光化学,它们可以与合适的溶剂和添加剂组合,或者与合适的主链聚合物聚合以提供可用作光敏涂层的物质。 这些涂层可以放置在基底上,在一种情况下可以放置在平版印刷版上。